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Search results for: HOMOCLINIC ORBIT
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Cathodic activation of synthesized highly defective monoclinic hydroxyl‐functionalized ZrO2 nanoparticles for efficient electrochemical production of hydrogen in alkaline media
PublicationThe high electrochemical stability of Zirconia (ZrO2) at high potentials strongly suggested it as an alternative to carbon supports, which experience reduced efficiency due to some corrosion problems particularly during prolonged electrocatalysis activity. However, the use of ZrO2 was limited by its low electrical conductivity and surface area. In this work, we developed a methodology for synthesizing monoclinic ZrO2 NPs with increased...
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A convergence result for mountain pass periodic solutions of perturbed Hamiltonian systems
PublicationIn this work, we study second-order Hamiltonian systems under small perturbations. We assume that the main term of the system has a mountain pass structure, but do not suppose any condition on the perturbation. We prove the existence of a periodic solution. Moreover, we show that periodic solutions of perturbed systems converge to periodic solutions of the unperturbed systems if the perturbation tends to zero. The assumption on...
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Programy lojalnościowe jako narzędzie tworzenia i kształtowania relacji z klientami na przykładzie wybranych programów Grupy Hotelowej Orbis
PublicationW opracowaniu poruszono problem stosowania programów lojalnościowych w kontekście tworzenia trwałych relacji z klientami. We wstępie zdefiniowano pojęcie programów lojalnościowych i omówiono ich cele. W pierwszej części omówiono teoretyczne podstawy tego zagadnienia niezbędne do późniejszej analizy programów. Dokonano prezentacji najczęściej stosowanych rodzajów programów. Następnie omówiono poziomy budowy programu lojalnościowego...
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Tensile and flexural moduli for human orbital wall bones – comparative study
PublicationThe main aims of the current research were: (1) to analyze in detail the tensile modulus and ultimate tensile strength (UTS) of orbital wall bones separately for the left and right orbit of the same cadaver and (2) to compare the obtained results with a flexural modulus of the left and right orbit reported earlier by A. C. van Leeuwen et al. [14]. A set of 54 specimens of orbital superior and/or medial walls harvested from 16 human...
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Tworzenie i umacnianie relacji z kluczowymi klientami jako narzędzie budowania przewagi konkurencyjnej na rynku czasu wolnego na przykładzie Grupy Hotelowej Orbis
PublicationW referacie przedstawiono wykorzystanie przez wybrane podmioty rynku czasu wolnego - świadczące usługi hotelarskie - procesu budowy relacji z kluczowymi klientami jako narzędzia uzyskania przewagi konkurencyjnej. Zagadnienie to zostało omówione na przykładzie hoteli Grupy Hotelowej Orbis. W odniesieniu do wspomnianego procesu, omówiono instrumenty wykorzystane na każdym z etapów, pozwalające na pozyskanie i utrzymanie klientów...
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Running characteristics of aerodynamic bearing with self-lifting capability at low rotational speed
PublicationAn aerodynamic journal bearing that is capable of self-generating squeeze-film pressure is presented and its dynamic characteristics investigated numerically and experimentally. A numerical method based on a time marching static model was applied to assess the orbit trajectory path of the rotor upon a perturbation. Experimental results were obtained to validate the effect of the self- generated squeeze-film pressure on the stability...
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Curlicues generated by circle homeomorphisms
PublicationWe investigate the curves in the complex plane which are generated by sequences of real numbers being the lifts of the points on the orbit of an orientation preserving circle homeomorphism. Geometrical properties of these curves such as boundedness, superficiality, local discrete radius of curvature are linked with dynamical properties of the circle homeomorphism which generates them: rotation number and its continued fraction...
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Posttraumatic Orbital Emphysema: A Numerical Model
PublicationOrbital emphysema is a common symptom accompanying orbital fracture. The pathomechanism is still not recognized and the usually assumed cause, elevated pressure in the upper airways connected with sneezing or coughing, does not always contribute to the occurrence of this type of fracture. Observations based on the finite model (simulating blowout type fracture) of the deformations of the inferior orbital wall after a strike in...
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Les Lumieres contre la torture et la peine de mort
PublicationArtykuł napisany jest w języku francuskim. Jego tytuł w polskim tłumaczeniu brzmi: "Oświecenie wobec tortur i kary śmierci". Artykuł ten dotyczy stanowiska Woltera, Monteskiusza oraz Beccari wobec nadużyć systemu prawnego przedrewolucyjnej Francji. Analizuje on ich krytyczne stanowisko wobec tych nadużyć i bada filozoficzne teorie, jakimi posługują się Wolter i Monteskiusz w celu zniesienia tortur, oraz Beccaria, który nie tylko...
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Orbital blowout trauma occurring at the workplace – clinical, biomechanical and legal aspects
PublicationIntroduction and objective: Craniofacial injury at the workplace may lead to orbital blowout fractures. The aim of the study is the development of own numerical model of the eye orbit, assessment of the damage zones, and comparing them with clinical examinations. In addition, the current legal status of patients after injuries is presented Material and methods: In laboratory tests performed on bones collected from the upper and...
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Electronic structure of intertwined kagome, honeycomb, and triangular sublattices of the intermetallics MCo2Al9 ( M = Sr, Ba)
PublicationIntermetallics are an important playground to stabilize a large variety of physical phenomena, arising from their complex crystal structure. The ease of their chemical tunabilty makes them suitable platforms to realize targeted electronic properties starting from the symmetries hidden in their unit cell. Here, we investigate the family of the recently discovered intermetallics MCo2Al9 (M=Sr, Ba) and we unveil their electronic structure....
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1 kapitola: Status report on frame sawing machines for narrow-kerf sawing
PublicationW opracowaniu przedstawiono genezę pilarek ramowych oraz przecinania drewna cienkimi piłami. Omówiono ekonomiczne i ekologiczne zalety tego typu obróbki. Zaprezentowano kinematykę współczesnych pilarek dostępnych na rynkach światowych: Orbit, Mamuth oraz DSG Sonic. Szczegółowo opisano układ napędowy pilarek DTPX-30 i PRW15 z hybrydowym napędem głównym i całkowitym wyrównoważeniem dynamicznym układu.
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Marketing relacji w nowoczesnym przedsiębiorstwie.
PublicationPrezentowana jest koncepcja marketingu relacji i sposób jej implikacji w polskiej firmie usługowej PBP ''Orbis''. W pierwszej części przedstawiana jest istota marketingu relacji (sposób definiowania tego pojęcia, specyfika koncepcji, proces kształtowania lojalnego klienta). W drugiej części ukazano tworzenie relacji z klientem instytucjonalnym w PBP ''Orbis''. Trzecia część dotyczy kształtowania wcześniej nawiązanych relacji z...
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Routing decisions independent of queuing delays in broadband leo networks
PublicationThis paper presents an analysis of queuing and propagation delays of Inter-Satellite Links (ISLs) in broadband Low-Earth Orbit (LEO) satellite networks. It is shown that queuing delays are negligible in all reasonable working conditions of the broadband ISL network. This fact makes it possible to simplify the routing protocols in such networks and permits using already known multi-commodity flow solutions for routing. The performance...
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Fixed points of planar homeomorphisms of the form Identity + Contraction
PublicationW pracy dowodzi się, przy użyciu indeksu, istnienia punktów stałych dla planarnych homeomorfizmów, których orbity spełniają pewien geometryczny warunek.
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Influence of Antimony Substitution on Spontaneous Strain and Thermodynamic Stability of Lanthanum Orthoniobate
PublicationThe analysis of the antimony substitution influence on temperature dependence of unit cell distortion has been done. The values of spontaneous strain and Landau order parameter for three different antimony contents varied had been calculated. The phase transition occurring for antimony substituted lanthanum orthoniobate was found to be second order. The high temperature solution calorimetry method has been used to investigate...
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Praseodymium Orthoniobate and Praseodymium Substituted Lanthanum Orthoniobate: Electrical and Structural Properties
PublicationIn this paper, the structural properties and the electrical conductivity of La1−xPrxNbO4+δ (x = 0.00, 0.05, 0.1, 0.15, 0.2, 0.3) and PrNbO4+δ are presented and discussed. All synthesized samples crystallized in a monoclinic structure with similar thermal expansion coefficients. The phase transition temperature between the monoclinic and tetragonal structure increases with increasing praseodymium content from 500 ◦C for undoped...
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Quasirelativistic potential energy curves and transition dipole moments of NaRb
PublicationWe report on extensive calculations of quasi-relativistic potential energy curves and, for the first time, transition dipole moments including spin-orbit and scalar-relativistic effects of the NaRb molecule. The calculated curves of the 0+, 0-, 1, 2 and 3 molecular states correlate for large internuclear separation with the fourteen lowest atomic energies up to the Na(3s ^2S_{1/2}) + Rb(7s ^2S_{1/2}) atomic limit. Several new features...
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Sophistication assessment of existing FEM models of orbital blowout trauma: Is models valuation justified?
PublicationAfter a thorough study of the work entitled “Development and validation of an optimized finite element model of the human orbit”, some doubts aroused concerning the sophistication assessment of the existing finite element method (FEM) models of orbital blow-out. Although the work was unquestionably innovative, and the results were not only fascinating but also invaluable, the authors stated that their model was the most sophisticated...
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Superconductivity in Bismuth Pyrochlore Lattice Compounds RbBi2 and CsBi2: The Role of Relativistic Effects
PublicationSuperconducting properties of two bismuthide intermetallic compounds, RbBi2 and CsBi2, were studied by means of experimental measurements and ab initio calculations. We show that in both compounds, the superconductivity emerges from the pyrochlore Bi lattice and its formation is heavily influenced by relativistic effects. Based on our analysis of the effect of spin–orbit coupling on the electron–phonon coupling, we suggest a possible...
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Structural phase transitions in multicomponent La0.2Nd0.2Sm0.2Gd0.2RE50.2NbO4 (RE5 = Ho, Y, Tb, Eu, Pr) oxides
PublicationIn this work, the influence of compositional complexity on the structural and thermal properties of multicomponent rare-earth ortho-niobates from the La0.2Nd0.2Sm0.2Gd0.2RE50.2NbO4 (RE5 = Ho, Y, Tb, Eu, Pr) series have been investigated. Based on X-ray powder diffraction studies using synchrotron radiation, it was found that all tested materials were pure single-phase compositions and showed stability in the monoclinic I2/c crystal...
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The shadowing chain lemma for singular Hamiltonian systems involving strong forces
PublicationW niniejszym artykule rozważamy autonomiczny układ Hamiltonowski na płaszczyźnie z potencjałem, który ma punkt osobliwy (studnię nieskończonej głębokości) i maksimum globalne właściwe równe zero przyjmowane w dwóch różnych punktach płaszczyzny. Przy założeniu, że w otoczeniu punktu osobliwego potencjał spełnia warunek Gordona(gradient tego potencjału w otoczeniu punktu osobliwego jest tzw. silną siłą, ang. a strong force) dowodzimy...
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Structure and paramagnetism in weakly correlated Y8Co5
PublicationWe report the basic physical properties of monoclinic Y8Co5 determined by means of magnetic susceptibility, electrical resistivity, and specific heat measurements. The crystal structure of Y8Co5 is monoclinic (P21/c) with lattice parameters a = 7.0582(6) Å, b = 7.2894(6) Å, c = 24.2234(19) Å, and β = 102.112(6)° as refined by using synchrotron powder x-ray diffraction data. The compound shows temperature independent paramagnetism...
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Wild oscillations in a nonlinear neuron model with resets: (I) Bursting, spike-adding and chaos
PublicationIn a series of two papers, we investigate the mechanisms by which complex oscillations are generated in a class of nonlinear dynamical systems with resets modeling the voltage and adaptation of neurons. This first paper presents mathematical analysis showing that the system can support bursts of any period as a function of model parameters, and that these are organized in a period-incrementing structure. In continuous dynamical...
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Crystal Structure of N-(2-Benzoyl-4,5-dimethoxyphenethyl)-2-phenylacetamide
PublicationThe crystal structure of N-(2-benzoyl-4,5-dimethoxyphenethyl)-2-phenylacetamide indicates that the compound crystallizes in the monoclinic C2/c space group with eight molecules in the unit cell. The heteroatoms from the amide group form a chain of intermolecular N-H ··· O hydrogen bonds propagating along the b axis. The carbonyl group from the benzoyl substituent participates in short contacts with two H-atoms from the ethyl or...
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Budowanie relacji wyższego stopnia jako sposób konkurowania na rynku usług hotelarskich
PublicationW artykule przedstawiono programy lojalnościowe jako główne narzędzie pozwalające na budowanie trwałych relacji z klientami. Programy te przedstawiono na przykładzie rynku usług hotelarskich. Są to programy stosowane przez Grupę Hotelową Orbis - największą grupę hotelową w Polsce. Tworzenie relacji wyższego stopnia ukazano jako sposób osiągnięcia przewagi konkurencyjnej.
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Influence of intermixing at the Ta/CoFeB interface on spin Hall angle in Ta/CoFeB/MgO heterostructures
PublicationWhen a current is passed through a non-magnetic metal with strong spin-orbit coupling, an orthogonal spin current is generated. This spin current can be used to switch the magnetization of an adjacent ferromagnetic layer or drive its magnetization into continuous precession. The interface, which is not necessarily sharp, and the crystallographic structure of the nonmagnetic metal can both affect the strength of current-induced...
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Stripe order and magnetic anisotropy in the S=1 antiferromagnet BaMoP2O8
PublicationMagnetic behavior of yavapaiite-type BaMoP2O8 with the spatially anisotropic triangular arrangement of the S=1Mo4+ ions is explored using thermodynamic measurements, neutron diffraction, and density-functional band-structure calculations. A broad maximum in the magnetic susceptibility around 46 K is followed by the stripe antiferromagnetic order with the propagation vector k=(12,12,12) formed below TN≃21 K. This stripe phase is...
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Enhanced acceptor concentration, proton conductivity, and hydration in multicomponent rare‐earth ortho‐niobates
PublicationThe structural properties of (La0.2Nd0.2Sm0.2Gd0.2Eu0.2)1−xCaxNbO4−δ (x = 0–0.05) series have been studied by X-ray powder diffraction at room temperature. The thermal properties were investigated using thermogravimetry, from which the concentration of proton defects was determined. Additionally, dilatometry studies were carried out, from which the thermal expansion coefficients and the phase transition temperature between low-...
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Electronic structure and magnetism of samarium and neodymium adatoms on free-standing graphene
PublicationThe electronic structure of selected rare-earth atoms adsorbed on a free-standing graphene was investigated using methods beyond the conventional density functional theory (DFT+U, DFT +HIA, and DFT+ED). The influence of the electron correlations and the spin-orbit coupling on the magnetic properties has been examined. The DFT+U method predicts both atoms to carry local magnetic moments (spin and orbital) contrary to a nonmagnetic...
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Ln2(SeO3)2(SO4)(H2O)2 (Ln=Sm, Dy, Yb): A Mixed‐Ligand Pathway to New Lanthanide(III) Multifunctional Materials Featuring Nonlinear Optical and Magnetic Anisotropy Properties
PublicationBottom-up assembly of optically nonlinear and magnetically anisotropic lanthanide materials involving precisely placed spin carriers and optimized metal-ligand coordination offers a potential route to developing electronic architectures for coherent radiation generation and spin-based technologies, but the chemical design historically has been extremely hard to achieve. To address this, we developed a worthwhile avenue for creating...
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Strong-coupling superconductivity of SrIr2 and SrRh2 : Phonon engineering of metallic Ir and Rh
PublicationExperimental and theoretical studies on superconductivity in SrIr2 and SrRh2 Laves phases are presented. The measured resistivity, heat capacity, and magnetic susceptibility confirm the superconductivity of these compounds with Tc = 6.07 and 5.41 K, respectively. Electronic structure calculations show that the Fermi surface is mostly contributed by 5d (4d) electrons of Ir (Rh), with Sr atoms playing the role of electron donors....
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Relacje usługodawca-usługobiorca na rynku usług hotelarskich
PublicationArtykuł poświęcono zagadnieniom relacji budowanych na rynku usług hotelarskich między klientami a pracownikami hoteli. Na podstawie - przeprowadzonych przez autorkę niniejszego opracowania - badań, dokonano oceny tworzonych więzi. Starano się wykazać wpływ jakości relacji na chęć powrotu do danego obiektu hotelarskiego. Badanie przeprowadzono na klientach wybranych hoteli Grupy Hotelowej Orbis - największej grupy hotelowej w Polsce...
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Wild oscillations in a nonlinear neuron model with resets: (II) Mixed-mode oscillations
PublicationThis work continues the analysis of complex dynamics in a class of bidimensional nonlinear hybrid dynamical systems with resets modeling neuronal voltage dynamics with adaptation and spike emission. We show that these models can generically display a form of mixed-mode oscillations (MMOs), which are trajectories featuring an alternation of small oscillations with spikes or bursts (multiple consecutive spikes). The mechanism by...
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Superconductivity in a new intermetallic structure type based on endohedral Ta@Ir7Ge4 clusters
PublicationWe report the observation of superconductivity at a temperature near 3.5 K for the previously unreported compound TaIr2Ge2. In addition to being a superconductor, this material displays a new crystal structure type that contains endohedral clusters, as determined by single-crystal x-ray diffraction structure refinement; the structure is more complex than those of the commonly observed tetragonal 122 intermetallic phases. Despite...
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Satellite Laser Ranging technique as a tool for the determination of the Schwarzschild, de Sitter and Lense-Thirring effects
PublicationSatellite Laser Ranging (SLR) is a modern technique used in various research areas and applications related to geodesy and geodynamics. It is commonly used for tasks such as establishing the International Terrestrial Reference Frame (ITRF), monitoring Earth Orientation Parameters (EOP), determining the geocenter, measuring fundamental physical constants, calibrating microwave tracking techniques, conducting time transfer experiments,...
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Bistability in a One-Dimensional Model of a Two-Predators-One-Prey Population Dynamics System
PublicationIn this paper, we study a classical two-predators-one-prey model. The classical model described by a system of three ordinary differential equations can be reduced to a one-dimensional bimodalmap. We prove that this map has at most two stable periodic orbits. Besides, we describe the bifurcation structure of the map. Finally, we describe a mechanism that leads to bistable regimes. Taking this mechanism into account, one can easily...
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Experimental evidence of the excited-state mixing in the blue emitter for organic light-emitting diodes
PublicationHigh hopes have been placed on organic emitters, which are supposed to solve the problem of low stability of blue OLEDs. A peculiar phenomenon of thermally activated delayed fluorescence (TADF), which brought such emitters to the range of the top-studied materials for organic optoelectronics within the last decade, remains poorly understood. Here, we report the results of comprehensive photophysical studies of one of the most successful...
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An oscillation-based built-in test scheme with AGC loop.
PublicationPrzedstawiono oscylacyjny tester wbudowany (OBIT) do testowania części analogowej elektronicznego układu mieszanego sygnałowo zmontowanego na pakiecie. W celu zwiększenia współczynnika pokrycia uszkodzeń, w testerze zastosowano pomiary w dziedzinie czasu i częstotliwości. Omówiono wybrane aspekty implementacji testera, w szczególności problem transformacji układu testowanego w oscylator. Przeprowadzono analizę stanu ustalonego...
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2-Methylphenyl 2-methoxyacridine-9-carboxylate
PublicationThe title compound, C22H17NO3, crystallizes in the monoclinic space group P21/c with four molecules per unit cell. The molecules are arranged in centrosymmetric pairs, joined via the C and attached H atoms in the meta position relative to the methoxy group. These pairs are bonded in the crystalline phase as a result of non-specific dispersive interactions, and through a network of C—H⋯O interactions involving the non-bonded O...
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Superconductivity in the Cu(Ir1-xPtx)2Se4 spinel
PublicationWe report the observation of superconductivity in the CuIr2Se4 spinel induced by partial substitution of Pt for Ir. The optimal doping level for superconductivity in Cu(Ir1-xPtx )2Se4 is x = 0.2, where Tc is 1.76 K. A superconducting Tc vs composition dome is established between the metallic, normal conductor CuIr2Se4 and semiconducting CuIrPtSe4. Electronic structure calculations show that the optimal Tc occurs near the electron count...
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Superconductivity in CaBi2
PublicationSuperconductivity is observed with critical temperature Tc = 2.0 K in self-flux-grown single crystals of CaBi2. This material adopts the ZrSi2 structure type with lattice parameters a = 4.696(1) Å, b = 17.081(2) Å and c = 4.611(1) Å. The crystals of CaBi2 were studied by means of magnetic susceptibility, specific heat and electrical resistivity measurements. The heat capacity jump at Tc is DC/gTc = 1.41, confirming bulk superconductivity;...
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Properties comparison of rubber and three layer PTFE-NBR-bronze water lubricated bearings with lubricating grooves along full bush circumference based on experimental tests
PublicationWater lubricated bearings have been in industrial use for well over a century. During the last decade their traditional range has been expanded with new, modern products. Despite that fact, certain solutions continue to employ the standard rubber bearing with lubricating grooves located along entire bush circumference. The work presents experimental research conducted on comparable sliding bearings with lubrication grooves along...
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Synthetic, Structural, and Spectroscopic Characterization of a Novel Family of High-Spin Iron(II) [(β-Diketiminate)(phosphanylphosphido)] Complexes
PublicationThis work describes a series of iron(II) phosphanylphosphido complexes. These compounds were obtained by reacting lithiated diphosphanes R2PP(SiMe3)Li (R = t-Bu, i-Pr) with an iron(II) β-diketiminate complex, [LFe(μ2-Cl)2Li(DME)2] (1), where DME = 1,2-dimethoxyethane and L = Dippnacnac (β-diketiminate). While the reaction of 1 with t-Bu2PP(SiMe3)Li yields [LFe(η1-Me3SiPPt- Bu2)] (2), that of 1 with equimolar amounts of i-Pr2PP(SiMe3)Li,...
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Stabilization of the pyrochlore phase of Mn2Sb2O7 by double substitution
PublicationPolycrystalline samples of (Ce4+Mn2+3)(Ga3+Sb5+3)O14 were synthesized by a high-temperature solid-state reaction. In contrast with the parent Mn2Sb2O7 compound that adopts a rhombohedral or monoclinic structure at T > 600 °C, the pyrochlore structure of CeMn3GaSb3O14 is retained up to at least T = 1070°C. High-resolution synchrotron x-ray diffraction measurements show no sign of a superstructure or distortion from cubic symmetry...
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A Comprehensive Experimental and Theoretical Study on the[{(η5-C5H5)2Zr[P(µ-PNEt2)2P(NEt2)2P]}2O Crystalline System
PublicationThe structure of tetraphosphetane zirconium complex C52H100N8OP10Zr21 was determined by single crystal X-ray diffraction analysis. The crystal belongs to the monoclinic system, space group P21/c, with a = 19.6452(14), b = 17.8701(12), c = 20.7963(14)Å, α = γ = 90°, β = 112.953(7)°, V = 6722.7(8)Å3, Z = 4. The electronic structure of the organometallic complex has been characterized within the framework of Quantum Chemical Topology....
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Ferromagnetism and structural phase transition in rhombohedral PrIr3
PublicationThe synthesis, structural, magnetic, thermal, and transport properties are reported for polycrystalline PrIr3. At room temperature PrIr3 displays the rhombohedral space group R-3m and a PuNi3-type structure. At around 70 K a phase transition to a monoclinic C2/m structure is observed and continued cooling reveals temperature independent behavior of the unit cell volume. Further, PrIr3 undergoes a paramagnetic to ferromagnetic transition with...
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Connection matrix theory for discrete dynamical systems
PublicationIn [C] and [F1] the connection matrix theory for Morse decomposition is developedin the case of continuous dynamical systems. Our purpose is to study the case of discrete timedynamical systems.
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Investigation of the Effect of the Rocket's Suborbital Flight on Biofilm, Enzymes and Biosynthesis on Autonomous, Modular and Scalable Platforms For Conducting Experiments of an Astrobiotechnological Nature
PublicationWith new incentives for human space exploration, biotechnological experiments in orbit became imperative. Answering this need, we build an autonomous, modular, and scalable platform that enables those experiments on rockets. We called it AMBER. The aim of the payload of the R6 suborbital rocket is to perform an experiment to study the influence of rocket flights on biofilm, molecular biology enzymes and biosynthesis using our platform....
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Routing Method for Interplanetary Satellite Communication in IoT Networks Based on IPv6
PublicationThe matter of interplanetary network (IPN) connection is a complex and sophisticated topic. Space missions are aimed inter alia at studying the outer planets of our solar system. Data transmission itself, as well as receiving data from satellites located on the borders of the solar system, was only possible thanks to the use of powerful deep space network (DSN) receivers, located in various places on the surface of the Earth. In...