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Search results for: EBERLINE SAMPLER
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Hard tissue samples as markers of occupational exposure in phosphatic fertilizer plant
PublicationW pracy opisano zastosowanie próbek włosów i paznokci do oceny narażenia pracowników zakładów nawozów fosforowych na zanieczyszczenie metalami ciężkimi. Jako metodę oznaczania 25 pierwiastków we włosach i paznokciach zastosowano aktywacje neutronową. Do opracowania wyników i ich oceny zastosowano szereg metod chemometrycznych.
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Microanalysis of volatile organic compounds (VOCs) in water samples - methods and instruments
PublicationW pracy przedstawiono stan wiedzy nt. metodyk analitycznych oraz urządzeń kontrolno-pomiarowych, wykorzystywanych w badaniach próbek wody na zawartość lotnych związków organicznych. Szczególną uwagę zwrócono na techniki izolacji i wzbogacania analitów przed etapem oznaczeń końcowych.
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Clasification of drinking water samples using the Chernoff's faces visualization approach
PublicationOpracowanie przedstawia wyniki zastosowania wizualizacji metodą twarzy Chernoffa w klasyfikacji obszarowych zmian jakości wody pitnej, na podstawie wyników oznaczeń chloro- i bromopochodnych produktów dezynfekcji wody w 12 dzielnicach Gdańska w okresie 1993-2000.
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Calibration of Passive Samplers for the Monitoring of Pharmaceuticals in Water-Sampling Rate Variation
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Quality problems in determination of organic compounds in environmental samples, such as PAHs and PCBs
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Speciation of trace element compounds in samples of biota from marine ecosystems
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Determination of Surfactants in Environmental Samples. Part III. Non-Ionic Compounds
PublicationNon-ionic surface active agents are a diverse group of chemicals which have an uncharged polar head and a non-polar tail. They have different properties due to amphiphilic structure of their molecules. Commercial available non-ionic surfactants consist of the broadest spectrum of compounds in comparison with other types of such agents. Typically, non-ionic compounds found applications in households and industry during formulation...
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Ionic liquids in extraction techniques: Determination of pesticides in food and environmental samples
PublicationThe intensive use of pesticides in agricultural practices has promoted the appearance of environmentaland public health problems. Due to that, scientists face challenges with developing simple, fast, sensitive,selective, and low-cost methods dedicated to determining pesticide residues in food and environmentalsamples. Following thefifth principle of Green Analytical Chemistry, chemists are searching for greeneralternatives for...
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The speciation of organotin compounds in sediment and water samples from the port of Gdynia
PublicationOrganotin compounds (OTC) are toxic towards all living organisms. The application of organitin-based antifouling systems is becoming the main source of OTC in the ocean. Harbor sediments and water contain large deposits of organotin compounds due to application of antifouling systems in the shipping industry. OTC contamination presents a potential risk to the marine environment. Sediment and water samples were collected in 2009...
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Comparison of Two Methods for the Determination of Selected Pesticides in Honey and Honeybee Samples
PublicationDeveloped and validated analytical methods for the determination of a wide spectrum of pesticide residues in honey and honeybee samples after the modification of QuEChERS extraction in combination with gas chromatography–tandem quadrupole mass spectrometry (GC-MS/MS) and liquid chromatography–tandem quadrupole mass spectrometry (LC-MS/MS) were discussed and compared. The developed methods were evaluated regarding the utilized equipment...
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Application of GC-MS/MS technique for the determination of benzodiazepines in blood samples
PublicationAbstract Benzodiazepines (BZD) are widely used as pharmaceuticals in medicine. However, due to psychostimulatory effect of BZD, in the last decade, they are more and more often used as drugs of abuse. These compounds produce similar effects to classical illicit drugs and are sold as “legal” alternatives to them as new psychoactive substances (NPS). Currently new BZD, named designer benzodiazepines (DBZD), are synthesized each year...
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Genetic and biochemical characterization of yeasts isolated from Antarctic soil samples
PublicationThe Polish Arctowski Station is situated in the maritime Antarctic on the western shore ot' Admiralty Bay and encompasses terrestrial habitats which are not perma-nently covered by ice, in contrast to morę than 90% of the island's surface area. Over the past several decades, stud-ies exploring the soils of those habitats have revealed a considerable diversity of bacteria, filamentous fungi, and, to a lesser extent, yeasts; however,...
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Formation, occurrence and determination of volatile fatty acids in environmental and related samples
PublicationKrótkołańcuchowe alifatyczne kwasy monokarboksylowe mogą być oznaczane w różnych próbkach środowiskowych,za pomocą techniki mikroekstrakcji do fazy stacjonarnej z fazy nadpowierzchniowej na etapie przygotowanie próbek oraz chromatografii gazowej sprzężonej ze spektrometrią mas na etapie oznaczeń końcowych.Opracowana metodykę z powodzeniem zastosowano do oznaczenia tych kwasów w próbkach ścieków pochodzących z farmy bydła.
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Challenges in preparing honey samples for chromatographic determination of contaminants and trace residues
PublicationThe determination of contaminations and residues in honey is of growing concern over past few years, especially that these compounds can not only diminish beneficial properties of honey but more importantly, if present in significant amounts, can pose serious threat to human health. Since honey is characterized by complex composition of the matrix sample, it is often necessary to apply clean-up step, in order to eliminate interfering...
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Microextraction by packed sorbent: Uncommon detection techniques, sorbents, samples and analytes
PublicationAmong sample preparation approaches, the most desirable are procedures that ensure high efficiency and reproducibility, that are cheap, fast and simple, that minimize the number of operational steps and that require a small amount of sample and solvent and are thus environmentally friendly. Microextraction by packed sorbent (MEPS) is a miniaturized form of solid-phase extraction, the use of which has been continuously expanding...
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Non-regulated organic compounds (NROC's) in the Odra River water samples.
PublicationW ramach badań opisanych w pracy podjęto próbę identyfikacji lotnych i średniolotnych związków z grupy Non-Regulated Organic Compounds obecnych w próbkach wody rzecznej. Analizie poddano 25 próbek wód pobranych z rzeki Odry w październiku 2000, w trakcie VIII kampanii zorganizowanej w ramach International Odra Project (IOP). W badaniach wykorzystano technikę PT-TD-GC-MS.Komputerowa analiza widm masowych wykazała obecność wielu...
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Determining PAHs and PCBs in aqueous samples: finding and evaluating sources of error
PublicationW pracy opisano wyniki badań modelowych (z wykorzystaniem dopowiednich roztworów wzorcowych), których celem było wykrycie źródeł błędów oznaczeń oraz oszacowanie ich wielkości. Przedmiotem badań było oszacowanie wpływu takich procesów jak:- adsorpcja na ściankach naczyń,- adsorpcja na cząstkach materii zawieszonej,- usuwanie nadmiaru rozpuszczalnika (z ekstraktu)na wyniki oznaczeń końcowych.
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Program URBAN II w Europie jako jedno z narzędzi polityki Unii Europejskiej w planowaniu przestrzennym miast - przypadek Berlina
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Dawid Zieliński dr inż.
PeopleDawid Zieliński uzyskał tytuł magistra inżyniera w 2017 roku na Wydziale Mechanicznych Politechniki Gdańskiej, kończąc kierunek: Mechanika i Budowa Maszyn, specjalność: Technologia Maszyn i Komputerowe Wspomaganie Produkcji. W okresie 2016-17 studiował na Uniwersytecie Technicznym w Berlinie (Technische Universität Berlin – TU Berlin) oraz pracował w instytucie naukowym – Institut für Werkzeugmaschinen und Fabrikbetrieb (IWF) Technische...
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SAMPLE-AND-HOLDING METHOD FOR GAS SENSING APPLIED FOR RESISTANCE GAS SENSORS
PublicationThe DC resistance of a Taguchi gas sensor is influenced by the ambient gas. To improve the selectivity and sensitivity of a sensor the fluctuation enhanced sensing (FES) was used. The paper proposes a novel methodology of utilizing FES technique that sample composition of an ambient atmosphere and hold it for further processing (sample-and-holding technique). The method uses the heated gas sensor to sample an ambient atmosphere...
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Coacervative extraction as a green technique for sample preparation for the analysis of organic compounds
PublicationOne of the present trends in analytical chemistry is miniaturization, which is one of the methods of green analytical chemistry application. A particular emphasis is placed on the elimination of the use of large amounts of organic solvents which are toxic and harmful to the environment, maintaining high efficiency of the extraction process, high recovery values and low values of quantification (LOQ) and detection (LOD) limits....
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Solventless sample preparation techniques based on solid- and vapour-phase extraction
PublicationThe main objective of this review is to critically evaluate recent developments in solventless sample preparation techniques. The potential of a variety of sample preparation techniques based on solid- and vapour-phase extraction techniques is evaluated. Direct thermal extraction and derivatization processes to facilitate the extraction of analytes in different areas are included. The applicability, disadvantages and advantages...
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Soxhlet Extraction and New Developments Such as Soxtec in: Comprehansive Sampling and Sample Preparation
PublicationSoxhlet extraction is one of the most popular techniques for extraction of analytes from solid materials. Since its discovery in 1879, the standard Soxhlet technique has been routinely applied in almost every analytical laboratory. Up to this day, Soxhlet extraction technique remains a standard technique to which the performance of modern extraction techniques is compared.Over the years, an intensive research on different modifications...
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Modern techniques of sample preparation for determination of organic analytes by gas chromatography
PublicationW pracy dokonano przeglądu szerokiego spektrum technik przygotowania próbki, ze szczególnym uwzględnieniem technik o charakterze prośrodowiskowym. Opisu technik dokonano pod kątem wykorzystywanych mechanizmów izolacji analitów oraz stosowanych rozwiązań aparaturowych. Przegląd rozwiązań aparaturowych uzupełniono o podstawy teoretyczne izolacji bazującej na zjawisku podziału analitów.
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Green sample preparation techniques for chromatographic determination of small organic compounds
PublicationAccurate monitoring of the state of the environment requires the introduction of additional isolation and/or preconcentration step prior to the chromatographic determination. In this work the information about novel methodological and instrumental solutions in relation to different variants of microextraction techniques are presented. Attention is focused on analytical procedure and suitable analytical tools for extraction of the...
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Variable Ratio Sample Rate Conversion Based on Fractional Delay Filter
PublicationIn this paper a sample rate conversion algorithm which allows for continuously changing resampling ratio has been presented. The proposed implementation is based on a variable fractional delay filter which is implemented by means of a Farrow structure. Coefficients of this structure are computed on the basis of fractional delay filters which are designed using the offset window method. The proposed approach allows us to freely...
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New sample preparation strategies for comprehensive lipidomics of human breast milk
PublicationGLOBAL PROFILING ANALYSIS OF HUMAN BREAST MILK (HBM) LIPIDS IS HINDERED BY COMPLEX COMPOSITION OF HBM. THIS PROBLEM IS HUGE FROM ANALYTICAL POINT OF VIEW, SINCE DUE TO THAT DETECTION OF ALL HBM LIPIDS DURING ONE ANALYTICAL RUN IS LIMITED. THUS, SAMPLE PREPARATION STEP CONSTITUTES A CRUCIAL STEP IN UNTARGETED LIPIDOMIC ANALYSIS OF HBM, ESPECIALLY WHEN SEMI-QUANTITATIVE ANALYSIS IS ASSUMED. HEREIN, WE PRESENT A COMPARISON OF PUBLISHED...
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Dynamic Headspace Sampling as an Initial Step for Sample Preparation in Chromatographic Analysis
PublicationThis work represents a brief summary of the use of dynamic headspace (DHS) as a technique for sample preparation in chromatographic analysis. Despite numerous developments in the area of analyte isolation and enrichment, DHS remains one of the fundamental methods used with GC. In our opinion, interest in this technique will not diminish significantly because it conforms to stipulations of green analytical chemistry. Moreover, DHS...
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Green analytical chemistry in sample preparation for determination of trace organic pollutants
PublicationW pracy przedstawiono przyjazne środowisku techniki analityczne, stosowane w celu izolacji i wzbogacania analitów. Ilość używanych rozpuszczalników jest ograniczana przez stosowanie alternatwnych rozpuszczalników, technik bezrozpuszczalnikowych, ekstrakcji wspomaganych czynnikami zewnętrznymi oraz przez wprowadzanie mikrosystemów analitycznych.
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Fractional delayor application in self-tuning sub-sample delay estimator
PublicationW artykule przedstawiono nowe rozwiązanie samonastrajalnego estymatora opóźnienia sygnału sinusoidalnego. Estymator działa w czasie dyskretnym. Proponowane rozwiązanie wykorzystuje kaskadowe połączenie cyfrowego filtru ułamkowo opóźniającego służącego do synchronizacji próbkowania i liniowo-fazowego cyfrowego filtru Hilberta. Oryginalność polega na zastosowaniu tu filtrów cyfrowych o bardzo małej złożoności numerycznej. Jest ona...
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Analytical applications of membrane extraction for biological and environmental liquid sample preparation
PublicationW niniejszej pracy przedstawiono informacje dotyczące technik ekstrakcji membranowej wykorzystywanych do oznaczania związków organicznych w ciekłych próbkach środowiskowych i biologicznych. Szczególną uwagę poświęcono podstawom teoretycznym tych technik, możliwości połączenia z technikami oznaczeń końcowych oraz obszarom praktycznego ich wykorzystania.
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Calibration of permeation passive samplers with silicone membranes based on physicochemical properties of the analytes.
PublicationW pracy opisano sposób kalibracji pasywnych dozymetrów permeacyjnych, wykorzystywanych w badaniach powietrza w oparciu o własności fizyko-chemiczne analitów. Stwierdzono silną zależność pomiędzy stałą kalibracyjną (K) dozymetrów i liczbą atomów węgla w cząsteczce analitu (w obrębie danej grupy związków chemicznych) dla alkoholi, alifatycznych i aromatycznych węglowodorów oraz estrów. Taka zależność występuje również pomiędzy...
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Organomercury compounds in environmental samples: emission sources, toxicity, environmental fate and determination.
PublicationIn view of the specific properties of mercury and its capability of forming compounds that can be bioaccumulated and biomagnified at successive levels of the trophic pyramid, it has become necessary to gather detailed information on the sources of emission of this element into the environment and its fate there. Moreover, the increasing awareness of the relationship between the toxicity of mercury and its chemical form has sharpened...
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Microextraction Techniques Used in the Procedures for Determining Organomercury and Organotin Compounds in Environmental Samples
PublicationDue to human activities, the concentrations of organometallic compounds in all parts of the environment have increased in recent decades. The toxicity and some biochemical properties of mercury and tin present in the environment depend on the concentration and chemical form of these two elements. The ever-increasing demand for determining compounds at very low concentration levels in samples with complex matrices requires...
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Greenness assessment of analytical methods used for antibiotic residues determination in food samples
PublicationFood of animal origin plays an important role in ensuring a healthy and sustainable human diet. However, residues of pharmaceuticals, especially antibiotics, can be the cause of many health problems. To protect consumers and improve food quality, analytical methods used to determine contaminants should be simple, selective, and have high throughput and low detection limits. Recently, greenness metric tools have proven useful in...
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Stability studies of selected phenoxyacid herbicides in water samples and detrmination of their transformation products
PublicationZbadano procesy przemian fenoksykwasów (takich jak: 2,4-D, MCPA, mekoprop, dichlorprop) w różnych roztworach wodnych. Sprawdzono wpływ parametrów (światło, temperatura oraz czas przechowywania próbki) na stabilność fenoksykwasów. Oznaczeń końcowych dokonano przy użyciu techniki chromatografii cieczowej sprzężonej ze spektrometrem mas.
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Comparison of Three Extraction Approaches for the Isolation of Neurotransmitters from Rat Brain Samples
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Determination of metals in water samples by atomic absorption spectrometry and flame emission spectrometry
PublicationMetal species in environmental waters are relevant to characterize the metal toxicity, the mobility between different environmental compartments, and for remediation purposes in case of contamination. The concentration of many trace metals in natural water samples are generally at µg/l level. The paper describes determination of metals in water samples based on flame atomic emission and flame atomic absorption spectrometry.
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Determination of Selected Organic Acids in Animal Farm Water Samples by Ion Chromatography
PublicationLow molecular mass carboxylic acids (LCAs) occur in many environmental compartments due to natural processes and human activity. They are an important group of organic pollutants of waste water that mainly includes, volatile fatty acids, and also dicarboxylic, aromatic, hydroxy- and ketoacids. LCAs are present in the environment at concentrations between 1 to 5000 ppm and different methods have been reported for their determination...
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The effect of adding a standard on the result of determination of polychlorinated biphenyls in bottom sediment samples
PublicationBottom sediments are a very important component of aquatic ecosystems. The sediment matrix is highly diverse and heterogeneous; in consequence, compounds entering the aquatic environment from different sources are considerably enriched at its surface. Bottom sediments are regarded as natural sorbents, since they accumulate many harmful substances, such as heavy metals and stable organic contaminants.Extraction is a key stage in...
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Application of chemometric approach in studies of dew chemistry (on the basis of samples collected in Poland)
PublicationPrzedstawiono wyniki badań wybranych związków chemicznych (aniony, kationy, formaldehyd, nadtlenek wodoru, suma fenoli, TC, TIC, TOC) oznaczonych w próbkach rosy zebranych z różnych obszarów na terenie Polski (Gdynia, Gdańsk, Sopot, Mława, Kraków). Zastosowano analizę funkcji dyskryminacyjnej aby dokonać klasyfikacji poszczególnych próbek w zależności od miejsca pobierania oraz wykryć podstawowe zależności pomiędzy poszczególnymi...
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Major ions and their relationship in rime and hoarfrost samples from highly urbanized regions
PublicationW ramach zaplanowanego programu badawczego przeprowadzono analizę próbek szronu i sadzi zebranych w wybranych punktach pomiarowych (Gdańsk i Działdowo) podczas zimy 2003/2004. Stężenie składników nieorganicznych w próbkach szronu jest średnio dwukrotnie wyższe niż w próbkach sadzi zebranych z tego samego terenu. Wyższe poziomy stężeń oznaczanych zanieczyszczeń w próbek szronu mogą wynikać z faktu, iż proces powstawania sadzi najczęściej...
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The triple-sorbents solid-phase extraction for pharmaceuticals and estrogens determination in wastewater samples
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Microextraction Techniques Used in the Procedures for Determining Organomercury and Organotin Compounds in Environmental Samples
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Determination of PCBs in river sediment samples—proficiency test for selected Polish laboratories
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Organomercury Compounds in Environmental Samples: Emission Sources, Toxicity, Environmental Fate, and Determination
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Chemical Derivatization Processes Applied to Amine Determination in Samples of Different Matrix Composition
PublicationAmines are important biological compounds, and so their analysis and monitoring in various matrices is worthy of investigation and development.Due to the polar nature of amines, chromatographic analysis of free amines is generally unsatisfactory owing to adsorption and decomposition of the solute on the column, resulting in peak tailing and losses. Therefore, many derivatization reactions are employed to reduce the polarity, improve...
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MECONIUM SAMPLES USED TO ASSESS INFANT EXPOSURE TO THE COMPONENTS OF ETS DURING PREGNANCY
PublicationThe aim of the study was to use meconium samples to assess fetal exposure to compounds present in environmental tobacco smoke (ETS). Material and Methods: In order to assess fetal exposure to toxic tobacco smoke compounds, samples of meconium from the offspring of women with different levels of tobacco smoke exposure, and the samples of saliva from the mothers were analyzed. Thiocyanate ion as a biomarker of tobacco smoke exposure,...
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Correlations between levels of dioxins and PCBs in environment samples and wild boar muscles
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Determination of MDPBP in postmortem blood samples by gas chromatography coupled with mass spectrometry
PublicationMDPBP (1-(3,4-methylenedioxyphenyl)-2-(1-pyrrolidinyl)-1-butanone) is a new psychoactive substance sold on the black market. It has been a controlled drug of abuse in Poland and China since 2015 as some toxic and fatal cases connected with use of synthetic cathinone derivatives were observed. The fatal case outlined here concerns a 19 year-old man, who was found dead with an envelope containing white powder lying nearby the cadaver....