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Search results for: MULTIFUNCTIONAL COMPOUND
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Role of Herbal Bioactive Compounds as a Potential Bioavailability Enhancer for Active Pharmaceutical Ingredients
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Cold-modulated leaf compounds in winter triticale DH lines tolerant to freezing and
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Adsorption from aqueous solutions of chlorinated organic compounds onto activated carbons
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Hydrazone Linker as a Useful Tool for Preparing Chimeric Peptide/Nonpeptide Bifunctional Compounds
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Application of deep eutectic solvents for separation and determination of bioactive compounds in medicinal plants
PublicationThe medicinal plants industry, particularly in regard to products rich in biologically active substances for maintaining health, has grown by leaps and bounds in the last decade, with sales of over-the-counter drugs containing these substances growing by billions of dollars. Attention has thus also been paid to the safety and effectiveness of these medicines. We are currently witnessing a rapid increase in the number of publications...
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Intermetallic disordered magnet Gd2Pt1.1Ge2.9 and its relation to other AlB2 -type compounds
PublicationThe intermetallic germanide Gd 2 Pt 1.1 Ge 2.9 was synthesized using an arc-melting method. The crystal structure was characterized using powder x-ray diffraction, revealing a disordered ternary AlB 2 -type structure (space group P 6 / m m m , No. 191) with lattice parameters a = 4.2092 ( 1 ) Å and c = 4.0546 ( 2 ) Å . Physical properties were investigated by magnetic susceptibility and heat capacity measurements, which...
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Nitrogen and phosphorus compounds in coastal aquifers in Puck municipality area (northern Poland)
Publication1. Groundwater study shows local variations in chemical composition of selected aquifers caused by human impact The diversity is mainly manifested in • time variation of groundwater chemical composition of all analyzed parameters especially in shallow aquifers (Q1) • relationship between t he ground water chemical composition and depth of the aquifer where an inverse concentration distribution occurs higher concentrations are observed...
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Comparison of the contents of bioactive compounds and the level of antioxidant activity in different kiwifruit cultivars
PublicationGłównym celem prowadzonych badań było stwierdzenie która z odmian owoców kiwi (''Hayward'', ''Daeheuhg'', ''Haenam'' oraz ''Bidan'') jest najbardziej odpowiednią z punktu widzenia konsumpcji przez człowieka. Z tego powodu w odpowiednio przygotowanych próbkach ekstraktów z owoców kiwi oznaczono:- profile związków bioaktywnych;- poziomy aktywności przeciwutleniającej. Wyniki pomiarów zawartości polifenoli (flawonoidy oraz kwasy fenolowe)...
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Organomercury compounds in environmental samples: emission sources, toxicity, environmental fate and determination.
PublicationIn view of the specific properties of mercury and its capability of forming compounds that can be bioaccumulated and biomagnified at successive levels of the trophic pyramid, it has become necessary to gather detailed information on the sources of emission of this element into the environment and its fate there. Moreover, the increasing awareness of the relationship between the toxicity of mercury and its chemical form has sharpened...
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Microextraction Techniques Used in the Procedures for Determining Organomercury and Organotin Compounds in Environmental Samples
PublicationDue to human activities, the concentrations of organometallic compounds in all parts of the environment have increased in recent decades. The toxicity and some biochemical properties of mercury and tin present in the environment depend on the concentration and chemical form of these two elements. The ever-increasing demand for determining compounds at very low concentration levels in samples with complex matrices requires...
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Miniaturized passive emission test chamber for in-situ measurement of emissions of organic compounds
PublicationThe results of many different studies have demonstrated unequivocally that the quality of indoor air is often much worse than that of atmospheric air (outdoor). One of the main groups of chemical compounds present in indoor air, with proven harmfulness to health,are volatile organic compounds (VOCs). VOCs present indoor comprise a wide variety of hydrocarbons and hydrocarbons derivatives including aliphatic, aromatics, alkylbenzens,...
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Application of BDD thin film electrode for electrochemical decomposition of heterogeneous aromatic compounds
PublicationThe aim of the presented study is to investigate the applicability of electrochemical oxidation of aromatic compounds containing heteroatoms, e.g. waste from production of pesticides or pharmaceutics, at a borondoped diamond (BDD) electrode. The BDD electrodes were synthesized by microwave plasma enhanced chemical vapour deposition (MW PE CVD). Investigation of the electrode surface by optical microscopy and scanning electron microscopy...
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Miniaturized Passive Emission Chambers for In Situ Measurement of Emissions of Volatile Organic Compounds
PublicationThe results of many different studies have demonstrated unequivocally that the quality of indoor air is often much worse than that of atmospheric air. The presence of dangerous chemical compounds in indoor air can have an adverse impact on human health and cause numerous diseases of the respiratory and circulatory systems. Such harmful chemicals get into indoor air as a result of their emission from building and indoor materials....
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New procedure for the control of the treatment of industrial effluents to remove volatile organosulfur compounds
PublicationWe present a new procedure for the determination of volatile organosulfur compounds in samples of industrial effluents using dispersive liquid–liquid microextraction and gas chromatography with flame photometric detection. Initially, the extraction parameters were optimized. These included: type and volume of extraction solvent, volume of disperser solvent, salting out effect, pH, time and speed of centrifugation as well as extraction...
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Characteristics of volatile organic compounds emission profiles from hot road bitumens
PublicationA procedure for the investigation and comparison of volatile organic compounds (VOCs) emission profiles to the atmosphere from road bitumens with various degrees of oxidation is proposed. The procedure makes use of headspace analysis and gas chromatography with universal as well as selective detection, including gas chromatography–mass spectrometry (GC–MS). The studies revealed that so-called vacuum residue, which is the main component...
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Organotin compounds in the liver tissue of marine mammals from the PolishCoast of the Baltic Sea.
PublicationOznaczono zawartość związków cynoorganicznych w próbkach wątrób pochodzących od ssaków morskich złowionych w polskiej strefie ekonomicznej Morza Bałtyckiego. W ramach przeprowadzonych badań opracowana została oryginalna metodyka analityczna. Całkowite stężenie związków z tej grupy wahało się w granicach od 43,9 do 7698 ng Sn/g próbki (w przeliczeniu na suchą masę). Badano zależność stężeń tych związków od wieku i płci osobników.
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The effect of chlorinated drinking water consumption on levels of volatile organohalogen compounds in urine.
PublicationW przedstawionej pracy podjęto próbę oznaczenia niezmienionych form lotnych rozpuszczalników chlorowcoorganicznych w próbkach materiału biologicznego jakim jest mocz dawców, używających w gospodarstwie domowym a także w pracy wody uzdatnianej między innymi w procesie chlorowania. Do wykonania oznaczeń zastosowano zmodyfikowaną technikę analizy fazy nadpowierzchniowej nad cienką warstwą cieczy z samoczynną generacją ciekłego sorbentu...
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Chemically modified glass fiber as a matrix-free reference material for volatile compounds
PublicationW pracy opisano sposób wytwarzania nowego typu bezmatrycowych materiałów odniesienia lotnych związków organicznych. Do otrzymywania lotnych analitów wykorzystano technikę termicznego rozkładu związków powierzchniowych. Jako nośnik zastosowano modyfikowane chemicznie włókna szklane. Związkiem oznaczanym był chlorek metylu.
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Exposure to cooking emitted volatile organic compounds with recirculating and extracting ventilation solutions
PublicationEnergy-efficient urban development leads to the compact design of apartments. Recirculating ventilation solutions are an attempt to minimize the space required for ventilation ducting, but more data on their performance are needed. Cooking is a major source of volatile organic compounds (VOCs) emissions. It is necessary to assess how well recirculating kitchen hoods perform in reducing the residents' exposure to cooking fumes compared...
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Problems and challenges associated with estimating the emissions of organic compounds from indoor materials
PublicationFor several years intensive research has been carried out with the aim of developing a database of the types and amounts of pollutants released from indoor materials to the indoor environment. The paper discusses in detail basic problems and challenges encountered when estimating the emissions of chemical compounds released from of indoor materials. Factors affecting the validity of data obtained by using two different types of...
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SURFACTANTS IN KLODNICA RIVER (KATOWICE, POLAND). PART II. QUATERNARY AMMONIUM COMPOUNDS
PublicationThe paper presents methods of determination of analytes of the cation group (alkyl benzyl dimethyl ammonium (BDDA-C12-C16), alkyl trimethyl ammonium (TMA), hexadecyl piridinium (HP)) in surface water and bottom sediment samples. In the sample preparation phase the solid phase extraction (SPE) or accelerated solvent extraction/ultrasound assisted extraction (ASE/UAE)-SPE technique was used and in the identification phase and quantitative...
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Investigating BiMeVOx compounds as potential photoelectrochemical and electrochemical materials for renewable hydrogen production
PublicationIn this study, BiMeVOx compounds (where Me: Co, Mo, Ce, Zr) were synthesized and characterized as potential photoelectrochemical materials for solar water splitting, the hydrogen evolution reaction (HER), and oxygen evolution reaction (OER). The analysis confirmed the successful formation of phase BiMeVOx compounds with the desired crystal structure. Among the tested materials, BiCoVOx(800) showed the highest photocurrent density...
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Superconductivity in Bismuth Pyrochlore Lattice Compounds RbBi2 and CsBi2: The Role of Relativistic Effects
PublicationSuperconducting properties of two bismuthide intermetallic compounds, RbBi2 and CsBi2, were studied by means of experimental measurements and ab initio calculations. We show that in both compounds, the superconductivity emerges from the pyrochlore Bi lattice and its formation is heavily influenced by relativistic effects. Based on our analysis of the effect of spin–orbit coupling on the electron–phonon coupling, we suggest a possible...
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Identification of aromatic compounds in odours mixture by gas chromatography and field olfactometry techniques
PublicationThis paper shows the results of investigation on identification aromatic compounds present in odorous mixture in atmospheric air samples collected in a vicinity of the oil refinery LOTOS S.A., located in Gdansk, during March and April period have be presented. The studies were conducted by the use of comprehensive two-dimensional gas chromatograph equipped with a cryogenic modulator and coupled with a time-of-flight mass spectrometer,...
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A new complex compound of chromium(III) with 5-aminopyridine-2-carboxylate anions – Structure, physicochemical and catalytic properties
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Dipole-driven dynamics for near-threshold electron/positron interactions with pyrimidinic DNA bases: a path to compound formations
PublicationCalculations are reported for electron and positron scattering from isolated cytosine and thymine, where the two pyrimidinic single-ring DNA bases, in the gas-phase at energies near the elastic threshold, they reveal the special features of the dipole-driven scattering states. All molecules examined exhibit, in fact, supercritical (>1.67 D) permanent dipoles which can therefore also support, below threshold, excited bound compound...
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Synthesis and thermal studies of flexible polyurethane nanocomposite foams obtained using nanoclay modified with flame retardant compound
PublicationThis work presents thermal studies of nanocomposites based on the flexible polyurethane (PU) matrix and filled using montmorillonite organically modified with organophosphorus flame retardant compound. Flexible PU nanocomposite foams were prepared in the reaction carried out between reactive alcoholic hydroxyl and isocyanate groups with the ratio of NCO to OH groups equal to 1.05. The amount of an organoclay ranging from 3 to 9...
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Hybrid Analysis of Structures Composed of Axially Symmetric Objects
Publication— A hybrid method for the scattering problems in shielded and open structures is presented. The procedure is based on the combination of body-of-revolution involving finite-element methods with impedance matrix formulation and the mode-matching technique, which can be utilized for the analysis of structures with axially symmetrical scatterers. In order to confirm the validity and efficiency of the proposed approach, a few examples...
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Inhibiting activity of HIV-1: protease, reverse transcriptase and integrase all together by novel compounds using computational approaches (flexible and rigid docking)
PublicationAcquired immunodeficiency syndrome (AIDS), caused by human immunodeficiency virus type 1 (HIV-1) infection, is one of the most challenging diseases in recent decades. Nevertheless the shortcomings of chemical drugs such as toxicity, lack of curative effects, the search for more potent anti-HIV agents have been focused in our study. In current study, novel scaffold was designed having a benzyl and imidazole in it which are very...
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Application of Bayesian Multilevel Modeling in the Quantitative Structure–Retention Relationship Studies of Heterogeneous Compounds
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Inhibition Ability of Natural Compounds on Receptor-Binding Domain of SARS-CoV2: An In Silico Approach
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Polysaccharide films modified by compounds of natural origin and silver having potential medical applications
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Investigations of New Phenothiazine-Based Compounds for Dye-Sensitized Solar Cells with Theoretical Insight
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Assessment of the glycaemic index, content of bioactive compounds, and their in vitro bioaccessibility in oat-buckwheat breads
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Antimicrobial Activities of Compounds Produced by Newly Isolated Streptomyces Strains from Mountain Caves
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Ab initio and density functional theory calculations of proton affinities for volatile organic compounds
PublicationThe Hatree-Fock method with 6-311G** split-valence molecular orbitals basis sets and the density function theory-B3LYP have been applied to geometrical optimizations and calculations of total electronic, zero point vibrational energies and proton affinities at 298 K for volatile organic compounds. Calculated values of proton affinities are compared with experimental data.
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New procedure for the examination of the degradation of volatile organonitrogen compounds during the treatment of industrial effluents
PublicationWe present a new procedure for the determination of 32 volatile organonitrogen compounds in samples of industrial effluents with a complex matrix. The procedure, based on dispersive liquid–liquid microex-traction followed by gas chromatography with nitrogen-phosphorus and mass spectrometric detection, wasoptimized and validated. Optimization of the extraction included the type of extraction and disperser sol-vent, disperser solvent...
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Bacterial presence in polar regions associated with environment modification by chemical compounds including contaminants
PublicationMicrobes are omnipresent and diverse members of all biological communities. In marine and freshwater ecosystems, microorganisms form the base of the food chain supporting higher trophic levels. Even though, microbes generally are thought to live in warm regions of Earth, many of them develop in cold climates. Polar regions remain relatively protected from widespread anthropogenic disturbances, which is a consequence of its remoteness...
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Assessment of Lipophilicity Indices Derived from Retention Behavior of Antioxidant Compounds in RP-HPLC
PublicationReverse phase high pressure liquid chromatography was employed in order to evaluate the lipophilicity of antioxidant compounds from different classes, such as phenolic acids, flavanones, flavanols, flavones, anthocyanins, stilbenes, xantonoids, and proanthocyanidins. The retention time of each compound was measured using five different HPLC columns: RP18 (LiChroCART, Purosphere RP-18e), C8 (Zorbax, Eclipse XDBC8), C16-Amide (Discovery...
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Investigation of Air Quality beside a Municipal Landfill: The Fate of Malodour Compounds as a Model VOC
PublicationThis paper presents the results of an investigation on ambient air odour quality in the vicinity of a municipal landfill. The investigations were carried out during the spring–winter and the spring seasons using two types of the electronic nose instrument. The field olfactometers were employed to determine the mean odour concentration, which was from 2.1 to 32.2 ou/m3 depending on the measurement site and season of the year. In...
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Analytical aspects of model compounds toxicity assessment using MTT and Microtox bioanalytica assays
PublicationMore and more increased intensity of anthropopressure processes can be observed, among other things, in the release of great quantities of synthetic substances into the environment, including the Endocrine Disrupting Compounds. The effects of the above-mentioned human impact on the environment not only can be noticed in the homeostasis disturbance in ecosystems, but they are also visible with respect to human. The high incidence...
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Highly effective asphaltene-derived adsorbents for gas phase removal of volatile organic compounds
PublicationA novel nitrated asphaltene-derived adsorbent (Asf-Nitro) was prepared using facile isolation and modification procedures. The successful modification was confirmed by Fourier-transform infrared spectroscopy (FTIR). The nitrated adsorbent was evaluated in terms of dispersive and specific interactions, Lewis acid-base properties and adsorption isotherms by means of inverse gas chromatography (IGC). Nitration was found to be extremely...
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Methods of assaying volatile oxygenated organic compounds in effluent samples by gas chromatography—A review
PublicationThe paper is a review of the procedures for the determination of volatile and semivolatile oxygenated organic compounds (O-VOCs) in effluent samples by gas chromatography. Current trends and outlook for individual steps of the procedure for the determination of O-VOCs in effluents are discussed. The available sample preparation techniques and their limitations are described along with GC capillary columns used for O-VOCs separation...
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Crossover from charge density wave stabilized antiferromagnetism to superconductivity in Nd1−xLaxNiC2 compounds
PublicationThe path from the charge density wave antiferromagnet NdNiC2 to the noncentrosymmetric superconductor LaNiC2 is studied by gradual replacement of Nd by La ions. The evolution of physical properties is explored by structural, magnetic, transport, magnetoresistance, and specific heat measurements. With the substitution of La for Nd, the Peierls temperature is gradually suppressed, which falls within the BCS mean-field relation for...
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Application of cyanated asphaltenes in gas-phase adsorption processes for removal of volatile organic compounds
PublicationThe paper presents an innovative, chemically modified (methylcyanated) asphaltene-based adsorbent that can be an inter-esting low-cost alternative for traditional adsorbents. Adsorption properties of adsorbents were examined by inverse gas chromatography technique, adsorption isotherms, and breakthrough curves. A significant increase in retention volume for pyridine, 2-pentanone, nitropropane, toluene, and 1-butanol was observed....
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The use of various species of fungi in biofiltration of air contaminated with odorous volatile organic compounds
PublicationAir pollution with odorous compounds is a significant social and environmental problem. This paper presents biological deodorization methods. The attention is focused on the application of biotrickling filters for air deodorization. Principles of their operation are discussed, indicating the key role of the selection of microorganisms responsible for the degradation of odorous compounds. A literature overview of the used fungal...
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Ginsenoside and phenolic compounds in hydromethanolic extracts of American ginseng cell cultures and their antioxidant properties
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Analytical techniques for trace organic compounds-III: Mass spectrometry in trace organic analysis
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Electroactive heterojunctions of iron-based compounds in oxygen evolution reaction—Insight into synergy and mechanism
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The effect of fixed adsorption bed height on adsorption of gaseous mixture of volatile organic compounds
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