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Wyniki wyszukiwania dla: BIO-BASED THERMOPLASTIC POLYURETHANE ELASTOMER FULLY BIO-BASED LINEAR POLYESTER POLYOL CHEMICAL STRUCTURE THERMAL ANALYSIS MECHANICAL PROPERTIES
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Green and sustainable hydrogels based on quaternized chitosan to enhance wound healing
PublikacjaHydrogel-based biomaterials applied as wound dressings provide the wound with a moist environment, which facilitates tissue regeneration through granulation and re-epithelialization. The inherent flexibility and adjustable architecture of hydrogels enables incorporation of cells, antimicrobial drugs, growth factors, and bioactive compounds, which leads to expediting wound contraction and enhancing the regeneration process. The...
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Mechanical Properties and Wear Susceptibility Determined by Nanoindentation Technique of Ti13Nb13Zr Titanium Alloy after “Direct Laser Writing”
PublikacjaLaser treatment has often been applied to rebuild the surface layer of titanium and its alloys destined for long-term implants. Such treatment has always been associated with forming melted and re-solidified thin surface layers. The process parameters of such laser treatment can be different, including the patterning of a surface by so-called direct writing. In this research, pulse laser treatment was performed on the Ti13Nb13Zr...
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Electrochemically Induced Synthesis of Triphenylamine-based Polyhydrazones
PublikacjaTriphenylamine-based hydrazones were subjected to electropolymerization process that gave well conductive hydrazone based polymers. The first example of polyhydrazone formation during the electrochemical process was shown. The estimation of polymer structure was demonstrated using IR spectroelectrochemistry. The EPR spectroelectrochemistry allowed to explain why in some cases dimer couldn’t be formed. The results of electrochemical,...
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Chemical composition analysis and authentication of whisky
PublikacjaW pracy przedstawiono informacje dotyczące porównania różnych rodzajów whisky i innych napojów alkoholowych, identyfikacji różnych rodzajów whisky, oceny jakości i potwierdzania autentyczności whisky. Ponadto w pracy omówiono różne techniki stosowane w analizie whisky, takie jak gazową i cieczową chromatografię z różnymi detektorami (FID, AED, UV-vis), nos elektroniczny, spektrometrię absorpcji atomowej i spektrometrię mas. Ponadto...
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Alkali-activated slag (AAS) and OPC-based composites containing crumb rubber aggregate: Physico-mechanical properties, durability and oxidation of rubber upon NaOH treatment
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An Analysis of Elliptical-Rectangular Patch Structure on Multilayer Elliptic Cylinders
PublikacjaThe resonance frequency problem of an ellipticalrectangular patch mounted on multilayered dielectric coated elliptic conducting cylinder, is investigated in this paper. A fullwave analysis and a moment-method calculation are employed. The analysis is carried out considering the expansion of the field as a series of Mathieu functions. An additional theorem for Mathieu functions is utilized to investigate the non-confocal ellipse...
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Structural Changes and Their Implications in Foamed Flexible Polyurethane Composites Filled with Rapeseed Oil-Treated Ground Tire Rubber
PublikacjaThe utilization of post-consumer car tires is an essential issue from an ecological andeconomic point of view. One of the simplest and the least harmful methods is their material recyclingresulting in ground tire rubber (GTR), which can be further applied as fillers for polymer-basedcomposites. Nevertheless, insufficient interfacial interactions implicate the necessity of GTR modi-fication before introduction into polymer matrices....
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Effect of starch fillers on the dynamic mechanical properties of rubber biocomposite materials
PublikacjaIn the paper the results of dynamic mechanical study of the biocomposites containing one of two types of (potato or corn) strach used as fillers in different amount were discussed. The composites were obtained from rubbery mixture containing natural rubber (NR) as a main component. Thermomechanical analyses (by DMA) showed that the used quantity of strach fillers only slightly influence on the glass transition temperature of vulcanizates.
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Generative Process Planning with Reasoning based on Geometrical Product Specification
PublikacjaThe focus of this paper is on computer aided process planning for parts manufacture in systems of definite process capabilities, involving the use of multi-axis machining centers for parts shaping and grinding machines for finishing. It presents in particular a decision making scheme for setup determination as a part of generative process planning. The planning procedurę consists of two stages. The first stage is associated with...
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Modification of cellulosic filler with diisocyanates – volatile organic compounds emission assessment and stability of chemical structure over time
PublikacjaThis paper investigated the impact of type and content of diisocyanate on the structure of modified cellulose fillers. Four the most popular isocyanates were applied – isophorone, hexamethylene, toluene and methylene diphenyl diisocyanate – at loadings of 1–15 wt%. Chemical structure, and its short-term storage stability, were investigated for eight weeks. Moreover, the main volatile organic compounds detected during modification,...
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Machine learning applied to acoustic-based road traffic monitoring
PublikacjaThe motivation behind this study lies in adapting acoustic noise monitoring systems for road traffic monitoring for driver’s safety. Such a system should recognize a vehicle type and weather-related pavement conditions based on the audio level measurement. The study presents the effectiveness of the selected machine learning algorithms in acoustic-based road traffic monitoring. Bases of the operation of the acoustic road traffic...
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Machine learning applied to acoustic-based road traffic monitoring
PublikacjaThe motivation behind this study lies in adapting acoustic noise monitoring systems for road traffic monitoring for driver’s safety. Such a system should recognize a vehicle type and weather-related pavement conditions based on the audio level measurement. The study presents the effectiveness of the selected machine learning algorithms in acoustic-based road traffic monitoring. Bases of the operation of the acoustic road traffic...
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Design analysis of ORC micro-turbines making use of thermal energy of oceans
PublikacjaThe article presents the results of the analysis of energy conversion cycles making use of thermal energy of oceans. The objects of analysis were two cases of closed Organic Rankine Cycle (ORC) power plants, which were: the cycle in which the vapour of the working medium was produced by warm oceanic water in the circum-equatorial zone, and the so-called “arctic” cycle in which this vapour was produced by non-frozen water in the circumpolar...
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Synthesis, characterization and Luminescent Properties of New Coordination Polymers Based on p-tert Butylcalix[4]arene-tetracarboxylic acid and Lanthanine cations
PublikacjaA series of new coordination polymers based on p-tert-butylcalix[4]arene-tetracarboxylic acid with Eu3+, Tb3+wrer prepared by hydro and solvothermal methods. the obtained solid compounds were characterized by infrared and luminescence spectroscopy, powder X-ray diffraction, scianning electron microscopy and thermogravimetric anylisis. The infrared curves and the x-ray diffraction patterns indicate that the same crystalline structure...
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Application of nanofluids in thermal technologies
PublikacjaNanofluids it is a relatively new category of thermal fluids that can serve as coolants, both in single- and two phase systems. However application of nanofluids in industrial applications requires faultless their thermophysical properties. Existing models originally developed for liquid/solid particles mixtures (slurries) fail in case of nanofluids. Moreover correlations used to calcuate heat transfer coefficients of conventional...
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The Application of Cluster Analysis in the Assessment of the Weldability of Unalloyed Steels
PublikacjaNon-alloy steels constitute a large group of steels characterised by diversified chemical composition, structural morphology and a wide range of mechanical properties (determining weldability). The paper presents results of multidimensional analyses (based on cluster analysis) of 110 selected unalloyed steel grades. Properties adopted as diagnostic features included the chemical composition, mechanical properties (yield point)...
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A new quaternion-based encryption method for DICOM images
PublikacjaIn this paper, a new quaternion-based lossless encryption technique for digital image and communication on medicine (DICOM) images is proposed. We have scrutinized and slightly modified the concept of the DICOM network to point out the best location for the proposed encryption scheme, which significantly improves speed of DICOM images encryption in comparison with those originally embedded into DICOM advanced encryption standard...
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OIL-ASSISTED THERMO-MECHANICAL RECLAMATION OF GROUND TIRE RUBBER
PublikacjaNowadays, it is crucial to seek for the methods of by-products and waste utilization, considering both environmental and economic factors. The example of waste material generated in the massive amounts, which requires the attention is ground tire rubber generated during recycling of post-consumer car tires. It can be applied as a filler into different polymer matrices, but to enhance its effectivity proper modifications should...
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Development of novel smartphone-based methods of wine quality assessment
PublikacjaThe doctoral dissertation concerns the development of novel smartphone-based analytical methods of wine quality evaluation, which would be in line with the stipulations of green and equitable analytical chemistry. This solution is based on the analysis of biogenic amines and selected bioactive compounds. The dissertation is based on four articles containing the results of research which led to the development of smartphone-based...
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Effect of multi-walled carbon nanotubes properties on the photocatalytic activity of bismuth-based composites synthesised via an imidazolium ionic liquid
PublikacjaThe use of various types of multi-walled carbon nanotubes in the synthesis of bismuth oxybromide semiconductors via imidazolium ionic liquid was studied in detail. The effect of the MWCNT shape, specific surface area, and various diameters on the morphology, surface properties and photoactivity of the Bi-based composites has been investigated for the first time. So far, the literature has only shown the enhancement of photocatalytic...
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Structure and Magnetic Properties of Eu2CaCu2O6
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Structure and magnetic properties of Eu2CaCu2O6
PublikacjaDyskutowany jest nowy typ związku na bazie tlenku miedzi. Jest to pierwszy związek o tzw. zero wymiarowym charakterze Cu-O.
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Multimodal Surveillance Based Personal Protection System
PublikacjaA novel, multimodal approach for automatic detection of abduction of a protected individual, employing dedicated personal protection device and a city monitoring system is proposed and overviewed. The solution is based on combining four modalities (signals coming from: Bluetooth, fixed and PTZ cameras, thermal camera, acoustic sensors). The Bluetooth signal is used continuously to monitor the protected person presence, and in case...
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On the Structure of Time in Computational Semantics of a Variable-Step Solver for Hybrid Behavior Analysis
PublikacjaHybrid dynamic systems combine continuous and discrete behavior. Often, computational approaches are employed to derive behaviors that approximate the analytic solution. An important part of this is the approximation of differential equation behavior by numerical integration. The accuracy and computational efficiency of the integration usually depend on the complexity of the method and its implicated approximation errors, especially...
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Machine learning-based prediction of residual drift and seismic risk assessment of steel moment-resisting frames considering soil-structure interaction
PublikacjaNowadays, due to improvements in seismic codes and computational devices, retrofitting buildings is an important topic, in which, permanent deformation of buildings, known as Residual Interstory Drift Ratio (RIDR), plays a crucial role. To provide an accurate yet reliable prediction model, 32 improved Machine Learning (ML) algorithms were considered using the Python software to investigate the best method for estimating Maximum...
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Effect of crystallinity on structural, thermal, and in vitro dissolution properties of Na2O-CaO-Nb2O5/MgO-P2O5 glass-ceramics
PublikacjaThe impact of the crystallinity on structural, thermal, and in vitro dissolution properties were examined for Na2O- CaO-Nb2O5/MgO-P2O5 glasses/glass-ceramics. Glass-ceramics were synthesized via a spontaneous crystallization process. The Nb content in the materials increased with melting temperature, furthermore, the crystallinity is proportional to the Nb content. The presence of crystalline niobates and phosphates is confirmed...
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Microwave Ring Resonator Based Pressure Sensor
PublikacjaThis paper demonstrates a microwave pressure sensor, which is based on microstrip line-fed ring resonators. The first ring resonator is loaded with the concentric cylindrical shafts, while the same number of the hollow shanks as the shafts are mounted on the second ring resonator. The arrangement of the cylindrical shaft and hollow shank allows for mechanical movement between two substrates while maintaining electrical contact....
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Mass Spectrometry-Based Direct Analytical Techniques
PublikacjaDirect analysis of samples is considered as one of the most environmentally sustainable solutions in analytical chemistry. In the ideal case, such solutions do not require sample preparation and analytes separation steps, therefore do not consumpt harmful substances (or consumpt only minimum amounts of them) and do not generate hazardous waste. Technical solutions for direct analysis also offer miniaturized and field-portable analyzers...
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Influence of several biodegradable components added to pure and nanosilver-doped PMMA bone cements on its biological and mechanical properties
PublikacjaAcrylic bone cements (BC) are wildly used in medicine. Despite favorable mechanical properties, processability and inject capability, BC lack bioactivity. To overcome this, we investigated the effects of selected biodegradable additives to create a partially-degradable BC and also we evaluated its combination with nanosilver (AgNp). We hypothesized that using above strategies it would be possible to obtain bioactive BC. The Cemex...
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Intelligent microbearing project with memory of stress-strain history
PublikacjaTaking into account the increasing need of intelligent micro-bearing with memory, this paper presents the optimization, simulation and practical application of operating parameters(load carrying capacity, friction forces, friction coefficient, wear), simulation for hydrodynamic HDD micro-bearing with curvilinear nano-grooved journal profile. One of the reason of such journal profile is that this journal profile contributes to the...
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Arsenic-Based Warfare Agents: Production, Use, and Destruction
PublikacjaSince the beginning of time, civilizations have looked for more creative ways to dominate and defeat their enemies. The rapid development of the chemical industry just before the Second World War started the era of modern chemical weapon production based on poisons, including toxic arsenic compounds. This paper provides a detailed overview of the production, usage and destruction of this dangerous chemical weapon. Milestones include:...
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Synergistic effects of hybrid advanced oxidation processes (AOPs) based on hydrodynamic cavitation phenomenon – A review
PublikacjaHigh-performance water treatment systems based on cavitational processes have received an increasing interest of scientific community in the past few decades. Numerous studies indicated the advantageous application of hydrodynamic cavitation as an alternative, reagent-free treatment method of various pollutants in water. Both approaches were proved as an effective method to achieve mineralization of many organic contaminants as...
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Thermal Properties of PLA/TPS Blends
PublikacjaFour types of polymer compositions having different amount of potato starch, glycerin and poly(lactic acid) was obtained and characterized by DSC. Adding of TPS to PLA lowered Tg.
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Complexes of silanethiolate ligands: Synthesis, structure, properties and application
PublikacjaThe purposeful syntheses of silanethiolate complexes started approximately in the mid-eighties of the 20th century but no summary of the synthetic efforts has been reported till now. The synthetic methods and the resulting complexes have some common features, which are emphasized throughout the review. Thereby specific difficulties during synthesis are outlined and the structures, properties and possible applications of the resulting...
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Detection of Closing Crack in Beam Based on Responses Induced by Harmonic Excitation
PublikacjaThe non-linear contact model was chosen to simulate the closed crack in the cantilever beam. The study examines the shape and characteristics of the phase diagram of a cantilever beam with closed cracks. It investigates how various crack properties influence the geometry of the phase diagram and proposes a method for identifying cracks based on their features. The area of each closed curve in the phase diagram is determined using...
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Analysis of the Capability of Deep Learning Algorithms for EEG-based Brain-Computer Interface Implementation
PublikacjaMachine learning models have received significant attention for their exceptional performance in classifying electroencephalography (EEG) data. They have proven to be highly effective in extracting intricate patterns and features from the raw signal data, thereby contributing to their success in EEG classification tasks. In this study, we explore the possibilities of utilizing contemporary machine learning algorithms in decoding...
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PVA-Based Films with Strontium Titanate Nanoparticles Dedicated to Wound Dressing Application
PublikacjaBioactive materials may be applied in tissue regeneration, and an example of such materials are wound dressings, which are used to accelerate skin healing, especially after trauma. Here, we proposed a novel dressing enriched by a bioactive component. The aim of our study was to prepare and characterize poly(vinyl alcohol) films modified with strontium titanate nanoparticles. The physicochemical properties of films were studied,...
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Transport of paracetamol in swellable and relaxing polyurethane nanocomposite hydrogels
PublikacjaPolyurethane hydrogels are potentially attractive materials for biomedical applications. They are able to absorb large amount of water, biological fluids or active substances, and thus, they have potential to be used as absorbents or wound-healing dressings. They are also used for the controlled release of therapeutics because of their capacity to embed biologically active agents in their water-swollen network. The presence of...
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Biological and mechanical properties of bone cement with nanoparticles - in vivo and in vitro research
PublikacjaDespite antibiotics preventive treatment, before and after an implant implementation, risk of infection are real. These infections at the implant surface develop in a few months after applying them into the body. To prevent the development of bacteria and to reduce the risk of infection, implants coated with nanoparticles come into use. The Mechanical Department of the Technical University of Gdańsk carried out a research with...
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Gigantic electro-chemo-mechanical properties of nanostructured praseodymium doped ceria
PublikacjaSome oxygen defective fluorites are non-Newnham electrostrictors, i.e., the electromechanical response does not depend on their dielectric properties. Here, we show gigantic electrostriction in nanocrystalline 25 mol% praseodymium doped ceria (PCO) bulk ceramics. The material was fabricated with a fieldassisted spark plasma sintering (SPS) process from high-purity nanoscale PCO powders (<20 nm). The SPS process consolidates the...
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Thermal Biomass Conversion: A Review
PublikacjaIn this paper, the most important methods of thermal conversion of biomass, such as: hydrothermal carbonization (180–250 °C), torrefaction (200–300 °C), slow pyrolysis (carbonization) (300–450 °C), fast pyrolysis (500–800 °C), gasification (800–1000 °C), supercritical steam gasification, high temperature steam gasification (>1000 °C) and combustion, were gathered, compared and ranked according to increasing temperature. A comprehensive...
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ON ESTIMATION OF OCCUPANT SAFETY IN VEHICULAR CRASHES INTO ROADSIDE OBSTACLES USING NON-LINEAR DYNAMIC ANALYSIS
PublikacjaThe article describes a comparison of two general methods of occupants safety estimation based on a numerical examples. The so-called direct method is mainly based on the Head Injury Criterion of a crash test dummy in a vehicle with passive safety system while the indirect method uses a European standards approach to estimate impact severity level. Numerical simulations in LS-DYNA have been conducted.
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Electro-mechanical shear buckling of piezoelectric nanoplate using modified couple stress theory based on simplified first order shear deformation theory
PublikacjaThis paper studies the electro-mechanical shear buckling analysis of piezoelectric nanoplate using modified couple stress theory with various boundary conditions.In order to be taken electric effects into account, an external electric voltage is applied on the piezoelectric nanoplate. The simplified first order shear deformation theory (S-FSDT) has been employed and the governing differential equations have been obtained using...
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Novel stationary phases based on asphaltenes for gas chromatography
PublikacjaWe present the results of investigations on the possibility of the application of the asphaltene fraction isolated from the oxidized residue from vacuum distillation of crude oil as a stationary phase for gas chromatography. The results of the investigation revealed that the asphaltene stationary phases can find use for the separation of a wide range of volatile organic compounds. The experimental values of Rohrschneider/McReynolds...
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Port-based approach to distributed transfer function method
PublikacjaIn the paper there is presented an uniform, port-based approach to modeling of both lumped and distributed parameter systems. Port-based model of distributed system has been defined by application of distributed transfer function method (DTFM). The approach proposed combines versatility of port - based modeling and accuracy of distributed transfer function method. It enables to formulate appropriate input data for computer analysis...
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Structure and properties of liquid Al–Cu alloys: Empirical potentials compared
PublikacjaWe report on the structure and mass transport properties of liquid Al–Cu alloys predicted by two recently-developed empirical many-body potentials: MEAM (Jelinek et al., 2012) and EAM-ADP (Apostol and Mishin, 2011), and by the well-known Gupta potential. Total and partial pair correlation functions, angular distribution functions, densities, coordination numbers and self-diffusion coefficients are compared with published experimental...
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From Structure to Luminescent Properties of B2O3-Bi2O3-SrF2 Glass and Glass-Ceramics Doped with Eu3+ Ions
PublikacjaGlass-ceramics with the composition B2O3 -Bi2O3 -SrF2 were synthesized by the conventional melt-quenching technique and subsequent crystallization of the parental glasses. The temperature at which the ceramization was carried out was selected based on differential scanning calorimetry (DSC) analysis. The structure of the studied materials and the formation of SrF2 nanocrystals were confirmed by the Fourier-transform infrared spectroscopy...
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Green monoterpenes based deep eutectic solvents for effective BTEX absorption from biogas
PublikacjaThe combustion of biogas which contains significant amounts of monoaromatic hydrocarbons, i.e. benzene, ethylbenzene, toluene, and xylene (BTEX) can cause many technological, environmental, and health problems. Therefore, in these studies, a new physical absorption method based on deep eutectic solvents (DES) consisting of monoterpenes and carboxylic acids was developed for BTEX removal. A total of 39 DES were synthesized, of which...
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Non-linear strain rate analysis of earthquake-induced pounding between steel buildings
PublikacjaPast and recent earthquakes have shown that ground motions may cause severe structural damage to civil engineering structures. Earthquake-induced pounding between adjacent buildings has been identified as one of the reasons which intensifies damages. The aim of this paper is to show the results of the detailed nonlinear FEM analysis of earthquake-induced pounding between two steel buildings. The elastic – perfectly plastic material...
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Analysis of turnouts with non-linear curvature of diverging track for different train running speeds
PublikacjaThe paper deals with the issue of shaping a variable curvature in the diverging track of the railway turnout. Solution without a circular arc in the central zone, comprising two zones of non-linear curvature, of the same length, having zero curvature values at the end points, was adopted as a model, on the basis of the previously conducted dynamic tests. Optimum type of curvature was selected from the point of view of the kinematic...