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Wyniki wyszukiwania dla: SOLID STATE REACTIONS
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Potentiometric Solid-Contact Ion-Selective Electrode for Determination of Thiocyanate in Human Saliva
PublikacjaA new solid-contact potentiometric ion-selective electrode for the determination of SCN− (SCN-ISE) has been described. Synthesized phosphonium derivative of calix[4]arene was used as a charged ionophore. The research included selection of the ion-selective membrane composition, determination of the ISEs metrological parameters and SCN-ISE application for thiocyanate determination in human saliva. Preparation of the ISEs included...
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Synthesis, single crystal growth and properties of Sr5Pb3ZnO12
PublikacjaAbstract The novel Sr5Pb3ZnO12 oxide was synthesized by the solid-state reaction method. The crystal structure was studied by means of the powder x-ray diffraction Rietveld method and was found to be similar to 3 other previously known Sr5Pb3MO12 compounds (M = Co, Ni, Cu). Crystals of several hundred microns in size of the new phase were grown in molten sodium chloride and imaged using confocal optical and scanning electron microscopy....
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Security of Cryptocurrencies: A View on the State-of-the-Art Research and Current Developments
Publikacja[Context] The goal of security is to protect digital assets, devices, and services from being disrupted, exploited or stolen by unauthorized users. It is also about having reliable information available at the right time. [Motivation] Since the inception in 2009 of the first cryptocurrency, few studies have been undertaken to analyze and review the state-of-the-art research and current developments with respect to the security...
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Studies of Nonlinear Sound Dynamics in Fluids Based on the Caloric Equation of State
PublikacjaThe sound speed and parameters of nonlinearity B/A, C/A in a fluid are expressed in terms of coefficients in the Taylor series expansion of an excess internal energy, in powers of excess pressure and density. That allows to conclude about features of the sound propagation in fluids, the internal energy of which is known as a function of pressure and density. The sound speed and parameters of nonlinearity in the mixture consisting...
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Annals of Solid and Structural Mechanics
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IZVESTIYA-PHYSICS OF THE SOLID EARTH
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System architecture of an INSPIRE-compliant green cadastre system for the EU Member State of Poland
PublikacjaIn response to the need for a sustainable agricultural policy, which would support activities such as decision making in precise agriculture and mitigation of crop threats, a concept agricultural information system was developed for the area of Poland. This innovative concept, called Green Cadastre (GC), proposes to create a uniform system designed for use on a national scale by both state administration as well as local farmers....
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Evolution of charge density wave order in continuous solid solutions Lu(Ni1-xCox)C2
PublikacjaPseudo-ternary solid solutions, Lu(Ni1-xCox)C2 (0 ≤ x ≤ 1), were studied by means of powder X-ray diffraction, differential thermal analysis as well as electrical resistivity and heat capacity measurements. The crystal structure of the Lu(Ni1-xCox)C2 series, as investigated by means of X-ray powder diffraction, is of structure type CeNiC2, space group Amm2, Pearson symbol oS8. The structural analysis reveals a non-monotonous evolution,...
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Electronic States of Tris(bipyridine) Ruthenium(II) Complexes in Neat Solid Films Investigated by Electroabsorption Spectroscopy
PublikacjaWe present the electric field-induced absorption (electroabsorption, EA) spectra of the solid neat films of tris(bipyridine) Ru(II) complexes, which were recently functionalized in our group as photosensitizers in dye-sensitized solar cells, and we compare them with the results obtained for an archetypal [Ru(bpy)3]2+ ion (RBY). We argue that it is difficult to establish a unique set of molecular parameter values by discrete parametrization...
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Zero-range potentials for Dirac particles: Bound-state problems
PublikacjaA model in which a massive Dirac particle in $\mathbb{R}^{3}$ is bound by $N\geqslant1$ spatially distributed zero-range potentials is presented. Interactions between the particle and the potentials are modeled by subjecting a particle's bispinor wave function to certain limiting conditions at the potential centers. Each of these conditions is parametrized by a $2\times2$ Hermitian matrix (or, equivalently, a real scalar and a...
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EFFECT OF SURFACE STATE AND STRESS ON AN OXIDATION OF THE ZIRCALOY-2 ALLOY
PublikacjaZr alloys are widely used as materials for nuclear fuel pellets in the nuclear industry. In the case of the LOCA or RIA happen, a temperature may locally reach high values. Even if the high temperature maintains shortly, the zirconium oxides may become permeable, absorb hydrogen appearing in cooling water from decomposition reaction and crack because of formation and brittle failure of hydrides. Such model cannot so far take into...
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Awareness evaluation of patients in vegetative state employing eye-gaze tracking system
PublikacjaApplication of eye-gaze tracking system to awareness evaluation is demonstrated. Hitherto awareness evaluation methods are presented. The assumptions of proposed method based on analysis of visual activity of patients in vegetative state are demonstrated. The eye-gaze tracking system ''Cyber-Eye'' developed at the Multimedia Systems Department employed to conducted experiments is presented. Research described in the paper indicates...
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Multidimensional Monitoring System of State Machines
PublikacjaTechnical systems are more complex every day as their electronics and mechanics. Technical advances tend to be autonomous in its performance and perform an auto-diagnosis that allows determining an abnormality existence in a component or subsystem and deciding if the system has to be stopped or not.
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On the superconducting state in Ba0.6K0.4BiO3 perovskite oxide
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Kikuchi-Fujimoto disease: State of the art
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Equation of state for Eu-doped SrSi2O2N2
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State of Deliverable D1.1 of INDECT Project
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State of the art report on fabric formwork
PublikacjaPrzedstawiono technologię wytwarzania i kształtowania elementów betonowych wylewanych w wiotkich formach. Omówiono szerokie zastosowanie takich elementów umożliwiające swobodne kształtowanie przestrzeni. Wskazano na możliwości wykorzystania omawianej technoloii betonowania w nietypowych warunkach, np. w pracach podwodnych. Zwrócono uwage a oszczędności w zastąpieniu drewnianych lub stalowych form, a także polepszenie własności...
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The essence and specificity of the state multiculturalism policy
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Incremental construction of finite-state automata
PublikacjaRozdział przedstawia algorytmy przyrostowego i półprzyrostowego tworzenia minimalnych deterministycznych automatów skończonych.
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Poroelastic Road Surfaces - State of The Art
PublikacjaPoroelastic Road Surfaces (PERS) constitute a specific group of pavements containing a great amount of crumbled rubber. In most cases rubber aggregate constitutes about 20% of the mixture (by weight) and a polyurethane resin is used as a binder. As a result, PERS is characterized by a much higher elasticity than asphalt and a high porosity typical for drainage pavements. Due to this, tire/road noise is greatly reduced and on top...
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A concept of the predicting of technical state of devices.
PublikacjaPrzedstawiono możliwości i ograniczenia dotyczące prognozowaia stanu technicznego urządzeń oraz wykazano potrzebę doskonalenia metod planowania ich obsług profilaktycznych. Wskazano możliwość przekształcenia rozkładów szybkości zużywania urządzeń na rozkłady czasu ich poprawnego działania do osiągnięcia stanu granicznego.
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─ Formation of a state institution on the basis of a process analysis - The concept of the institution of cadastre
PublikacjaModification of the structures of public administration encounters major obstacles. Institutional changes are difficult to introduce due to their complexity and broad impact. Non-substantial (political) factors are of importance as well. The resistance to change is aggravated by how difficult it is for decision-makers to assess the impact of the changes that are proposed. We present a method of handling such issues based on the...
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SYNTHETIZED MEMBRANES FOR ULTRASOUND-ASSISTED SOLVENT EXTRACTION OF POROUS MEMBRANE PACKED SOLID SAMPLES.
PublikacjaMembranes are becoming more and more popular in analytical chemistry, which is why they are used, among others, in extraction processes. Therefore, this work focuses on the process of synthesis PVDF membranes and its optimization. The obtained membranes were used as bags for the phthalate extraction in disposable diapers for babies. Extraction was accomplished by method ultrasound-assisted solvent extraction of porous PVDF membrane...
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Microscopic traffic simulation models for connected and automated vehicles (CAVs) – state-of-the-art
PublikacjaResearch on connected and automated vehicles (CAVs) has been gaining substantial momentum in recent years. However, thevast amount of literature sources results in a wide range of applied tools and datasets, assumed methodology to investigate thepotential impacts of future CAVs traffic, and, consequently, differences in the obtained findings. This limits the scope of theircomparability and applicability and calls for a proper standardization...
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Is the Solid Electrolyte Interphase an Extra-Charge Reservoir in Li-Ion Batteries?
PublikacjaAdvanced metal oxide electrodes in Li-ion batteries usually show reversible capacities exceeding the theoretically expected ones. Despite many studies and tentative interpretations, the origin of this extra-capacity is not assessed yet. Lithium storage can be increased through different chemical processes developing in the electrodes during charging cycles. The solid electrolyte interface (SEI), formed already during the first...
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Preparation and characterization of asphaltene based adsorbents for gas-solid adsorption systems
PublikacjaThe dissertation presents results of the experimental research on asphaltene-based adsorbents (support coated with asphaltene layer) for gas-solid adsorption systems, with special reference to volatile organic compounds (VOCs) removal from gas streams. Analysis of gas adsorption properties revealed that asphaltenes isolated from oxidized bitumen have strong affinity toward VOCs. Interactions with target gas molecules, and selectivity...
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Effect of interconnect coating procedure on solid oxide fuel cell performance
PublikacjaChromium (Cr) species vaporizing from chromia-forming alloy interconnects is known as a source of degradation in solid oxide fuel cell (SOFC) stacks called “cathode poisoning”. (Mn,Co)3O4 spinel coatings offer good protection against Cr evaporation during operation. In this study, Crofer 22 APU steel interconnects were electrophoretically deposited in different mediums to obtain high packing of green coating layer. The optimized...
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Comparison of state feedback and PID control of pressurizer water level in nuclear power plant
PublikacjaThe pressurizer water level control system in nuclear power plant with pressurized water reactor (PWR) is responsible for coolant mass balance. The main control goal is to stabilize the water level at a reference value and to suppress the effect of time-varying disturbances (e.g. coolant leakage in primary circuit pipeline system). In the process of PWR power plant operation incorrect water level may disturb pressure control or...
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Multi-state vibronic interactions in the fluorobenzene radical cation: The importance of quadratic coupling terms
PublikacjaThe multi-mode multi-state vibronic interactions in the set of X^2B_1 - D^2A_1 electronic states of the monofluoro benzene radical cation are investigated theoretically, based on a quadratic vibronic coupling approach. The underlying ionization potentials and coupling constants are obtained from ab initio coupled-cluster calculations. Previous investigations (relying on the linear coupling approach) are extended by including all...
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Availability of UAV Fleet Evaluation Based on Multi-State System
PublikacjaUnmanned Aerial Vehicle (UAV) applications are extended extremely. Some applications need to use several UAVs for a general mission which can be considered a UAV fleet. One of the important characteristics for the evaluation of a UAV or UAV fleet is reliability. There are studies in which methods for analysis of their reliability are considered. Reliability analysis of UAV fleets is less frequently studied, although a single UAV...
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Thermal Imaging Aided Assessment of a State of Equipment Under Test and its Protecting Elements
PublikacjaIn the paper the investigation results using thermal imaging methods are presented. The examined is a state of equipment under test and its protecting components. The estimations are done for the chosen protecting elements during surge immunity testing. The results show that the thermal imaging methods are useful for early detection of possible damage of a device being tested
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Legislation and Practice of Selected State Aid Issues, According to EU and Polish Law
PublikacjaThe dataset encompasses several tables, each consisting of three elements: legislation, jurisprudence and scientific articles on numerous subjects and economic activities receiving public financial support in the form of state aid instruments. The set includes a subjective list of the most commonly used and/or disputable examples of granting aid, such as for (local) airports and airlines, steel production, shipyards, and coalmines....
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Excited-state proton transfer and geminate recombination in the molecular cage of β-cyclodextrin
PublikacjaExcited-state proton transfer and geminate recombination in aqueous heptakis(2,6-di-O-methyl)-β-cyclodextrin have been compared with those in water by monitoring the photoinduced prototropic tautomerization of 6-hydroxyquinoline, which occurs via forming anionic intermediate. Enol deprotonation decelerates by 18 times whereas its reverse process accelerates slightly with encapsulation. The imine protonation of the intermediate...
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Radosław Szmytkowski prof. dr hab.
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Quantum-state transfer in spin chains via isolated resonance of terminal spins
PublikacjaWe propose a quantum-state transfer protocol in a spin chain that requires only the control of the spins at the ends of the quantum wire. The protocol is to a large extent insensitive to inhomogeneity caused by local magnetic fields and perturbation of exchange couplings. Moreover, apart from the free evolution regime, it allows one to induce an adiabatic spin transfer, which provides the possibility of performing the transfer...
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Letter to the Editor: Discussion on the Paper “State-of-the-Art of Research on Seismic Pounding Between Buildings with Aligned Slabs”
PublikacjaThe paper “State-of-the-art of research on seismic pounding between buildings with aligned slabs” (by Kharazian and López-Almansa) has recently been published in the journal of Archives of Computational Methods in Engineering. It can be considered as a kind of continuation of previous ‘state-of-the-art’ publications, including two papers and a book. Unfortunately, the paper contains a number of misleading or wrong statements as...
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Four-state stochastic model of changes in the reliability states of a motor vehicle
PublikacjaThe properties of semi-Markov processes have been generally characterized and the applicability of the theory of such processes to the determining of the reliability of motor cars and other road vehicles has been explained. A formal description of the process of changes in the motor vehicle technical states considered as reliability states and a model of this process in the form of a one-dimensional stochastic process have been...
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State of the art in sample preparation for human breast milk metabolomics—merits and limitations
PublikacjaHuman breast milk (HBM) contains metabolites that are diverse in chemical structure and concentration. These metabolites range from high-abundance to low-abundance compounds and from polar to nonpolar. This complex nature of HBM makes HBM samples difficult to analyze, especially in global metabolomic studies for the determination and characterization of complete sets of metabolites. In this review, the state of the art in sample...
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Interaction of Acoustic and Thermal Modes in the Gas with Nonequilibrium Chemical Reactions: Possibilities of Acoustic Cooling
PublikacjaNonlinear generation of thermal mode during propagation of dominative sound in a chemically reacting gas is considered. The dynamic equation of excess temperature associated with the thermal mode is derived. It is instantaneous and includes quadratic nonlinear acoustic source reflecting the nonlinear character of interaction between acoustic and non-acoustic types of gas motion. Both periodic and aperiodic sound may be considered...
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Stock market reactions under the shadow of the COVID-19 pandemic: Evidence from China
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Selective monoprotection of 1,4,7,10-tetraazacyclododecane via direct reactions with 4-nitrophenyl active esters
Publikacja1,4,7,10-tetraazacyklododekan jest cykliczną tetraaminą. Z chemicznego punktu widzenia wszystkie atomy azotu posiadają takie same właściwości fizykochemiczne. Jedyną różnicę stanowią ich właściwości kwasowo-zasadowe. Cyklen posiada dwa atomy azotu o obniżonej zasadowości. Właściwość ta z powodzeniem wykorzystywana jest w reakcjach jednoczesnej selektywnej substytucji dwóch atomów w pozycji 1 i 7. W przypadku bezpośredniej reakcji...
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Proton transfer reactions from NH acid to various N-bases in acetonitrile
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High catalytic performance of tungsten disulphide rodes in oxygen evolution reactions in alkaline solutions
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Numerical model for thin liquid film with evaporation and condensation on solid surfaces in systems with conjugated heat transfer
PublikacjaCondensation and evaporation processes from wetted surfaces are of utmost importance in many technological or industrial applications. In many devices such as home-appliances and air conditioning systems just to name a few, condensation and evaporation processes greatly impact their performance and energy efficiency; The physics of these processes is quite complex, involving conjugate heat transfer among solid–liquid film-gaseous...
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Superconductivity in the Einstein solid V Al10.1
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Conductivity improvement of Ce0.8Gd0.2O1.9 solid electrolyte
PublikacjaW pracy przedstawiono metodę zwieszenia przewoności domieszkowanego tlenku ceru wprowadzając podczas syntezy 2% wapnia. Zbadano metody wprowadzenia wapnia z użyciem prekursorów polimerowych. Uzyskano zwiększenie przewodności oraz syntezowalności elektrolitu stałego.
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The structure and conductivity of solid polyurethane electrolyte
PublikacjaPrzedstawiono badania właściwości i struktury stałych elektrolitów poliuretanowych. Otrzymano je z prepolimeru zsyntezowanego z MDI oraz PTMG. Jako przedłużacz łańcucha wykorzystano butanodiol. W celu poprawy przewodnictwa domieszkowano poliuretan solami LiClO4 lub LiCl, które wprowadzono za pomocą wytłaczarki dwuślimakowej. Otrzymane elektrolity poddano badaniom: wytrzymałościowym, twardości, spektroskopii FTIR oraz przewodnictwa...
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Solid road environment and its hazards
PublikacjaAccidents that involve vehicles departing the road tend to have very high severity, as they often result in the vehicle hitting a permanent obstacle (which can be a ree, a pole, facility pillar, front wall of a culvert or a barrier). In recent years, this type of accident caused approx. 19% of all road deaths in Poland. A particularly high risk can be observed on roads located in northern and western...
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The structure and conductivity of solid polyurethane electrolytes
PublikacjaPrzedmiotem badań były stałe elektrolity poliuretanowe otrzymane w wyniku syntezy MDI, PTMO, BD oraz TG z DMPA. Domieszkowanie LiCl zostało wykonane przy zastosowaniu przedłużacza. Badano przewodnictwo jonowe otrzymanych elektrolitów stałych przy użyciu technik stało i zmiennoprądowych. Przedstawiono również wyniki badań z wykorzystaniem technik mikroskopii elektronowej oraz FTIR-ATR.