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Search results for: ION EXCLUSION CHROMATOGRAPHY
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Treatment of effluents from the regeneration of ion exchangers using the MD process
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The Effects of Silver Ion Implantation on Structural and Morphological Performance of Hydroxyapatite Coatings
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Azomacrocyclic derivatives of imidazole: synthesis, structure, and metal ion complexation properties
PublicationOtrzymano nowe azokorony zawierające resztę imidazolu w makropierścieniu. Na drodze sprzęgania z solami diazoniowymiotrzymano pochodne imidazolu 2-metylo, 4-metylo oraz 4-fenyloimidazolu. Synteza była prowadzona w warunkach wysokiego ciśnienia. Dla 21-członowej pochodnej 4-metyloimidazolu określono strukturę jej adduktu z wodą przy pomocy metod rentgenograficznych.Zdolność kompleksowania jonów metali badano spektrofotometrycznie...
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An Insight into the Stages of Ion Leakage during Red Blood Cell Storage
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Digital harmonic analysis of cadmium ion reduction on a dropping mercury electrode
PublicationBadano redukcję jonów kadmu na rtęciowej elektrodzie kroplowej. Jako pobudzenie zastosowano sinusoidalny sygnał napięciowy nałożony na liniowo zmieniający się potencjał dc. Przeprowadzono analizę czasowo-częstotliwościową prądu polarograficznego dla reakcji redukcji jonu kadmu na rtęciowej elektrodzie kroplowej. Klasyczna transformacja Fouriera prowadzi do dekompozycji prądu polarograficznego na składowe harmoniczne. Harmoniczne...
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Ab initio molecular treatment for charge transfer by S3+ ion on hydrogen.
PublicationPoliczono adiabatyczne potencjały oddziaływania między jonem siarki i wodoru. Dokonano obliczeń nieadiabatycznych sprzężeń pomiędzy tymi potencjałami. Obliczenia wykazały, że należy wziąć pod uwagę niezbadany wcześniej poziom energetyczny jonu siarki aby dokładnie wyjaśnić mechanizm przechwytu ładunku.
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Negative Ion Formation in Sodium Chloride TrimerAn ab Initio Study
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Creation of mesopores in carbon nanotubes with improved capacities for lithium ion batteries
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Counter-ion effect on antistaphylococcal activity and cytotoxicity of selected antimicrobial peptides
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Influence of Cr Ion Implantation on Physical Properties of CuO Thin Films
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Composite Materials Based on Silicon Oxycarbide as Anodes for Lithium-Ion Batteries
PublicationIn this work, the properties of binary SiOC/graphite and SiOC/tin, as well as ternary SiOC/graphite/tin obtained from various preceramic precursors are described. During the first step, the materials were synthesized using various techniques such as sol-gel and hydrosilylation. To prevent sedimentation and agglomeration of graphite particles during the gelation stage without using surfactants and thickeners, a new gelation technique...
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Effect of Ion and Binding Site on the Conformation of Chosen Glycosaminoglycans at the Albumin Surface
PublicationAlbumin is one of the major components of synovial fluid. Due to its negative surface charge, it plays an essential role in many physiological processes, including the ability to form molecular complexes. In addition, glycosaminoglycans such as hyaluronic acid and chondroitin sulfate are crucial components of synovial fluid involved in the boundary lubrication regime. This study presents the influence of Na+, Mg2+ and Ca2+ ions...
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Aquatic biomass containing porous silica as an anode for lithium ion batteries
PublicationA composite electrode was manufactured by pyrolysis of Red Algae (Polysiphonia fucoides) covered by diatoms (Diatomophyceae). Electrodes were tested as a half cell with capacity of 500 mA h g−1 after 80 cycles. XPS analysis shows formation of lithium silicate under reduction of silica in an aprotic electrolyte containing LiPF6 salt.
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Focused ion beam-based microfabrication of boron-doped diamond single-crystal tip cantilevers for electrical and mechanical scanning probe microscopy
PublicationIn this paper, the fabrication process and electromechanical properties of novel atomic force microscopy probes utilising single-crystal boron-doped diamond are presented. The developed probes integrate scanning tips made of chemical vapour deposition-grown, freestanding diamond foil. The fabrication procedure was performed using nanomanipulation techniques combined with scanning electron microscopy and focused ion beam technologies....
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Rapid Characterization of the Human Breast Milk Lipidome Using a Solid-Phase Microextraction and Liquid Chromatography-Mass Spectrometry-Based Approach.
PublicationHuman breast milk (HBM) is a biofluid consisting of various biomolecules such as proteins, lipids, carbohydrates, minerals and bioactive substances. Due to its unique and complex composition, HBM provides not only nutritional components required for the growth of the infant, but also additional protection against infections. Global insight into the composition of HBM is crucial to understanding the health benefits infants receive...
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Identification of acrylate copolymers using pyrolysis and gas chromatography
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Calixarenes as stationary phases in High Performance Liquid Chromatography
PublicationPraca przeglądowa przedstawia dotychczasowe metody syntezy faz stacjonarnych na bazie pochodnych kaliksarenów, kaliksrezorcyarenów i kalikspiroli chemicznie ziązanych z żelem krzemionkowym lub dynamicznie na nim obsadzonych. Podsumowano zastosowanie tych faz w rozdzielaniu szeregu klas związków organicznych i nieorganicznych metodą wysokosprawnej chromatografii cieczowej.
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DIAGNOSES MADE BY LEADERS OF EMERGENCY MEDICA L SERVICES TEAMS WITHIN THE OPERAT ION AREA OF THE EMERGENCY MEDICA L SERVICES STAT ION IN MINSK MAZOWIECKI IN 2013-2017
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Direct solid phase microextraction combined with gas chromatography – Mass spectrometry for the determination of biogenic amines in wine
PublicationA direct method based on immersion solid phase microextraction (DI-SPME) gas chromatography mass-spectrometry (GC-MS) was optimized and validated for the determination of 16 biogenic amines in Polish wines. In the analysis two internal standards were used: 1,7-diaminoheptane and bis-3-aminopropylamine. The method allows for simultaneous extraction and derivatization, providing a simple and fast mode of extraction and enrichment....
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Sensitive determination of isoprostanes in exhaled breath condensate samples with use of liquid chromatography–tandem mass spectrometry
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Determination of Pesticide Residues in Honeybees using Modified QUEChERS Sample Work-Up and Liquid Chromatography-Tandem Mass Spectrometry
PublicationIncreasing emissions of chemical compounds to the environment, especially of pesticides, is one of factors that may explain present honeybee colony losses. In this work, an analytical method employing liquid chromatography-tandem mass spectrometry (LC-MS/MS) was optimized for the simultaneous screening of 19 pesticides which have not been yet determined in honeybee samples from northern Poland (Pomerania). The sample preparation,...
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Discrepancies in determination of biogenic amines in beer samples by reversed phase and hydrophilic interaction liquid chromatography coupled with tandem mass spectrometry
PublicationBiogenic amines (BAs) are nitrogenous organic bases occurring mainly in fermented food and beverages as a result of free amino acids bacterial decarboxylation. The reversed phase liquid chromatography (RPLC) and hydrophilic interaction liquid chromatography (HILIC) based methods were compared in terms of usefulness for determination of BAs in beer samples. Analysis of BAs with the use of RPLC method were carried out after their...
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Journal of Chromatography & Seperation Techniques
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Paweł Możejko dr hab.
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Cell Membrane Transport Mechanisms: Ion Channels and Electrical Properties of Cell Membranes
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Poly(3-octylthiophene) as solid contact for ion-selective electrodes: contradictions and possibilities
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Gold-modified paper as microfluidic substrates with reduced biofouling in potentiometric ion sensing
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Hollow carbon sphere/metal oxide nanocomposites anodes for lithium-ion batteries
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A review on the critical challenges and progress of SiOx-based anodes for lithium-ion batteries
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Solid-phase microextraction and ion chromatographic analysis of anions based on polypyrrole electrode
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Binder-induced surface structure evolution effects on Li-ion battery performance
PublicationA comparative investigation on binder induced chemical and morphological evolution of Li4Ti5O12 electrodes was performed via X-ray photoemission spectroscopy, scanning electron microscopy, and electrochemical measurements. Composite electrodes were obtained using three different binders (PAA, PVdF, and CMC) with 80:10:10 ratio of active material:carbon:binder. The electrochemical performances of the electrodes, were found to be...
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Tailoring of SiOC composition as a way to better performing anodes for Li-ion batteries
PublicationPolymer derived silicon oxycarbide (SiOC) ceramics are investigated as potential anodes for lithiumion batteries. Different SiOC ceramics are prepared by pyrolysis (1000 °C and 1400 °C under controlled argon atmosphere) of polysiloxanes ceramic precursors. Preceramic polymers are synthesized using the sol–gel method. Phenyltriethoxysilane (PhTES) and methyltriethoxysilane (MTES) have been used as starting precursors and mixed with...
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Chemometric analysis for optimizing derivatization in gas chromatography-based procedures
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Gradient reversed-phase high-performance chromatography of ionogenic analytes
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Chiral gas chromatography as a tool for investigation into illicitly manufactured methamphetamine
PublicationW pracy przedstawiono zastosowanie gazowej chromatografii chiralnej do rozdzielania związków ubocznych powstających w trakcie syntezy metylamfetaminy. Opisano rozdzielanie enancjomerów efedryny, pseudoefedryny, chlorowanych związków posrednich i metylamfetaminy stosując do derywatyzacji bezwodniki fluorowanych kwasów. Jako fazę chiralną zastosowano CHIRALDEX B-DM. Do rozdzielenia enancjomerów pseudoefedryny oraz chlorowanych produktów...
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Sorption properties of asphaltene stationary phases for gas chromatography separations
PublicationW pracy przedstawiono wyniki badań nad możliwością wykorzystania faz stacjonarnych na bazie frakcji asfaltenowych do rozdzielania mieszanin związków chemicznych z wykorzystaniem chromatografii gazowej oraz porównano selektywność faz przygotowanych z frakcji asfaltenowych wyizolowanych z różnych surowców. Na podstawie uzyskanych wyników obliczono wartości liniowych indeksów retencji oraz stałych Rohrschneidera McReynoldsa, za pomocą...
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Determination of antifreeze substances in the airport runoff waters by solid-phase microextraction and gas chromatography–mass spectrometry method
PublicationA new method has been developed for the determination of antifreeze agents such as ethylene glycol (EG), propylene glycol (PG), and diethylene glycol (DEG) in the samples of airport runoff water. The method is based on headspace solid–phase microextraction (HS–SPME) of target analytes, which is coupled with gas chromatography–mass spectrometry (GC–MS). Until now, there was a lack of appropriate methodology for collecting reliable...
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Monolithic capsule phase microextraction prior to gas chromatography-mass spectrometry for the determination of organochlorine pesticides in environmental water samples
PublicationIn this study, a capsule phase microextraction (CPME) protocol followed by gas chromatography-mass spectrometry is proposed for the accurate and sensitive monitoring of organochlorine pesticides (OCPs) in environmental water samples. Different monolithic sol–gel encapsulated sorbents were compared and monolithic sol–gel poly(ethylene glycol)-based sorbent incorporated into porous microextraction capsules resulted in the highest...
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Investigation of poly(3,4-ethylenedioxythiophene) deposition method influence on properties of ion-selective electrodes based on bis(benzo-15-crown-5) derivatives
PublicationGlassy carbon electrodes modified by conductive polymers and membrane with derivatives of bis(benzo-15-crown-5) were tested as solid contact ion selective electrodes for K+ ions concentration determination. PEDOT with PSS, Cl- and ClO4- counter ions was electrochemically deposited onto glassy carbon substrates using four different electrochemical approaches (potentiostatic, galvanostatic, potentiodynamic and potentiostatic pulses)....
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Determination of Butyltin Species in Sea Water Samples Using Solid Phase Extraction Followed by Liquid Chromatography - Tandem Mass Spectrometry
PublicationReverse phase liquid chromatography (RP-HPLC)-electrospray ionization-tandem mass spectrometry (ESI-MS-MS) was evaluated for the analysis of TBT using solid phase extraction as sample preparation method. TBT was extracted from acidified water samples (spiked with tripropyltin as internal standard) using reversed phase polymeric Strata-X cartridges. Analytes were eluted from cartridges using acetonitrile-water mixture and the volume...
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Determination of flavanols by liquid chromatography with fluorescence detection. Application to the characterization of cranberry-based pharmaceuticals through profiling and fingerprinting approaches
PublicationIn this work, a new method based on reversed-phase high-performance liquid chromatography (HPLC) with fluorescence detection (FLD) was established for the determination of catechins and related oligomeric proanthocyanidins (PACs) in cranberry-based pharmaceuticals. Compounds were recovered by liquid extraction using methanol/water/hydrochloric acid (60:39:1, v:v:v) as the extraction solvent. The chromatographic separation was carried...
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JPC-JOURNAL OF PLANAR CHROMATOGRAPHY-MODERN TLC
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Evaluation, Pitfalls and Recommendations for the “Water Layer Test” for Solid Contact Ion‐selective Electrodes
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Ion-selective electrodes based on p-tert-butyl-homooxacalixarene di(ethyl)amides
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Ion-selective electrodes based on p-tert-butyl-homooxacalixarene di(ethyl) amides
PublicationPochodne dietyloamidowe p-tert-butylodihomooksakaliks[4]arenu (1), p-tert-butyloheksahomotrioksakaliks[3]arenu (2) oraz p-tert-butylokaliks[4]arenu (3) były wykorzystane jako materiał aktywny w membranach elektrod jonoselektywnych w celu sprawdzenia detekcji kationów różnych rodzajów (Na+, K+, Cs+, Mg2+, Ca2+, Mn2+, Cu2+, Zn2+, Cd2+, Pb2+ oraz kation tetrametyloammoniowy). Wyznaczono charakterystyki elektrod oraz współczynniki...
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Nonlinear Impedance as Possible Result of Ion-Polaron Interaction in Cu2O-Al2O3-SiO2 Glass
PublicationNonlinear a.c. impedance measurements were performed in Cu2O-Al2O3-SiO2 glass in wide frequency range. The obtained results shows that a large nonlinearity in the impedance signal is observed at moderate electric fields of an order 1V/mm. The contents of the third harmonics reaches about 10% and strongly depends on temperature and frequency. The investigated glass exhibits mixed electronic-ionic conductivity. Electronic conduction...
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Fabrication of 3D graphene/MoS2 spherical heterostructure as anode material in Li-ion battery
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Carbon nanotubes decorated by mesoporous cobalt oxide as electrode material for lithium-ion batteries
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Lithium ion insertion into poly(3,4-ethylenedioxythiophene) films from propylene carbonate electrolytes.
PublicationPolimerowa matryca złożona z poli(3,4-etylenodioksytiofenu z poli(styrenosulfonianem) otrzymana została na drodze syntezy elektrochemicznej. Transport jonowy w matrycy polimerowej w kontakcie z węglanem propylenu zawierającym LiClO4 został scharakteryzowany za pomocą metody impedancji ac oraz chronowoltoamperometrii. Wyznaczono przewodność jonową matrycy oraz efektywne współczynniki dyfuzji dla kationu Li+. Wielkości te...
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Well-Designed Porous Graphene Flakes for Lithium-Ion Batteries with Outstanding Rate Performance
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