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Wyniki wyszukiwania dla: time-resolved spectroscopy
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Limonene: electronic state spectroscopy by high-resolution vacuum ultraviolet photoabsorption, electron scattering, He(I) photoelectron spectroscopy and ab initio calculations
PublikacjaZbadano limonen metodami spektroskopii absorpcyjnej, elektronowej, fotojonizacyjnej. Wyniki porównano z obliczeniami ab initio. Otrzymano strukturę wibracyjną molekuły.
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ADAPTIVE IDENTIFICATION OF TIME-VARYING IMPULSE RESPONSE OF UNDERWATER ACOUSTIC COMMUNICATION CHANNEL
PublikacjaThe transmission properties of underwater acoustic communication channel can change dynamically due to the movement of acoustic system transmitter and receiver or underwater objects reflecting transmitted signal. The time-varying impulse response measurement and estimation are necessary to match the physical layer of data transmission to instantaneous channel propagation conditions. Using the correlative measurement method, impulse...
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Determination of pseudocapacitance chan ges of nickel oxide NiO electrode with use of dynamic electrochemical impedancje spectroscopy
PublikacjaThe electrochemical capacitors (ECs) are attractive energy storage devices which can be applied in many electronic products (e.g., cameras, laptops, cell phones) or hybrid electric vehicles (HEV). The energy storage in ECs is based on capacitive (the electrical double layer charging/discharging) and pseudocapacitive (additional charge provided by faradic reaction) phenomena. Considering the electrodes exhibiting pseudocapacitance,...
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The generalized quasilinearization for integro-differential equations of Volterra type on time scales
PublikacjaBadano równania całkowo-różniczkowe on ''time scales'' i podano warunkidostateczne na zbieżność metody kwazilinearyzacji do jego rozwiązania. Podano warunki na to, aby zbieżność ta była kwadratową.
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Time Synchronization between the eNBs in E-UTRAN under the Asymmetric IP Network
PublikacjaIn this paper, we present a method for a time synchronization between the two eNodeBs (eNBs) in E-UTRAN (Evolved Universal Terrestrial Radio Access) network. The...
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Time & Mind-The Journal of Archaeology Consciousness and Culture
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Electronic International Journal of Time Use Research
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On the Structure of Time in Computational Semantics of a Variable-Step Solver for Hybrid Behavior Analysis
PublikacjaHybrid dynamic systems combine continuous and discrete behavior. Often, computational approaches are employed to derive behaviors that approximate the analytic solution. An important part of this is the approximation of differential equation behavior by numerical integration. The accuracy and computational efficiency of the integration usually depend on the complexity of the method and its implicated approximation errors, especially...
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JOURNAL OF RAMAN SPECTROSCOPY
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Assessing the time effectiveness of trust management in fully synchronised wireless sensor networks
PublikacjaThe paper presents the results of the time effectiveness assessment of the distributed WSN Cooperative Trust Management Method - WCT2M in a fully synchronized Wireless Sensor Network (WSN). First we introduce some basic types of synchronization patterns in WSN based on the idea of sleep scheduling. Then we explain how WCT2M works in the network applying the fully synchronized sleep scheduling pattern. Such networks were subjected...
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Electrical and mechanical characterization of two-phase alloys by means of scanning probe microscopy in dynamic impedance spectroscopy mode
PublikacjaDynamic impedance spectroscopy, evaluated for measuring non-stationary systems, was used in combination with scanning probe microscope. Using this approach, localized impedance measurements in the AFM contact mode could be carried out. Additionally, impedance–force curves were made at each phase of investigated materials to illustrate the relation between impedance and the force applied to a probe. Therefore, correlation of electrical...
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Simulation of Residence Time Distribution and Mixing in Reactors with Recirculation Using 2D Approach
PublikacjaIn this paper, we propose a 2D approach in order to create a mathematical model for the determination of the residence time distribution for a flow reactor with recirculation. Apart from characterizing the functional residence time distribution, this model can help improve the operation of the reactor at the design stage. The mathematical model was validated by comparison with experiments carried out in a hydraulic laboratory.
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On the influence of the acceleration recording time on the calculation of impact severity indexes
PublikacjaThe paper concerns with the analysis of normative requirements pertaining to experimental setup of a crash test and its numerical modelling. An overview of parameters describing the collision of a vehicle with a road restraining system is presented. A short description of a concrete road safety barrier is presented. A brief description of numerical modelling procedures for crash tests is given as well. The parametric influence...
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The model of end-to-end call setup time calculation for Session Initiation Protocol
PublikacjaEnd-to-end call setup delay is one of the most important grade of service (GoS) parameters for VoIP networks with Session Initiation Protocol (SIP). A typical subscriber wants to have a connection established as soon as possible. From the operator's perspective call setup time is also crucial because he needs to know how probability of successful packet transmission on SIP links is related to a call setup delay. Then he can make...
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REAL-TIME VOICE QUALITY MONITORING TOOL FOR VOIP OVER IPV6 NETWORKS
PublikacjaThe primary aim of this paper is to present a new application which is at this moment the only open source real-time VoIP quality monitoring tool that supports IPv6 networks. The application can keep VoIP system administrators provided at any time with up-to-date voice quality information. Multiple quality scores that are automatically obtained throughout each call reflect influence of variable packet losses and delays on voice...
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Modified dynamic time warping method applied to handwritten signature authenticity verification
PublikacjaA signature verification system based on static features and time-domain functions of signals obtained using a tablet has been presented in the paper. The signature verification method, based mainly on dynamic time warping coupled with some signature image features, has been described. The FRR measures reflecting the method’s efficiency have been evaluated for verification attempts performed directly after obtaining model signatures...
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Evaluation of organic coating systems for corrosion protection of industrial equipment using impedance spectroscopy
PublikacjaThe high economic impact of corrosion can be reduced by enhanced corrosion management and prevention based on appropriate means. This applies in particular to the protection of structures with organic protective coatings. Steel is subject to corrosion that reduces its service life and leads to destruction in most severe cases. The application of paints to metallic objects for corrosion control has been known for a long time and...
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Finding small-width connected path decompositions in polynomial time
PublikacjaA connected path decomposition of a simple graph $G$ is a path decomposition $(X_1,\ldots,X_l)$ such that the subgraph of $G$ induced by $X_1\cup\cdots\cup X_i$ is connected for each $i\in\{1,\ldots,l\}$. The connected pathwidth of $G$ is then the minimum width over all connected path decompositions of $G$. We prove that for each fixed $k$, the connected pathwidth of any input graph can be computed in polynomial-time. This answers...
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Analysis of friction ridge evidence for trace amounts of paracetamol in various pharmaceutical industries by Raman spectroscopy
PublikacjaThe detection of potentially harmful substances presents a multifaceted challenge. On one hand, it can directly save lives, on the other, it can significantly aid and enhance police work, thereby increasing the effectiveness of investigations. The research conducted in this study primarily aims to identify paracetamol in fingerprints, considering situations involving direct contact of a person with paracetamol either chronically...
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Numerical Analysis of Recharge Rates and Contaminant Travel Time in Layered Unsaturated Soils
PublikacjaThis study focused on the estimation of groundwater recharge rates and travel time of conservative contaminants between ground surface and aquifer. Numerical simulations of transient water flow and solute transport were performed using the SWAP computer program for 10 layered soil profiles, composed of materials ranging from gravel to clay. In particular, sensitivity of the results to the thickness and position of weakly permeable...
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Modeling the effect of parasitic capacitances on the dead-time distortion in multilevel NPC inverters
PublikacjaA simple model is derived and verified for evaluating the effect of parasitic capacitances on the dead-time related voltage distortion in multilevel NPC voltage source inverters. The model permits well-defined and precise compensation of dead-time distortion, exhibiting meaningful improvement on compensation methods neglecting the effects of parasitic capacitances. A simple formula is given for evaluating the capacitances as serial/parallel...
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Dynamic Electrochemical Impedance Spectroscopy (DEIS) as a Tool for Analyzing Surface Oxidation Processes on Boron-Doped Diamond Electrodes
PublikacjaSurface oxidation processes play a key role in understanding electrochemical properties of boron-doped diamond (BDD) electrodes. The type of surface termination groups, which create the potential window of electrolytic water stability or hydrophobicity, influences such properties. In this study the kinetics of oxidation process under anodic polarization were studied in situ by means of Dynamic Electrochemical Impedance Spectroscopy...
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Cross-Platform Real-Time Nuclear Reactor Basic Principle Simulator
PublikacjaAbstract—In the paper several approaches to building the real-time basic principle simulators of nuclear reactor processes are presented and their characteristics are analyzed. The characteristics of developed simulators for MATLAB/Simulink including their limitations, and the idea of a cross-platform simulator independent of specific hardware or software are presented. Mathematical models of selected nuclear reactor’s processes...
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An Overview of the Development of a Real-Time System for Endoscopic Video Classification
PublikacjaThe article presents the results of improving endoscopic image classification algorithms in an effort towards applying them in a real-time diagnosis supporting system. Methods for the detection and removal of personal data are presented and discussed. The currently developed recognition algorithms have been improved in terms of accuracy and performance to make them suitable for a real-life implementation. Their test results are...
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Real-time hybrid model of a wind turbine with doubly fed induction generator
PublikacjaIn recent years renewable sources have been dominating power system. The share of wind power in energy production increases year by year, which meets the need to protect the environment. Possibility of conducting, not only computer simulation, but also laboratory studies of wind turbine operation and impact on the power system and other power devices in laboratory conditions would be very useful. This article presents a method...
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Solvation of cobalt(II) and trifluoromethanesulfonate ions in N,N-dimethylformamide-methanol mixed solvent studied by means of FT-IR spectroscopy
PublikacjaWidma FT-IR roztworów Co(CF3SO3)2-N,N-dimetyloformamid-metanol były analizowane w zakresie pasm CO i OH za pomocą metody widm różnicowych. Wyznaczono liczbę cząsteczek DMF i MeOH w pierwszej sferze solwatacji jonu Co(II) w zależności od składu rozpuszczalnika. Stwierdzono także obecność drugiej sfery solwatacji jonu Co(II) i scharakteryzowano ją ilościowo. Zbadano również solwatację jonu tifluorometanosulfonowego oraz asocjację...
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The influence of different time durations of thermal processing on berries quality
PublikacjaBioactive compounds (polyphenols, flavonoids, flavanols, tannins, anthocyanins and ascorbic acid) and the level of antioxidant activity by ABTS, DPPH, FRAP and CUPRAC of water, acetone and hexane extracts of Chilean 'Murtilla' (Ugni molinae Turcz) and 'Myrteola' berries (Myrtaceae, Myrteola nummularia (Poiret) Berg.), Chilean and Polish blueberries (Vaccinium corymbosum), Chilean raspberries (Rubus idaeus), and Polish black chokeberry...
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Formulation of Time-Fractional Electrodynamics Based on Riemann-Silberstein Vector
PublikacjaIn this paper, the formulation of time-fractional (TF) electrodynamics is derived based on the Riemann-Silberstein (RS) vector. With the use of this vector and fractional-order derivatives, one can write TF Maxwell’s equations in a compact form, which allows for modelling of energy dissipation and dynamics of electromagnetic systems with memory. Therefore, we formulate TF Maxwell’s equations using the RS vector and analyse their...
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CRUNCH Time na 17 Biennale Architektury w Wenecji, w Pawilonie Włoskim
Publikacjahttps://arch.pg.edu.pl/strona-glowna/wydarzenia/crunch-time-na-biennale-architektury-w-wenecji-2021 https://pg.edu.pl/aktualnosci/2021-10/sukces-gdanskich-urbanistow-crunch-time-na-biennale-architektury-w-wenecji
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Low cost real time UAV stereo photogrammetry modelling technique – accuracy considerations
PublikacjaThe paper presents accuracy considerations regarding three 3D modelling techniques. The tested new consumer type stereo camera (ZED 3D Stereolabs) has been implemented info an aerial mapping system, on board micro air vehicle MAV) and tested object has been mapped using a real-time photogrammetry with original real-time software application. The evaluated results has been compared with model gained with a state of art unmanned...
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The influence of esterification time on the physicochemical properties of poly (glycerol sebacate-co- butylene sebacate)
PublikacjaThe study presents the results of the physicochemical properties of ester elastomer based on sebacic acid, glycerol and 1,4 - butanediol. The process of obtaining elastomers at variable esterification times of 14, 16 and 21 h is described. It was found that the material with an esterification time of 21 h is characterized by the best mechanical properties while maintaining high content of the gel fraction. In the technological...
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Statistically efficient smoothing algorithm for time-varying frequency estimation
PublikacjaThe problem of extraction/elimination of a nonstationary sinusoidal signal from noisy measurements is considered. This problem is usually solved using adaptive notch filtering (ANF) algorithms. It is shown that the accuracy of frequency estimates can be significantly increased if the results obtained from ANF are backward-time filtered by an appropriately designed lowpass filter. The resulting adaptive notch smoothing (ANS) algorithm...
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Asynchronous distributed state estimation for continuous-time stochastic processes
PublikacjaWe consider the problem of state estimation of a continuous-time stochastic process using an asynchronous distributed multi-sensor estimation system (ADES). In an ADES the state of a process of interest is estimated by a group of local estimators. Each local estimator based, for example, on a Kalman filter, performs single sensor filtration but also fusion of its local results and results from other (remote) processors to compute...
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Prediction of Processor Utilization for Real-Time Multimedia Stream Processing Tasks
PublikacjaUtilization of MPUs in a computing cluster node for multimedia stream processing is considered. Non-linear increase of processor utilization is described and a related class of algorithms for multimedia real-time processing tasks is defined. For such conditions, experiments measuring the processor utilization and output data loss were proposed and their results presented. A new formula for prediction of utilization was proposed...
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Comments on “Closed Form Variable Fractional Time Delay Using FFT”
PublikacjaIn this letter drawbacks of the aforementioned paper are pointed out. The proposed approach is improved with minor modifications of the discrete frequency response. This allows for design of fractional delay filters which are close to optimal and can be efficiently implemented in the frequency domain using the sliding DFT based structure. Alternatively, the derived equivalent closed form formulae for offset windows can be used...
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Discrimination of Apple Liqueurs (Nalewka) Using a Voltammetric Electronic Tongue, UV-Vis and Raman Spectroscopy
PublikacjaThe capability of a phthalocyanine-based voltammetric electronic tongue to analyze strong alcoholic beverages has been evaluated and compared with the performance of spectroscopic techniques coupled to chemometrics. Nalewka Polish liqueurs prepared from five apple varieties have been used as a model of strong liqueurs. Principal Component Analysis has demonstrated that the best discrimination between liqueurs prepared from different...
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The voltage across and current through the RC model object tested using pulse excitation in impedance spectroscopy measurement method
Dane BadawczeThe raw data (voltage across and current through RC model object ) obtained using pulse excitation EIS impedance spectroscopy measurement method. The data was acquired using 12-bit ADC (LTC1420) with sampling frequency changed in time segments. The 1V voltage pulse excitation duration was set to 0.1s and the total acqusition time was set to 1000s. For...
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Synchrotron radiation photoemission spectroscopy of the oxygen modified CrCl3 surface
PublikacjaWe investigate the experimentally challenging CrCl3 surface by photon energy dependent photoemission (PE). The core and valence electrons after cleavage of a single crystal, either in a ultrahigh vacuum (UHV) or in air, are studied by keeping the samples at 150 1C, aiming at confirming the atomic composition with respect to the expected bulk atomic structure. A common spectroscopic denominator revealed by data is the presence of...
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Corrosion rate measurements by non-linear electrochemical impedance spectroscopy
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Evaluation of pitting corrosion by means of dynamic electrochemical impedance spectroscopy
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Raman spectroscopy study on concentrated acid treated carbon nanotubes
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Hydration of aprotic donor solvents studied by means of FTIR spectroscopy
PublikacjaThe paper attempts to explain the mutual influence of nonpolar and electron-donor groups on solute hydration,the problem of big importance for biological aqueous systems. Aprotic organic solvents have been used asmodel solutes, differing in electron-donating power. Hydration of acetonitrile, acetone, 2-butanone, andtriethylamine has been studied by HDO and (partially) H2O spectra. The quantitative version of...
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Conformational studies of neurohypophyseal hormones analogues with glycoconjugates by NMR spectroscopy
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Quality assessment of varistor ZnO structures by resonant ultrasound spectroscopy
PublikacjaWarystory sa wytwarzane z tlenku cynku ZnO jako cylindrycznie uformowane struktury, a ich jakość zależy od zmieniających się uwarunkowań technologicznych na etapach formowania ich kształtu oraz spiekania. W związku z tym są one testowane w końcowej fazie produkcji, a elementy wadliwe się odrzuca. Proponujemy testowanie jakości struktur ZnO we wcześniejszej fazie ich wytwarzania w celu wyeliminowania elementów wadliwych z dalszej,...
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Vibrational Spectroscopy in Analysis of Stimuli-Responsive Polymer–Water Systems
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Vibrational spectroscopy of semiheavy water (HDO) as a probe of solute hydration
PublikacjaSpektroskopia oscylacyjna jest idealną metodą w badaniach zjawisk hydratacyjnych. Przy zastosowaniu techniki rozcieńczenia izotopowego, gdy mała ilość D2O zostaje wprowadzona do H2O lub vice versa i powstaje woda półciężka (HDO), ominąć można wiele problemów technicznych i interpretacyjnych związanych z pomiarem widm w podczerwieni wody ciekłej. Zwłaszcza izotopowe rozprzężenie drgań rozciągających ułatwia interpretację widm. Systematycznie...
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Spectroscopy and Dynamics of Cryptolepine in the Nanocavity of Cucurbit[7]uril and DNA
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Raman Spectroscopy for Investigation of Sol-Gel Materials and Ceramic Materials.
PublikacjaPrzedstawiono rezultaty prac nad zastosowanie spektroskopii ramanowskiej do badania polimerów hybrydowych wytwarzanych metodą zol-żel oraz ceramik ferroelektrycznych. Wykonano pomiary dla próbek objętościowych i struktur cienkowarstwowych. Zademonstrowano możliwośc monitorowania procesu syntezy w czasie rzeczywistym.
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Evaluating and predicting the performance of organic coatings using impedance spectroscopy
PublikacjaPrzedstawiono wyniki badań cyklicznych, sinusoidalnych zmian temperatury na powłokowe systemy ochronne o skrajnie różnych właściwościach antykorozyjnych. Porównano zachowanie nowej powłoki poliestrowej typu "coil-coating" na ocynkowanej stali uprzednio eksponowanej w warunkach atmosferycznych alkidowej powłoki malarskiej na podłożu stalowym. Badania przeprowadzono przy zastosowaniu techniki spektroskopii impedancyjnej. Stwierdzono...
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Dynamic electrochemical impedance spectroscopy of the first order electrode reaction
PublikacjaCiągłe transformaty STFT sinusoidalnego sygnału pobudzenia i odpowiedzi prądowej zostały wyznaczone dla reakcji elektrodowej pierwszego rzędu. Wyznaczono impedancję elektrody w łącznej dziedzinie czasu i częstotliwości. Wykonano pomiary dla reakcji redukcji Cd(II) na rtęciowej elektrodzie kroplowej w funkcji potencjału. Przedstawiono możliwość wyznaczenia chwilowych widm impedancyjnych. Opisano zależność rezystancji przeniesienia...