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Wyniki wyszukiwania dla: THERMOGRAVIMETRIC ANALYSIS
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Thermogravimetric analysis/ pyrolysis of used tyres and waste rubber
PublikacjaThe process of pyrolysis is investigated in this paper. The pyrolysis results of two samples: waste tyres and rubber at different heating rates (10, 20, 50 K/min), were compared. In other experiments the degradation of two pyrolysis products, char and oil was examined. The kinetic study using the thermogravimetry equipment (TG) was done, which allowed determination of the kinetic mechanism of the process. The elemental analysis...
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Thermogravimetric analysis (TGA ) and derivative thermogravimetry (DTG) results for potassium citrate
Dane BadawczeThese data contains thermogravimetric analysis (TGA ) and derivative thermogravimetry (DTG) results for thermal decomposition of potassium citrate.
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Thermogravimetric analysis data of hydration in air and nitrogen for BaCe0.6Zr0.2Y0.1M0.1O3-δ (M = Fe, Pr, Tb)
Dane BadawczeThe dataset consists of 6 files of thermogravimetric analysis (TGA) data. The TGA experiments of hydration for BaCe0.6Zr0.2Y0.1Fe0.1O3-δ (BCZYFe), BaCe0.6Zr0.2Y0.1Pr0.1O3-δ (BCZYPr), and BaCe0.6Zr0.2Y0.1Tb0.1O3-δ (BCZYTb) were conducted on Netzsch STA 449.
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FTIR spectroscopic and thermogravimetric characterization of ground tyre rubber devulcanized by microwave treatment
PublikacjaIn this work, the phenomena involved in the microwave devulcanization of ground tyre rubber (GTR) were investigated. Three types of GTR with different content of organic compounds (elastomers, plasticizers, etc.), carbon black and ash have been studied. The chemical structure of GTR before and after a microwave devulcanization process was analyzed by Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA)...
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Validation of polyurethane-wood composites properties
Dane BadawczeThis study focuses on the development of the PU-WC manufacturing method, the determination of properties of this type of composite, and the indication of its potential application. The mechanical properties of PU-WC were characterized by flexural tests. To determine the thermal properties, dynamic mechanical analysis (DMA) and thermogravimetric analysis...
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Thermgravimetric analysis (TGA) data of cement pastes containing pristine and silica-coated bismuth oxide and gadolinium oxide particles
Dane BadawczeThermogravimetric (TGA) data of cement pastes after 2, 7 and 28 days. Samples designations: Control, BG, BG-A and BG-B are associated with the specimen names in the associated publication.
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Thermal stability of V2O5 nanorods under oxidizing atmosphere
Dane BadawczeThe DataSet contains the TGA curves of V2O5 nanorods obtained at 650°C. The information about nanorods synthesis is described in the Journal of Nanomaterials.
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Thermal stability analysis of poly(lactic acid)-carbon black-nanodiamond composite
Dane BadawczeThis dataset contains thermal stability tests carried out on new 3D printing-dedicated composites with poly-lactic acid (PLA), carbon black (CB) and nanodiamond fillers. Two types of nanodiamonds were studied: detonation nanodiamonds (DND) and boron-doped carbon nanowalls (BCNW). The investigated techniques include: thermogravimetric analysis (TGA)...
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Water uptake analysis of acceptor-doped lanthanum orthoniobates
PublikacjaIn this work, lanthanum orthoniobates doped with either antimony, calcium, or both have been synthesized and studied. The water uptake of the investigated materials has been analyzed by means of thermogravimetric studies. The results show the difference between the thermodynamics of hydration between the lanthanum orthoniobate system and other proton conducting ceramics. The relation between the water uptake and effective acceptor...
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Influence of bio-polyols with different molecular weight on properites of PUR-PIR foams
Dane BadawczeThis work attempts to validate the possibility of replacing petrochemical polyols with previously synthesized bio-polyols and their impact on the structure and properties of rigid polyurethane-polyisocyanurate (PUR-PIR). The influence of bio-polyols addition on foam properties was investigated by mechanical testing, Fourier transform infrared spectroscopy...
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Decomposition kinetics of vanadium xerogel powder
Dane BadawczeThe DataSet contains the TGA curves of vanadium As-prepared xerogel powder with different heating rates. The information about sol synthesis is described in the Journal of Nanomaterials.
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Thermal behaviour of vanadium xerogel powder under different inert atmosphere
Dane BadawczeThe DataSet contains the results of the thermal behavior of the vanadium xerogel powder. The information about xerogel powder synthesis is described in the Journal of Nanomaterials.
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Thermal stability of V2O5 nanorods under inert atmosphere
Dane BadawczeThe DataSet contains the TGA curves of V2O5 nanorods obtained at 650°C. The information about nanorods synthesis is described in the Journal of Nanomaterials.
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Structure analysis and thermal degradation characteristics of bio-based poly(propylene succinate)s obtained by using different catalyst amounts
PublikacjaLinear bio-based polyester polyols were prepared with the use of succinic acid and 1.3-propanediol (both with natural origin). As a catalyst was used tetraisopropyl orthotitanate (TPT). In order to determine the effect of various catalyst content on the thermal degradation characteristics, three different TPT amounts, as a 1.3-propanediol equivalent, were used, namely 0.1 mass% (PPS-0.1), 0.2 mass% (PPS-0.2) and 0.25 mass% (PPS-0.25)....
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Thermal stability of vanadium xerogel powder under different atmpshere
Dane BadawczeThe DataSet contains the results of the thermal behavior of the vanadium xerogel powder. The information about xerogel powder synthesis is described in the Journal of Nanomaterials.
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TG and DTG profiles for plastics: LDPE, HDPE, PP, PD and PET
Dane BadawczeThe dataset includes:
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Thermal behaviour of vanadium xerogel powder and V2O5 nanorods under helium atmosphere
Dane BadawczeThe DataSet contains the results of the thermal behavior of the vanadium xerogel powder and V2O5 nanorods obtained at 650C. The information about xerogel powder and V2O5 nanorods synthesis is described in the Journal of Nanomaterials.
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Valorization of bio-based polyols synthesized via biomass liquefaction
Dane BadawczeAs the properties of polyols have a huge impact on the properties of manufactured polyurethanes, this study aims to determine the influence of polyethylene glycols with different molecular masses on the course of the biomass liquefaction process and bio-polyol properties. The obtained polyols were characterized by rheological studies. To confirm the...
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Thermal properties of VO2 and V2O3 nanostructures
Dane BadawczeThe DataSet contains the DSC and TG curves of VO2 and V2O3 nanostructures obtained by the sol-gel with different reaction conditions. The information about xerogel powder synthesis is described in the Journal of Nanomaterials. The xerogel powder was annealing under argon atmosphere at the selected temperature: 500C, 600C, and 1000C.
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Fully bio-based poly(propylene succinate) synthesis and investigation of thermal degradation kinetics with released gases analysis
PublikacjaOne of the most important information about polyesters is their thermal stability and phase transition tem- peratures. These characteristics give information about the promising behavior of the polyester during proces- sing. In this work, linear bio-based polyester polyols were prepared with the use of succinic acid and 1.3- propanediol (both with natural origin). As a polycondensation catalyst was used tetraisopropyl orthotitanate...
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Cellulose Nanofibers Isolated from the Cuscuta Reflexa Plant as a Green Reinforcement of Natural Rubber
PublikacjaIn the present work, we used the steam explosion method for the isolation of cellulose nanofiber (CNF) from Cuscuta reflexa, a parasitic plant commonly seen in Kerala and we evaluated its reinforcing efficiency in natural rubber (NR). Fourier Transform Infrared Spectroscopy (FTIR), X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), and Thermogravimetric analysis (TGA) techniques...
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Hydrothermal reactions: From the synthesis of ligand to new lanthanide 3D-coordination polymers
PublikacjaThe organic ligand 2,5-piperazinedione-1,4-diaceticacid (H2PDA) was synthesized under hydrothermal conditions starting from the iminodiacetic acid and catalyzed by oxalic acid. The X-ray powder diffraction data indicates that the compound crystallizes in the P21/c space group as reported in the literature. The ligand was also characterized by elemental analysis, magnetic nuclear resonance, infrared spectroscopy and thermogravimetric...
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Bio based PUR-PIR foams thermal degradation (TG) and isoconversional kinetics
Dane BadawczeIn the present work, we perform a thorough thermogravimetric (TG) analysis of the bio-based polyurethane – polyisocyanurate (PUR-PIR) foams in both nitrogen and oxygen atmosphere. A sustainable element of the foam was a biopolyol obtained via acid-catalyzed liquefaction of Zostera Marina and Enteromorpha Algae biomass. Based on isoconversional analysis...
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Structural and physico-mechanical properties of natural rubber/GTR composites devulcanized by microwaves: Influence of GTR source and irradiation time
PublikacjaGround tire rubber from car and truck was modified using microwave irradiation at variable time. The irradiated ground tire rubber was used as filler in composites based on natural rubber. The composites, with high content of ground tire rubber, were prepared using an internal batch mixer and subsequently cross-linked at 160℃. The influence of the ground tire rubber source (car/truck) and irradiation time on structure, physico-mechanical...
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Enhancement of PUR/PIR foam thermal stability after addition of Zostera marina biomass component investigated via thermal analysis and isoconversional kinetics
PublikacjaIn the present work, a thorough thermogravimetric (TG) analysis of bio-based polyurethane–polyisocyanurate (PUR–PIR) foams in both nitrogen and oxygen atmosphere is performed. A sustainable element of the foam is a biopolyol obtained via acid-catalyzed liquefaction of Zostera marina and Enteromorpha Algae biomass. Based on isoconversional analysis and apparent activation energies, several conclusions are obtained. In contradiction...
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Terbium Substituted Lanthanum Orthoniobate: Electrical and Structural Properties
PublikacjaThe results of electrical conductivity studies, structural measurements and thermogravimetric analysis of La1−xTbxNbO4+δ (x = 0.00, 0.05, 0.1, 0.15, 0.2, 0.3) are presented and discussed. The phase transition temperatures, measured by high-temperature x-ray diffraction, were 480 °C, 500 °C, and 530 °C for La0.9Tb0.1NbO4+δ, La0.8Tb0.2NbO4+δ, and La0.7Tb0.3NbO4+δ, respectively. The impedance spectroscopy results suggest mixed conductivity...
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Thermal behaviour of vanadium xerogel powder under oxidizing atmosphere
Dane BadawczeThe DataSet contains the results of the thermal behavior of the vanadium xerogel powder. The information about xerogel powder synthesis is described in the Journal of Nanomaterials.
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Thermal behaviour of vanadium xerogel powder under argon atmosphere
Dane BadawczeThe DataSet contains the results of the thermal behavior of the vanadium xerogel powder. The information about xerogel powder synthesis is described in the Journal of Nanomaterials.
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Thermal behavior of (NH4)V4O10xH2O
Dane BadawczeThe DataSet contains the results of the thermal behavior of the (NH4)V4O10xH2O obtained by the hydrothermal method using different precursors: microstructured (commercially available) or nanostructured. The information about samples synthesis is described in the Materials.
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Thermal behaviour of NH4VO3 microcasketoids
Dane BadawczeThe DataSet contains the results of the thermal behavior of the ammonium metavanadate microcasketoids under argon and nitrogen atmosphere. Thermogravimetric analysis (TG) was carried out under argon or nitrogen atmosphere from 40C to 560C (with a heating rate of 10 C/min) using Netzsch STA 449 F1. The thermal behavior was also studied with mass spectrum...
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Thermal behaviour of NH4VO3 nanoflowers
Dane BadawczeThe DataSet contains the results of the thermal behavior of the ammonium metavanadate nanoflowers under argon and nitrogen atmosphere. Thermogravimetric analysis (TG) was carried out under argon or nitrogen atmosphere from 40C to 560C (with a heating rate of 10 C/min) using Netzsch STA 449 F1. The thermal behavior was also studied with mass spectrum...
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Thermal behaviour of NH4VO3 elongated microcrystals
Dane BadawczeThe DataSet contains the results of the thermal behavior of the ammonium metavanadate elongated microcrystals under argon and nitrogen atmosphere. Thermogravimetric analysis (TG) was carried out under argon or nitrogen atmosphere from 40C to 560C (with a heating rate of 10 C/min) using Netzsch STA 449 F1. The thermal behavior was also studied with mass...
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Thermal behaviour of commercial avaible NH4VO3
Dane BadawczeThe DataSet contains the results of the thermal behavior of the commercially available ammonium metavanadate (CAS 7803-55-6) under argon and nitrogen atmosphere. Thermogravimetric analysis (TG) was carried out under argon or nitrogen atmosphere from 40C to 560C (with a heating rate of 10 C/min) using Netzsch STA 449 F1. The thermal behavior was also...
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Thermal behaviour of NH4VO3 microflowers
Dane BadawczeThe DataSet contains the results of the thermal behavior of the ammonium metavanadate microflowers under argon and nitrogen atmosphere. Thermogravimetric analysis (TG) was carried out under argon or nitrogen atmosphere from 40C to 560C (with a heating rate of 10 C/min) using Netzsch STA 449 F1. The thermal behavior was also studied with mass spectrum...
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Thermal behaviour of ammonium vanadate nanocrystals
Dane BadawczeThe DataSet contains the thermal behavior of the ammonium vanadate nanostructures obtained by the hydrothermal method with different conditions. Thermogravimetric analysis (TG) was carried out under an argon atmosphere from 40C to 560C (with a heating rate of 10 C/min) using Netzsch STA 449 F1. The thermal behavior was also studied with mass spectrum...
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Thermal behavior of TeOx xerogel powder under different atmospheres
Dane BadawczeThe DataSet contains the results of the thermal behavior of the TeOx xerogel powder measured under different atmospheres. The material was obtained by the sol-gel method. The starting solution was prepared by mixing telluric acid (precursor) with thetraetylene glycol, water, and ethanol. The sol was obtained by vigorously stirring precursor solution...
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Materials for Mediator-free Electron Transfer in the Enzymatic Electrodes of Biobatteries and Biofuel Cells
PublikacjaWe present functionalization of single-walled carbon nanotubes (SWCNTs) and their application in the enzymatic fuel cells construction. SWCNTs were covalently modified with different types of aromatic moieties. Free radical reaction was employed to create direct carbon-carbon bond between moiety and SWCNTs. In second approach functionalization takes place through amide bonding. Functionalized SWCNTs were characterized by spectroscopy...
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Rigid polyurethane foams modified with ground tire rubber - mechanical, morphological and thermal studies
PublikacjaRigid polyurethane foams, prepared by a single step method, were modified with the two types of ground tire rubber particles, i.e. untreated and thermo-mechanically reclaimed by using a co-rotating twin screw extruder. The foaming process as well as the structure and the physical, mechanical and thermal properties of the resulting foams were investigated. The presence of ground tire rubber decreased the velocity of polymerization....
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Preliminary Investigation on Auto-Thermal Extrusion of Ground Tire Rubber
PublikacjaGround tire rubber (GTR) was processed using an auto-thermal extrusion as a prerequisite to green reclaiming of waste rubbers. The reclaimed GTR underwent a series of tests: thermogravimetric analysis combined with Fourier-transform infrared spectroscopy (TGA-FTIR), scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR), and static headspace and gas chromatography-mass spectrometry (SHS-GC-MS) in order...
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The luminescence study of (C10H16N)2MnBr4 Organic–Inorganic Hybrid
Dane BadawczeOrganic–inorganic hybrid metal halides have recently attracted attention in the global research field for their bright light emission, tunable photoluminescence wavelength, and convenient synthesis method. This study reports the detailed properties of (C10H16N)2MnBr4, which emits bright green light with a high photoluminescence quantum yield. Results...
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Thermal behavior of VO2/V2O3 nanostructures obtained at 500°C under argon atmosphere
Dane BadawczeThe DataSet contains the results of the thermal behavior of the VO2/V2O3 nanostructures. The vanadium oxides nanostructures were synthesized by the sol-gel method, where obtained xerogel powder was annealing at 500°C under an argon atmosphere. The information about xerogel powder synthesis is described in the Journal of Nanomaterials.
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Thermal behavior of VO2/V2O3 nanostructures obtained at 1000°C under argon atmosphere
Dane BadawczeThe DataSet contains the results of the thermal behavior of the VO2/V2O3 nanostructures. The vanadium oxides nanostructures were synthesized by the sol-gel method, where obtained xerogel powder was annealing at 1000°C under an argon atmosphere. The information about xerogel powder synthesis is described in the Journal of Nanomaterials.
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Thermal behavior of VO2/V2O3 nanostructures obtained at 650°C under reducing atmosphere
Dane BadawczeThe DataSet contains the results of the thermal behavior of the VO2/V2O3 nanostructures. The vanadium oxides nanostructures were synthesized by the sol-gel method, where obtained xerogel powder was annealing at 650°C under a reducing atmosphere (95% Ar 5% H2). The information about xerogel powder synthesis is described in the Journal of Nanomaterials.
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Thermal behavior of VO2/V2O3 nanostructures obtained at 400°C under argon atmosphere
Dane BadawczeThe DataSet contains the results of the thermal behavior of the VO2/V2O3 nanostructures. The vanadium oxides nanostructures were synthesized by the sol-gel method, where obtained xerogel powder was annealing at 400°C under an argon atmosphere. The information about xerogel powder synthesis is described in the Journal of Nanomaterials.
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Thermal behavior of VO2/V2O3 nanostructures obtained at 700°C under argon atmosphere
Dane BadawczeThe DataSet contains the results of the thermal behavior of the VO2/V2O3 nanostructures. The vanadium oxides nanostructures were synthesized by the sol-gel method, where obtained xerogel powder was annealing at 700°C under an argon atmosphere. The information about xerogel powder synthesis is described in the Journal of Nanomaterials.
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Thermal behavior of TeOx powder
Dane BadawczeThe DataSet contains the results of the thermal behavior of the TeOx powder. The material was obtained by the sol-gel method. The starting solution was prepared by mixing telluric acid (precursor) with thetraetylene glycol, water, and ethanol. The sol was obtained by vigorously stirring precursor solution at 50°C for 2h, then the temperature was raised...
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Thermal behavior of VO2/V2O3 nanostructures obtained at 800°C under argon atmosphere
Dane BadawczeThe DataSet contains the results of the thermal behavior of the VO2/V2O3 nanostructures. The vanadium oxides nanostructures were synthesized by the sol-gel method, where obtained xerogel powder was annealing at 800°C under an argon atmosphere. The information about xerogel powder synthesis is described in the Journal of Nanomaterials.
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Thermal behavior of VO2/V2O3 nanostructures obtained at 600°C under argon atmosphere
Dane BadawczeThe DataSet contains the results of the thermal behavior of the VO2/V2O3 nanostructures. The vanadium oxides nanostructures were synthesized by the sol-gel method, where obtained xerogel powder was annealing at 600°C under an argon atmosphere. The information about xerogel powder synthesis is described in the Journal of Nanomaterials.
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Thermal and mechanical properties of polyurethanes modified with L-ascorbic acid
PublikacjaIn this study we report the thermal and mechanical properties of polyurethanes modified with ascorbic acid (AA). Ascorbic acid was used as a modifier at concentration of 1 or 2 mass%. The antioxidative properties of AA may improve the biocompatibility of the obtained materials, which were designed for biomedical applications. In this paper we describe characterization of obtained unmodified and ascorbic acid modified polyurethanes...
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PROCESSING, MECHANICAL AND THERMAL PROPERTIES OF RECYCLED LOW-DENSITY POLYETHYLENE STREAMS
PublikacjaThe recycling of plastics is currently one of the most significant industrial challenges. Due to the enormous amounts of plastic wastes generated by various industry branches, it is essential to look for the potential methods of their utilization. Nevertheless, for the efficient application of recycled materials it is crucial to analyze their performance. Therefore, in presented paper we investigated the processing (melt flow index),...
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Characterization of Highly Filled Glass Fiber/Carbon Fiber Polyurethane Composites with the Addition of Bio-Polyol Obtained through Biomass Liquefaction
PublikacjaThis work aims to investigate the process of obtaining highly filled glass and carbon fiber composites. Composites were manufactured using previously obtained cellulose derived polyol, polymeric methylene diphenyl diisocyanate (pMDI). As a catalyst, dibutyltin dilaurate 95% and Dabco® 33-LV were used. It was found that the addition of carbon and glass fibers into the polymer matrix causes an increase in the mechanical properties...
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Morphology changes in Fe-Cr porous alloys upon high-temperature oxidation quantified by X-ray tomographic microscopy
PublikacjaThe effect of high-temperature oxidation at 850 C (10 h, 30 h, 100 h) and 900 C (10 h) on porous (30 % porosity) ferritic stainless steel (Fe22Cr) has been investigated using synchrotron tomographic microscopy, which allowed for visualisation, separation and quantitative analysis of the metallic core, closed pores, open pores and oxide scale phase. The same regions within the samples were investigated before and after oxidation...
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Influence of chemical structure on physicochemical properties and thermal decomposition of the fully bio-based poly(propylene succinate-co-butylene succinate)s
PublikacjaIn this work, two polyesters and four copolyesters were studied. All materials were synthesized to obtain the monomers dedicated for thermoplastic polyurethane elastomers. For this type of PUR, the monomers should characterize by appropriate selected physicochemical properties and macromolecular structure distribution, which depends on synthesis conditions. The study of chemical structure with extensive and knowledgeable analysis...
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Recycled Polyurethane as a Second Phase in Thermoset Blends and Its Effect on Thermal Degradation Kinetics Studies
PublikacjaA new approach is introduced in the modification of thermosetting polymer by using different amount of polyurethane of waste origin. The post consumer polyurethane foam coatings are degraded using glycolysis process and the recycled product is further converted into new polyurethane. The blending of recycled polyurethane with epoxy exhibits transparency and produces nanostructures. The effective interaction between two polymers...
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Novel cast polyetherurethanes based on dispersed polymeric polyols
PublikacjaOur study was focused on obtaining polyetherurethanes synthesized with using polymeric polyether based polyols differing in dispersed copolymer content (10, 20 and 40 wt%). The polyetherurethane materials were synthesized via two step method. The influence of different polymeric polyether based polyols on the chemical structure, morphology, mechanical and thermal properties of the obtained polyetherurethanes was investigated. The...
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Effect of bio-polyol molecular weight on the structure and properties of polyurethane-polyisocyanurate (PUR-PIR) foams
PublikacjaThe increasing interest in polyurethane materials has raised the question of the environmental impact of these materials. For this reason, the scientists aim to find an extremely difficult balance between new material technologies and sustainable development. This work attempts to validate the possibility of replacing petrochemical polyols with previously synthesized bio-polyols and their impact on the structure and properties...
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Reclaimed Rubber/Poly(ε‐caprolactone) Blends: Structure, Mechanical, and Thermal Properties
PublikacjaThe amount of elastomeric waste, especially from tires is constantly increasing on a global scale. The recycling of these residua should be considered a priority. Compounding the waste rubbers with other polymers can be an excellent alternative to reuse waste materials. This procedure requires solving the issue of the lack of compatibility between the waste rubber particles and other polymers. Simultaneously, there is a claim for...
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Study of nanomechanical properties of (1-y)BST-yMgO thin films
PublikacjaIn the present study thin films of MgO – modified Ba0.6Sr0.4TiO3 (BST60/40) solid solution were prepared by the sol-gel-type chemical solution deposition method on stainless steel substrates. A multilayer spin-coating approach was utilized for the Ba0.6Sr0.4TiO3-MgO thin film deposition with subsequent thermal annealing at T=650-750C. Dried BST60/40-MgO gel powders were studied with thermogravimetric and differential thermal analysis...
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Synergistic Effects of Bitumen Plasticization and Microwave Treatment on Short-Term Devulcanization of Ground Tire Rubber
PublikacjaGround tire rubber (GTR) was mechano-chemically modified with road bitumen 160/220 and subsequently treated using a microwave radiation. The combined impact of bitumen 160/220 content and microwave treatment on short-term devulcanization of GTR was studied by thermal camera, wavelength dispersive X-ray fluorescence spectrometry (WD-XRF), static headspace, and gas chromatography-mass spectrometry (SHS-GC-MS), thermogravimetric analysis...
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Influence of hydrogen on a nanocrystalline high-entropy oxide with application potential in hydrogen technologies
PublikacjaThe influence of hydrogen on a (Co0⋅2Cu0⋅2Mg0⋅2Ni0⋅2Zn0.2)O HEO with a rock salt structure was studied. Two forms of this HEO (nanopowder and sinter) were prepared via mechanochemical synthesis (MS) and additional heat treatment, respectively. The chemical stability of the synthesized samples in a pure hydrogen atmosphere was investigated using Sievert’s technique. High-pressure hydrogenation at 250 ◦C had no noticeable effect...
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Assessment of the impact of bacteria Pseudomonas denitrificans, Pseudomonas fluorescens, Bacillus subtilis and yeast Yarrowia lipolytica on commercial poly(ether urethanes)
PublikacjaThe assessment of the impact of the bacteria Pseudomonas denitrificans, Pseudomonas fluorescens, Bacillus subtilis and yeast Yarrowia lipolytica on commercial poly(ether urethanes) Tecoflex® and Tecothane® is presented. The polyurethane samples were incubated with pure cultures of the microorganisms at 30 °C for five months. The changes in the chemical structure of the polymers were evaluated using loss of weight and contact angle...
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Softwood-lignin/natural rubber composites containing novel plasticizing agent: Preparation and characterization
PublikacjaComposite materials based on natural rubber were obtained by using glycerolysate (decomposition prod- uct of polyurethane) as a novel plasticizer. In order to determine the effect of various lignin content, four different filler amounts were used, namely, 5 phr (parts per 100 parts of natural rubber) of lignin (WLI5G), 10 phr (WLI10G), 20 phr (WLI20G), and 40 phr (WLI40G). The reference specimen without lignin (WLI0G) was also...
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Compatibility of Sustainable Mater-Bi/poly(ε-caprolactone)/cellulose Biocomposites as a Function of Filler Modification
PublikacjaDespite their popularity and multiplicity of applications, wood–polymer composites (WPCs) still have to overcome particular issues related to their processing and properties. The main aspect is the compatibility with plant-based materials which affects the overall performance of the material. It can be enhanced by strengthening the interfacial adhesion resulting from physical and/or chemical interactions between the matrix and...
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Solvent-Free Synthesis of Phosphonic Graphene Derivative and Its Application in Mercury Ions Adsorption
PublikacjaFunctionalized graphene was efficiently prepared through ball-milling of graphite in the presence of dry ice. In this way, oxygen functional groups were introduced into material. The material was further chemically functionalized to produce graphene derivative with phosphonic groups. The obtained materials were characterized by spectroscopic and microscopic methods, along with thermogravimetric analysis. The newly developed material...
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Isothermal Vulcanization and Non-Isothermal Degradation Kinetics of XNBR/Epoxy/XNBR-g-Halloysite Nanotubes (HNT) Nanocomposites
PublikacjaThe effect of several concentrations of carboxylated nitrile butadiene rubber (XNBR) functionalized halloysite nanotubes (XHNTs) on the vulcanization and degradation kinetics of XNBR/epoxy compounds were evaluated using experimental and theoretical methods. The isothermal vulcanization kinetics were studied at various temperatures by rheometry and differential scanning calorimetry (DSC). The results obtained indicated that the...
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Investigation of Thermoplastic Polyurethanes Synthesized via Two Different Prepolymers
PublikacjaThe man aim of this work was to investigate the effect of the molecular weight of polyols, mixture of prepolymers, and [NCO]/[OH] molar ratio used during the prepolymer chain extending step on the chemical structure, thermomechanical and mechanical properties, and thermal stability of thermoplastic poly(ether-urethane)s In this work thermoplastic poly(ether-urethane)s were synthesized by using polyols with a various molecular weight,...
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Effect of sisal fiber filler on thermal properties of bio-based polyurethane composites
PublikacjaThis work is mainly focused on study of thermal and thermomechanical properties of obtained bio-based polyurethane (coded as bio-PU) composites via using different types of bio-components (bio-glycol, modified soybean oil and sisal fiber) in the procedure. The chemical structure, morphology and mechanical properties were also investigated and described in this manuscript in order to know more perfect characterization of produced...
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Cast polyurethanes obtained from reactive recovered polyol intermediates via crude glycerine decomposition process
PublikacjaIn this work, the possibility of applying intermediates from polyurethane waste recycling in polyurethane synthesis was presented. Polyurethanes were synthesised in a two-step method using a mixture of petrochemical polyol and glycerolysate, used as a reactive component, 4,4-diphenylmethane diisocyanate (MDI) and 1,4-buthanediol (BD). Glycerolysates were produced during decomposition of polyurethane elastomer by crude glycerine...
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Study on the Structure-Property Dependences of Rigid PUR-PIR Foams Obtained from Marine Biomass-Based Biopolyol
PublikacjaThe paper describes the preparation and characterization of rigid polyurethane-polyisocyanurate (PUR-PIR) foams obtained with biopolyol synthesized in the process of liquefaction of biomass from the Baltic Sea. The obtained foams differed in the content of biopolyol in polyol mixture (0–30 wt%) and the isocyanate index (IISO = 200, 250, and 300). The prepared foams were characterized in terms of processing parameters (processing...
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Morphology, Mechanical and Thermal Properties of Thermoplastic Polyurethane Containing Reduced Graphene Oxide and Graphene Nanoplatelets
PublikacjaPolyurethane/graphene nanocomposites were synthesized using commercial thermoplastic polyurethane (TPU, Apilon 52DE55), and two types of graphene derivatives: graphene nanoplatelets (GNP) and reduced graphene oxide (RGO). Fourier Transformation Infrared Spectroscopy Fourier Transformation Infrared Spectroscopy (FTIR) spectroscopy, TEM, and SEM microscopy and XRD techniques were used to chemically and structurally characterize GNP...
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Interrelationship between total volatile organic compounds emissions, structure and properties of natural rubber/polycaprolactone bio-blends cross-linked with peroxides
PublikacjaNatural rubber/polycaprolactone (NR/PCL) bio-based blends with different organic peroxides were prepared using an internal batch mixer and subsequently cross-linked at 170°C. Two types of commonly used organic peroxides, dicumyl peroxide and di(tert-butylperoxyisopropyl)benzene peroxide, were applied as free-radical initiator. Cross-linking efficiency of NR/PCL blends were investigated using oscillating disc rheometer measurements,...
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The influence of thermal conditions on V2O5 nanostructures prepared by sol-gel method
PublikacjaThis work presents the result of structure investigations ofV 2O5 nanorods grown from thin films and powders prepared by sol-gel method. To examine the best temperature of nanorods crystallization, thin films deposited by spin-coating method on quartz glass or silicon substrates and bulk xerogel powders were annealed at various temperatures ranging from 100∘C to 600∘C. The structure of the samples was characterized by X-ray diffraction...
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High temperature corrosion resistance of porous hastelloy alloy
PublikacjaTo further understand the suitability of Ni-Cr-base alloy for solid oxide fuel cell (SOFC), a commercial Ni-Cr-Fe-Mo alloy, Hastelloy X was selected and evaluated for oxidation behaviour under high temperature conditions. HastelloyX was chosen due to its unusual resistance to oxidizing, reducing and neutral atmospheres. For long term stability of metal supported fuel cell, the corrosion resistance plays a vital role and must be...
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Effect of small quantities of potassium promoter and steam on the catalytic properties of nickel catalysts in dry/combined methane reforming
PublikacjaCarbon dioxide and methane are two of the principal greenhouse gases. Reduction of their content in the atmosphere is currently the subject of much worldwide research. Dry and combined reforming of methane are effective methods of CO2 and CH4 utilization and production of synthesis gas (syngas) in chemical technology. Testing of catalysts that provide the desired H2/CO ratio and long operation time is one of the critical aspects...
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Structural Adaptive, Self-Separating Material for Removing Ibuprofen from Waters and Sewage
Publikacja-cyclodextrin nanosponge (CDM) was used for the adsorption of ibuprofen (IBU) from water and sewage. The obtained material was characterized by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), Brunauer–Emmett–Teller (BET), Barrett– Joyner–Halenda (BJH), Harkins and Jura t-Plot, zeta potential, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and elementary analysis (EA)....
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Synthesis and characterization of novel renewable polyesters based on 2,5-furandicarboxylic acid and 2,3-butanediol
PublikacjaNovel polyesters from 2,5-furandicarboxylic acid or 2,5-dimethyl-furandicarboxylate and 2,3-butanediol have been synthesized via bulk polycondensation catalyzed by titanium (IV) n-butoxide, tin (IV) ethylhexanoate, or zirconium (IV) butoxide. The polymers were analyzed by size exclusion chromatography, nuclear magnetic resonance spectroscopy, Fourier transform infrared spectroscopy (FTIR), matrix-assisted laser ionization-desorption...
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Silica Gel Impregnated by Deep Eutectic Solvents for Adsorptive Removal of BTEX from Gas Streams
PublikacjaThe paper presents the preparation of new adsorbents based on silica gel (SiO2) impregnated with deep eutectic solvents (DESs) to increase benzene, toluene, ethylbenzene, and p-xylene (BTEX) adsorption efficiency from gas streams. The DESs were synthesized by means of choline chloride, tetrapropylammonium bromide, levulinic acid, lactic acid, and phenol. The physico-chemical properties of new sorbent materials, including surface...
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Insights into modification of lignocellulosic fillers with isophorone diisocyanate: structure, thermal stability and volatile organic compounds emission assessment
PublikacjaThis study presents an analysis of the structure and properties of different types of lignocellulosic fillers modified by isophorone diisocyanate (IPDI) to provide insights into the possibility of their application to the manufacturing of wood polymer composites (WPCs). Moreover, it deals with the environmental aspects of modified fillers, by assessment of volatile organic compounds (VOCs) emitted during modification, as well as...
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A study of the kinetics of bismuth telluride synthesis by an oxide reduction method
PublikacjaThe kinetics of a reduction of bismuth and tellurium oxides in a hydrogen atmosphere, leading to the formation of thermoelectric bismuth telluride is investigated. The evaluation of the reaction kinetics was based on a thermogravimetric analysis performed in non-isothermal conditions. A non-parametric analysis method and the Friedman method were used for the evaluation of the data. Additionally, for a better understanding of the...
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Thermal degradation kinetics of poly(propylene succinate) prepared with the use of natural origin monomers
PublikacjaLinear biobased polyester polyols were prepared with the use of succinic acid and 1,3-pro- panediol (both with natural origin). Tetraisopropyl orthotitanate (TPT) was used as a catalyst. In order to determine the effect of various synthesis temperature conditions on the thermal degradation kinet- ics, nine sequences of temperature conditions were used during two-step polycondensation reaction. Thermogravimetric analysis was conducted...
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Fabrication of toughened plastic using styrene butadiene rubber-poly (methyl methacrylate) interpenetrating polymer networks
PublikacjaA standard set of interpenetrating polymeric networks (IPNs) has been contrived using an elastomerstyrene butadiene rubber and a thermoplastic poly (methyl methacrylate) through sequential polymerization protocol. This low-cost material can be hopefully engaged as a toughened plastic with cocontinuous morphology. Different morphological protocols including Raman imaging are effectively utilized to envisage the effect of blend ratio...
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Synthesis of Phosphonated Carbon Nanotubes: New Insight into Carbon Nanotubes Functionalization
PublikacjaCarbon nanotubes were successfully functionalized for the first time in a free radical phosphonylation reaction. Three synthetic protocols were proposed. Carbon nanotubes and diethylphosphite reacted in the presence of known radical initiator, such as azobisisobutyronitrile, single electron oxidant—Mn(OAc)3, or under UV radiation. The functionalized material was fully characterized by means of spectroscopic methods, together with...
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Synthesis and characterisation of polyurethane elastomers with semi-products obtained from polyurethane recycling
PublikacjaIn this work polyurethane elastomers were synthesised by using different mixtures of a petrochemical and glycerolysate polyols and 4,4-diphenylmethane diisocyanate (MDI). Glycerolysate polyol was produced from polyurethane foam decomposition using crude glycerine as a decomposition agent. The structure and thermal properties of obtained semi-product were similar to the polyol used in the synthesis of original foam. Glycerolysate...
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Structural, mechanical and thermal behavior assessments of PCL/PHB blends reactively compatibilized with organic peroxides
PublikacjaThe efficiency of two commercially available organic peroxides, dicumyl peroxide (DCP) and di-(2-tert-butyl-peroxyisopropyl)-benzene (BIB), during reactive processing of poly (ε-caprolactone)/poly (3-hydroxybutyrate) (PCL/PHB) blends was investigated. The changes in chemical structure of PCL/PHB blends, as a function of organic peroxide type (DCP/BIB) and content (in range: 0–1.0 parts by weight - pbw), were characterized by Fourier...
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Effect of high loading of titanium dioxide particles on the morphology and selected properties of natural rubber-based composites
PublikacjaThe aim of this work was to prepare and characterize the natural rubber vulcanizates contained different amounts of titanium dioxide particles. At first rubber mixture was prepared using a laboratory two-roll mill and then samples were vulcanized in a hydraulic press. The formulation of rubber mixture and rubber-processing technique is based on our earlier investigations. Materials were obtained at the different titanium dioxide...
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Ground tire rubber thermo-mechanically devulcanized in the presence of waste engine oil as asphalt modifier
PublikacjaCross-linked elastomers network is main limitation for industrial usage of ground tire rubber (GTR) as asphalts’ and road pavements modifier. GTR was thermo-mechanically devulcanized via extrusion in the presence of waste engine oil (WEO) at temperature ranges from 150 to 280 °C. Combined impact of WEO content and extruder barrel temperature on the change of cross-linked structure of degraded GTR (DTGR) was investigated through...
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Hybrid TiO2–Polyaniline Photocatalysts and their Application in Building Gypsum Plasters
PublikacjaHybrid materials of conjugated polymer and titanium(IV) oxide have attracted considerable attention concerning their potential benefits, including (i) ecient exploitation of visible light, (ii) a high adsorption capacity for organic contaminants, (iii) and eective charge carriers separation. The new class of the photocatalysts is promising for the removal of environmental pollutants in both aqueous and gaseous phases. For the first...
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The Effect of Surface Treatment with Isocyanate and Aromatic Carbodiimide of Thermally Expanded Vermiculite Used as a Functional Filler for Polylactide-Based Composites
PublikacjaIn this work, thermally expanded vermiculite (TE-VMT) was surface modified and used as a filler for composites with a polylactide (PLA) matrix. Modification of vermiculite was realized by simultaneous ball milling with the presence of two PLA chain extenders, aromatic carbodiimide (KI), and 4,4’-methylenebis(phenyl isocyanate) (MDI). In addition to analyzing the particle size of the filler subjected to processing, the efficiency...
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PLA–Potato Thermoplastic Starch Filament as a Sustainable Alternative to the Conventional PLA Filament: Processing, Characterization, and FFF 3D Printing
PublikacjaThe growing popularity of the fused filament fabrication (FFF) 3D printing technology in science, industry, and in-home use is associated with an increased demand for high-quality polymer filaments. This study presents an in-depth characterization and analysis of a self-made bio-based polylactide (PLA)/thermoplastic potato starch (TPS) filament dedicated for the FFF 3D printing technology. The obtained results were compared with...
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Physico‐Mechanical Properties and Flammability of PUR/PIR Foams Containing Expandable Graphite Core‐Shell Composite Particles
PublikacjaIn this work, polyurethane/polyisocyanurate (PUR/PIR) foams were modified by two types of expandable graphite (EG) core-shell composite particles. The pulverized EG core-shell composite particles were prepared during emulsion polymerization using methyl methacrylate or glycidyl methacrylate for the synthesis of the polymeric shells (poly(methyl methacrylate) (PMMA) and poly (glycidyl methacrylate) (PGMA)), and then the obtained EG_PMMA...
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Structure and performance properties of environmentally-friendly biocomposites based on poly(ɛ-caprolactone) modified with copper slag and shale drill cuttings wastes
PublikacjaThe potential application of two types of industrial wastes, drill cuttings (DC) and copper slag (CS), as silica-rich modifiers of poly(ɛ-caprolactone) (PCL) was investigated. Chemical structure and physical properties of DC and CS fillers were characterized using X-ray diffractometer, X-ray fluorescence spectroscopy, particle size and density measurements. PCL/DC and PCL/CS composites with a variable content of filler (5 to 50...
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New synthesis route of highly porous InxCo4Sb12 with strongly reduced thermal conductivity
PublikacjaHighly porous, In-filled CoSb3 skutterudite materials with an attractive thermoelectric figure of merit (ZT * 1) and corresponding dense samples were fabricated through the cost-effective method of reduction in oxides in dry hydrogen and the pulsed electric current sintering (PECS) method, respectively. The reduction process was described in detail using in situ thermogravimetric analysis of Co2O3, Sb2O3 and In(NO3)35H2O separately...
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POM/EVA Blends with Future Utility in Fused Deposition Modeling
PublikacjaPolyoxymethylene (POM) is one of the most popular thermoplastic polymers used in the industry. Therefore, the interest in its potential applications in rapid prototyping is understandable. Nevertheless, its low dimensional stability causes the warping of 3D prints, limiting its applications. This research aimed to evaluate the effects of POM modification with ethylene-vinyl acetate (EVA) (2.5, 5.0, and 7.5 wt.%) on its processing...
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Thermal-Resistant Polyurethane/Nanoclay Powder Coatings: Degradation Kinetics Study
PublikacjaIn the present study, thermal degradation kinetics of polyurethane (PU) powder coatings reinforced with organo-modified montmorillonite (OMMT) was investigated. PU nanocomposites were prepared in different concentrations of 1, 3, and 5 wt.% of OMMT via the extrusion method. The microstructure of the nanocomposites was observed by scanning electron microscope (SEM) illustrating uniform dispersion of OMMT nano-clay platelets in the...
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Perovskite-type KTaO3–reduced graphene oxide hybrid with improved visible light photocatalytic activity
PublikacjaNovel rGO–KTaO3 composites with various graphene content were successfully synthesized using a facile solvothermal method which allowed both the reduction of graphene oxide and loading of KTaO3 nanocubes on the graphene sheets. The as-prepared photocatalysts were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM) with energy dispersive X-ray analysis (EDX), Fourier...
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Poly(ε-Caprolactone)/Poly(Lactic Acid) Blends Compatibilized by Peroxide Initiators: Comparison of Two Strategies
PublikacjaPoly(ε-caprolactone) (PCL) and poly(lactic acid) (PLA) blends were compatibilized by reactive blending and by copolymers formed during reaction in the solution. The reactive blending of PCL/PLA was performed using di-(2-tert-butyl-peroxyisopropyl)benzene (BIB) or dicumyl peroxide (DCP) as radical initiator. PCL-g-PLA copolymers were prepared using 1.0 wt. % of DCP or BIB via reaction in solution, which was investigated through...
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The changes of crosslink density of polyurethanes synthesised with using recycled component. Chemical structure and mechanical properties investigations.
PublikacjaThis paper aims at the utilisation of glycerolysate (Gly) obtained in polyurethane recycling process by means of crude glycerine, which has in its structure hydroxyl end groups that allow for further processing. Polyurethanes (PUs) were synthesised using prepolymer method with the mixture of neat polyol and glycerolysate, in different ratios, with 4,4-diphenylmethane diisocyanate (MDI). The prepolymer was subsequently extended...
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Influence of Surface-Modified Montmorillonite Clays on the Properties of Elastomeric Thin Layer Nanocomposites
PublikacjaIn recent years, polyurethane nanocomposites have attracted more attention due to the massive demand for materials with increasingly exceptional mechanical, optical, electrical, and thermal properties. As nanofillers have a high surface area, the interaction between the nanofiller and the polymer matrix is an essential issue for these materials. The main aim of this study is to validate the impact of the montmorillonite nanofiller...
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Conversion of waste biomass into activated carbon and evaluation of environmental consequences using life cycle assessment
PublikacjaIn this article, activated carbon was produced from Lantana camara and olive trees by H3PO4 chemical activation. The prepared activated carbons were analyzed by characterizations such as scanning electron microscopy, energy-dispersive X-ray spectroscopy, Brunauer–Emmett–Teller, X-ray diffraction, thermogravimetric analysis, and Fourier transform infrared spectroscopy. H3PO4 is used as an activator agent to create an abundant pore...
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Novel Class of Proton Conducting Materials—High Entropy Oxides
PublikacjaHere, for the first time, we present data on proton conductivity of high-entropy, single-phase perovskites. The BaZr0.2Sn0.2Ti0.2Hf0.2Ce0.2O3−δ, BaZr0.2Sn0.2Ti0.2Hf0.2Y0.2O3−δ, BaZr1/7Sn1/7Ti1/7Hf1/7Ce1/7Nb1/7Y1/7O3−δ, and BaZr0.15Sn0.15Ti0.15Hf0.15Ce0.15Nb0.15Y0.10O3−δ single-phase perovskites were synthesized. Before electrical measurements, materials were characterized using X-ray diffraction (XRD), scanning electron microscopy...