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Search results for: FTIR spectrum of formaldehyde
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Data analysis of FTIR spectra for study of outlet gases of Solid Oxide Fuel Cells fuelled by biogas
PublicationW pracy przedstawiono system umożliwiający połączenie spektroskopii FTIR z specjalnie zaprojektowanym oprogramowaniem w celu uzyskania informacji o stężeniach gazów wylotowych z ogniw paliwowych SOFC. Przebadane zostały główne produkty reformingu biogazu: tlenek węgla, dwutlenek węgla, metan oraz wodór. Opisane oprogramowanie umożliwia w prosty i szybki sposób uzyskanie informacji o gazach wylotowych ogniwa paliwowego.
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On adaptive covariance and spectrum estimation of locally stationary multivariate processes
PublicationWhen estimating the correlation/spectral structure of a locally stationary process, one has to make two important decisions. First, one should choose the so-called estimation bandwidth, inversely proportional to the effective width of the local analysis window, in the way that complies with the degree of signal nonstationarity. Too small bandwidth may result in an excessive estimation bias, while too large bandwidth may cause excessive...
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The formation of formaldehyde via the carbon monoxide hydrogenation catalyzed by the HSbF6 superacid
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Synthesis and characterization of resorcinol–formaldehyde resin chars doped by zinc oxide
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FTIR- SPECTROSCOPIC CHARACTERISTICS OF THE DZHAKSY-KLYCH DEPOSIT SALTS
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Isotope shifts in the spectrum of Pb I
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Analysis of Satellite Compass Error’s Spectrum
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The problem of “spectrum leakage” in the measurement of harmonics
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Employees With Autism Spectrum Disorders in the Digitized Work Environment: Perspectives for the Future
PublicationThe aim of this article is to examine the opportunities for employees with autism spectrum disorders (ASDs), arising from digital technology (DT) development. The author discusses assistive technology (AT) as a mean of creating a better work environment, making the digitized workplace more friendly for people with ASD. A possible solution of communication problems is replacing the interpersonal communication between employees with...
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A COMPARISON OF THE WIND SPECTRUM ACCORDING TO DIFFERENT METHODS - AN ORIGINAL PROJECT OF A BUILDING ON A CLIFF IN GDYNIA
PublicationThe article presents numerical simulations of the dynamic wind loads on the structure of a building designed on a cliff in Gdynia. The results obtained from the two methods: Davenport’s and Karman’s are compared. The results allowed a comparison of the two methods, and they provided an answer to the question how a construction, designed in such an unusual condition of a cliff behaves under the influence of the gusting wind. The...
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Combined chemoresistive and in situ FTIR spectroscopy study of nanoporous NiO films for light-activated nitrogen dioxide and acetone gas sensing
PublicationThe chemoresistive sensor response of nanoporous NiO films prepared by advanced gas deposition was investigated by combined resistivity and in situ FTIR spectroscopy, with and without simultaneous light illumination, to detect NO2 and acetone gases. The sensitivity towards NO2 increased dramatically under UV irradiation employing 275 nm light. Improved sensitivity was observed at an elevated temperature of 150 °C. In situ FTIR...
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Dynamic analysis of lightweight structure of the Viaduct Millau in France subjected to the wind fluctuations described by Karman’s and Davenport’s spectrum
PublicationThe article presents numerical simulations for wind impact modelling on the Millau Viaduct structure in France performed with two independent spectrum generation methods. The viaduct's construction in affected by strong forces, as it is situated in the Tarn river's valley. Thus, the loading coming from the wind cannot be modelled, the way it is in case of simple structures as static loading, but as a loading in a form of a spectrum...
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Chemical modification of tannins from Acacia mearnsii to produce formaldehyde free flocculant
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Effect of nanosilica on characteristics of carbonizates of phenol-formaldehyde resin – Fe(acac)3
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Formaldehyde in various forms of atmospheric prepicitation and deposition from highly urbanized regions
PublicationOznaczono stężenie formaldehydu w próbkach różnych form opadów i osadów atmosferycznych pobieranych przez okres 12 miesięcy, w trakcie występowania opadu lub osadu atmosferycznego lub tuż po jego ustąpieniu, na terenie dwóch aglomeracji miejskich i wzdłuż dróg o różnym natężeniu ruchu. Formaldehyd wykryto w 303 próbkach z 500 pobranych (stężenia od 0.05 do 10.7 mg/dm3). Wyniki analiz potwierdziły iż:- opady i osady atmosferyczne...
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15 N NMR and FTIR studies of 2,4-dinitroanilines and their salts
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Hydration of aprotic donor solvents studied by means of FTIR spectroscopy
PublicationThe paper attempts to explain the mutual influence of nonpolar and electron-donor groups on solute hydration,the problem of big importance for biological aqueous systems. Aprotic organic solvents have been used asmodel solutes, differing in electron-donating power. Hydration of acetonitrile, acetone, 2-butanone, andtriethylamine has been studied by HDO and (partially) H2O spectra. The quantitative version of...
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Context of Digitalized Employment for Older Adults with Autism Spectrum Disorder in the New Normal
PublicationEmployers are actively considering how to normalize remote work technology across different industries. The residual risk of coronavirus disease-19 (COVID-19) will necessarily lower the bar for allowing some workers to stay remote on a more permanent basis. This is based on the realization that many essential jobs can be teleworked while retaining or enhancing productivity. The decisions employers make regarding future work arrangements...
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Inclusive Communication Model Supporting the Employment Cycle of Individuals with Autism Spectrum Disorders
PublicationDifficulties with interpersonal communication experienced by individuals with autism spectrum disorders (ASD) significantly contribute to their underrepresentation in the workforce as well as problems experienced while in employment. Consistently, it is vital to understand how communication within the employment cycle of this group can be improved. This study aims to identify and analyze the possibilities of modifying the communication...
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The role of Herzberg-Teller effects on the resonance Raman spectrum of trans-porphycene investigated by time dependent density functional theory.
PublicationThe S1 excited state properties as well as the associated absorption and resonance Raman (RR) spectra of trans-porphycene are investigated by means of time dependent density functional theory calculations. The relative magnitude of the Franck-Condon (FC) contribution and of the Herzberg-Teller (HT) effects is evaluated for both the absorption and RR intensities. The accuracy of the calculated spectra is assessed by employing different...
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The common effect of hydrophobic and electrophilic types of hydration dependent on protonation in the sec-butyloamine/HCl/H2O system studied by FTIR spectroscopy
PublicationZbadano hydratację sec-butyloaminy w zależności od pH roztworów wodnych przy pomocy spektoskopii FTIR, z zastosowaniem techniki rozcieńczenia izotopowego HDO w H2O. Dane widmowe poddano analizie przy pomocy ilościowej metody widm różnicowych. Stwierdzono, iż wiązania wodorowe cząsteczek wody tworzących klatratopodobną otoczkę hydratacyjną wokół aminy ulegają wzmocnieniu na skutek oddziaływania z grupą elektrofilową aminy.
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Physicochemical and Volatile Compounds Analysis of Fruit Wines Fermented with Saccharomyces cerevisiae: FTIR and Microscopy Study with Focus on Anti-Inflammatory Potential
PublicationThe growing trend in fruit wine production reflects consumers’ interest in novel, diverse drinking experiences and the increasing demand for healthier beverage options. Fruit wines made from kiwi, pomegranates, and persimmons fermented using S. bayanus Lalvin strain EC1118 demonstrate the versatility of winemaking techniques. Kiwifruit, persimmon, and pomegranate wines were analyzed using HPLC and GC-TOFMS analyses to determine...
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Robot-Based Intervention for Children With Autism Spectrum Disorder: A Systematic Literature Review
PublicationChildren with autism spectrum disorder (ASD) have deficits in the socio-communicative domain and frequently face severe difficulties in the recognition and expression of emotions. Existing literature suggested that children with ASD benefit from robot-based interventions. However, studies varied considerably in participant characteristics, applied robots, and trained skills. Here, we reviewed robot-based interventions targeting...
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Detection and Direction-of-Arrival Estimation of Weak Spread Spectrum Signals Received with Antenna Array
PublicationThis paper presents a method for the joint detection and direction of arrival (DOA) estimation of low probability of detection (LPD) signals. The proposed approach is based on using the antenna array to receive spread-spectrum signals hidden below the noise floor. Array processing exploits the spatial correlation between phase-delayed copies of the signal and allows us to evaluate the parameter used to make the decision about the...
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Catalytic aldol condensation of formaldehyde with acetic acid on titanium phosphates modified by different techniques
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Simulation of Direct-Sequence Spread Spectrum Data Transmission System for Reliable Underwater Acoustic Communications
PublicationUnderwater acoustic communication (UAC) system designers tend to transmit as much information as possible, per unit of time, at as low as possible error rate. It is a particularly difficult task in a shallow underwater channel in which the signal suffers from strong time dispersion due to multipath propagation and refraction phenomena. The direct-sequence spread spectrum technique (DSSS) applied successfully in the latest standards...
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Investigation of the Membrane Localization and Interaction of Selected Flavonoids by NMR and FTIR Spectroscopy
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FTIR Study and Mechanical Properties of Cellulose Fiber-Reinforced Thermoplastic Composites
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A New Direct-Sequence Spread Spectrum Signal Detection Method for Underwater Acoustic Communications in Shallow-Water Channel
PublicationDirect-Sequence Spread Spectrum (DSSS) is one of the modulation and coding techniques used in Underwater Acoustic Communication (UAC) systems for reliable data transmision even at low signal levels. However, in a shallow water channel, there is a strong multipath propagation which causes a phase fluctuation of the received signal, affecting the performance of the spread-spectrum system. The article presents a differential method...
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On autoregressive spectrum estimation using the model averaging technique
PublicationThe problem of estimating spectral density of a nonstationary process satisfying local stationarity conditions is considered. The proposed solution is a two step procedure based on local autoregressive (AR) modeling. In the first step Bayesian-like averaging of AR models, differing in order, is performed. The main contribution of the paper is development of a new final-prediction-error-like statistic, which can be used to select...
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Influence of local electron interactions on phonon spectrum in iron
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Uncertainty in measuring the power spectrum density of a random signal
PublicationPrzedstawiono sposób oszacowania niepewności wyznaczania gęstości widmowej mocy przebiegu losowego. Przeprowadzono ocenę niepewności estymacji gęstości widmowej mocy biorąc pod uwagę propagację niepewności związanej z rejestracją pojedynczej próbki sygnału w algorytmie cyfrowego przetwarzania sygnału oraz błąd obciążenia estymatora wynikający z zastosowanego modelu matematycznego wielkości wyznaczanej. Wyprowadzono zależności na...
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Matrix representation of the ARMA(p, q) process spectrum
PublicationPraca dotyczy szeregów czasowych i ich modelowania scałkowanymi procesami autoregresji i średniej ruchomej ARIMA(p,q). Dla dowolnych parametru modelu p i q, zaproponowano opis spektrum wykorzystując zapis macierzowy. Takie podejście pozwoliło na znaczne uproszczenia przy różnego rodzaju wyprowadzeniach, a w efekcie i obliczeniach.
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Pounding force response spectrum under earthquake excitation
PublicationW artykule przedstawiono możliwość wykorzystania spektrum siły zderzenia jako zaproponowanego przez autora narzędzia pomocnego przy projektowaniu budynków narażonych na zderzenia podczas trzęsień ziemi. Przedstawione wykresy spektrów pokazały, iż właściwy dobór parametrów budowli, takich jak szerokość przerwy pomiędzy budynkami, okres drgań własnych konstrukcji, liczba tłumienia, masa, współczynnik ciągliwości, czy też przesunięcie...
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FFT spectrum based matching algorithm for activedynamic thermography
PublicationIn Active Dynamic thermography (ADT) sequences of consecutive temperature distributions are analyzed. In biomedical applications of ADT, the problems of a patient's movements in front of a thermal camera should be eliminated before data analysis. Complete mechanical stabilization of the patients is impossible due to natural voluntary and involuntary moves caused by pulse breathing, etc. This paper presents a simple and efficient...
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Effect of pyridine extraction on the pyrolysis of a perhydrous coal based on in-situ FTIR analysis
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Polyurethane Nanocomposites Containing Reduced Graphene Oxide, FTIR, Raman, and XRD Studies
PublicationRecently, graphene and other graphene-based materials have become an essential part of composite science and technology. Their unique properties are not only restricted to graphene but also shared with derivative compounds like graphene oxide, reduced graphene oxide, functionalized graphene, and so forth. One of the most structurally important materials, graphene oxide (GO), is prepared by the oxidation of graphite. Though removal...
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Anticarcinogenic and antioxidant activities of leaves and flowers hydroalcoholic extracts of Nerium oleander L.: PCA analysis and phytochemical content by FTIR spectroscopy
PublicationAims: The aim of this work is the evaluation the anticarcinogenic effect on HT29 cancer cells lines and antioxidant effect of three extracts from different morphological parts (leaves (LE), pink flowers (PFE) and white flowers (WFE)) of Nerium oleander lin. Methods: This research provides the anticarcinogenic activity of extracts from N. oleander white flowers. Principal Component Analysis (PCA) was applied to estimate the relationship...
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Badania struktury chemicznej (metodami FTIR i NMR) oraz własności termicznych (metodą DSC) materiałów i ustalenie rodzaju tworzywa sztucznego - Numer umowy: 032257
PublicationPrzeprowadzono badania struktury chemicznej (metodami 1H NMR oraz FTIR) oraz własności termicznych (metodą DSC) materiałów pobranych z dostarczonych obiektów i ustalono typ tworzywa sztucznego z jakiego zostały wykonane dostarczone obiekty.
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Supply current spectrum estimation of digital cores at early design
PublicationPrzedstawiono nową aproksymacyjną metodę obliczania widma prądu zasilania układów cyfrowych. Metoda oparta jest na charakterystyce impulsów prądowych w kategoriach ich czasu narastania, opadania i długości impulsu. Górną granicę widma (obwiednię) można obliczyć posługując się gęstością prawdopodobieństwa zmian stanu sygnałów w węzłach układu cyfrowego. W odróżnieniu od znanych metod, metoda proponowana wykorzystuje ograniczoną...
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The optimized Rayleigh–Ritz scheme for determining the quantum-mechanical spectrum
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Simulations of impact force spectrum for earthquake-induced structural pounding.
PublicationCelem artykułu jest analiza możliwości zastosowanie tzw. spektrum siły zderzenia przy projektowaniu sąsiadujących ze sobą konstrukcji budowlanych na terenach sejsmicznych, w przypadku zbyt małej przerwy dylatacyjnej między nimi. W artykule przedstawiono wyniki symulacji numerycznych przeprowadzonych dla różnych wartości parametrów dynamicznych konstrukcji.
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The Effect of the Phenomenon of “Spectrum Leakage” on the Measurement of Power Quality Parameters
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Spectrum-based modal parameters identification with Particle Swarm Optimization
PublicationThe paper presents the new method of the natural frequencies and damping identification based on the Artificial Intelligence (AI) Particle Swarm Optimization (PSO) algorithm. The identification is performed in the frequency domain. The algorithm performs two PSO-based steps and introduces some modifications in order to achieve quick convergence and low estimation error of the identified parameters’ values for multi-mode systems....
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On Adaptive Spectrum Estimation of Multivariate Autoregressive Locally Stationary Processes
PublicationAutoregressive modeling is a widespread parametricspectrum estimation method. It is well known that, in the caseof stationary processes with unknown order, its accuracy canbe improved by averaging models of different complexity usingsuitably chosen weights. The paper proposes an extension of thistechnique to the case of multivariate locally stationary processes.The proposed solution is based on local autoregressive...
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Characteristics of hydration water around hen egg lysozyme as the protein model in aqueous solution. FTIR spectroscopy and molecular dynamics simulation
PublicationW niniejszej pracy przedstawiono wyniki badań dotyczące hydratacji białka modelowego - lizozymu z jaja kurzego w roztworze wodnym. Wiodącą techniką stosowaną w badaniach była spektroskopia oscylacyjna FTIR z zastosowaniem techniki rozcieńczenia izotopowego wody półciężkiej HDO w roztworze wody zwykłej. Analiza widma HDO przy pomocy "metody widm zaburzonych" pozwoliła na wyizolowanie widma wody zaburzonej przez lizozym, a tym samym...
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Quantitative assessment of the main antioxidant compounds, antioxidant activities and FTIR spectra from commonly consumed fruits, compared to standard kiwi fruit
PublicationBioactive compounds (polyphenols and ascorbic acid) and dietary fibers, and related antioxidant activities of commonly consumed apples, bananas, peaches, pears, blond and red grapefruits, pomelos, oranges, lemons, red plums, white grapes, mango, persimmon and strawberries grown in the same geographical and climatic conditions were compared with standard kiwi fruit. The presence of polyphenols was studied by Fourier transform infrared...
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Remote Work Support Needs of Employees with Autism Spectrum Disorder in Poland: Perspectives of Individuals with Autism and Their Coworkers
PublicationBackground and Aims: With remote work becoming more common across industries, employees with autism may experience different work support needs from neurotypical peers. However, the specific remote work needs of this group of employees are underexplored in the literature. We aim to propose ways to assess workplace digital adaptation needs for individuals with autism and a framework for communicating these needs to employers. Methods:...
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TG-FTIR, DSC and quantum chemical studies of the thermal decomposition of quaternary methylammonium halides
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Spektroskopia refleksyjna w podczerwieni (ATR-FTIR) w aspekcie badań trwałości leku
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