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Effects of metallic silver island films on resonance energy transfer between N,N´-(dipropyl)-tetramethylindocarbocyanine (Cy3)- and N,N´-(dipro- pyl)-tetramethylindodicarbocyanine ( Cy5 )-labeled DNA.
PublikacjaZbadano nową metodę zwiększania odległości rezonansowego przekazywania energii poprzez umieszczanie znakowanych donorami i akceptorami oligomerów DNA pomiędzy dwoma płytkami pokrytymi nanocząsteczkami metalicznego srebra.
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Badanie właściwości czujników wilgotności na bazie nanocząstek tlenku cynku
PublikacjaW celu pomiaru wilgotności szeroko stosowane są czujniki elektryczne. Warstwą czynną, zmieniającą swoje właściwości pod wpływem pary wodnej, stanowią najczęściej materiały ceramiczne lub polimerowe. Tlenek cynku jest jednym z materiałów ceramicznych będących dobrym kandydatem do zastosowania go jako warstwy czynną w czujnikach wilgotności. W tej pracy przedstawiono wyniki badań właściwości struktur czujnikowych z warstwą tlenku...
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Uwodornienie oleju sojowego i rzepakowego na katalizatorach miedziowych promotorowanych niklem i tlenkiem glinu. Hydrogenation of soybean and rapeseed oil with copper catalysts activated with nickel and aluminium oxide
PublikacjaBadano nowy typ katalizatorów miedziowych promotorowanych niklem, o stosunku Cu do Ni w granicach od 1:0,0036 do 1:0,018 w?w, osadzonych na Al2O3, przeznaczonych do selektywnego uwodornienia kwasu linolenowego w olejach roślinnych. Uwodornienie prowadzono w laboratoryjnym reaktorze typu "dead end" na oleju sojowym i rzepakowym, a kontakty mieszane - w stęż. 0,5% i 1% Cu. Na podstawie badań stwierdzono, że promotorowanie znacząco...
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Design, engineering, and performance of nanorod-Fe2O3@rGO@LaSrFe2-Co O6 (n = 0, 1) composite architectures: The role of double oxide perovskites in reaching high solar to hydrogen efficiency
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Electrophoretic co-deposition of Mn1.5Co1.5O4, Fe2O3 and CuO: Unravelling the effect of simultaneous addition of Cu and Fe on the microstructural, thermo-mechanical and corrosion properties of in-situ modified spinel coatings for solid oxide cell interconnects
PublikacjaA systematic microstructural, thermo-mechanical and electrical characterization of simultaneous Fe–Cu doped Mn–Co spinel coatings processed by electrophoretic co-deposition on Crofer 22 APU is here reported and discussed. An innovative approach for the simultaneous electrophoretic deposition of three spinel precursors is designed, conceived and optimised, with the aim of outlining time- and energy-saving spinel modification routes....
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La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3-δ oxygen electrodes for solid oxide cells prepared by polymer precursor and nitrates solution infiltration into gadolinium doped ceria backbone
PublikacjaInfiltration is a method, which can be applied for the electrode preparation. In this paper oxygen electrode is prepared solely by the infiltration of La0.6Sr0.4Co0.2Fe0.8O3‐δ (LSCF) into Ce0.8Gd0.2O2-δ (CGO) backbone. The use a polymer precursor as an infiltrating medium, instead of an aqueous nitrate salts solution is presented. It is shown that the polymer forms the single-phase perovskite at 600 °C, contrary to the nitrates...
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Functional properties of packaging materials from chemical modified stach.
PublikacjaThis work is focused on study of the mechanical and barrier properties of films obtained from potato starch modified with sodium tetrahydroxozincate generated in situ. The results show that the chemical modification of starch improved the water vapor permeability by about 25%, unfortunately decreased the elongation at break by 60%, when compared with unmodified starch films. However, placitization of films with glycerol at a concentration...
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The Physicochemical and Antibacterial Properties of Chitosan-Based Materials Modified with Phenolic Acids Irradiated by UVC Light
PublikacjaThis paper concerns the physicochemical properties of chitosan/phenolic acid thin films irradiated by ultraviolet radiation with wavelengths between 200 and 290 nm (UVC) light. We investigated the preparation and characterization of thin films based on chitosan (CTS) with tannic (TA), caffeic (CA) and ferulic acid (FA) addition as potential food‐packaging materials. Such materials were then exposed to the UVC light (254 nm) for...
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Application of ferric chloride for arsenic removal in the integrated process: coagulation/microfiltration
PublikacjaThe study presents results of using iron coagulation integrated with microfiltration to remove arsenic from water. Tested samples of natural groundwater contained approximately 32 μg/L of arsenic, 0.13 mg/L of iron and 0.085 mg/L of manganese. As a coagulant the aqueous solution of ferric chloride was dosed in portions from 1.0 to 10.5 mg/L. In the research microfiltration membranes with 400 kDa MWCO were used. Tests indicated...
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Nitrogen-Incorporated Boron-Doped Nanocrystalline Diamond Nanowires for Microplasma Illumination
PublikacjaThe origin of nitrogen-incorporated boron-doped nanocrystalline diamond (NB-NCD) nanowires as a function of substrate temperature (Ts) in H2/CH4/B2H6/N2 reactant gases is systematically addressed. Because of Ts, there is a drastic modification in the dimensional structure and microstructure and hence in the several properties of the NB-NCD films. The NB-NCD films grown at low Ts (400 °C) contain faceted diamond grains. The morphology...
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Conducting polymers for biodegradable metallic implants
PublikacjaNowadays permanent metallic cardiovascular stents are long-term implants. The long-time presence of such an implant in human body can cause overgrowth of tissue within the treated portion of the vessel, blockage of the circulatory system and many other clinical complications, such as thrombosis, prolonged physical irritations or chronic inflammation. Therefore, in recent years, there is an interest to create biodegradable metallic...
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Badania stabilności chemicznej kompozytowego elektrolitu 3-YSZ-Al2O3 w stosunku do materiałów elektrodowych do zastosowania w średniotemperaturowych ogniwach paliwowych
PublikacjaJednym z podstawowych wymogów stawianych mate- riałom na elektrolity do średniotemperaturowych ogniw paliwowych IT-SOFC (ang. intermediate-temperature solid oxide fuel cells) jest ich kompatybilność chemiczna z elektrodami w temperaturach zarówno eksploatacji, jak i wytwarzania ogniw. W celu sprawdzenia, czy badany w pracy kompozytowy elektrolit o osnowie z częściowo stabilizowanego ditlenku cyrkonu i z wtrąceniami tlenku glinu...
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RAMAN DIAGNOSTICS OF CVD DIAMOND GROWTH
PublikacjaDevelopment of Raman spectroscopic system for diagnostics of growth of diamond and BDD (Boron- Doped-Diamond) thin films during μPA CVD (Microwave Plasma Assisted Chemical Vapour Deposition) process is described. Raman studies of such films were carried out as in-situ monitoring of film deposition as ex-situ measurements conducted for a sample outside the reaction vessel after manufacturing process. Modular system for the in-situ...
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[N,N'-Bis(2,6-diisopropylphenyl)pentane-2,4-diamine(1-)-2[kappa]2N,N']-[mu]2-chlorido-1:2[kappa]2Cl:Cl-chlorido-2[kappa]Cl-bis(1,2-dimethoxyethane-1[kappa]2O,O')iron(II)lithium
PublikacjaIn the title compound, [FeLi(C29H41N2)Cl2(C4H10O2)2], theFeII atom is coordinated by two N and two Cl atoms,generating a distorted FeN2Cl2 tetrahedral geometry. Additionally,one of the chloride atoms bridges to a lithium ion,which is solvated by two dimethoxyethane molecules and iscoordinated in a distorted trigonal-bipyramidal environment.The central Fe, Cl (*2) and Li atoms are coplanar with amaximum deviation of 0.034 A ° .
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From evil demiurge to caring hero: Images of geneticists in the movies
PublikacjaAlthough images of science and scientists depicted in popular culture have been criticized as an exaggeration and fear mongering, the cinema is an important resource that influences individuals’ beliefs about science. Because popular depictions of science play a crucial role in constructing the public’s ‘scientific imaginary’ they constitute an inherent dimension of the social understanding of science and are as important for...
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Fully scalable one-pot method for the production of phosphonic graphene derivatives
PublikacjaGraphene oxide was functionalized with simultaneous reduction to produce phosphonated reduced graphene oxide in a novel, fully scalable, one-pot method. The phosphonic derivative of graphene was obtained through the reaction of graphene oxide with phosphorus trichloride in water. The newly synthesized reduced graphene oxide derivative was fully characterized by using spectroscopic methods along with thermal analysis. The morphology...
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AN OVERVIEW OF HEAT TRANSFER ENHANCEMENT BASED UPON NANOPARTICLES INFLUENCED BY INDUCED MAGNETIC FIELD WITH SLIP CONDITION VIA FINITE ELEMENT STRATEGY
PublikacjaThe mathematical model of heat generation and dissipation during thermal energy transmission employing nanoparticles in a Newtonian medium is investigated. Dimensionless boundary layer equations with correlations for titanium dioxide, copper oxide, and aluminium oxide are solved by the finite element method. Parameters are varied to analyze their impact on the flow fields. Various numerical experiments are performed consecutively...
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Przydatność białka rybiego w postaci kolagenu lub żelatyny oraz polisacharydu - kapa-karagenu do wytwarzania aktywnych opakowań biodegradowalnych = Usefulness of fish collagen, gelatin and carrageenan for preparation of active biodegradable packages
PublikacjaSummary - The possibility of use of protein films made of fish collagen or gelatin as well as polysaccharide carrageenan films as carriers of enzymes (lysozyme or lysostaphyne), for preparation of microbiologically active packages, was investigated. It was found that crosslinking of such systems with N-[3(dimethylamino)propyl]-N'-ethylcarboimide (EDC) does not influence the activity of lysozyme immobilized in the films (Table 1)....
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Novel ABTS-dot-blot method for the assessment of antioxidant properties of food packaging
PublikacjaThe new ABTS-dot-blot method for the direct determination of antioxidant activity of active packaging that is in contact with foodstuffs has been developed. The usefulness of the new method was verified with the use of agarose, pork gelatin, bacterial cellulose and cellulose-chitosan films with incorporated standard antioxidant – Trolox or plant phytochemicals derived from three types of berry juices (chokeberry, blue-berried honeysuckle,...
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Evaluation of La 2 Ni 0.5 Cu 0.5 O 4+δ and Pr 2 Ni 0.5 Cu 0.5 O 4+δ Ruddlesden-Popper-type layered oxides as cathode materials for solid oxide fuel cells
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Wpływ procesu redukcji na właściwości strukturalne i mechaniczne szkieł tlenkowych z grupy (Pb,Bi)-(Si,Ge)-O = Influence of reduction process on the structural and mechanical properties of (Pb,Bi)-(Si,Ge)-O oxide glasses
PublikacjaThe effect of the reduction process in H2 at 380 °C on the microstructure and elemental composition of a glass Bi0.4Pb0.2Si0.4Ox has been investigated. It has been shown that after reduction a clearly separated top layer with a thickness of approx. 50 µm was formed on the surface of the sample. This layer is depleted of oxygen and has higher electrical conductivity than the interior of the glass. It has also been found that some...
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Mechanism of hopping conduction in Be–Fe–Al–Te–O semiconducting glasses and glass–ceramics
PublikacjaElectrical properties of beryllium-alumino-tellurite glasses and glass–ceramics doped with iron ions were studied using impedance spectroscopy. The conductivity was measured over a wide frequency range from 10 mHz to 1 MHz and the temperature range from 213 to 473 K. The D.C. conductivity values showed a correlation with the Fe-ion concentration and ratio of iron ions on different valence states in the samples. On the basis of...
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Structural and electronic properties of diamond-composed heterostructures
PublikacjaDiamond is a promising material for 21st century electronics due to its high thermal and electronic conductivity, biocompatibility, chemical stability, high wear resistance, and possibility of doping. However, the semiconductor properties of diamond, especially free-standing films, have not been fully explored. Nor have their integration with polymers and fragile materials and their applications as electronic components. In this...
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DETERMINATION OF SP3 FRACTION IN ta-C COATING USING XPS AND RAMAN SPECTROSCOPY
PublikacjaThe paper presents results of studies on the structure of tetrahedral amorphous carbon films (ta-C) with a thickness in the range from 20 to 280 nm, deposited using pulsed vacuum arc technique with an electromagnetic Venetian blind plasma filter. The results of the phase structure analysis, obtained using visible Raman spectroscopy and UV Raman spectroscopy methods, showed a strong dependence of the results on the presence, on...
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Nucleation and growth of CVD diamond on fused silica optical fibres with titanium dioxide interlayer
PublikacjaNucleation and growth processes of thin diamond films on fused silica optical fibres have been investigated. Fibres were coated with diamond film using microwave plasma enhanced chemical vapour deposition (µPE CVD) system. Since the growth of diamond on the fused silica glass requires high seeding density, two types of glass pre-treatment were applied: titanium dioxide (TiO2) interlayer deposition and sonication in nanodiamond...
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An adaptive approach to non-destructive evaluation (NDE) of cast irons containing precipitated graphite particles with the help of magnetoacoustic emission
PublikacjaPhysical properties of cast irons strongly depend on both their microstructure and the presence of casting defects. The paper analyses the possibility of application of magnetoacoustic emission (MAE) for nondestructive detection of flawed cast iron components. The investigated samples containing dross, chunky graphite and lamellar graphite were compared with the reference, flawless, spheroidal cast iron sample. The optimisation...
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Airborne wear particle emission from train brake friction materials with different contents of steel and copper fibres
PublikacjaThis study investigated the influence of the amount of steel and copper fibres in a train brake friction material on the tribological performance, emission intensity and characteristics of airborne wear particles. The particles were generated on a pin-on-disc tribometer under controlled friction and environmental conditions. It was found that the steel fibre results in a more intensive emission of 0.3–10 μm particles compared to...
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Acid–base properties of the crosslinked polysaccharide–polyimine layer deposited on the surface of siliceous material (acid–base properties of the polysaccharide–polyimine layer)
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On small signal capacitance spectra of organic diode formed by ITO-palladium phthalocyanine-Al sandwich system
PublikacjaPraca poświęcona jest widmom małosygnalowej pojemności w zakresie 25 Hz-1 MHz i charakterystyce prądowo-napięciowej planarnego układu utworzonego przez ITO/ftalocyanina palladu/Al.
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Small-signal admittance for Schottky-Richardson emission into an organic layer
PublikacjaPraca przedstawia małosygnalową admitancję emisji Schottky'ego-Richardsona do warstwy organicznej. Analiza obejmuje obie składowe zespolonej odpowiedzi.
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Electrochromic foil-based devices: optical transmittance and modulation range, effect of ultraviolet irradiation,and quality assessment by 1/f current noise
PublikacjaPrzedstawiono technologię wytwarzania elementów wykazujących zjawisko elektrochromizmu - zmiany transmitancji optycznej pod wpływem gromadzenia ładunku. Pokazano, że zastosowanie warstwy odbijającej może poprawić stopień zmian transmitancji optycznej. Ponadto, pokazano, że zjawiska losowe generujące szum typu 1/f w tych elementach może być wykorzystane do oceny ich jakości.
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Fabrication and characterization of composite TiO2 nanotubes/ boron-doped diamond electrodes towards enhanced supercapacitors
PublikacjaThe composite TiO2 nanotubes / boron-doped diamond electrodes were deposited using Microwave Plasma Enhanced Chemical Vapor Deposition resulting in the improved electrochemical performance. This composite electrode can deliver high specific capacitance of 7.46 mF cm‐− 2 comparing to boron-doped diamond (BDD) deposited onto flat Ti plate (0.11 mF cm‐− 2).The morphology and composition of composite electrode were characterized...
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Ordered titania nanotubes layer selectively annealed by laser beam for high contrast electrochromic switching
PublikacjaThe phase conversion from amorphous into crystalline one in the selected area of as-anodized titania nanotubes was achieved via laser treatment. The optimized processing parameters enable fast, one-minute crystallization of titania within an area limited by a shadow mask and without any morphology damage of ordered TiO2 tubular film. The laser annealed titania nanotubes could be easily overgrown by a conducting polymer without...
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Interactions between amphotericin B 3-(N',N'-dimethylamino)propyl amide and cellular membrane components in Langmuir monolayers
PublikacjaPublikacja zawiera charakterystykę monowarstw Langmuir'a tworzonych przez pochodną amfoterycyny B tj.amid 3-(N',N'-dimetyloamino)propylowy (AMA) oraz wyniki badań nad jej oddziaływaniem z cholesterolem, ergosterolem i fosfolipidami. Znaleziono, iż stan jonowy cząsteczki pochodnej AMA, a także jej wielkość mają znaczący wpływ na właściwości biologiczne związku.
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Small signal spectra of complex capacitance obtained on organic heterojunction formed from copper phthalocyanine and perylene dye
PublikacjaPraca przedstawia małosygnałowe widma zespolonej pojemności otrzymane na strukturze z heterozłączem organicznym CuPc/Py-PTC w zakresie 25Hz-1MHz.
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Optical and photoelectrochemical characterization of pulsed laser deposited Bi4V2O11, BICUVOX, and BIZNVOX
PublikacjaThin layers of three compounds from the BIMEVOX family (Bi4V2O11, Bi2V0.9Cu0.1O5.35, and Bi2V0.9Zn0.1O5.35) were prepared via pulsed laser deposition technique on quartz, silicon, and platinum foil and tested as photoanodes for water photooxidation. The film formation, as well as the crystallization upon heating, was characterized using X-ray diffraction and Raman spectroscopy. The optical properties were investigated using spectroscopic...
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Structure and electrochemical reactivity of 3-[tris(2-methoxyethoxy)silyl]-propanethiol adsorbed on silver surface
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Impact of low-temperature sintering on the Fe-based amorphous coatings
PublikacjaBulk metallic glasses (BMGs) have gained a lot of attention in recent years due to their outstanding properties such as high hardness and excellent wear and corrosion resistance. However, they are restricted in industrial applications due to their extreme brittleness. Iron based amorphous coatings from BMGs are the best solution to use them by overcoming the problem of extreme brittleness. The coatings can be sprayed by various...
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The study on possibilities of recovery non-magnetic fraction by utilisation the magnetic separation technology in conditions of KGHM Polska Miedz S.A. division of concentrators = Próby odzysku frakcji niemagnetycznej metodą separacji magnetycznej w warunkach KGHM Polska Miedź S.A. Oddział Zakłady Wzbogacania Rud
PublikacjaW referacie przybliżono wyniki badań prowadzonych w kierunku określenia możliwości odzysku frakcji niemagnetycznej i słabomagnetycznej ze strumieni materiałowych O/ZWR, poprzez wykorzystanie metody separacji magnetycznej. Przeprowadzony cykl badawczy obejmował analizę występowania frakcji magnetycznej i związanej z nią frakcji niemagnetycznej w obiegach technologicznych w Rejonie ZWR Lubin, oraz możliwości ich odzysku. Uzyskane...
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Towards high quality ITO coatings: the impact of nitrogen admixture in HiPIMS discharges
PublikacjaThe paper reports controlled deposition of optically transparent and electrically conductive ITO films prepared by a combination of rf (13.56 MHz) and High Power Impulse Magnetron Sputtering (HiPIMS) systems without any post deposition thermal treatment/annealing. It is shown that (i) reactive admixture of N2 gas to the process and (ii) pressure in the deposition chamber enable to optimize optical properties of ITO films. Furthermore,...
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Emission of 1.3–10 nm airborne particles from brake materials
PublikacjaOperation of transport vehicle brakes makes a significant contribution to airborne particulate matter in urban areas, which is subject of numerous studies due to the environmental concerns. We investigated the presence and number fractions of 1.3–10 nm airborne particles emitted from a low-metallic car brake material (LM), a non-asbestos organic car brake material (NAO) and a train brake cast iron against a cast iron. Particles...
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Representation of magnetic hysteresis in single-phase transformer for circuit simulations
PublikacjaThe paper presents a mathematical model for the hysteresis phenomenon in a multi-winding single-phase core type transformer. In the circuit transformer model, it is assumed that there is a flux common Φ to all windings as nonlinear and hysteretic function of the total currents Θ (Ampere turns) of all windings. To simulate magnetic behaviour of the iron core the feedback scalar Preisach model of hysteresis is developed. The Preisach...
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X-Ray Computer Tomography Study of Degradation of the Zircaloy-2 Tubes Oxidized at High Temperatures
PublikacjaThe investigations of high-temperature oxidation of zirconium alloys, applied for fuel pellets in nuclear power plants, are usually limited to oxidation kinetics, phase transformations and microstructural characterization. The purpose of this research was to characterize the degradation phenomena occurring within oxide layer and at the interface oxide/metal, on internal and external Zircaloy-2 tube...
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Electrical characterization of diamond/boron doped diamond nanostructures for use in harsh environment applications
PublikacjaThe polycrystalline boron doped diamond (BDD) shows stable electrical properties and high tolerance for harsh environments (e.g. high temperature or aggressive chemical compounds) comparing to other materials used in semiconductor devices. In this study authors have designed electronic devices fabricated from non-intentionally (NiD) films and highly boron doped diamond structures. Presented semiconductor devices consist of highly...
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Fabrication and characterization of boron-doped nanocrystalline diamond-coated MEMS probes
PublikacjaFabrication processes of thin boron-doped nanocrystalline diamond (B-NCD) films on silicon-based micro- and nano-electromechanical structures have been investigated. Nanocrystalline boron doped -diamond (B-NCD) films were deposited using Microwave Plasma Assisted Chemical Vapour Deposition (MW PA CVD) method. The variation of B-NCD morphology, structure and optical parameters were particularly investigated. The use of truncated...
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Potentiometric Oxygen Sensor with Solid State Reference Electrode
PublikacjaThe concentration or the partial pressure of oxygen in an environment can be determined using different measuring principles. For high temperature measurements of oxygen, ceramic-based sensors are the most practical. They are simple in construction, exploration and maintenance. A typical oxygen potentiometric sensor consists of an oxygen ion conducting solid electrolyte and two electrodes deposited...
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Photoinduced K+ Intercalation into MoO3/FTO Photoanode—the Impact on the Photoelectrochemical Performance
PublikacjaIn this work, thin layers of MoO3 were tested as potential photoanodes for water splitting. The influence of photointercalation of alkali metal cation (K+) into the MoO3 structure on the photoelectrochemical properties of the molybdenum trioxide films was investigated for the first time. MoO3 thin films were synthesized via thermal annealing of thin, metallic Mo films deposited onto the FTO substrate using a magnetron sputtering...
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Wpływ surfaktantu anionowego LAS na mobilność frakcji fosforu w osadzie czynnym w zmiennych warunkach fizyczno-chemicznych
PublikacjaPrzedstawiono wyniki badań wpływu anionowego surfaktantu LAS na mobilność frakcji fosforu w osadzie czynnym. Podstawową rolę w procesie uwalniania fosforu do cieczy nadosadowej w warunkach beztlenowych pełniły: frakcja związana z substancją organiczną i frakcja związana z żelazem.
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Engineering Au nanoparticle arrays on SiO2 glass by pulsed UV laser irradiation
PublikacjaWe study semi-regular arrays of Au nanoparticles (NP) obtained via UV laser irradiation of thin Au films on glass substrate. The NP structures are prepared from films of a thickness up to 60 nm produced by discharge sputtering or pulsed laser deposition, and annealed by nanosecond laser pulses at 266 or 308 nm, respectively, at fluencies in the range of 60-410 mJ/cm2. For the rare- and close-packed NP structures, consistent description...
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Synergistic effects in micellization and surface tension reduction in nonionic gemini S-10 and cationic RTAB surfactants mixtures
PublikacjaMixtures of nonionic gemini surfactant S-10 (α,α′-[2,4,7,9-tetrametyl-5-decyne-4,7-diyl]bis[ω-hydroxy -polioxyetylene] with cationic alkyltrimethylammonium bromides of different alkyl chain length (RTAB) were investigated. Basing on surface tension measurements the cmc values and other adsorption parameters were found. The Clint, Rubing’s and Rosen theories were applied for evaluation of the synergistic effects in mixed films and...