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Search results for: CHARGE TRANSFER CHROMOPHORE
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Electrochemistry from first-principles in the grand canonical ensemble
PublicationProgress in electrochemical technologies, such as automotive batteries, supercapacitors, and fuel cells, depends greatly on developing improved charged interfaces between electrodes and electrolytes. The rational development of such interfaces can benefit from the atomistic understanding of the materials involved by first-principles quantum mechanical simulations with Density Functional Theory (DFT). However, such simulations are...
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Self-Organizing Wireless Nodes Monitoring Network
PublicationThe concept of data monitoring system and self-organizing network of multipurpose data transfer nodes are presented. Two practical applications of this system are also presented. The first of these is the wireless monitoring system for containers, and the second is the mobile monitoring system for gas air pollution measurements.
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Pool boiling of nanofluids on rough and porous coated tubes: experimental and correlation
PublicationThe paper deals with pool boiling of water-Al2O3 and water- Cu nanofluids on rough and porous coated horizontal tubes. Commercially available stainless steel tubes having 10 mm outside diameter and 0.6 mm wall thickness were used to fabricate the test heater. The tube surface was roughed with emery paper 360 or polished with abrasive compound. Aluminium porous coatings of 0.15 mm thick with porosity of about 40% were produced by...
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Thermal and Hydrodynamic Phenomena in the Stagnation Zone — Impact of the Inlet Turbulence Characteristics on the Numerical Analyses
PublicationOne of the methods of heat transfer enhancement is utilization of the turbulent impinging jets, which were recently applied, for example, in the heat exchangers. Their positive impact on the heat transfer performance was proven, but many questions related to the origin of this impact are still unanswered. In general, the wall-jet interaction and the near-wall turbulence are supposed to be its main reason, but their accurate numerical...
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Numerical Study on Mitigation of Flow Maldistribution in Parallel Microchannel Heat Sink: Channels Variable Width Versus Variable Height Approach
PublicationMicrochannel heat sink on one hand enjoys benefits of intensified several folds heat transfer performance but on the other hand has to suffer aggravated form of trifling limitations associated with imperfect hydrodynamics and heat transfer behavior. Flow maldistribution is one of such limitation that exaggerates temperature nonuniformity across parallel microchannels leading to increase in maximum base temperature. Recently, variable...
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Field investigation of low-temperature cracking and stiffness moduli on selected roads with conventional and high modulus asphalt concrete
PublicationHigh Modulus Asphalt Concrete (HMAC) was introduced in Poland as a one of the solutions to the problem of rutting, type of deterioration common in the 1990s. After first encouraging trials in 2002 HMAC was widely used for heavily loaded national roads and motorways. However some concerns were raised about low-temperature cracking of HMAC. This was the main reason of the studies presented in this article were started. The article...
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Automated Design of Linear Phase Filters
PublicationThis paper presents a fast technique for an automated design of microwave filters with linear phase. The proposed method exploits the cost function defined using the location of complex zeros and poles of the filter’s transfer and reflection function. The effectiveness of the proposed technique is presented with two illustrative examples.
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Comparative study of flow condensation in conventional and small diameter tubes
PublicationIn the paper a method developed earlier by the first author is applied to calculations of heat transfer coefficient for inside tube condensation. The method has been verified using experimental data from literature on several fluids in different microchannels and compared to three well established correlations.
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Electrical properties of hybrid planar diode based on palladium phthalocyanine and titanium dioxide
PublicationThis work details experimental studies of a planar diode made of indium tin oxide/titanium dioxide/palladium phthalocyanine/gold. The rectification ratio of current was 105 at 1.5 V. The analysis of the electrical properties of the system was based on small signal complex capacitance spectra measured in the frequency range of 25 Hz-1 MHz at different values of bias. No depletion region at the TiO2/PdPc interface was observed. Forward...
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High order of nongeminate recombination in organic bulk heterojunction solar cells
PublicationWe analyze high order of nongeminate recombination in organic donor–acceptor bulk heterojunction solar cells. The model of recombination where an exciton annihilates on an electron–hole Langevin bound pair near donor–acceptor interface has been applied in our studies. We obtained satisfactory agreement between experimental results and theoretical calculations for the concentration dependences of several parameters characterizing...
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Wireless systems of threats monitoring
PublicationThe concept of wireless system of threats monitoring with self-organizing network of multipurpose data transfer nodes are presented. Two practical applications of this system are also presented. The first of these is the Global Wireless Monitoring System for Containers, and the second is the Mobile Monitoring System for Gas Air Pollution Measurements.
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Wireless Systems of Threats Monitoring
PublicationConcept of wireless system of threats monitoring with self-organizing network of multipurpose data transfer nodes are presented. Two practical applications of this system are also presented. The first of these is the Global Wireless Monitoring System for Containers and the second is the Mobile Monitoring System for Gas Air Pollution Measurements.
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Wireless systems of threats monitoring
PublicationThe concept of wireless system of threats monitoring with self-organizing network of multipurpose data transfer nodes are presented. Two practical applications of this system are also presented. The first of these is the Global Wireless Monitoring System for Containers, and the second is the Mobile Monitoring System for Gas Air Pollution Measurements.
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Performance of a plate heat exchanger operated with water-Al2O3 nanofluid
PublicationThis study is focused on experimental investigation of a selected type of brazed plate heat exchanger (PHEx). The main aim of the paper was to experimentally check the ability of nanofluids to enhance the performance of PHEx. A typical water-Al2O3 nanofluid was tested and compared to that of the base fluid, i.e. water. Nanoparticles were tested at the concentration of 0.1% and 1% by weight. Impact of the 1 day and 3 days break...
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Performance of a plate heat exchanger operated with water-Al2O3 nanofluid
PublicationThis study is focused on experimental investigation of a selected type of brazed plate heat exchanger (PHEx). The main aim of the paper was to experimentally check the ability of nanofluids to enhance the performance of PHEx. A typical water-Al2O3 nanofluid was tested and compared to that of the base fluid, i.e. water. Nanoparticles were tested at the concentration of 0.1% and 1% by weight. Impact of the 1 day and 3 days break...
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Carboxylation Enhances Fragmentation of Furan upon Resonant Electron Attachment
PublicationWe report a dissociative electron attachment study to 2-furoic acid (C5H4O3) isolated in a gas phase, which is a model molecule consisting of a carboxylic group and a furan ring. Dissociation of furan by low energy electrons is accessible only via electronic excited Feshbach resonances at energies of incident electrons above 5 eV. On the other hand, carboxylic acids are well- known to dissociate via attachment of electrons at subexcitation energies....
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Performance of a plate heat exchanger operated with water-Al2O3 nanofluid
PublicationThis study is focused on experimental investigation of a selected type of brazed plate heat exchanger (PHEx). The main aim of the paper was to experimentally check the ability of nanofluids to enhance the performance of PHEx. A typical water-Al2O3 nanofluid was tested and compared to that of the base fluid, i.e. water. Nanoparticles were tested at the concentration of 0.1% and 1% by weight. Impact of the 1 day and 3 days break...
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The hydration properties of protein stabilizer, trimethylamine-N-oxide in aqueous solutions of N-methylacetamide – The volumetric and compressibility studies between 288.15 and 308.15 K
PublicationApparent molar volumes and apparent molar isentropic compressions of the protein stabilizer, trimethylamine-N-oxide (TMAO) were determined from the densities and speed of sound measured at T = (288.15, 298.15 and 308.15) K in aqueous solutions of N-methylacetamide (NMA) at four different concentrations (2, 4, 6 and 8 mol/kg). The concentration dependencies of the calculated quantities extrapolated to the infinite dilution lead...
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Synthesis of isotactic polypropylene- block -polystyrene block copolymers as compatibilizers for isotactic polypropylene/polyphenylene oxide blends
PublicationPoly(2,6-dimethyl-1,4-phenylene oxide) (PPO) and isotactic polypropylene (iPP) are highly incompatible and consequently their uncompatibilized blends are quite brittle regardless of the molecular weights and ductility of the individual components. Isotactic polypropylene-polystyrene block copolymers, to be applied as compatibilizers for a broad range of PPO/iPP blend compositions, were prepared by mechanism transformation from...
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-- Trophic transfer of labile mercury in benthic communities of a temperate marine ecosystem
ProjectsProject realized in Uniwersytet Gdański according to 2018/31/N/ST10/00214 agreement from 2019-07-03
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Art Composition
e-Learning CoursesPerson in charge: prof. Krzysztof Wróblewski, Department of Visual Arts Teacher: mgr Patryk Różycki, Department of Visual Arts Five Words. Society and Politics. What? By What? General assumptions. The aim of the proposed two artistic compositions is a creative processing of emotions related to the socio-political issues. In general, it is about personal views and feelings, but it must be also considered that architects are...
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Krzysztof Malik prof. dr hab.
PeopleKrzysztof Malik, professor of economics, heads the Department of Economics, Finance, Regional and International Research at the Faculty of Economics and Management of the Opole University of Technology. Prof. Malik conducts research on the regional economy, development strategy, knowledge transfer and specialization of regional development, economic evaluation of regional public programmes and policies. He is the author and co-author...
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The luminescence study ofNaK2Li[Li3SiO4]4:Eu coumpounds.
Open Research DataNarrowband green phosphors with high quantum efficiency are required for backlighting white light-emitting diode (WLED) devices. Materials from the A[Li3SiO4]4:Eu2+ family have recently been proposed as having superior properties to industry-standard β-SiAlON green phosphors. Here, we show that a cheap, easily synthesized host NaK2Li[Li3SiO4]4 (NKLLSO)...
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Silver complexes stabilized by large silanethiolate ligands – crystal structures and luminescence properties
PublicationBulky silanethiolate and disiladithiolate ligands were applied to synthesize one mononuclear and three trinuclear silver complexes including two cyclic “microclusters” and a linear tri-nuclear silanethiolate complex. All obtained compounds are characterized by X-ray diffraction and FT-IR. NMR and emission spectroscopies were used where possible. The first trinuclear anionic silver thiolate is structurally characterized. The influence...
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The field–dependent interface recombination velocity for organic–inorganic heterojunction
PublicationWe have derived an analytical formula which describes the field–dependent interface recombination velocity for the boundary of two materials characterized by different permittivities. The interface recombination of charge carriers has been considered in the presence of image force Schottky barrier. We suggest that this effect may play an important role in the loss of current for organic–inorganic hybrid heterojunctions. It has...
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Międzypokoleniowa sieć współpracy zawodowej jako baza do transferu wiedzy
PublicationW artykule przedstawiono koncepcje międzypokoleniowej sieci współpracy zawodowej umożliwiającej wsparcie współczesnego biznesu poprzez transfer wiedzy związany z wykorzystaniem doświadczenia i wieloletniej praktyki zawodowej osób starszych. Prezentowana w artykule koncepcja podkreśla konieczność tworzenia sieci międzypokoleniowej współpracy zawodowej
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Creative sprints: an unplanned broad agile evaluation and redesign process.
PublicationWe report how a request for routine usability work rapidly evolved into a novel agile process for evaluation and redesign. This process is described and then analysed to identify reasons for success. This analysis supports realistic knowledge transfer between User Experience professionals by outlining how similar future processes could succeed.
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Adsorption behavior and corrosion inhibitive characteristics of newly synthesized cyano-benzylidene xanthenes on copper/sodium hydroxide interface: Electrochemical, X-ray photoelectron spectroscopy and theoretical studies
PublicationElegant process for synthesis of 3-(7H-dibenzo[c,h]xanthen-7-yl)benzaldehyde (3), as new starting material to create a set of novel xanthene analogues, 2-(3-(7H-dibenzo[c,h]xanthen-7-yl)benzylidene)malononitrile (4), 3-(3-(7H-dibenzo[c,h]xanthen-7-yl)phenyl)-2-cyanoacrylic acid (5), and Ethyl-3-(3-(7H-dibenzo[c,h]xanthen-7-yl)phenyl)-2-cyanoacrylate (6), was achieved starting with available materials under mild conditions. Various...
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Effects of Ni-NCAL and Ni–Ag electrodes on the cell performances of low-temperature solid oxide fuel cells with Sm0.2Ce0·8O2-δ electrolyte at various temperatures
PublicationThree low-temperature solid oxide fuel cells are built using Sm0.2Ce0·8O2-δ (SDC) as the electrolyte. Cell A is symmetrical and features Ni–LiNi0.8Co0·15Al0·05O2 (Ni–NCAL) electrodes, Cell B comprises a Ni–NCAL anode and a Ni–Ag cathode, and Cell C is fabricated using a Ni–NCAL cathode and a Ni–Ag anode. The ohmic resistance and polarization resistance (Rp) of Cells B and C are significantly higher than those of Cell A. The reduction...
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Hybrid TiO2–Polyaniline Photocatalysts and their Application in Building Gypsum Plasters
PublicationHybrid materials of conjugated polymer and titanium(IV) oxide have attracted considerable attention concerning their potential benefits, including (i) ecient exploitation of visible light, (ii) a high adsorption capacity for organic contaminants, (iii) and eective charge carriers separation. The new class of the photocatalysts is promising for the removal of environmental pollutants in both aqueous and gaseous phases. For the first...
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Controlling the europium oxidation state in diopside through flux concentration
PublicationThis paper explores the connection between the H3BO3 flux concentration and the co-existence of Eu2+ and Eu3+ dopants within CaMgSi2O6 crystals (diopside). The samples were synthesised using a solid-state synthesis method under varying atmospheric conditions, including oxidative (air), neutral (N2), and reductive (H2/N2 mixture) environments. Additionally, some materials underwent chemical modification by partially substituting...
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Properties of Oxygen Vacancy and Hydrogen Interstitial Defects in Strontium Titanate: DFT + Ud,p Calculations
PublicationThis work presents extensive theoretical studies focused on the mixed ion-electron transport in cubic strontium titanate (STO). A new approach to the description of this difficult system was developed within the framework of linear-scaling Kohn–Sham density functional theory, as realized in the ONETEP program. The description we present is free of any empirical parameters and relies on the Hubbard U and Hund’s J corrections applied...
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Scheelite-Type Wide-Bandgap ABO4 Compounds (A = Ca, Sr, and Ba; B = Mo and W) as Potential Photocatalysts for Water Treatment
PublicationIn the present study, alkaline-earth metal scheelite-type compounds ABO4 (A = Ca, Sr, Ba, B = Mo, W) synthesized by a hydrothermal method were systematically studied. The as-obtained photocatalysts were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Brunauer-Emmett-Teller surface area analysis (BET), UV–Vis diffuse reflectance spectroscopy (DR/UV-Vis), photoluminescence, and thermoluminescence (TL)...
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Advanced Potential Energy Surfaces for Molecular Simulation
PublicationAdvanced potential energy surfaces are defined as theoretical models that explicitly include many-body effects that transcend the standard fixed-charge, pairwise-additive paradigm typically used in molecular simulation. However, several factors relating to their software implementation have precluded their widespread use in condensed-phase simulations: the computational cost of the theoretical models, a paucity of approximate models...
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Rola uczelni na rynkach rozwiniętych krajów Unii Europejskiej
PublicationOmówiono powiązania uczelni i ludzi nauki z praktyką gospodarczą na rynkach rozwiniętych krajów Unii Europejskiej. Przedstawiono rozwiązania ułatwiające transfer wiedzy i wynalazków z uniwersytetów do firm na przykładzie rozwiązań z Finlandii, Belgii oraz Wielkiej Brytanii. Sformułowano wnioski.
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Mobile wireless measurement system for potatoes storage management
PublicationThe paper discusses the idea and the design of a remote control system for a storage management of agricultural products which temperature may rise in a result of biological processes during the storage. Exemplary potatoes storehouse is discussed as an application of the automation system. Because of existing buildings and infrastructure in the farm, wireless data transfer system has been proposed for both sensors to data acquisition...
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Analysis of exhaled breath for dengue disease detection by low-cost electronic nose system
PublicationThis paper presents a procedure and a set-up of an electronic nose system analyzing exhaled breath to detect the patients suffering from dengue – a mosquito-borne tropical disease. Low-power resistive gas sensors (MiCS-6814, TGS8100) were used to detect volatile organic compounds (VOCs) in the exhaled breath. The end-tidal phase of patients exhaled breath was collected with a BioVOCTM breath sampler. Two strategies were assessed...
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Thermal analysis of Magnetohydrodynamics (MHD) Casson fluid with suspended Iron (II, III) oxide-aluminum oxide-titanium dioxide ternary-hybrid nanostructures
PublicationThis study is carried out to enhance and analyze the thermal performance of non-Newtonian Casson fluid by immersing Ternary hybrid nanoparticles Fe3O4-Al2O3-TiO2 uniformly. To model the behaviour of such complex phenomena mathematically, a system of complex transport differential equations is developed by utilizing a non-Fourier heat transfer model for energy transport. The non-dimensional system of transport equations involving...
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Rozdział 10.2 Metody oznaczania właściwości przeciwutleniających próbek żywności
PublicationWystępowanie większości chorób cywilizacyjnych może być rezultatem stresu oksydacyjnego prowadzącego do różnorodnych zmian w ludzkim organizmie, wywołanych działaniem tzw. reaktywnych form tlenu. Z tego też powodu pojawiło się olbrzymie zapotrzebowanie na szybkie testy umożliwiające pomiar całkowitej zawartości przeciwutleniaczy czy też ogólnej siły przeciwutleniającej produktów żywnościowych a w szczególności świeżych warzyw...
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Agricultural products' storage control system
PublicationThe paper discusses the idea and the design of a remote control system for storage management of agricultural products which temperature may rise as the result of biological processes during the storage. An actual potatoes storehouse is discussed as an application for the proposed automation system. Because of existing buildings and infrastructure at the farm, wireless data transfer system has been proposed for communication between...
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Konzetrationslöschung durch Energieübertragung bei der Lumineszenz von Lösungen
PublicationThe absorption spectra and quantum yields of the fluorescence of rhodamine 6 G are investigated in two different water-glycerol mixtures as a function of the rhodamine concentration. The observed concentration quenching is attributed to the formation of rhodamine dimers and the decrease in quantum yield is compared with theoretical concepts about concentration quenching by energy transfer to the dimers.
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Induced Sheath Voltages In 110 Kv Power Cables – Case Study
PublicationThe paper considers shock hazard due to induced sheath voltages in 110 kV power cables. Various configurations of the metallic sheaths bonding and earthing (single-point bonding, both-ends bonding, cross-bonding) are analysed. Taking into account shock hazard and ability of the system to power transfer an optimal configuration is proposed.
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Excitation energy transport and trapping in concentrated solid solution of flavomononucleotide
PublicationW pracy analizowano bez promienisty transfer energii w stężonych stałych roztworach (folie polimerowe) FMN. W w/w roztworach występują świecące dimery FMN. Pokazano, że jedynie uwzględnienie powrotnego transferu energii pozwala zadowalająco wyjaśnić mechanizm przenoszenia energii w badanych układach.
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Red Algae – An Alternative Source of Carbon Material for Energy Storage Application
PublicationNew electrode material obtained by pyrolysis of aquatic biomass macro (red algae) soaked with glucose solution has been characterized by SEM, EDX and Raman spectroscopy. Graphitized carbon was identified by Raman spectroscopy. Galvanostatic cyclic polarization of the materials in contact with 1M LiPF6 electrolyte in EC:DMC (1:1 v/v) and Li as a counter electrode was performed. Specific capacity of the novel material was enhanced...
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Ammonium <i>O</i>,<i>O</i>'-diethyl dithiophosphate
PublicationIn the title compound, NH4+·(C2H5O)2PS2−, the ammonium cation is connected by four charge-assisted N−H···S hydrogen bonds to four tetrahedral O,O'-diethyl dithiophosphate anions, forming layers parallel to (100). The polar and non-polar constituents of the layers are stacked alternately along [100]. Interlacing of the external ethyl groups...
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Weak localization competes with the quantum oscillations in a natural electronic superlattice: The case of Na1.5(PO2)4(WO3)20
PublicationWe report an investigation of the combined structural and electronic properties of the bronze Na1.5(PO2)4(WO3)20. Its low-dimensional structure and possible large reconstruction of the Fermi surface due to charge density wave instability make this bulk material a natural superlattice with a reduced number of carriers and Fermi energy. Signatures of multilayered two-dimensional (2D) electron weak localization are consequently reported,...
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Electrochemically Induced Synthesis of Triphenylamine-based Polyhydrazones
PublicationTriphenylamine-based hydrazones were subjected to electropolymerization process that gave well conductive hydrazone based polymers. The first example of polyhydrazone formation during the electrochemical process was shown. The estimation of polymer structure was demonstrated using IR spectroelectrochemistry. The EPR spectroelectrochemistry allowed to explain why in some cases dimer couldn’t be formed. The results of electrochemical,...
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Influence of the thermal modernization of window on transmission heat losses
PublicationThe article presents the results of calculations of the heat transfer coefficient for the state before and after renovation for the historic windows. The aim of the analysis was to obtain the values of thermal insulation parameters demanded by the regulations, while not losing the historical value of the window. The described example of the renovation of the existing window consisted in installing an additional window panel from...
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Możliwości ograniczenia zużycia energii napędowej urządzeń przez optymalizację doboru wymienników ciepła, właściwą konfigurację i kontrolę przepływu płynów roboczych
PublicationArtykuł poświęcony możliwości ograniczenia zużycia energii napędowej urządzeń na drodze optymalizacji doboru wymienników ciepła, właściwej konfiguracji i kontroli przepływu płynów roboczych. Przedstawiono w nim ocenę zużycia energii w systemach energetycznych o największej energochłonności w realiach Polski. Zwrócono uwagę na możliwość wykorzystania wymienników ciepła o wysokiej efektywności dla zmniejszenia oporu przenoszenia...
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Education4+ Education for sustainable development: transfering V4 countries' experience for Ukraine's recovery
ProjectsProject realized in Department of Process Engineering and Chemical Technology