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Search results for: in-tube extraction
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Determination of parent and methylated polycyclic aromatic hydrocarbons in water samples by dispersive liquid–liquid microextraction–two dimensional gas chromatography–time-of-flight mass spectrometry
PublicationPolycyclic aromatic hydrocarbons (PAHs) are contaminants frequently found in environmental waters. Owing to their toxic effects, it is important to develop analytical methodologies that allow their fast and reliable determination. Dispersive liquid–liquid microextraction (DLLME) allows a quick extraction of analytes with little organic solvent consumption. The best results regarding sample preparation are obtained when 40 mL of...
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Deep eutectic solvent (DES) with silver nanoparticles (Ag-NPs) based assay for analysis of lead (II) in edible oils
PublicationThis paper presents an application of silver nanoparticles impregnated by Deep Eutectic Solvents (DES) as ultrasonication aided microextraction system for lead (II) determination in edible oils. The paper presents a systematic optimization of method parameters and examples of its application for analysis of real samples. Maximum recovery for lead (II) extraction was obtained for choline chloride and phenol with a 1:2 molar ratio....
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Optimization of capillary isotachophoretic method for determination of major macroelements in blue honeysuckle berries (Lonicera caerulea L.) and related products
PublicationA reliable and repeatable isotachophoretic method for the simultaneous determination of K+, Na+, Ca2+, Mg2+ and ammonium in berries of different blue honeysuckle cultivars was developed. The usefulness of the complex-forming equilibria in determining the cations mentioned above was studied. The addition of 7.5 mM 18-crown-6 and 2 mM α-hydroxyisobutyric acid to sulfuric acid enhanced the separation capacity of the leading electrolyte....
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Multicriteria decision analysis in ranking of analytical procedures for aldrin determination in water
PublicationThe study presents the possibility of multi-criteria decision analysis (MCDA) application when choosing analytical procedures with low environmental impact. A type of MCDA, Preference Ranking Organization Method for Enrichment Evaluations (PROMETHEE), was chosen as versatile tool that meets all the analytical chemists – decision makers requirements. Twenty five analytical procedures for aldrin determination in water samples (as...
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Development and validation of a GC–MS/MS method for the determination of 11 amphetamines and 34 synthetic cathinones in whole blood
PublicationPurpose Psychoactive compounds that contain a phenylethylamine structure (such as amphetamine-type stimulants and synthetic cathinones) are one of the major classes of stimulants on the recreational drug market. Approximately 670 new psychoactive substances (NPS) are monitored only in Europe; however, new psychoactive compounds are being developed for illicit trade each year. In this context, the development of new analytical procedures...
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An idea of an approach to self-testing of mixed signal systems based on a quadratic function stimulation
PublicationA new approach to self-testing of the analog parts of mixed-signal electronic systems controlled by microcontrollers equipped with an ADC and a DAC is presented. It is based on a BIST and a new fault diagnosis method. A novelty is the use of the DAC as a component of the BIST, allowing to generate a stimulating signal with a quadratic function shape. It contributes to a better extraction of information about the state of the circuit...
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Analytical chemistry with biosolvents
PublicationOne of the current trends in green analytical chemistry is the introduction of green solvents, some of which are biobased. At the same time, the development of the biorefinery concept has allowed more biochemicals to be obtained with increased efficiency and from a wider range of feedstocks. The first examples of the use of biosolvents in analytical applications included extractions performed with alcohols, esters, and terpenes....
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Regulation of Plant Microprocessor Function in Shaping microRNA Landscape
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Comparative study of donor-induced quantum dots in Si nano-channels by single-electron transport characterization and Kelvin probe force microscopy
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OVARY, Ovary - Female, 35 - Tissue image [2220630014952251]
Open Research DataThis is the histopathological image of OVARY tissue sample obtained in Medical University Gdańsk and deposited in ZMDL-GUMED. The sample image was taken using: Pannoramic 250 3DHistech slide scanner (20x magnification) and saved to DICOM format.
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OVARY, Ovary - Female, 35 - Tissue image [2220630014959561]
Open Research DataThis is the histopathological image of OVARY tissue sample obtained in Medical University Gdańsk and deposited in ZMDL-GUMED. The sample image was taken using: Pannoramic 250 3DHistech slide scanner (20x magnification) and saved to DICOM format.
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OVARY, Ovary - Female, 35 - Tissue image [2220630014958491]
Open Research DataThis is the histopathological image of OVARY tissue sample obtained in Medical University Gdańsk and deposited in ZMDL-GUMED. The sample image was taken using: Pannoramic 250 3DHistech slide scanner (20x magnification) and saved to DICOM format.
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OVARY, Ovary - Female, 35 - Tissue image [2220630014954521]
Open Research DataThis is the histopathological image of OVARY tissue sample obtained in Medical University Gdańsk and deposited in ZMDL-GUMED. The sample image was taken using: Pannoramic 250 3DHistech slide scanner (20x magnification) and saved to DICOM format.
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OVARY, Ovary - Female, 35 - Tissue image [222063001495731]
Open Research DataThis is the histopathological image of OVARY tissue sample obtained in Medical University Gdańsk and deposited in ZMDL-GUMED. The sample image was taken using: Pannoramic 250 3DHistech slide scanner (20x magnification) and saved to DICOM format.
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Mucinous carcinoma - Female, 73 - Tissue image [3160630007336501]
Open Research DataThis is the histopathological image of BREAST tissue sample obtained in Medical University Gdańsk and deposited in ZMDL-GUMED. The sample image was taken using: Pannoramic 250 3DHistech slide scanner (20x magnification) and saved to DICOM format.
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Mucinous carcinoma - Female, 73 - Tissue image [3160630007334621]
Open Research DataThis is the histopathological image of BREAST tissue sample obtained in Medical University Gdańsk and deposited in ZMDL-GUMED. The sample image was taken using: Pannoramic 250 3DHistech slide scanner (20x magnification) and saved to DICOM format.
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Mucinous carcinoma - Female, 73 - Tissue image [3160630007332211]
Open Research DataThis is the histopathological image of BREAST tissue sample obtained in Medical University Gdańsk and deposited in ZMDL-GUMED. The sample image was taken using: Pannoramic 250 3DHistech slide scanner (20x magnification) and saved to DICOM format.
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Mucinous carcinoma - Female, 73 - Tissue image [3160630007334121]
Open Research DataThis is the histopathological image of BREAST tissue sample obtained in Medical University Gdańsk and deposited in ZMDL-GUMED. The sample image was taken using: Pannoramic 250 3DHistech slide scanner (20x magnification) and saved to DICOM format.
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Mucinous carcinoma - Female, 73 - Tissue image [3160630007337261]
Open Research DataThis is the histopathological image of BREAST tissue sample obtained in Medical University Gdańsk and deposited in ZMDL-GUMED. The sample image was taken using: Pannoramic 250 3DHistech slide scanner (20x magnification) and saved to DICOM format.
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Reduction of steel chimney vibrations with a pendlum damper.
PublicationKarman vortices observed around chimneys may induce dangerous structural vi-brations at certain wind velocities. The aim of this paper is to analyse theeffectiveness of pendulum damper in vibration reduction of a steel chimney. A two degree-of-freedom system is used to model the behaviour of the struc-ture equipped with a damper. The results of the study show that the use of pendulum with tuned frequency leads to significant...
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Ridged horn antenna for ground penetrating radar
PublicationOmówiono modyfikację tuby grzbietowej polegającą na jej wypełnieniu dielektrykiem, w celu wykorzystania do układu pozwalającego na poszukiwanie obiektów znajdujących się pod ziemią. Omówiono badania, które doprowadziły do opracowania konstrukcji anteny z wypełnieniem dielektrycznym. Przedstawiono wyniki testu takiej anteny w układzie do detekcji obiektu metalowego umieszczonego pod ziemią.
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Facile synthesis and characterization of graphene and N-doped graphene by CVD method from liquid precursors for promising electrode materials
PublicationIn this study, high-quality and few-layered graphene was synthesized using the chemical vapor deposition (CVD) method from liquid sources. Two different liquid carbon sources, pyridine, and benzene, were used and deposited on nickel foam under heat conditions using a bubbler in a quartz tube. X-ray diffraction (XRD) and Raman analysis confirmed the crystalline properties of graphene and N-doped graphene, demonstrating the high...
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Laser patterned platform with PEDOT–graphene composite film for NO2 sensing
PublicationThis work presents a simple and fully electrochemical route used for fabricating of a NO2 gas sensor made of reduced-graphene-oxide-poly(3,4-ethylenedioxythiophene) composite film. The sensing platform was fabricated from alumina substrate and equipped with gold interdigitated electrodes and built-in heater.The temperature distribution on the surface of interdigitated electrodes was investigated by a thermalimaging camera and compared...
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CFFT columns in road through railroad crossings
PublicationThere were 12801 road through railroad one-level crossings in Poland in 2018. 215 accidents happened at them in 2018. In order to increase safety in rail and road traffic two-level crossings should be used. They are definitely safer and make the traffic more smooth. In the design and construction of two-level intersections of railway and road or path columns of circular cross-section are often used. They can be successfully replaced...
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Effect of Temperature and Nanoparticle Concentration on Free Convective Heat Transfer of Nanofluids
PublicationA theoretical analysis of the influence of temperature and nanoparticle concentration on free convection heat transfer from a horizontal tube immersed in an unbounded nanofluid was presented. The Nusselt (Nu) number and heat transfer coefficient were parameters of the intensity of the convective heat transfer. For free convection, the Nu number was a function of the Rayleigh (Ra) number and Prandtl (Pr) number. The Rayleigh (Ra)...
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Spatial development in the EU in the global context
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Sorbents modified by deep eutectic solvents in microextraction techniques
PublicationIn recent years, considerable attention has been directed towards the employment of green solvents, specifically deep eutectic solvents (DES), in liquid phase microextraction techniques. However, comprehensive and organized knowledge regarding the modification of sorbent surface structures with DES remains limited. Therefore, this paper reviews the application of DES in modifying and improving the properties of sorbents for microextraction...
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Investigation of vortex assisted magnetic deep eutectic solvent based dispersive liquid–liquid microextraction for separation and determination of vanadium from water and food matrices: Multivariate analysis
PublicationA new and simple vortex assisted magnetic deep eutectic solvent dispersive liquid–liquid microextraction procedure (VA-MDES-DLLME) was developed for the determination of vanadium (V) in food and water samples by flame atomic absorption spectrometry (FAAS). In the extraction medium, a bis(acetylpivalylmethane) ethylenediimine (H2APM2en) was used for the complexation of V(V) in sample solution at pH 6. The VA-MDES-DLLME was optimized...
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Hazard Control in Industrial Environments: A Knowledge-Vision-Based Approach
PublicationThis paper proposes the integration of image processing techniques (such as image segmentation, feature extraction and selection) and a knowledge representation approach in a framework for the development of an automatic system able to identify, in real time, unsafe activities in industrial environments. In this framework, the visual information (feature extraction) acquired from video-camera images and other context based gathered...
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Chemometric Assessment and Best-Fit Function Modelling of the Toxic Potential of Selected Food Packaging Extracts
PublicationFood packaging materials constitute an ever more threatening environmental pollutant. This study examined options to specifically assess the ecotoxicity of packaged wastes, such as cans, subjected to various experimental treatments (in terms of extraction media, time of exposure, and temperature) that imitate several basic conditions of the process of food production. The extracts were studied for their ecotoxicity with bioluminescent...
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Multivariate Assessment of Procedures for Molecularly Imprinted Polymer Synthesis for Pesticides Determination in Environmental and Agricultural Samples
PublicationIn the case of quantitative and qualitative analysis of pesticides in environmental and food samples, it is required to perform a sample pre-treatment process. It allows to minimalize the impact of interferences on the final results, as well as increase the recovery rate. Nowadays, apart from routinely employed sample preparation techniques such as solid-phase extraction (SPE) or solid-phase microextraction (SPME), the application...
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Comparison of Two Methods for the Determination of Selected Pesticides in Honey and Honeybee Samples
PublicationDeveloped and validated analytical methods for the determination of a wide spectrum of pesticide residues in honey and honeybee samples after the modification of QuEChERS extraction in combination with gas chromatography–tandem quadrupole mass spectrometry (GC-MS/MS) and liquid chromatography–tandem quadrupole mass spectrometry (LC-MS/MS) were discussed and compared. The developed methods were evaluated regarding the utilized equipment...
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Comparison of Methods for Real and Imaginary Motion Classification from EEG Signals
PublicationA method for feature extraction and results of classification of EEG signals obtained from performed and imagined motion are presented. A set of 615 features was obtained to serve for the recognition of type and laterality of motion using 8 different classifications approaches. A comparison of achieved classifiers accuracy is presented in the paper, and then conclusions and discussion are provided. Among applied algorithms the...
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Thermal Imaging in Wound Healing Diagnostics
PublicationResults of a project searching for objective, quantitative evaluation of postoperative wound healing in cardiosurgery are presented. We propose simple thermal models of the healing processes after cardiosurgery interventions as objective descriptors allowing classification of patients for extraction and following recovery at home or for prolonged treatment in a hospital. Classification of healing as the normal process or as a process...
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Oxidation step in the preparation of benzocamalexin: The crystallographic evidence
PublicationThe study of oxidation step in the preparation of benzocamalexin by the α-amidoalkylation–oxidation sequence revealed the formation of perchloro-1,2-phenylene dibenzoate as the product of transformation of tetrachloro- 1,2-benzoquinone applied as the oxidant. The structures of benzocamalexin and perchloro-1,2-phenylene dibenzoate were confirmed by X-ray diffraction analysis. The extraction step in the final isolation of benzocamalexin...
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OVARY, Ovary - Female, 62 - Tissue image [3220630024678001]
Open Research DataThis is the histopathological image of OVARY tissue sample obtained in Medical University Gdańsk and deposited in ZMDL-GUMED. The sample image was taken using: Pannoramic 250 3DHistech slide scanner (20x magnification) and saved to DICOM format.
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Geometrically nonlinear analysis of shells - Benchmark problems for Autocad Robot Analysis Professional
PublicationThe aim of this work is to verify the suitability of commercial engineering software for geometrically nonlinear analysis of shells. This paper deals with the static, geometrically nonlinear analysis of shells made of an isotropic material. The Finite Element Method (FEM) is chosen to solve the problem. The results of the commercial software Autocad Robot Structural Analysis Professional (ARSAP) are compared with the litera-ture...
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Physics of Strongly-coupled Dopant-atoms in Nanodevices
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Determination of volatile organic compounds in water samples using membrane-solid phase microextraction (M-SPME) (headspace version)
PublicationThe results of a study on the use of membrane-solid phase microextraction (M-SPME) for sampling volatile organic compounds (VOCs) from the headspace above the liquid medium are presented. The sampled VOCs were subsequently quantified by gas chromatography (GC). Two systems were compared in this study, i.e. a novel two-phase sorption system (M-SPME), and a commercial fibre. Headspace sampling using SPME was optimized with respect...
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Preconcentration and Analytical Methods for Determination of Methyl Tert-Butyl Ether and Other Fuel Oxygenates and Their Degradation Products in Environment: A Review
PublicationFuel oxygenates (FOs) are mainly ethers or alcohols which are added to gasoline either to boost the octane number or to make the fuel burning process more "cleaner" with increasing the oxygen content, or to obtain a combination of both effects. FOs are water soluble with high mobility in the environment which presence even at very low concentrations lower the quality of water making it unsafe or unpleasant due to their objectionable...
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GIS Solution for Weather Forecast Data Analysis
PublicationIn this paper authors present the GIS system for the analysis of the numerical weather prediction data. This kind of data has multidimensional character (three dimensions and time) and its analysis should consider all the available factors. Proposed GIS system consists of RASDAMAN application with implemented OLAP cube mechanism, which enables the user to process data in the spatial-time domain. It also simplifies the meteorological...
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Manufacturing of Lightweight Aggregates as an Auspicious Method of Sewage Sludge Utilization
Publication: Sewage sludge is a high-volume and low-cost waste commonly generated worldwide, so its utilization is a vital issue. The application of this waste in the manufacturing of lightweight aggregates was investigated. The process was performed using intensive mixers with volumes of 5 and 30 L, as well as the industrial 500 L mixer. Then, granulates were sintered in a tube furnace. The influence of composition and mixer size on the...
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EFFECT OF NANOFLUID CONCENTRATION ON TWO-PHASE THERMOSYPHON HEAT EXCHANGER PERFORMANCE
PublicationAn approach – relaying on application of nanofluid as a working fluid, to improve performance of the two-phase thermosyphon heat exchanger (TPTHEx) has been proposed. The prototype heat exchanger consists of two horizontal cylindrical vessels connected by two risers and a downcomer. Tube bundles placed in the lower and upper cylinders work as an evaporator and a condenser, respectively. Distilled water and nanofluid water-Al2O3...
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The interaction of the pulsed laser irradiation with titania nanotubes - Theoretical studies on the thermal effect
PublicationThis paper reports temperature dispersion simulations of titania nanotubes irradiated by the 355 nm, pulsed, nanosecond laser. The modelling with the use of Finite Elements Method concerns titania nanotubes of the length and the wall thickness in the range of 0.5–2 μm and 5–20 nm, respectively. The uniqueness of the morphology was preserved by ensuring the wall thickness variation along the height of the tube, which was determined...
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Free Convection Heat Transfer from Horizontal Cylinders
PublicationThe results of experimental investigation of free convection heat transfer in a rectangular container are presented. The ability of the commonly accepted correlation equations to reproduce present experimental data was tested as well. It was assumed that the examined geometry fulfils the requirement of no-interaction between heated cylinder and bounded surfaces. In order to check this assumption recently published correlation equations...
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Spatial development in EU in a global context (2022/2023).
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Magnetic hydrophobic deep eutectic solvents for orbital shaker-assisted dispersive liquid-liquid microextraction (MAGDES-OS-DLLME) - determination of nickel and copper in food and water samples by FAAS
PublicationIn this work, a cheap and widely applicable dispersive liquid-liquid microextraction (DLLME) method was developed for the extraction of Ni(II) and Cu(II) from water and food samples and analysis using flame atomic absorption spectrometry. DLLME was assisted by orbital shaker, while ferrofluid as an extractant was based on deep eutectic solvent (DES). This ferrofluid was made of hydrophobic DES (hDES), composed of lauric acid and...
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Investigation of tetrabutylammonium bromide-glycerol-based deep eutectic solvents and their mixtures with water by spectroscopic techniques
PublicationDeep eutectic solvents (DES) are formed by an acceptor and a donor of hydrogen bonds. They are generally considered as a possible alternative to hazardous organic solvents in various fields. Very recently they have also appeared in analytical chemistry, used mainly for the separation of analytes before instrumental quantification. For the development of new extraction procedures, it is important, among other things, to understand...
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Determination of flavanols by liquid chromatography with fluorescence detection. Application to the characterization of cranberry-based pharmaceuticals through profiling and fingerprinting approaches
PublicationIn this work, a new method based on reversed-phase high-performance liquid chromatography (HPLC) with fluorescence detection (FLD) was established for the determination of catechins and related oligomeric proanthocyanidins (PACs) in cranberry-based pharmaceuticals. Compounds were recovered by liquid extraction using methanol/water/hydrochloric acid (60:39:1, v:v:v) as the extraction solvent. The chromatographic separation was carried...
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Semantic URL Analytics to Support Efficient Annotation of Large Scale Web Archives
PublicationLong-term Web archives comprise Web documents gathered over longer time periods and can easily reach hundreds of terabytes in size. Semantic annotations such as named entities can facilitate intelligent access to the Web archive data. However, the annotation of the entire archive content on this scale is often infeasible. The most efficient way to access the documents within Web archives is provided through their URLs, which are...