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Synteza bio-cyklicznych węglanów z wykorzystaniem oligoeteroli różniących się masą molową
PublikacjaCykliczne węglany mogą być otrzymywane w wyniku cykloaddycji CO2 do eterów glicydylowych. Biorąc pod uwagę stopniowe wyczerpywanie się, a co za tym idzie, zauważalny wzrost cen substratów ropopochodnych należy wziąć pod uwagę zastąpienie surowców petrochemicznych przez związki pochodzenia naturalnego. Ponadto, wykorzystanie CO2 przyczynić się może do rozwoju perspektyw utylizacji tego gazu w syntezach organicznych. Otrzymanie węglanów...
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Badania nośności na zginanie innowacyjnego kształtownika giętego na zimno typu GEB
PublikacjaLekkie konstrukcje metalowe wytwarzane z kształtowników giętych na zimno to jedna z najszybciej rozwijających się dyscyplin w zakresie budownictwa. Do niedawna profile gięte na zimno stosowano wyłącznie jako elementy drugorzędne, czyli płatwie oraz rygle. Nowo opatentowany przekrój typu GEB ma być wykorzystywany jako element nośny konstrukcji ramowych. Jednak jego zaistnienie na rynku budowlanych konstrukcji metalowych jest uwarunkowane...
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Żuławski dom podcieniowy - przykłady i skala współczesnych działań konserwatorskich
PublikacjaPoczątki zainteresowania architekturą regionalną na terenach Prus Zachodnich sięgają przełomu XIX/XX wieku i związane są z osobą Bernharda Schmida. Koniec II wojny światowej przyniósł na Żuławach zniszczenie ponad 2 744 zagród chłopskich. Ze względu na priorytet ratowania zabytków Gdańska, historyczne obiekty z okolicznych wsi doczekały się szerszej uwagi służb konserwatorskich dopiero w połowie lat pięćdziesiątych. Opracowanie...
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Ewolucyjny rozwój uczelnianej infrastruktury komunikacyjno-informacyjnej na potrzeby e-uczelni
PublikacjaStosowane i proponowane rozwiązania w obszarze technologii informacyjnych stwarzają szerokie możliwości w rozwoju i wdrażaniu systemów komunikacyjno-informacyjnych wspomagających i usprawniających specyficzną działalności uczelni a szczególnie wspierających e-Uczelnię. Wymaga to jednak wprowadzenia zmian w infrastrukturze technicznej i organizacji pracy. W artykule rozpa-trzono możliwości wykorzystania uczelnianych infrastruktur...
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Economic crisis in Croatia
PublikacjaCroatia is becoming the 28th member of the European Union on July 1st, 2013. Croatia has gone a long way from a socialistic republic to an independent country recognized as one of the economic tigers of the Western Balkans in the first decade of the 21st century. Croatia has been hit by a global crisis which turned out to be a huge external shock for the region of the Western Balkans. Although it does not enter the economy through...
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Interaction of cisplatin and two potential antitumoral platinum(ii) complexes with a model lipid membrane: a combined NMR and MD study
PublikacjaIn this study, the interaction of cisplatin (1) and two potential antitumoral Pt(II) complexes (2 and 3) with a model DMPC bilayer was investigated by multinuclear NMR spectroscopy and MD simulations in order to understand its implication for the different antitumoral properties shown by the three complexes. In particular, 31P, 13C and 2H solid state NMR experiments were performed to obtain information on the phase structure, phase...
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Shaking table experimental study on damage mechanism of the disconnecting switch under seismic excitation
PublikacjaThe efficiency of the energetic network is a very import safety issue in the region experienced by the earthquake. High voltage disconnecting switches are important elements of the energetic infrastructure used to separate electric circuits (i.e. during repairs), which should not be damaged remaining fully operational. The aim of the paper is to show the results of the shaking table experimental investigation focused on damage...
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A CNN based coronavirus disease prediction system for chest X-rays
PublikacjaCoronavirus disease (COVID-19) proliferated globally in early 2020, causing existential dread in the whole world. Radiography is crucial in the clinical staging and diagnosis of COVID-19 and offers high potential to improve healthcare plans for tackling the pandemic. However high variations in infection characteristics and low contrast between normal and infected regions pose great challenges in preparing radiological reports....
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Heat exchange enhancement of jet impingement cooling with the novel humped-cone heat sink
PublikacjaJet impingement cooling technology is applicable to control temperature of devices, where very high heat flux is generated within a small area. This paper is about the improvement of the jet impingement cooling efficiency by the heat sink geometry modification. Two reference cases were sourced from the literature – flat heat sink and modified one with cone in the jet stagnation region. Such a change improves cooling capability...
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Numerically Efficient Miniaturization-Oriented Optimization of an Ultra-Wideband Spline-Parameterized Antenna
PublikacjaDesign of ultra-wideband radiators for modern handheld applications is a challenging task that involves not only selection of an appropriate topology, but also its tuning oriented towards balancing the electrical performance and size. In this work, a low-cost design of a compact, broadband, spline-parameterized monopole antenna has been considered. The framework used for the structure design implements trust-region-based methods,...
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Fast EM-Driven Parameter Tuning of Microwave Circuits with Sparse Sensitivity Updates via Principal Directions
PublikacjaNumerical optimization has become more important than ever in the design of microwave components and systems, primarily as a consequence of increasing performance demands and growing complexity of the circuits. As the parameter tuning is more and more often executed using full-wave electromagnetic (EM) models, the CPU cost of the overall process tends to be excessive even for local optimization. Some ways of alleviating these issues...
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The effectiveness of financial and economic regulation of land relations in the context of stimulating entrepreneurial activity in the regions of Ukraine
PublikacjaSolving the problem of enhancing the efficiency of the financial and economic regulation of land relations contributes to the development of entrepreneurship in Ukraine. The purpose of the paper is to determine new incentives for encouraging entrepreneurial activity by increasing the efficiency of the financial and economic regulation of land relations by local governments. The study is based on applying the method for predicting...
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Design and Optimization of Metamaterial-Based 5G Millimeter Wave Antenna for Gain Enhancement
PublikacjaIn this brief, a low profile, broadband, high-gain antenna array based on optimized metamaterials (MMs) with dual-beam radiation is reported for 5G millimeters wave (mm-wave) applications. The design is a simple bow tie operating at a 5G band of 28 GHz. It consists of two bow ties with substrate integrated waveguide (SIW)-based power splitter. A broad impedance bandwidth of 26.3−29.8 GHz is obtained by appropriately combining the...
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Structure and Molecular Dynamics in Renewable Polyamides from Dideoxy-Diamino Isohexide
PublikacjaThe chemical structure, the conformation, andthe flexibility of the polymer chain fragments present in thepolyamides synthesized from 2,5-diamino-2,5-dideoxy-1,4;3,6-dianhydrosorbitol, 1,4-diaminobutane, and either sebacic orbrassylic acid have been studied by liquid-state 2D NMRspectroscopy viz. correlation spectra (COSY) and heteronuclearmultiple-bond correlation spectra (gHMBC), by 13Ccross-polarization/magic-angle spinning...
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Brain-computer interaction based on EEG signal and gaze-tracking information = Analiza interackji mózg-komputer wykorzystująca sygnał EEg i informacje z systemu śledzenia punktu fiksacji wzroku
PublikacjaThe article presents an attempt to integrate EEG signal analysis with information about human visual activities, i.e. gaze fixation point. The results from gaze-tracking-based measurement were combined with the standard EEG analysis. A search for correlation between the brain activity and the region of the screen observed by the user was performed. The preliminary stage of the study consists in electrooculography (EOG) signal processing....
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A Novel Ru(II) Polypyridine Black Dye Investigated by Resonance Raman Spectroscopy and TDDFT Calculations
PublikacjaThe optical properties of a new(bipyridine)2Ru(4H-imidazole) complex presenting a remarkablebroad absorption in the visible range are investigated. Thestrong overlap of the absorption with the solar radiationspectrum renders the studied complex promising as a blackabsorber and hence as a starting structure for applications inthe field of dye-sensitized solar cells. The correlations betweenstructural and electronic features for...
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Low-cost data-driven modelling of microwave components using domain confinement and PCA-based dimensionality reduction
PublikacjaFast data-driven surrogate models can be employed as replacements of computationally demanding full-wave electromagnetic simulations to facilitate the microwave design procedures. Unfortunately, practical application of surrogate modelling is often hindered by the curse of dimensionality and/or considerable nonlinearity of the component characteristics. This paper proposes a simple yet reliable approach to cost-efficient modelling...
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Nonlinear dynamic analysis of the pure “buckling” mechanism during blow-out trauma of the human orbit
PublikacjaConsidering the interplay between orbital bones and intraorbital soft tissues, commonly accepted patterns of the blow-out type of trauma within the human orbit require more thorough investigation to assess the minimal health-threatening impact value. Two different three-dimensional finite element method (FEM) models of the human orbital region were developed to simulate the pure “buckling” mechanism of orbital wall fracture in...
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Diamine derivatives of dimerized fatty acids and bio-based polyether polyol as sustainable platforms for the synthesis of non-isocyanate polyurethanes
PublikacjaA series of environmentally friendly non-isocyanate polyurethanes (NIPUs) were successfully prepared via the polyaddition reaction of bio-based polyether polyol-based cyclic carbonate with diamine derivative of dimerized fatty acids. The syntheses of NIPUs were realized by the three-step method in the absence of toxic solvents and, importantly, the process of carbonation did not require the use of elevated pressure. The effect...
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Examination of cyp51A and cyp51B expression level of the first Polish azole resistant clinical Aspergillus fumigatus isolate
PublikacjaAspergillus fumigatus is one of the most prevalent airborne fungal pathogens causing infections worldwide. Most A. fumigatus strains are susceptible to azoles, which are administered as the first line therapeutics. However, during last decade the acquired resistance to triazoles by these species has been described. There is a number of publications concerning the examination of clinical A. fumigatus strains from different countries,...
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Gustav Oelsners Werk aus polnischer Perspektive. das Erbe der moderne in der polnischen Architektur und Stadtplannung
PublikacjaDie Leistungen des Architekten Gustav Oelsner sind ein Beispiel für das gemeinsame Erbe der Region, das gemeinsam betrachtet werden sollte – ohne eine de facto künstliche Aufteilung in die Aktivitäten deutscher und polnischer Künstler. Eine solche Herangehensweise ist notwendig bei der Analyse der Biographie nicht nur des Altonaer Architekten, sondern vieler anderer, die das Schicksal der Geschichte in die nationale Einteilung...
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Starter for Voltage Boost Converter to Harvest Thermoelectric Energy for Body-Worn Sensors
PublikacjaThis paper examines the suitability of selected configurations of ultra-low voltage (ULV) oscilla-tors as starters for a voltage boost converter to harvest energy from a thermoelectric generator (TEG). Important properties of particularly promising configurations, suitable for on-chip imple-mentation are compared. On this basis, an improved oscillator with a low startup voltage and a high output voltage swing is proposed. The applicability...
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Study on Microstructural Characterization, Mechanical Properties and Residual Stress of GTAW Dissimilar Joints of P91 and P22 Steels
PublikacjaThis article deals with the dissimilar joining of two different grade Cr-Mo steel (2.25Cr-1Mo: P22 and modified 9Cr-1Mo: P91) for power plant application. The dissimilar butt-welded joint was produced for conventional V groove design by using the gas tungsten arc welding (GTAW) process with the application of an ERNiCrMo-3 Ni-based super alloy filler. A microstructure characterization was performed to measure the inhomogeneity...
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Computationally-efficient design optimisation of antennas by accelerated gradient search with sensitivity and design change monitoring
PublikacjaElectromagnetic (EM) simulation tools are of primary importance in the design of contemporary antennas. The necessity of accurate performance evaluation of complex structures is a reason why the final tuning of antenna dimensions, aimed at improvement of electrical and field characteristics, needs to be based on EM analysis. Design automation is highly desirable and can be achieved by coupling EM solvers with numerical optimisation...
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Problemy termomodernizacji tradycyjnego ceglanego budynku mieszkalnego na Kaszubach.
PublikacjaTematem opracowania jest utrata walorów architektonicznych i krajobrazowych tradycyjnej wsi kaszubskiej na skutek przeprowadzanej termomodernizacji. W pracy opisano stan zachowania tradycyjnej, ceglanej zabudowy mieszkaniowej, przedstawiono ocenę wpływu termomodernizacji na stan zachowania dziedzictwa architektonicznego i krajobrazu wsi kaszubskiej oraz opisano stosowane metody termomodernizacji. Analizę przeprowadzono na podstawie...
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Selection of circuit geometry for miniaturized microwave components based on concurrent optimization of performance and layout area
PublikacjaThe paper presents a framework for automated EM-driven circuit geometry selection of miniaturized microwave components. Selection of a particular layout is based directly on miniaturization rates achieved for a set of candidate circuit geometries. Size reduction of the considered structures is obtained by replacing their main building blocks (i.e., conventional transmission lines) with slow-wave composite cells and meander lines....
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Investigation of Thermoplastic Polyurethanes Synthesized via Two Different Prepolymers
PublikacjaThe man aim of this work was to investigate the effect of the molecular weight of polyols, mixture of prepolymers, and [NCO]/[OH] molar ratio used during the prepolymer chain extending step on the chemical structure, thermomechanical and mechanical properties, and thermal stability of thermoplastic poly(ether-urethane)s In this work thermoplastic poly(ether-urethane)s were synthesized by using polyols with a various molecular weight,...
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Problemy termomodernizacji tradycyjnego ceglanego budynku mieszkalnego na Kaszubach.
PublikacjaTematem opracowania jest utrata walorów architektonicznych i krajobrazowych tradycyjnej wsi kaszubskiej na skutek przeprowadzanej termomodernizacji. W pracy opisano stan zachowania tradycyjnej, ceglanej zabudowy mieszkaniowej, przedstawiono ocenę wpływu termomodernizacji na stan zachowania dziedzictwa architektonicznego i krajobrazu wsi kaszubskiej oraz opisano stosowane metody termomodernizacji. Analizę przeprowadzono na podstawie...
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Homogeneity study of candidate reference material (contaminated soil) based on determination of selected metals, PCBs and PAHs
PublikacjaReference materials (RMs) are an indispensable part of QA/QC system and have played a critical role in the continual expansion of analytical capabilities of the analytical laboratories. The homogeneity study of the candidate for reference material is essential for the quality of reference material (certified reference material) used in quality assurance activities. The homogeneity study of candidate for reference materials of contaminated...
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Specialist Pavilion Hospitals Of West Prussia In The 19th Century – Evolution Of The Idea
PublikacjaThe size and shape of the largest pavilion hospitals established in West Prussia in the 19th century changed along with the advancing technical and medical knowledge, the progress of ideas regarding modern society, architectural patterns, and the needs for which the hospitals were built. Apart from the medical treatment section, there were administrative, social and technical facilities, all constituting parts of the complex. The...
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Evaluation of the factors influencing business bankruptcy risk in Poland
PublikacjaThis article is devoted to the issue of assessing the causes of business failure. The presented studies answer two research questions – what are the causes of corporate bankruptcies in Poland and how to more efectively predict the scale of bankruptcies in the country. The author has conducted a study to analyze the specic endogenous and exogenous causes of company bankruptcy depending on the type of the bankruptcy with consideration...
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Wsparcie małych i średnich przedsiębiorstw w procesie rekrutacji
PublikacjaPrzedsiębiorcy działający na małą skalę nie przywiązują zbyt dużej wagi do zarządzania zasobami ludzkimi, dotyczy to wszystkich jego elementów, w tym zatrudniania. Brak im umiejętności, czasu i chęci na prawidłowe określanie brakujących kompetencji, a pracowników poszukują wśród rodziny, znajomych czy w urzędach pracy. Ten uproszczony i niemal bez kosztowy sposób zarządzania tylko iluzorycznie obniża koszty funkcjonowania przed-siębiorstwa....
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Theoretical Assessment of Excited State Gradients and Resonance Raman Intensities for the Azobenzene Molecule
PublikacjaThe ground state geometries and vibrational frequencies as well as the excitation energies and excited state gradients of the S 1(nπ*) and S 2(ππ * ) states of trans - and cis -azobenzene are investigated by several DFT methods, namely B3LYP, PBE, M06-2X, CAM-B3LYP, and ω B97X. Excited state properties and in particular gradients are also assessed using the wave function based methods EOM-CCSD and RASPT2/RASSCF. Comparison with...
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REVERSE MODELLING OF MICROSEISMIC WAVES PROPAGATION FOR THE INTERPRETATION OF THE DATA FROM HYDRAULIC FRACTURING MONITORING IN POLAND
PublikacjaA hydraulic fracturing job was performed to stimulate gas flow from a horizontal wellbore located in Poland. The whole operation was overseen by means of microseismic monitoring. For this purpose, an array of 12000 geophones was deployed on ground in form of patches distributed unevenly in a region of 4km from the wellbore. The array was constantly recording seismic signals during whole fracturing processed. Such recorded signals...
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Rapid multi-criterial design of microwave components with robustness analysis by means of knowledge-based surrogates
PublikacjaManufacturing tolerances and uncertainties concerning material parameters, e.g., operating conditions or substrate permittivity are detrimental to characteristics of microwave components. The knowledge of relations between acceptable parameter deviations (not leading to violation of design specifications) and the nominal performance (not considering uncertainties), and is therefore indispensable. This paper proposes a multi-objective...
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New light on the photocatalytic performance of NH4V4O10 and its composite with rGO
PublikacjaSolar-driven photocatalysis has shown great potential as a sustainable wastewater treatment technology that utilizes clean solar energy for pollutant degradation. Consequently, much attention is being paid to the development of new, efficient and low-cost photocatalyst materials. In this study, we report the photocatalytic activity of NH4V4O10 (NVO) and its composite with rGO (NVO/rGO). Samples were synthesized via a facile one-pot...
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The regional energy transformation in the context of renewable energy sources potential
PublikacjaThe topics addressed in the article concern the problem of exploiting the potential of renewable energy sources (RES) at the regional level and the problem of the course of regional energy transition processes. Throughout the world, energy transition proceeds in a specific way for each country, due to the different potential of the selected RES and political, institutional and socio-economic conditions. Energy transition processes...
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Alternatywne metodyki wydzielania, identyfikacji oraz oznaczania siarki elementarnej w glebie z wykorzystaniem ekstrakcji do nisko polarnej cieczy, chromatografii cieczowej i spektrofotometrii
PublikacjaW niniejszej pracy - na podstawie przeglądu literatury oraz badań -opracowano nowe metodyki wydzielania, rozdzielania od składników towarzyszących, identyfikacji oraz oznaczania siarki elementarnej w glebach, szczególnie zanieczyszczonych nisko lotnymi produktami pochodzącymi z ropy naftowej. Zastosowano ekstrakcję siarki, nisko oraz średnio polarnych składników gleby do niepolarnego n-heksanu. Rozdzielano składniki ekstraktów...
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Parasites of the digestive tract of sheep and goats from organic farms in Western Pomerania, Poland
PublikacjaThe aim of the study was to determine the prevalence and intensity of parasite infection of the digestive tract in sheep and goats from the West Pomerania region following anti-parasite treatment. Feces were freely collected from sheep and goats kept on organic farms and subjected to analysis by the Willis-Schlaf and McMaster’s flotation methods. The mean extensity of infection by gastrointestinal parasites...
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Vibrational Sum-Frequency Generation Activity of a 2,4-Dinitrophenyl Phospholipid Hybrid Bilayer: Retrieving Orientational Parameters from a DFT Analysis of Experimental Data
PublikacjaThe vibrational nonlinear activity of films of 2,4-dinitrophenyl phospholipid (DNP) at the solid interface is measured by sum-frequency generation spectroscopy (SFG). Hybrid bilayers are formed by a LangmuirSchaefer approach in which the lipid layer is physisorbed on top of a self-assembled monolayer of dodecanethiol on Pt with the polar heads pointing out from the surface. The SFG response is investigated in two vibrational frequency...
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Thin layer of ordered boron-doped TiO2 nanotubes fabricated in a novel type of electrolyte and characterized by remarkably improved photoactivity
PublikacjaThis paper reports a novel method of boron doped titania nanotube arrays preparation by electrochemical anodization in electrolyte containing boron precursor – boron trifluoride diethyl etherate (BF3 C4H10O), simultaneously acting as an anodizing agent. A pure, ordered TiO2 nanotubes array, as a reference sample, was also prepared in solution containing a standard etching compound: ammonium fluoride. The doped and pure titania...
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PARTICLE SIZE ANALYSIS OF SUSPENSIONS IN REMOVING OF ORGANIC MATTER AND PHOSPHORUS FROM WASTEWATER AND SURFACE WATER
PublikacjaIn this paper the particle size of suspended solids in the removing of organic matter and phosphorus compounds from lake water and wastewater treated in the Ecological Treatment Systems (ETS) was analyzed. The invesigated materials were taken from two ETS located in Pomerania Region/Poland. Object in Swarzewo is 3rd stage of biological treatment of municipal wastewater, while object in Kartuzy has task to remove a phosphorus from...
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Effect of alkyl sulfate on the phase behavior of microemulsions stabilized with monoacylglycerols
PublikacjaIn this study the effect of an anionic surfactant (sodium dodecyl sulfate SDS) and oils (hydrocarbons: C12-C16) on the formation and phase behavior of the systems of oil/monoacylglycerols (MAG):SDS/propylene glycol/water has been investigated. The effects of the surfactant mixture on the phase behavior and the concentrationof water or oil in the systems were studied at three temperatures (50, 55, 60 C). Electrical conductivity...
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Determination of the active ingredient in pharmaceutical gel formulation by NIR spectroscopy
PublikacjaPharmaceuticals of their intended must be thoroughly controlled. The traditional analytical methods are very costly and time consuming. NIR spectroscopy allows to analyze pharmaceutical materials very quickly and with very low costs. First pharmaceutical applications of the NIR spectroscopy appeared with some incuriosity in the late 1960s. Application of NIR in the contemporary pharmaceutical industry is very large. The most common...
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Antibiotic resistance in wastewater, does the context matter? Poland and Portugal as a case study
PublikacjaAntibiotic resistance has been considered a major human health threat that may endanger the success of medicine. Recent studies have unveiled worldwide asymmetries of antibiotic resistance occurrence, being factors as diverse as climate, socioeconomic, or antibiotic use possible drivers of such asymmetric distribution. In Europe, where clinical antibiotic resistance is surveyed for more than 20 years, the European Center for Disease...
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Expedited Globalized Antenna Optimization by Principal Components and Variable-Fidelity EM Simulations: Application to Microstrip Antenna Design
PublikacjaParameter optimization, also referred to as design closure, is imperative in the development of modern antennas. Theoretical considerations along with rough dimension adjustment through supervised parameter sweeping can only yield initial designs that need to be further tuned to boost the antenna performance. The major challenges include handling of multi-dimensional parameter spaces while accounting for several objectives and...
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Accelerated multi-objective design of miniaturized microwave components by means of nested kriging surrogates
PublikacjaDesign of microwave components is an inherently multiobjective task. Often, the objectives are at least partially conflicting and the designer has to work out a suitable compromise. In practice, generating the best possible trade‐off designs requires multiobjective optimization, which is a computationally demanding task. If the structure of interest is evaluated through full‐wave electromagnetic (EM) analysis, the employment of...
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Expedited antenna optimization with numerical derivatives and gradient change tracking
PublikacjaDesign automation has been playing an increasing role in the development of novel antenna structures for various applications. One of its aspects is electromagnetic (EM)-driven design closure, typically applied upon establishing the antenna topology, and aiming at adjustment of geometry parameters to boost the performance figures as much as possible. Parametric optimization is often realized using local methods given usually reasonable...
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Enhanced gas sensing by graphene-silicon Schottky diodes under UV irradiation
PublikacjaThe effect of ultraviolet (UV) or blue irradiation on graphene/n-doped silicon Schottky junctions toward gas sensing was investigated. Schottky diodes were subjected to oxidizing nitrogen dioxide (NO2, 1–3 ppm) and reducing tetrahydrofuran (THF, 50–200 ppm), showing significantly different responses observed on the currentvoltage (I-V) characteristics, especially under UV light (275 nm). NO2 affected the resistive part of the forward region...
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Explainable machine learning for diffraction patterns
PublikacjaSerial crystallography experiments at X-ray free-electron laser facilities produce massive amounts of data but only a fraction of these data are useful for downstream analysis. Thus, it is essential to differentiate between acceptable and unacceptable data, generally known as ‘hit’ and ‘miss’, respectively. Image classification methods from artificial intelligence, or more specifically convolutional neural networks (CNNs), classify...