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Search results for: CRUMB RUBBER MODIFICATION
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Improving the CPX method by specifying reference tyres and including corrections for rubber hardnes and temperature
PublicationRecently completed work in the EU project ROSANNE and in working group ISO/TC43/SC1/WG33 has allowed substantial improvements to measurements made by the Close-Proximity (CPX) method, intended for measurement of noise properties of road surfaces.The paper summarizes the experimental work and describes the conclusions and implementation in ISO/FDIS 11819-2 (CPX method) and in the supporting ISO (draft) Technical Specifications 11819-3...
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Monitoring of Rubber Belt Material Performance and Damage
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Determining the viscoplastic parameters of rubber-toughened plastics
PublicationW artykule omówiono szczegółowo zastosowanie sprężysto-lepkoplastycznego prawa Bodnera-Partoma do opisu zachowania się tworzywa sztucznego (kopolimer etylenowo-propylenowy). Parametry materiałowe ustalono na podstawie jednoosiowych testów jednoosiowego rozciągania. Proponowane podejście jest zilustrowane przykładami obliczeniowymi w programie MSC.Marc z wykorzystaniem procedury UVSCPL.
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Influence of Surface Modification of Titanium and Its Alloys for Medical Implants on Their Corrosion Behavior
PublicationTitanium and its alloys are often used for long-term implants after their surface treatment. Such surface modification is usually performed to improve biological properties but seldom to increase corrosion resistance. This paper presents research results performed on such metallic materials modified by a variety of techniques: direct voltage anodic oxidation in the presence of fluorides, micro-arc oxidation (MAO), pulse laser treatment,...
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Ground Tire Rubber Modified by Ethylene-Vinyl Acetate Copolymer: Processing, Physico-Mechanical Properties, Volatile Organic Compounds Emission and Recycling Possibility
PublicationGround tire rubber (GTR) was reclaimed and modified with 10 phr of ethylene-vinyl acetate copolymer via low-temperature extrusion process. Processing, physico-mechanical properties, volatile organic compounds emission, and recycling possibility were investigated. In order to better understand the impact of used modifiers, their efficiency was compared with transpolyoctenamer, which is an additive that is commercially dedicated...
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Effect of surface modification on starch biopolymer wettability
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Effect of surface modification on starch/phospholipid wettability
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New procedure of silica gel surface modification
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Modification of titanium phosphate precipitated from titanylsulfate
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Properties of corn starch subjected hydrothermal modification
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Totally laparoscopic feeding jejunostomy – a technique modification
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Surface modification of cotton fabrics for sublimation printing
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Influence of titanium dioxide modification on the antibacterial properties
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Proposition of the steam turbine governor structure modification
PublicationThere is considered the steam turbine governor operation during defense and restoration of the power system. It points out weaknesses of currently used governor structures. The new controller is proposed, that takes advantages of those curently used. The new controller allows for more effective control of the turbine in emergency situations, at frequencies much different from the nominal value.
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Enhanced interfacial and mechanical performance of styrene-butadiene rubber/silica composites compatibilized by soybean oil derived silanized plasticization
PublicationSilanized plasticizer (SP) was chemically derived and synthesized from soybean oil (SBO) co-vulcanized with bis-(3-(triethoxysilyl)-propyl) tetrasulfide (TESPT) by using the sulfur-accelerated curing system. SP extended styrene-butadiene rubber (SBR)/silica composites have been studied for their improved filler dispersion through coupling interaction at the SBR/silica interface. The effect of SP on cross-link density, thermal,...
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Fabrication of toughened plastic using styrene butadiene rubber-poly (methyl methacrylate) interpenetrating polymer networks
PublicationA standard set of interpenetrating polymeric networks (IPNs) has been contrived using an elastomerstyrene butadiene rubber and a thermoplastic poly (methyl methacrylate) through sequential polymerization protocol. This low-cost material can be hopefully engaged as a toughened plastic with cocontinuous morphology. Different morphological protocols including Raman imaging are effectively utilized to envisage the effect of blend ratio...
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High-performance method of carbon nanotubes modification by microwave plasma for thin composite films preparation
PublicationIn this work we present a simple and efficient method of nitrogen plasma modification of carbon nanotubes (CNTs). The process allows for treatment of the nanotubes in the form of powder with quite a high yield (65 mg of CNTs per hour). The modified carbon nanotubes contain approx. 3.8% of nitrogen, mostly in the pyridinic form. Plasma treated CNTs exhibit better dispersibility in water and higher electric capacitance than pristine...
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Waste printer ink as modifier for natural rubber/carbon black composites: No haste, use waste
PublicationFrom a sustainability perspective, achieving a greener future with a minimal carbon footprint requires maximizing waste materials' reuse. The four pillars of satisfying customer demands are processing, price, properties, and performance. Along with such a global policy, this work seeks to utilize waste printer ink (WPI) as a source of carbon in combination with low- and high-surface carbon black (LCB and HCB, respectively) additives...
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Modification of cellulosic filler with diisocyanates – volatile organic compounds emission assessment and stability of chemical structure over time
PublicationThis paper investigated the impact of type and content of diisocyanate on the structure of modified cellulose fillers. Four the most popular isocyanates were applied – isophorone, hexamethylene, toluene and methylene diphenyl diisocyanate – at loadings of 1–15 wt%. Chemical structure, and its short-term storage stability, were investigated for eight weeks. Moreover, the main volatile organic compounds detected during modification,...
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ATTEMPT AT EVALUATING THE INFLUENCE OF BENDING STRESS ON SHAFT WEAR PROCESSES IN WATER LUBRICATED SLIDING BEARING WITH A RUBBER BUSHING
PublicationWater lubricated bearings find increasingly wide application in shipbuilding or hydro–power industry, the popularity stemming from their numerous advantages. Unfortunately, as it turns out, water lubricated bearings do not always meet expectations, as on occasion they become subject to intense, premature wear which requires costly repair. One of the still unexplained phenomena is the process of excessive bearing wear, in particular...
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Thermal decomposition kinetics of dynamically vulcanized polyamide 6-acrylonitrile butadiene rubber-halloysite nanotube nanocomposites
PublicationThermally stable thermoplastic elastomer nanocomposites based on polyamide 6 (PA6), acrylonitrile butadiene rubber (NBR), and halloysite nanotubes (HNTs) were dynamically vulcanized, and their nonisothermal decomposition kinetics were examined. The Friedman, Kissinger–Akahira–Sunose (KAS), Ozawa–Wall–Flynn (FWO), and modified Coats–Redfern (m‐CR) isoconversional models were used to obtain information about the kinetics of the thermal...
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Fire-Retardant Flexible Foamed Polyurethane (PU)-Based Composites: Armed and Charmed Ground Tire Rubber (GTR) Particles
PublicationInadequate fire resistance of polymers raises questions about their advanced applications. Flexible polyurethane (PU) foams have myriad applications but inherently suffer from very high flammability. Because of the dependency of the ultimate properties (mechanical and damping performance) of PU foams on their cellular structure, reinforcement of PU with additives brings about further concerns. Though they are highly flammable and...
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Insights into modification of lignocellulosic fillers with isophorone diisocyanate: structure, thermal stability and volatile organic compounds emission assessment
PublicationThis study presents an analysis of the structure and properties of different types of lignocellulosic fillers modified by isophorone diisocyanate (IPDI) to provide insights into the possibility of their application to the manufacturing of wood polymer composites (WPCs). Moreover, it deals with the environmental aspects of modified fillers, by assessment of volatile organic compounds (VOCs) emitted during modification, as well as...
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Insights into Stoichiometry Adjustments Governing the Performance of Flexible Foamed Polyurethane/Ground Tire Rubber Composites
PublicationPolyurethanes (PU) are widely applied in the industry due to their tunable performance adjusted by changes in the isocyanate index—stoichiometric balance between isocyanate and hydroxyl groups. This balance is affected by the incorporation of modifiers of fillers into the PU matrix and is especially crucial for PU foams due to the additional role of isocyanates—foaming of the material. Despite the awareness of the issue underlined...
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Optimum shapes and dimensions of rubber bumpers in order to reduce structural pounding during seismic excitations
PublicationLarge displacement of structures observed during seismic excitations may lead to collisions between two adjacent, insufficiently-separated buildings and may result in major damages of both of them. In many building codes, appropriate equations or approximately recommended distances between structures in order to avoid pounding hazard have been introduced. Unfortunately, further, more detailed considerations show that safety situation...
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The Impact of Hybrid Flame Retardant Compositions on the Performance of Foamed Flexible Polyurethane/Ground Tire Rubber Composites
PublicationCurrent sustainability-oriented trends affect polyurethane (PU) materials and stimulate the incorporation of recycled or waste-based materials as fillers. Ground tire rubber (GTR) poses as an auspicious candidate due to the excellent performance of car tires. Despite the benefits related to the mechanical performance, it contributes to the increasing flammability of the resulting composites. Herein, presented work assessed the...
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Microstructure and Mechanical Properties of Carboxylated Nitrile Butadiene Rubber/Epoxy/XNBR-grafted Halloysite Nanotubes Nanocomposites
PublicationThe effect of various amounts of carboxylated nitrile butadiene rubber (XNBR) functionalized halloysite nanotubes (XHNTs) on the cure characteristics, mechanical and swelling behavior of XNBR/epoxy compounds was experimentally and theoretically investigated. The morphology of the prepared XNBR/epoxy/XHNTs nanocomposites was imaged using scanning electron microscopy (SEM). The effects of various XNBR-grafted nanotubes on the damping...
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Recycled rubber wastes-based polymer composites with flame retardancy and electrical conductivity: Rational design, modeling and optimization
PublicationPolymer recycling techniques experience a maturity period of design and application. Rubbers comprise a high proportion of polymer wastes, highly flammable and impossible to re-melt. Polymer composites based on ground tire rubber (GTR) and ethylene-vinyl acetate copolymer (EVA) containing carbon black (CB) (1–50 phr), with variable EVA/GTR weight composition (10/90, 25/75, 50/50, 75/25 and 90/10), and processing temperature (Low:...
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Experimental tests of water lubricated marine rubber bearing
PublicationW referacie przedstawiono stosowane obecnie rodzaje łożysk gumowych smarowanych wodą. Omówiono ich zalety i wady.W drugiej części pracy przedstawiono wyniki badań eksperymantalnych typowego okrętowego łożyska gumowego. Uzyskane rezultaty porównano z wynikami badań łożysk z polimerową panwią.
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Non-linear model of high damping rubber bearing.
PublicationCelem artykułu jest analiza modelu łożyska wykonanego z wysokotłumiącej gumy, które wykorzystywane są do posadowienia konstrukcji budowlanych na terenach sejsmicznych. Model umożliwia numeryczną symulację pracy urządzenia pod zadanym obciążeniem i w danych warunkach termiczno-wilgotnościowych. Wyniki analizy pokazują, iż proponowany model umożliwia symulację zachowania się łożyska w szerokim zakresie odkształceń.
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The phenomenon of increasing capacitance induced by 1T/2H-MoS2 surface modification with Pt particles – Influence on composition and energy storage mechanism
PublicationIn this paper, several approaches to the synthesis of molybdenum-based electrode materials for supercapacitors are presented, including anodization, hydrothermal process and annealing. For the material prepared via anodization of a molybdenum plate, followed by a hydrothermal process in thiourea aqueous solution, a thorough study of the Pt-surface modification through repetitive cycling in 1 M sulfuric acid with Pt acting as a...
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Human voice modification using instantaneous complex frequency
PublicationThe paper presents the possibilities of changing human voice by modifying instantaneous complex frequency (ICF) of the speech signal. The proposed method provides a flexible way of altering voice without the necessity of finding fundamental frequency and formants' positions or detecting voiced and unvoiced fragments of speech. The algorithm is simple and fast. Apart from ICF it uses signal factorization into two factors: one fully...
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Modification of Lightweight Aggregate Concretes with Silica Nanoparticles—A Review
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Modification of cement-ash composites with steel fibre addition
PublicationPraca zawiera wyniki badań kompozytów cementowo-popiołowych, w których popiół zastosowano jako częściowy zamiennik cementu. Do kompozytów dodano niewielkie ilości dwóch rodzajów włókien stalowych. Zbadano właściwości techniczne kompozytów. Wytrzymałości kompozytów cementowo-popiołowych z włóknami stalowymi w stosunku do wytrzymałości kompozytów bez włókien po wszystkich okresach wiązania i twardnienia były wyższe od kilku do kilkudziesięciu...
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Selected Propagation Models Modification for Application in Container Terminal
PublicationIt is particularly important to look for any propagation model that could be useful for designing mobile radio systems in container terminal environment. The selected propagation models have been investigated. The applied research methodology has been described too. Results of the statistical adjustment in terms of signal loss determination in such environment have been analysed. The analysis have proved effectiveness of adjustment...
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The Influence of Titania Electrode Modification with Lanthanide Ions Containing Thin Layer on the Performance of Dye-Sensitized Solar Cells
PublicationThe lanthanide and scandium groups ions (except Pm and Ac) have been used as dopants of TiO2 film in dye-sensitized solar cells. The X-ray diffraction spectra show that the modification has no influence on the structure of the electrode; however, the diffuse reflectance UV-Vis measurements exhibit significant changes in the electronic properties of modified electrodes. The appearance of energy barrier preventing photoexcited electron...
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In-Out Surface Modification of Halloysite Nanotubes (HNTs) for Excellent Cure of Epoxy: Chemistry and Kinetics Modeling
PublicationIn-out surface modification of halloysite nanotubes (HNTs) has been successfully performed by taking advantage of 8-hydroxyquinolines in the lumen of HNTs and precisely synthesized aniline oligomers (AO) of different lengths (tri- and pentamer) anchored on the external surface of the HNTs. Several analyses, including FTIR, H-NMR, TGA, UV-visible spectroscopy, and SEM, were used to establish the nature of the HNTs’ surface engineering....
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Mechanical and thermo-mechanical properties of natural rubber composites filled with submicron- and nano-sized silica particles and prepared using glycolysate as a plasticizer
PublicationThe main aim of this work was to examine the selected mechanical and thermo-mechanical properties of natural rubber/silica composites prepared using glycolysate as a plasticizer. Prepared composites contained different amounts of submicron- (10, 15, 20 or 25 pphr) or nano-particles (0.5, 0.75, 1.0 or 1.25 pphr). The tensile properties, tear resistance, hardness, abrasion resistance and resilience of prepared materials were determined....
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Cellulosic bionanocomposites based on acrylonitrile butadiene rubber and Cuscuta reflexa: adjusting structure-properties balance for higher performance
PublicationDesign and manufacture of cellulosic nanocomposites with acceptable performance is in the period of a transition from fantasy to reality. Typically, cellulosic nanofillers reveal poor compatibility with polymer matrices. Thus, adjusting the balance between structure and properties of cellulosic bionanocomposites by careful selection of parent ingredients is the first priority. Herein, we incorporated Cuscuta reflexa derived cellulose...
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The chemistry, properties and performance of flame-retardant rubber composites: Collecting, analyzing, categorizing, machine learning modeling, and visualizing
PublicationRubbers combine the flexibility with mechanical strength, supporting myriad applications, but suffer from inherent flammability. Formulation and production of flame-retardant rubber composites (FRRCs) have intensively been practiced over years, but not comprehensively reviewed. This necessity has outlined collecting, analyzing, screening, classifying, and interpreting the literature with the aim of classifying the FRRCs. We quantified...
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The estimation of total volatile organic compounds emissions generated from peroxide cured natural rubber/polycaprolactone blends
PublicationNatural rubber (NR)/polycaprolactone (PCL) blends at the ratio of 90/10% wt. (NR/PCL90/10) and 70/30% wt. (NR/PCL70/30), with a constant amount of dicumyl peroxide, were prepared by compounding in an internal mixer. Obtained NR/PCL bio-based blends were cured at three different temperatures (150 °C, 160 °C and 170 °C). The total content of volatile organic compounds (TVOC) as a function of the NR/PCL blends ratio, and their curing...
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The Impact of Isocyanate Index and Filler Functionalities on the Performance of Flexible Foamed Polyurethane/Ground Tire Rubber Composites
PublicationThe structure and performance of polyurethane (PU) foams are strongly driven by the stoichiometry of the polyaddition reaction, quantitatively described by the isocyanate index. It determines the balance between isocyanate and hydroxyl groups in the reacting system and is affected by the introduction of additional functionalities originated, e.g., from applied fillers. Nevertheless, this issue is hardly taken into account in research...
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Inspection of rubber linings operating in flue gas desulphurisation units
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Weather aging effects on modified asphalt with rubber-polyethylene composites
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Nonlinear rate dependent model of high damping rubber bearing.
PublicationCelem artykułu jest analiza nieliniowego modelu łożyska wykonanego z wysokotłumiącej gumy, który symuluje pracę urządzenia pod zadanym obciążeniem. Parametry modelu dobrane są na podstawie wyników badań eksperymentalnych. Wyniki pracy pokazują, iż analizowany model umożliwia symulację zachowania się łożyska w szerokim zakresie odkształceń
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The effect of mercerized sisal fibres on natural rubber composites' properties
PublicationW pracy omówiono wyniki badań fizyko-mechanicznych kompozytów otrzymanych z mieszanek zawierających kauczuk naturalny oraz statystycznie zdyspergowane krótkie włókno sisalowe. Włókno naturalne przed użyciem poddano merceryzacji.Otrzymane wulkanizaty poddano badaniom wytrzymałościowym w warunkach statycznych w celu określenia wpływu parametrów wulkanizacji i ilości dodanego włókna na właściwości otrzymanych produktów. Stwierdzono...
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METHODS OF THE MODIFICATION OF VEGETABLE OILS IN ORDER TO OBTAIN BASE OILS
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Hydrothermal, microwave and mechanochemical modification of amorphous zirconium phosphate structure
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Modification of Tin Phosphate Nanoporous Structure under Hydrothermal Conditions
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Modification of titanium dioxide with platinum ions and clusters: application in photocatalysis
PublicationW celu polepszenia właściwości fotokatalitycznych, TiO2 (komercyjny-P25 oraz syntezowany metoda zol-żel) był domieszkowany za pomocą jonów lub klasterów [Pt3(CO)6]62- platyny. Własności fizyczne fotokatalizatorów były badane za pomocą elektronowego mikroskopu transmisyjnego (TEM), dyfraktometru rentgenowskiego (XRD) oraz analizatora powierzchni właściwej (BET). Dyfuzyjna spektrometria odbiciowa (DRS) została zastosowana w celu...