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Wyniki wyszukiwania dla: energy transition
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The unstable thermoelectric effect in non-stoichiometric Cu2Se during the non-equilibrium phase transition
PublikacjaThe superionic α ↔ β phase transition in Cu1.96Se thermoelectric material is investigated by means of thermal analysis (DSC) and measurements of Seebeck coefficient and electrical conductivity. Results of the DSC measurements with 1–10 K/min heating and cooling rates show that the material is close to the equilibrium phase composition during the transformation. However, the kinetic limitation of the process exists, which is indicated...
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Extended non-linear relations of elastic shells undergoing phase transitions
PublikacjaThe non-linear theory of elastic shells undergoing phase transitions was proposed by two first authors in J. Elast. 79, 67-86 (2004). In the present paper the theory is extended by taking into account also the elastic strain energy density of the curvilinear phase interface as well as the resultant forces and couples acting along the interface surface curve itself. All shell relations are found from the variational principle of...
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Ab Initio Study of the Electronic Spectrum of 7-Hydroxyquinoline
PublikacjaThe electronic spectrum of 7-hydroxyquinoline has been studied by using ab initio Multi-State Multi-Reference Møller-Plesset Second-Order Perturbation Theory (MSMRMP2). The energy range up to 6.5 eV is taken into consideration. The lowest π–π* transition is calculated to have an energy of 3.65 eV in good agreement with experimental data. Several other π–π* transitions are predicted to have excitation energies of 4.93, 5.20, 5.47,...
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TIME-OF-FLIGHT DIFFERENTIAL ELECTRON SCATTERING FROM MOLECULAR TARGETS: BENCHMARK CROSS SECTIONS
PublikacjaWe report time-of-flight differential cross section (DCS) measurements for the electron impact excitation transition in H2. In this work, agreement between available theory and experiment is excellent overall, and marks a transition in electron molecule scattering where differential scattering of excitation is found to be in such precise agreement. We also prove that the newly built apparatus can be used for accurate measurement...
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ALTERNATIVE, DIRECT SYNTHESIS METHOD OF THE CERAMIC SOLID SOLUTIONS BASED ON BaTiO3 THROUGH A HIGH ENERGY BALL MILLING
PublikacjaPolycrystalline samples BaTiO3 and the solid solutions Ba0.9Sr0.1TiO3, Ba0.9Sr0.1Ti0.9Sn0.1O3, Ba0.9Sr0.1Ti0.8Sn0.2O3 were obtained by means of a mechanochemical treatment based on the high-energy ball milling technique and next a high temperature solid state reaction method. The influence of synthesis condition on microstructural, dielectric and ferroelectric properties of obtained solid solutions were investigated. The structure...
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High temperature monoclinic-to-tetragonal phase transition in magnesium doped lanthanum ortho-niobate
PublikacjaMagnesium doped lanthanum ortho-niobate (La0.98Mg0.02NbO4) was prepared by the molten salt synthesis method. X-ray diffraction and dilatometry methods were used to study high temperature behavior of the ceramic material. Special attention was paid to the phase transition between the monoclinic and tetragonal phases. The values of spontaneous strain on the basis of unit cell parameter, obtained by Rietveld refinement, have been...
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Improving Social Justice, Environmental Integrity, and Geopolitical Resilience in EU Electric Mobility Transition
PublikacjaWe recommend improving social justice, environmental integrity, and geopolitical resilience in electric mobility transition. To achieve this policy recommendation, we propose the following: (1) Increase societal acceptance and justice of climate policies by engaging local stakeholders; (2) Prioritize sustainable mobility practices over replacement of internal combustion engine vehicle (ICEV) with battery electric vehicle (BEV);...
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How Do Intermolecular Interactions Evolve at the Nematic to Twist–Bent Phase Transition?
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Anomalous Thermal Behavior of Salicylsalicylic Acid and Evidence for a Monotropic Transition to a Nematic Phase
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Surface area investigation of materials with transition layers of continuously changing electron density
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Assessment of the effect of vegetation on the transition of the flood wave using hydraulic 2D models
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Identification of multisite behavior in a broadly emitting transition-metal system using pressure
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Transition-Metal-Promoted Oxidative Cyclization To Give 1,2,4-Trisubstituted Carbazole Scaffolds
PublikacjaHerein, we describe the synthesis of a 1,2,4-trisubstituted carbazole core from 5-(1H-indol-3-yl)-3-oxopentanoic acid esters or amides. For oxidative cyclization, we tested two different approaches. First, we used manganese triacetate as a conventional moderate oxidizer to ensure the radical course of the reaction. Second, we examined the use of a more complex oxidizing agent I2/Me(OTf)3. In both cases, formation of a fused-ring...
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The time of the first transition of the semi-Markov process in the evaluation of diesel engine operation
PublikacjaW referacie przedstawiono rozwinięcie prezentowanej w literaturze metody ilościowej oceny działania na przykładzie okrętowego silnika głównego z zapłonem samoczynnym. Według tej interpretacji, działanie silnika może zostać przedstawione jako wielkość fizyczna. W tym aspekcie, na przykładzie okrętowego silnika napędu głównego dokonano oceny przydatności tej wielkości do opisu własności niezawodnościowych silnika. Precyzyjne określenie...
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Apparent molar volumes of divalent transition metal bromides in dimethyl sulfoxide solutions
PublikacjaWyznaczono pozorne i cząstkowe molowe objętości bromków dwuwartościowych metali przejściowych szeregu Mn(II)-Zn(II)w roztworach w dimetylosulfotlenku. Przedyskutowano korelacje między objętościami molowymi a stanami koordynacyjnymi i sposobem jonizacji soli.
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Gel glass transition in silica and nitrided silica aerogels experiment and computer modelling.
PublikacjaPrzedstawiono dane eksperymentalne i symulacje komputerowe metodą dynamiki molekularnej procesu densyfikacji do szkła aerożeli krzemianowych i azotowanych aerożeli krzemianowych.
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Optimization of the femtosecond laser impulse for excitation and the spin-orbit-mediated dissociation in the NaRb molecule
Dane BadawczeHigh accuracy ab initio potential energy curves (1tSigma+, 2sSigma+, 1tPi), electronic transition dipole moment function (1tSigma+ - 1tPi), and spin-orbit coupling (2sSigma+ - 1tPi) have been calculated for the NaRb molecule. The time-dependent excitation and dissociation processes in the polar alkali diatomic NaRb molecule and the quantum properties...
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Modelling of saturated, subcooled and post-dryout flow boiling with the energy dissipation based semi-empirical model
PublikacjaA comprehensive semi-empirical model for saturated, subcooled and post dryout heat transfer is presented based on considerations of energy dissipation in the flow. The fundamental hypothesis in the model is the fact that heat transfer during flow boiling can be treated as a sum of two contributions constituting the total energy dissipation in the flow, namely the energy dissipation due to the shearing flow without the bubbles and...
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Innovative Urban Blue Space Design in a Changing Climate: Transition Models in the Baltic Sea Region
PublikacjaWaterfront areas in cities are subject to constant changes. The desire to integrate the transformed waterside areas with the urban fabric involves shaping high-quality public spaces related to water, which are often referred to as urban blue spaces (UBS). The aim of the research was to examine the transformation processes of urban waterfront areas in the Baltic Sea Region and identify emerging transition models and types of blue...
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Bonding in Phosphanylphosphinidene Complexes of Transition Metals and their Correlation with Structures, 31 P NMR Spectra, and Reactivities
PublikacjaTheoretical studies of the bonding interactions and most important properties are carried out for isolable phosphanylphosphinidene complexes of transition metals. Three main types of phosphanylphosphinidene complexes are distinguished, based on the way in which the phosphanylphosphinidene ligand bonds to the metal center: (i) side-on complexes of platinum, where the R2Pβ–Pα ligand mimics structural features of free singlet phosphanylphosphinidenes...
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Detailed investigation of the phase transition inKxP4W8O32and experimental arguments for a charge density wave due to hidden nesting
PublikacjaDetailed structural and magnetotransport properties of monophosphate tungsten bronze Kx(PO2)4(WO3)8 single crystals are reported. Both galvanomagnetic and thermal properties are shown to be consistent with a charge density wave electronic transition due to hidden nesting of the quasi-1D portion of the Fermi surface. We also observe the enhancement of electronic anisotropy due to reconstruction of the Fermi surface at the Peierls...
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Experimental study on the feasibility of alternative materials for tilting pad thrust bearings operating in transition to mixed friction
PublikacjaIn hydrodynamic bearings traditional bearing alloys: Babbitts and bronzes are most frequently utilized. Polymer sliding layers are sometimes applied as a valuable alternative. Hard diamond-like carbon (DLC) coatings, which are also considered for certain applications may show some advantages, as well. Although material selection is of secondary importance in a full film lubrication regime it becomes important in mixed friction...
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Antagonist adhesion effects due to variable substrate surface
PublikacjaThe effects of variability of intrinsic adhesion within a joint have been studied using a single cantilever beam (SCB) test. Fracture energy was found not to be a simple function of relative areas of 2 surface pre-treatments: a 'weak' zone decreased strength more than expected from simple, additive considerations. By severing the adhesive along the strong-weak transition, fracture energy increased.The prior antagonist effect appears...
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Adiabatic Compressibilities of Divalent Transition-Metal Perchlorates and Chlorides in N,N-Dimethylacetamide and Dimethylsulfoxide
PublikacjaZmierzono prędkości rozchodzenia się dźwięku roztworów nadchloranów i chlorków manganu(II), kobaltu(II), niklu(II), miedzi(II) i cynku(II) w N,N-dimetyloacetamidzie i dimetylosulfotlenku w temperaturze 298.15 K. Obliczono ściśliwości adiabatyczne i pozorne ściśliwości adiabatyczne badanych roztworów. Przedyskutowano wpływ anionu i rodzaju rozpuszczalnika na uzyskane graniczne wartości pozornych ściśliwości adiabatycznych soli.
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Origin of the liquid-liquid phase transition for trans-1,2-dichloroethylene observed by IR spectroscopy
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Potential Modulatory Role of Phoenixin-14 in Epithelial–Mesenchymal Transition of Endometriotic 12Z Cells
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Family business as a breeding ground for nascent entrepreneurs. An insight into transition economy: the case of Poland
PublikacjaArtykuł przedstawia analizę zagadnienia zdolności firm rodzinnych do generowania postaw preprzedsiębiorczych na przykładzie Polski jako kraju o gospodarce transformującej się od centralnie sterowanej do rynkowej. Część empiryczna oparta jest wynikach pilotażowych badań przeprowadzonych na studentach pierwszego roku WZiE PG, które to wyniki posłużyły do stworzenia wstępnej wersji modelu opisującego determinanty procesu generowania...
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MicroscopicA75sNMR study of the effect of impurities on the first-order spin-density-wave transition inBaFe2As2
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Mechanical properties and interfacial transition zone microstructure of concrete with waste basalt powder addition
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Apparent molar volumes of divalent transition metal perchlorates and chlorides in N,N-dimethylacetamide.
PublikacjaZmierzono gęstości roztworów nadchloranów i chlorków manganu(II), kobaltu(II), niklu(II), miedzi(II) i cynku(II) w temperaturach 10, 20,25, 30, 40, 50 i 60(o)C. Obliczono pozorne objętości molowe. Wyznaczono graniczne wartości cząstkowych molowych objętości tych soli oraz odpowiednie rozszerzalności. Przeanalizowano i wyjaśniono różnice we właściwościach wolumetrycznych roztworów nadchloranów i chlorków.
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Management of the transition spaces - comparison of the East European, West European and North American examples
PublikacjaArtykul dotyczy zagadnienia zagospodarowania przestrzeni stykowych pomiędzy strukturami portowymi i miejskimi w miastach portowych. Opisano w nim szereg przygkładów oraz zarysowano możliwe strategie zarządznaia tymi obszarami..
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Apparent molar volumes of divalent transition metal chlorides and perchlorates in dimethyl sulfoxide solutions.
PublikacjaZmierzono gęstości roztworów nadchloranów i chlorków dwuwartościowych metali szeregu Mn(II)-Zn(II) w dimetylosulfotenku. Wyznaczone na drodze ekstrapolacji cząstkowe objętości molowe nadchloranów rozdzielono na udziały jonowe. Przeanalizowano wpływ pola ligandów na cząstkowe objętości molowe kationów. Przedstawiono związek między wartościami pozornych objętości molowych a stanami koordynacyjnymi soli w DMSO.
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Enhancement of self-trapped excitons and near-infrared emission in Bi3+/Er3+ co-doped Cs2Ag0.4Na0.6InCl6 double perovskite
Dane BadawczeErbium (Er) complexes are used as optical gain materials for signal generation in the telecom C-band at 1540 nm, but they need a sensitizer to enhance absorption. Na+ substitution for Ag+ and Bi3+ doping at the In3+ site is a possible strategy to enhance the broadband emission of Cs2AgInCl6, which could be used as a sensitizer for energy transfer to...
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Powering the Future by Iron Sulfide Type Material (FexSy) Based Electrochemical Materials for Water Splitting and Energy Storage Applications: A Review
PublikacjaWater electrolysis is among the recent alternatives for generating clean fuels (hydrogen). It is an efficient way to produce pure hydrogen at a rapid pace with no unwanted by-products. Effective and cheap water-splitting electrocatalysts with enhanced activity, specificity, and stability are currently widely studied. In this regard, noble metal-free transition metal-based catalysts are of high interest. Iron sulfide (FeS) is one...
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Mathematical modeling and prediction of pit to crack transition under cyclic thermal load using artificial neural network
PublikacjaThe formation of pitting is a major problem in most metals, which is caused by extremely localized corrosion that creates small holes in metal and subsequently, it changes into cracks under mechanical load, thermo-mechanical stress, and corrosion process factors. This research aims to study pit to crack transition phenomenon of steel boiler heat tubes under cyclic thermal load, and mathematical modeling...
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Seaweed as a resource for Anaerobic Digestion
PublikacjaExtensive growth of algae contributes to disruptive changes to the water ecosystems. This is mainly caused by redundant nutrients that are washed off the land and end up in waters. Tackling eutrophication by recovery of nutrients can be a solution to the problem. Cast marine biomass can be a resource for renewable energy technologies like anaerobic digestion. Such approach can contribute to the transition to a circular bio-economy and...
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On the critical temperature discontinuity at the theoretical bcc-fcc phase transition in compressed selenium and tellurium superconductors
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First-order magnetic transition in single-crystalline CaFe2As2 detected by 75As nuclear magnetic resonance
PublikacjaPrzedstawione są wyniki badań jądrowego rezonansu magnetycznego na 75As dla kryształów CaFe2As2. Wyniki wskazują, że strukturalne i magnetyczne przejścia w CaFe2As2 są silnie skorelowane i są pierwszego rodzaju.
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The influence of strain on the Verwey transition as a function of dopant concentration: towards a geobarometer for magnetite-bearing rocks
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Magnetic Field Influence on the Superconducting Transition in Granular (BiPb)-Sr-Ca-Cu-O Superconductors
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The analysis of firms’ involvement in internationalisation and determinants of its intensity – an analysis for developing and post-transition economies
PublikacjaThe study presents the empirical analysis of firms’ involvement in different forms of internationalisation: export, indirect export, import, indirect import and finally simultaneous exporting and importing. The analysis is based on firm-level data from the World Bank Enterprise Survey (March 2017 release). The empirical part is divided into two stages. Firstly account is taken of firms’ heterogeneity and then a Melitz type analysis...
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Mixed electronic-ionic conductivity in transition metal oxide glasses con-taining alkaline ions
PublikacjaOpisano właściwości elektryczne szkieł z tlenkami metali przejściowych zawierających jony metali alkalicznych. Szczególną uwagę zwrócono na typowe zmiany przewodnictwa występujące przy domieszkowaniu tego typu szkieł jonami metali alkalicznych. Porównano przewodnictwo elektryczne szkieł fosforanowo-żelazowych zawierających jony sodu z przewodnictwem szkieł bizmutowo-miedziowych.
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Overview of the Synthesis and Catalytic Reactivity of Transition Metal Complexes Based on C═P Bond Systems
PublikacjaThis report provides an overview of the use of phosphaalkenes (C=P) in syntheses of various complexes. Going through successive complexes containing the d-block metals, we sought how this area of chemistry was formed over the years. Additionally, this work contains information on the possible coordination types and means of constructing the complexes. In addition, this review reveals the reactivities of phosphaalkene complexes...
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The chemical and mechanical pressure influence on chromium luminescence
Dane BadawczeIn this study, we aim to compare the changes in the luminescence properties of Ga2O3:Cr3+ modified by Al or Sc ion substitution (chemical pressure) and hydrostatic pressure. We find the same behavior for Ga2–xAlxO3:Cr3+ and different behavior for Ga2–xScxO3:Cr3+ in terms of the optical properties under chemical and mechanical pressure. We consider Al...
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Effect of isovalent substitution on microstructure and phase transition of LaNb1−xMxO4 (M=Sb, V or Ta; x=0.05–0.3)
PublikacjaLaNb1−xMxO4 oxides with pentavalent elements of different ionic sizes (M=Sb, Ta and V, x=0.05–0.3) were synthesized by the solid state reaction method. Special interest was devoted to the antimony substituted lanthanum niobate which is a new material in this group. Rietveld analysis of the X-ray diffraction patterns was used to determine the influence of the material composition on unit cell parameters. On the basis of dilatometric...
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Organic pollutants photodegradation increment with use of TiO2 nanotubes decorated with transition metals after pulsed laser treatment
PublikacjaAmong various titanium(IV) oxide (TiO2, titania) structures, 1D nanotubes (TiO2 NTs) produced during the two-electrode anodization process, are extensively utilized in sensors or supercapacitors as well as in photo(electro)catalytic water splitting. However, due to wide bandgap and fast electron-hole recombination additional modifications, mostly concerned on materials surface, are required. According to the recent research, TiO2...
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Poverty and social exclusion in the transition Baltic States during the implementation of the European Union Lisbon Strategy - comparative analysis
PublikacjaThe problem of poverty and social exclusion in the Baltic States generates serious social, economic and political consequences. The scope of the analysis includes primarily the scale and structure of poverty and social exclusion in the Baltic Region in the years 2004-2010 in the context of the Lisbon Strategy of the European Union. The results show that during the transition and implementation of the Lisbon Strategy, the problem...
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Nonlinear and linear impedance of bismuth vanadate ceramics and its relation to structural properties
PublikacjaThe nonlinear and linear electrical properties, topography, and microstructure of bismuth-vanadate ceramics, were studied. The structurewas observed with the use of X-ray diffraction (XRD), scanning electronmicroscopy (SEM), atomic force microscopy (AFM) and confocal microscopy methods. The obtained results showed that ceramic is porous. Two phase transitionswere determinedwith the use of DSC measurements. The linear and nonlinear ac...
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Review—Advances in Rechargeable Lithium-Ion Batteries Utilizing Polyoxometalate-Functionalized Nanocarbon Materials
PublikacjaPolyoxometalates (POMs) are inorganic nanoclusters that consist of oxygen and transition metals. These nanoclusters serve as excellent precursors for creating electrode materials that contain transition metals. Additionally, the interaction between POMs and carbon substrates produces positive synergistic effects. There has been considerable attention on employing POMs and carbon nanostructures (for example carbon nanotubes, graphene,...
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Comprehensive thermodynamic analysis of steam storage in a steam cycle in a different regime of work: A zero-dimensional and three-dimensional approach
PublikacjaDue to the current trends aiming to reduce carbon dioxide emissions by increasing the use of renewable energy sources, changes are required in the operation of coal-fired steam units. The unstable nature of renewable energy sources, depending on weather conditions, means that the amount of energy produced varies and is not always in line with peak demand. To ensure the security and stability of energy supplies in the energy system,...