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Scoring ofsolventsusedinanalyticallaboratoriesbytheirtoxicological and exposurehazards
PublicationGreen analyticalchemistry,althoughawellrecognisedconcept,stilllacksreliableenvironmentalimpact assessment procedures.Thisarticledescribesscoringofsolvents,frequentlyusedinanalyticallabora- tories, withCHEMS-1model.Themodelusestoxicologicalandexposuredatatocalculatehazardvalues relatedtotheutilisationofsolvents. The originalmodelwasmodified toincorporatehazardsrelatedtothevolatilityofchemicals.The scoring ofhazardvaluesshowedthatpolarsolventsarelesshazardous.Thescoringresultswereapplied to...
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Katarzyna Kubiszewska dr
PeopleKatarzyna Kubiszewska has taught finance and banking at the Department of Finance since 2008. In his scientific work, he is interested in the transformation of banking systems in the Central and Eastern European region, but also in the financing of the cultural sector. The publications concern the field of social sciences in the discipline of economics and finance. Since 2019, he has been collaborating with journals such as Economic...
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Polyisocyanates from Sustainable Resources
PublicationIsocyanates, next to polyols, constitute the major components essential for polyurethane (PU) production. They have a significant impact on physicochemical, mechanical, and thermal properties of PU materials. They also have an impact on those materials’ purposes, forms, textures, and other features. The available and used isocyanates are of a petrochemical origin. With the development of a trend toward green chemistry in the science...
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Application of deep eutectic solvents in analytical sample pretreatment (update 2017–2022). Part A: Liquid phase microextraction
PublicationSustainable development in all branches of human activity has become an unequivocal necessity in the last two decades, and green chemistry goes hand in hand with it. Various ways have been proposed in analytical chemistry to meet the current requirements of green chemistry. One such approach is the research of new reagents and solvents for analytical purposes. Deep eutectic solvents (DESs) began being investigated and used in analytical...
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The effect of Sr and Mg substitutions on structure, mechanical properties and solubility of fluorapatite ceramics for biomedical applications
PublicationIonic substitutions play important role in the modifications of biological apatites. Recently, attention has been focused on the co-doping effects on the functional properties of apatite-based biomaterials. In this research work, the dense samples of fluorapatites, Ca10(PO4)6F2 and Ca8MgSr(PO4)6F2, were produced after sintering at 1250 °C for 6 h in air. Structural characterization carried out with XRD, IR, Raman and SEM, confirmed...
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Estimating Regions of Absolute Stability with the Use of Piecewise Linear Lyapunov Functions
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Physics I - 2021/2022
e-Learning CoursesLECTURE "Physics I - 2021/2022" Kierunek: Green Technology and Monitoring Wydział Chemiczny stopień I, semestr 1
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Application of deep eutectic solvents in bioanalysis
PublicationThe application of deep eutectic solvents (DESs) is sharply surging as a green alternative to conventional solvents due to their unique properties in terms of simplicity of preparation, designability and low cost. A great deal of attention has been paid to the application of these green solvents in analytical chemistry in recent years, and a lot of interesting work has been reported. This review summarizes the most relevant applications...
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Correlation between physicochemical properties of doxorubicin-loaded silica/polydimethylsiloxane xerogel and in vitro release of drug
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Biomateriały i nanobiomateriały z podstawami anatomii
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Bacterial nanocellulose as a microbiological derived nanomaterial
PublicationBacterial nanocellulose (BNC) is a nanofibrilar polymer produced by strains such as Gluconacetobacter xylinus, one of the best bacterial species which given the highest efficiency in cellulose production. Bacterial cellulose is a biomaterial having unique properties such as: chemical purity, good mechanical strength, high flexibility, high absorbency, possibility of forming any shape and size and many others. Such a large number...
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Thermoplastic starch nanocomposites using cellulose-rich Chrysopogon zizanioides nanofibers
PublicationGreen thermoplastic starch (TPS) nanocomposite films aided by cellulose nanofibers (CNFs) from Chrysopogon zizanioides roots were developed and characterized. When compared to other lignocellulosic fibers, Chrysopogon zizanioides roots revealed exceptionally high cellulose content (~48%). CNFs were separated using an environmentally friendly acid isolation technique that included three stages: (i) alkali treatment; (ii) bleaching;...
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Flow cytometry analysis of caspase 3/7 activation in A549, H460 and U2OS cells after exposure to TXT2 and TXT4
Open Research DataThe data contains flow cytometry analysis of caspase 3/7 activation in A549, H460 and U2OS cells after exposure to equitoxic concentrations of TXT2 and TXT4. DMSO and MTX were used as positive and negative controls, respectively. Caspase 3/7 activity was detected using CellEvent™ Caspase-3/7 Green Flow Cytometry Assay Kit (#C10427, Thermo Fisher Scientific)....
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Production and Properties of the Porous Layer Obtained by the Electrochemical Method on the Surface of Austenitic Steel
Publication: The growing demand for implants has seen increasing interest in the introduction of new technologies and surface modification methods of metal biomaterials. This research aimed to produce and characterize a porous layer grown on austenitic stainless steel 316L, obtained via the anodization process near the micro-arc oxidation, i.e., low voltage micro-arc oxidation (LVMAO). The discussed layer significantly influences the properties...
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Molecularly imprinted polymers based on deep eutectic solvents as a greenest materials for selective extraction of emerging contaminants from complex samples
PublicationSome of the reagents applied in the synthesis of molecularly imprinted polymers (MIPs) may impact on health and the environment. Thus, a new generation of promising green chemicals are nowadays introduced and investigated, including deep eutectic solvents (DESs). DESs seems to be a reasonable choice as they are characterized as non-toxic, low cost, easy to prepare and biodegradable chemicals. This review presents the information...
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Synthesis, Structure and Properties of Poly(ester-Urethane-Urea)s Synthesized Using Biobased Diamine
PublicationModern polymer science and technology is focused on the development of partial or fully green polymers. This focus is related to green chemistry trends, which propose using natural and renewable resources as monomers in the synthesis of polymers. In this study, biobased diamine was used as a chain extender of ester-urethane prepolymer. Obtained poly(ester-urethane-urea) contains 16 wt% of biobased diamine. There is mention of an...
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Targ Węglowy as the keystone of two ring road complexes of Gdańsk city centre
PublicationThe urban structure of Gdansk city centre is determined by two ring road complexes. The first of them, the Gdansk Ring, has been created as a result of a city defortification at the turn of the 19th and 20th centuries and has been destroyed in the end of World War Two with the rest of Gdansk. The second, the Main Town Green Belt, has been formed in place of the medieval fortification system of the city’s most important historical...
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Cyanobacterial blooms in the Gulf of Gdańsk - photo archvive
Open Research DataCyanobacterial blooms are recorded in the Gulf of Gdańsk every summer. The dataset contains 20 photographs of the blooms of these microorganisms taken between 2004 and 2012. In addition to the photos, the dataset also contains a file with supporting information, such as the coordinates of the point where the photo was taken, the salinity and temperature...
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Advanced nanomaterials and metal-organic frameworks for catalytic bio-diesel production from microalgal lipids – A review
PublicationIncreasing energy demands require exploring renewable, eco-friendly (green), and cost-effective energy resources. Among various sources of biodiesel, microalgal lipids are an excellent resource, owing to their high abundance in microalgal biomass. Transesterification catalyzed by advanced materials, especially nanomaterials and metal-organic frameworks (MOFs), is a revolutionary process for overcoming the energy crisis. This review...
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Miniaturized solid phase microextratcion
PublicationWithout any doubt analytical laboratories have an essential role in environmental protection due to the fact that they takes an active part in the monitoring pollutants present in air, water or soil. From the other side, the analytical activity is involved in the generation of toxic waste what is associated with the use of not eco-friendly reagents and solvents. For these reasons, green analytical chemistry (GAC) was introduced...
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Is it possible to create a unified urban greenery management system (UGMS) on a national scale? The concept for EU Member State of Poland
PublicationMotives: Currently developed urban greenery management systems (UGMS) are limited in scope and profiled towards solving particular issues. Moreover, due to the lack of common standards and solutions, UGMS implementation requires considerable financial effort, which is only feasible for wealthy urban centres. There is a need for universal, cost-effective technological solutions which could constitute a common urban green infrastructure...
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AGREE—Analytical GREEnness Metric Approach and Software
PublicationGreen analytical chemistry focuses on making analytical procedures more environmentally benign and safer to humans. The amounts and toxicity of reagents, generated waste, energy requirements, the number of procedural steps, miniaturization, and automation are just a few of the multitude of criteria considered when assessing an analytical methodology’s greenness. The use of greenness assessment criteria requires dedicated tools. We...
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Use of Bi-Temporal ALS Point Clouds for Tree Removal Detection on Private Property in Racibórz, Poland
PublicationTrees growing on private property have become an essential part of urban green policies. In many places, restrictions are imposed on tree removal on private property. However, monitoring compliance of these regulations appears difficult due to a lack of reference data and public administration capacity. We assessed the impact of the temporary suspension of mandatory permits on tree removal, which was in force in 2017 in Poland,...
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Sustainable Waste Management for Implementation of a Circular Economy Model in a Port
PublicationThe manuscript presents the management of waste from marine vessels and cargo handling companies in a selected European Union port. The main objective of the paper is to analyse and evaluate the existing waste management model in the port of Szczecin in the context of circular economy. The expert research carried out is aimed, inter alia, at identifying which of the solutions currently in use need to be improved from an environmental...
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Polysaccharides in fabrication of membranes: A review
PublicationSustainability concerns have motivated and directed a great deal of interest over the past decade towards the development of green technologies. Polysaccharides are green polymers, which experienced growing demand to substitute chemically synthetic polymers. Different types of polysaccharides i.e. cellulose-, starch-, chitin- alginate-, and chitosan-based carbohydrate polymers have been applied in the fabrication of separation...
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Use of hop cone extract obtained under supercritical CO2 conditions for producing antibacterial all-purpose cleaners
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Improving the prediction of biochar production from various biomass sources through the implementation of eXplainable machine learning approaches
PublicationExamining the game-changing possibilities of explainable machine learning techniques, this study explores the fast-growing area of biochar production prediction. The paper demonstrates how recent advances in sensitivity analysis methodology, optimization of training hyperparameters, and state-of-the-art ensemble techniques have greatly simplified and enhanced the forecasting of biochar output and composition from various biomass...
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Ab initio chemical kinetics of Isopropyl acetate oxidation with OH radicals
PublicationGlobal reactivity descriptors of isopropyl acetate (IPA) and thermo-kinetic aspects of its oxidation via OH radicals have been studied. Transition state theory (TST) was utilized to estimate the bimolecular rate constants. Ten oxidation pathways have been investigated, and all of them are exothermic. The potential energy diagram has been sketched using different pre- and post-reactive complexes for all reaction pathways. Rate coefficient...
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Green Technologies II sem. - Egzamin z języka angielskiego B2 – 20.06.2022
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Green Technologies II sem. - Egzamin z języka angielskiego C1 – 20.06.2022
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Nanotubular oxide layers and hydroxyapatite coatings on porous titanium alloy Ti13Nb13Zr
PublicationThe surface condition of an implant has a significant impact on response occurring at the implant-biosystem border. The knowledge of physical-chemical and biological processes allows for targeted modification of biomaterials to induce a specified response of a tissue. The present research was aimed at development of technology composing of obtaining the nanotube oxide layers on a porous titanium alloy Ti13Nb13Zr, followed by the...
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Evaluation of Three Peptide Immobilization Techniques on a QCM Surface Related to Acetaldehyde Responses in the Gas Phase
PublicationThe quartz-crystal microbalance is a sensitive and universal tool for measuring concentrations of various gases in the air. Biochemical functionalization of the QCM electrode allows a label-free detection of specific molecular interactions with high sensitivity and specificity. In addition, it enables a real-time determination of its kinetic rates and affinity constants. This makes QCM a versatile bioanalytical screening tool for...
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Biomedical engineering of polysaccharide-based tissue adhesives: Recent advances and future direction
PublicationTissue adhesives have been widely used for preventing wound leaks, sever bleeding, as well as for enhancing drug delivery and biosensing. However, only a few among suggested platforms cover the circumstances required for high-adhesion strength and biocompatibility, without toxicity. Antibacterial properties, controllable degradation, encapsulation capacity, detectability by image-guided procedures and affordable price are also...
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Research, theories and practical experience of therapeutic landscapes as a tool for urban open space design
PublicationThis paper reviews the research on therapeutic landscapes and discusses the design of urban parks and open green space. Firstly, the most relevant research on therapeutic landscapes is reviewed. Secondly, the practical experience of healing and therapeutic gardens is discussed. Finally, the conclusions leading to future use of therapeutic landscape concept in urban open space design are presented.
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Reactions on the surface of the implant under the influence of biofilm
PublicationThe contact of a biomaterial with the biological environment in in vitro and in vivo tests leads to the production of a particular ecosystem in which the active roles perform both, the material surface and the extracellular matrix protein forming a biofilm. Proteins affect cell and bacteria adhesion processes, biological activity of cells and activation of inflammatory response.The knowledge of the reaction mechanisms active on...
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Mateusz Brodowski
PeopleMateusz Brodowski received his engineer degree in 2019 at the of Chemical Technology with a specialization in Anti-Corrosion Protection Technologies, in his engineer thesis he examined the effectiveness of green corrosion inhibitors. He finished a Master's degree in the field of Mechatronics, realizing the work of creating software for data acquisition from the electrochemical measurement system. Since 2019, he has been working...
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Theory of Rural Architecture - EXAM
e-Learning CoursesThe series of lectures touching upon the history of rural architecture and regarding the composition of landscape designs. The lectures were designed to give students of architecture the tools to work with the nature and strengthen the presence of green spaces in their future designs. The exam is prepared to check what skills and competencies have been gained during the course.
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Blanka Tundys dr hab.
PeopleBlanka Tundys is an Associate Professor at University of Szczecin, Poland. Her research interests span green supply chain, sustainable supply chain, close loop chain, eco-innovation, city logistics, logistics, transport systems, city economics, strategy in logistics, transportation, performance measurement in logistics and supply chain, efficiency in logistics, circular economy, smart city, risk management in the supply chain,...
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Raman spectra for pyrolized natural compounds
Open Research DataThe presented data showcases the results of Raman spectroscopy analysis conducted on pyrolyzed natural compounds both with and without the inclusion of graphene. The study delved into four specific compounds: methylcellulose with lysine (ML), methylcellulose with lysine-graphene composite (MLG), algae (A), and algae-graphene composite (AG). Raman spectra...
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Ultrasound assisted extraction
PublicationThe use of green and sustainable extraction techniques is very popular topic in the multidisciplinary area of chemistry, biology and technology. There is no doubt that extraction constitutes a very important step of analytical procedures of separation, detection, identification and determination of wide spectrum analytes from samples characterized by complex and very often nonhomogeneous composition of matrix. Traditional techniques...
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ENERGY EFFICIENT SMALL INLAND PASSENGER SHUTTLE FERRY WITH HYBRID PROPULSION - CONCEPT DESIGN, CALCULATIONS AND MODEL TESTS
PublicationIn recent years, there has been a significant development in “green” and energy efficient propulsion systems, which fits into the general trend of environmentally friendly “green shipping”. The pursued goal is to construct a safe passenger ship that is low in energy demand and equipped with a highly energy efficient, emission-free propulsion system. The paper presents main problems encountered by designers of a small, hybrid-powered...
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Application of TOPSIS for Selection and Assessment of Analytical Procedures for Ibuprofen Determination in Wastewater
PublicationThis paper describes the possible implementation of the Technique for Order Preference by Similarity to Ideal Solution (TOPSIS) as green analytical chemistry metrics tools. TOPSIS is one of the multi-criteria decision analysis (MCDA) tools that is applied in the selection of the best alternative from many possible. In this case we have applied it to assess the nineteen analytical procedures for ibuprofen determination in wastewater...
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Selected issues related to the toxicity of ionic liquids and deep eutectic solvents—a review
PublicationGreen Chemistry plays a more and more important role in implementing rules of sustainable development to prevent environmental pollution caused by technological processes, while simultaneously increasing the production yield. Ionic liquids (ILs) and deep eutectic solvents (DESs) constitute a very broad group of substances. Apart from many imperfections, ILs and DESs have been the most promising discoveries in the world of Green...
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Multicriteria decision analysis in ranking of analytical procedures for aldrin determination in water
PublicationThe study presents the possibility of multi-criteria decision analysis (MCDA) application when choosing analytical procedures with low environmental impact. A type of MCDA, Preference Ranking Organization Method for Enrichment Evaluations (PROMETHEE), was chosen as versatile tool that meets all the analytical chemists – decision makers requirements. Twenty five analytical procedures for aldrin determination in water samples (as...
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Expert System as a classification method for optimal Legg-Calve-Perthes Disease treatment
PublicationZaproponowano utworzenie systemu eksperckiego jako metody klasyfikacji w prognozowaniu dowolnej formy leczenia dzieci z chorobą Legg-Calve-Perthesa. Obecnie nie ma jednego optymalnego sposobu leczenia choroby Perhtes'a i proponowana metoda jest próbą utworzenia wymiernego i uniwersalnego narzędzia, które będzie stanowiło podstawę przy podejmowaniu decyzji o najlepszym sposobie leczenia chorego stawu biodrowego. System ekspercki,...
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The possibility of an use of laser treatment to improve the behaviour of the Ti-6Al-4V alloy
PublicationPrezentowana praca miała na celu stworzenie warunków ultraszybkiego chłodzenia przetopionej warstwy w obecności azotu tak, aby otrzymać twardą i gruba warstwę wierzchnią na stopie Ti-6Al-4V , najczęściej używanm stopie Ti, zawierającą struktury martenzytu i azotku tytanu.
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Estimation of the expected effects of different surface modifications on mechanical, chemical and biological behaviour of endoprostheses
PublicationPrzedstawiono koncepcję nowej endoprotezy o szczególnie wysokiej odporności na zużycie i pękanie. Koncepcja zakada wytwarzanie wieloetapową obróbkę powierzchniową kompozytu metalowo-ceramicznego.
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The phase composition of the surface layer of laser melted Ti-6Al-4V bioalloy
PublicationZastosowanie metody obróbki laserowej stopów Ti zwiekszyły twardość i odporność stopu na korozję. Jednakże uzyskane warstwy były stosunkowo cieńkie. W pracy zastosowano laser o dużej mocy dla stopu schłodzonego w ciekłym azocie, aby uzyskać grubszą warstwę, która w strefie zewnętrznej złożona będzie z tlenku i azotku tytanu, ważnych faz w biostopach.
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Maximum contact stress estimation on acetabular surface in total hip replacement using fuzzy reasoning system
PublicationArtykuł przedstawia rozmyty system wnioskowania dla oszacowania maksymalnego naprężenia kontaktowego na powierzchni panewki endoprotezy stawu biodrowego. Maksymalne naprężenie kontaktowe zostało określone na podstawie kąta Wiberga oraz masy ciała pacjenta.
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Badania obszarów zagrożonych zniszczeniem w biomateriałach koron stomatologicznych
PublicationDo analizy obszarów zagrożonych zniszczeniem w biomateriałach koron stomatologicznych zastosowano analizę strukturalną elementów skończonych MES. Opracowano dwu wymiarowy model korony stomatologicznej zamocowanej na kikucie zęba, w którym określono obszary występowania poszczególnych materiałów. Przyjęte do obliczeń numerycznych wartości modułu Younga i współczynniki Poissona odniesiono do rzeczywistych biomateriałów korony stomatologicznej....