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Ranking of Heterogeneous Catalysts Metals by Their Greenness
PublikacjaCatalysis is very important process in industry and laboratory practice, especially from the point of green chemistry principles. However, eco-friendly character of heterogeneous catalysts, containing transition metal components has not been evaluated, yet. Therefore, we perform a comprehensive assessment of 18 heterogeneous metal catalysts (Pd, Pt, V, Co, Ni, Mo, Ru, Mn, Au, Cu, Cd, Zr, Fe, Rh, Ir, Sn, Zn, Ag) using multicriteria...
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New Unsymmetrical Bisacridine Derivatives Noncovalently Attached to Quaternary Quantum Dots Improve Cancer Therapy by Enhancing Cytotoxicity toward Cancer Cells and Protecting Normal Cells
PublikacjaThe use of nanoparticles for the controlled drug delivery to cells has emerged as a good alternative to traditional systemic delivery. Quantum dots (QDs) offer potentially invaluable societal benefits such as drug targeting and in vivo biomedical imaging. In contrast, QDs may also pose risks to human health and the environment under certain conditions. Here, we demonstrated that unique combination of nanocrystals core components...
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Scalable Route toward Superior Photoresponse of UV-Laser-Treated TiO2 Nanotubes
PublikacjaTitanium dioxide nanotubes gain considerable attention as a photoactive material due to chemical stability, photocorrosion resistance, or lowcost manufacturing method. This work presents scalable pulsed laser modification of TiO2 nanotubes resulting in enhanced photoactivity in a system equipped with a motorized table, which allows for modifications of both precisely selected and any-large sample area. Images obtained from scanning...
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Facile formation of self-organized TiO2 nanotubes in electrolyte containing ionic liquid - ethylammonium nitrate and their remarkable photocatalytic properties
PublikacjaThe oriented TiO2 nanotube arrays (NTs) are identified as a stable, active and recyclable photocatalytic surface. However, their photoactivity is strictly depended on morphology (especially length), which could be controlled by anodic oxidation parameters, including electrolyte properties. To control the morphology, were successfully synthesized a series of NTs by a novel approach where ionic liquid (IL), ethylammonium nitrate...
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Effect of Different Bromine Sources on the Dual Cation Mixed Halide Perovskite Solar Cells
PublikacjaRecent research has shown that perovskite solar cells with a mixed dual A-cation have much better structural stability without loss of efficiency than single cation devices. Mixed cation perovskites create a lot of questions about the salts being used for the formation of the best-quality layer. Here, we have investigated three sources of bromide in the perovskite absorption layer, using lead bromide (PbBr2), formamidinium bromide...
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PLA–Potato Thermoplastic Starch Filament as a Sustainable Alternative to the Conventional PLA Filament: Processing, Characterization, and FFF 3D Printing
PublikacjaThe growing popularity of the fused filament fabrication (FFF) 3D printing technology in science, industry, and in-home use is associated with an increased demand for high-quality polymer filaments. This study presents an in-depth characterization and analysis of a self-made bio-based polylactide (PLA)/thermoplastic potato starch (TPS) filament dedicated for the FFF 3D printing technology. The obtained results were compared with...
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Synthesis and ionophoric properties of functionalized p-tert-butyl-calix[4]arenes
PublikacjaProjektowanie struktury związków o właściwościach jonoforowych stanowi ważny element chemii supramolekularnej. W pracy przedstawiono wyniki badań nad funkcjonalizacją makrocyklicznych kaliks[4]arenów prowadzacą do nowych związków o zróżnicowanych właściwościach kompleksujących. Syntezowane przez nas jonofory badane były w membranowych elektrodach jonoselektywnych. Wyznaczono potencjometryczne współczynniki selektywności oraz stałe...
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Modelling long-term technological transition of Polish power system using MARKAL: Emission trade impact
PublikacjaThe need for technological transition of electricity production becomes a global problem. However, in coal-dominated Polish power system this need is even more crucial than anywhere, since technical lifetime of the most domestic power plants is ending. In this paper, the impact of the EU Emission Trading Scheme (EU ETS) for CO2 combined with sulfur dioxide (SO2) and nitrogen oxides (NOx) emission trading mechanism on power technology...
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Two-spinors, oscillator algebras, and qubits: aspects of manifestly covariant approach to relativistic quantum information
PublikacjaThe first part of the paper reviews applications of 2-spinor methods to relativistic qubits (analogies between tetrads in Minkowski space and 2-qubit states, qubits defined by means of null directions and their role for elimination of the Peres-Scudo-Terno phenomenon, advantages and disadvantages of relativistic polarization operators defined by the Pauli-Lubanski vector, manifestly covariant approach to unitary representations...
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Electrostatic interactions in finite systems treated with periodic boundary conditions: Application to linear-scaling density functional theory
PublikacjaWe present a comparison of methods for treating the electrostatic interactions of finite, isolated systems within periodic boundary conditions (PBCs), within density functional theory (DFT), with particular emphasis on linear-scaling (LS) DFT. Often, PBCs are not physically realistic but are an unavoidable consequence of the choice of basis set and the efficacy of using Fourier transforms to compute the Hartree potential. In such...
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Influence of Surface-Modified Montmorillonite Clays on the Properties of Elastomeric Thin Layer Nanocomposites
PublikacjaIn recent years, polyurethane nanocomposites have attracted more attention due to the massive demand for materials with increasingly exceptional mechanical, optical, electrical, and thermal properties. As nanofillers have a high surface area, the interaction between the nanofiller and the polymer matrix is an essential issue for these materials. The main aim of this study is to validate the impact of the montmorillonite nanofiller...
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Novel fast analytical method for indirect determination of MCPD fatty acid esters in edible oils and fats based on simultaneous extraction and derivatization
PublikacjaA novel method for indirect determination of MCPD esters levels in lipid samples has been developed. The method is based on combination of extraction and derivatisation in the same sample preparation step. It is achieved by the application of diethyl ether as extraction solvent for isolation of released from esterified forms analytes from water phase and dilution solvent for solid PBA – derivatisation agent. It is a noteworthy...
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Higher platelet counts correlate to tumour progression and can be induced by intratumoural stroma in non-metastatic breast carcinomas
PublikacjaBackground Platelets support tumour progression. However, their prognostic significance and relation to circulating tumour cells (CTCs) in operable breast cancer (BrCa) are still scarcely known and, thus, merit further investigation. Methods Preoperative platelet counts (PCs) were compared with clinical data, CTCs, 65 serum cytokines and 770 immune-related transcripts obtained using the NanoString technology. Results High normal...
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Novel ABTS-dot-blot method for the assessment of antioxidant properties of food packaging
PublikacjaThe new ABTS-dot-blot method for the direct determination of antioxidant activity of active packaging that is in contact with foodstuffs has been developed. The usefulness of the new method was verified with the use of agarose, pork gelatin, bacterial cellulose and cellulose-chitosan films with incorporated standard antioxidant – Trolox or plant phytochemicals derived from three types of berry juices (chokeberry, blue-berried honeysuckle,...
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Catalytic Activity of Nickel and Ruthenium–Nickel Catalysts Supported on SiO2, ZrO2, Al2O3, and MgAl2O4 in a Dry Reforming Process
PublikacjaDry reforming of methane (DRM) is an eco-friendly method of syngas production due to the utilization of two main greenhouse gases—methane and carbon dioxide. An industrial application of methane dry reforming requires the use of a catalyst with high activity, stability over a long time, and the ability to catalyze a reaction, leading to the needed a hydrogen/carbon monoxide ratio. Thus, the aim of the study was to investigate the...
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Bankruptcy system model and efficiency versus the entrepreneurship and innovation in selected European countries
Publikacjamodel and its efficiency on the development of entrepreneurship and innovation in selected European countries and Turkey. This goal was achieved by examining the relationships between debtor-friendliness of the bankruptcy law model and its efficiency on one side and entrepreneurship and innovation on the other. The cross-sectional ANOVA test and OLS regression method were chosen as the research method. In order to verify the research...
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Chemical hazard in glacial melt? The glacial system as a secondary source of POPs (in the Northern Hemisphere). A systematic review
PublikacjaToxicity of compounds belonging to persistent organic pollutants (POPs) iswidely known, and their re-emission from glaciers has been conclusively demonstrated. However, the harmful effects associated with such secondary emissions have yet to be thoroughly understood, especially in the spatial and temporal context, as the existing literature has a clear sampling biaswith the best recognition of sites in the European Alps. In this...
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STEROWNIK MIKROSIECI ELEKTROENERGETYCZNEJ
PublikacjaW artykule rozpatruje się konstrukcję sterownika mikrosieci elektroenergetycznej. Sterownik zarządza zasobamienergii elektrycznej w celu pokrycia zapotrzebowania lokalnych gospodarstw domowych z uwzględnieniem kwestii ekonomicznych. Przedstawiono strukturę sterowania, zdefiniowano zadanie optymalizacji, dokonano badań symulacyjnych dla przykładowej mikrosieci o zróżnicowanych sposobach generowania i magazynowania. Zaproponowano...
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Determination of high-intensity sweeteners in beverages by high-performance liquid chromatography with mass spectrometry detection.
PublikacjaThe objective of the present study was to measure the concentration of nine high intensity sweeteners (acesulfame-K, aspartame, alitame, cyclamate, dulcin, neohesperidin dihydrochalcon, neotame, saccharin and sucralose) in different types of beverages available on the polish market. The proposed methodology reported here consists of a extraction with buffer composed of formic acid and N,N-diisopropylethylamine (pH 4.5) followed...
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Optoelektroniczny monitoring stanu wzbudzenia plazmy niskotemperaturowej w procesach syntezy optycznych warstw diamentopodobnych
PublikacjaZrealizowana praca jest jednym z głównych zadań wieloletniego projektu badawczego z zakresu syntezy warstw diamentopodobnych. Celem bezpośrednim pracy było określenie rozkładu wzbudzenia plazmy w komorze technologicznej stanowiska PA ECR CVD. Głównym celem było opracowanie optoelektronicznego systemu pomiarowego, na którego potrzeby zastosowano przestrzennie selektywną optyczną spektroskopię emisyjną dedykowaną do badania procesu...
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Realizacja warstwy serwerów sterowania połączeniami dla ASON/GMPLS
PublikacjaW materiale przedstawiono wyniki prac badawczych wykonanych w ramach projektu PBZ w podprojekcie Architektury i protokoły sieciowe. Obejmują krótką charakterystykę wytworzonych modeli analitycznych i symulacyjnych przeznaczonych do badania sieci pakietowych z gwarancją jakości klas usług dla technologii IP QoS, MPLS, OBS oraz uzyskane wyniki. Jednakże główny punkt ciężkości został położony na sieci z architekturą ASON/GMPLS dla...
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Greencoin – educational information system for ecoinclusion and empowering urban adaptability.
PublikacjaThe SARS-CoV19 pandemic exposed a broad spectrum of challenges for modern cities, societies and the environment at large. The post-Covid transformation requires new social, ecological and educational solutions, adjusted to modern challenges, but also equipped with technological advances that allow for digital inclusion and sustainable urban development to benefit the local economy and society. Many information systems designed...
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Proximity and the Cluster Organization
PublikacjaIncluding the category of proximity in theoretical considerations and empirical analyzes in cluster organizations is an attempt to integrate existing approaches to understand and explain the specificity of inter-organizational cooperation developed in geographical proximity. The importance of geographical proximity to create a competitive advantage is emphasized in all theories on the establishment and development of industrial...
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A screening of select toxic and essential elements and persistent organic pollutants in the fur of Svalbard reindeer
PublikacjaReindeers play an important role in the polar ecosystem, being long-lived sole vegetarians feeding on local vegetation. They can be used as a valuable bioindicator, helping us to understand contaminants’ impact on the polar terrestrial ecosystem. Still, scarce data exist from research in which polar herbivores (especially those from the European parts of the Arctic) were a major study subject for trace elements and persistent organic...
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Three-dimensional modeling and automatic analysis of the human nasal cavity and paranasal sinuses using the computational fluid dynamics method
PublikacjaPurpose The goal of this study was to develop a complete workflow allowing for conducting computational fluid dynam- ics (CFD) simulation of airflow through the upper airways based on computed tomography (CT) and cone-beam computed tomography (CBCT) studies of individual adult patients. Methods This study is based on CT images of 16 patients. Image processing and model generation of the human nasal cavity and paranasal sinuses...
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Reduced expression of ELAVL4 in male meningioma patients
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Treatment of high blood pressure in elderly and octogenarians: European Society of Hypertension statement on blood pressure targets
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Electromagnetic Control and Dynamics of Generalized Burgers’ Nanoliquid Flow Containing Motile Microorganisms with Cattaneo–Christov Relations: Galerkin Finite Element Mechanism
PublikacjaIn our research work, we have developed a model describing the characteristics of the bio-convection and moving microorganisms in the flows of a magnetized generalized Burgers’ nanoliquid with Fourier’s and Fick’s laws in a stretchable sheet. Considerations have been made to Cattaneo–Christov mass and heat diffusion theory. According to the Cattaneo–Christov relation, the Buongiorno phenomenon for the motion of a nanoliquid in...
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Cyfrowy akcelerator wybranych modułów standardu kompresji wideo H.264
PublikacjaW komunikacie przedstawiono konfigurowalny cyfrowy akcelerator estymacji ruchu (motion estimation) przeznaczony dla enkodera wideo standardu H.264. Akcelerator został wstępnie zaimplementowany w układzie FPGA VIRTEX6-VLX365T, a następnie w układzie ASIC w technologii UMC 90 nm. Obie implementacje zostały zweryfikowane pozytywnie, a szczegółowe wyniki symulacji i pomiarów akceleratora ASIC zostały porównane z innymi dostępnymi w...
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In vivo and in vitro study of a novel nanohydroxyapatite sonocoated scaffolds for enhanced bone regeneration
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China’s international trade and global value chains under One-Belt One-Road initiative
PublikacjaResearch background: After China acceded to the WTO in 2001, its foreign trade has expanded rapidly to be the largest share in the world. However, China's economic development changing from high-speed growth to medium high-speed growth in recent years. At the same time, the increase in labour cost and overcapacity also hinder China’s international trade. In order to solve these challenges and strengthening ties...
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The Simulation of Activated Sludge System for Optimization of Predictive Aeration at Large WWTP
PublikacjaEffective use of biodegradable substrates as an internal carbon sources (ICS) for denitrification and EBPR and predicting performance of aeration systems during nitrification in activated sludge bioreactors, may be useful in realization the sustainable development by potentially saving energy consumption at WWTPs. A large number of WWTPs use activated sludge systems with an integrated removal of carbon, nitrogen and phosphorus...
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RAGE as a Novel Biomarker for Prostate Cancer: A Systematic Review and Meta-Analysis
PublikacjaThe receptor for advanced glycation end-products (RAGE) has been implicated in driving prostate cancer (PCa) growth, aggression, and metastasis through the fueling of chronic inflammation in the tumor microenvironment. This systematic review and meta-analysis summarizes and analyzes the current clinical and preclinical data to provide insight into the relationships among RAGE levels and PCa, cancer grade, and molecular effects....
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ZnO-decorated green-synthesized multi-doped carbon dots from Chlorella pyrenoidosa for sustainable photocatalytic carbamazepine degradation
PublikacjaThe promising green synthesis of carbon dots (CDs) from microalga Chlorella pyrenoidosa was achieved using simple hydrothermal and microwave-assisted methods. Doping of nanomaterials by nonmetals (N, S, and P) was confirmed by X-ray photoelectron spectroscopy (XPS), while the existence of metals in the CDs was confirmed by inductively coupled plasma optical emission spectroscopy (ICP-OES) and transmission electron microscopy (TEM),...
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Technological vs. Non-Technological Mindsets: Learning From Mistakes, and Organizational Change Adaptability to Remote Work
PublikacjaThe permanent implementation of the change in working methods, e.g., working in the virtual space, is problematic for some employees and, as a result, for management leaders. To explore this issue deeper, this study assumes that mindset type: technological vs. non-technological, may influence the organizational adaptability to change. Moreover, the key interest of this research is how non-technological mindsets...
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Wisdom from Experience Paradox: Organizational Learning, Mistakes, Hierarchy and Maturity Issues
PublikacjaOrganizations often perceive mistakes as negligence and low-performance indicators, yet they can be a precious learning resource. However, organizations cannot learn from mistakes if they have not accepted them. This study aimed to explore how organizational hierarchy and maturity levels influence the relationship between mistakes acceptance and the ability to change. A sample composed of 380 Polish employees working in knowledge-driven...
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Governmental supported space internship programmes in new ESA member states - Polish perspective
PublikacjaOver last 10 years ve new countries - Czech Republic, Romania, Poland, Hungary and Estonia - have joined the European Space Agency. These countries are currently experiencing a considerable increase of space activities aiming to take part in the European and Global space market. New companies, start-ups and consortiums have been created alongside oces of foreign entities have opened their premises in these countries. All of them...
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Enhanced hydrogen evolution reaction on highly stable titania-supported PdO and Eu2O3 nanocomposites in a strong alkaline solution
PublikacjaIn this work, PdO/TiO2 and Eu2O3/TiO2 nanocomposites (NCs), were synthesized using a new facile, template-free and one-step solvothermal approach, and characterized by several instrumentation techniques. X-ray photoelectron spectroscopy (XPS) studies revealed the presence of oxidised form of the Pd and Eu nanoparticles within the nanocomposite materials (PdO and Eu2O3). The two catalysts exhibited remarkable activity for the HER...
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Akcelerator predykcji wewnątrzramkowej H.264 do kompresji obrazu w sensorach wizyjnych
PublikacjaW komunikacie przedstawiono konfigurowalny cyfrowy akcelerator predykcji wewnątrzramkowej przeznaczony dla enkodera wideo standardu H.264. Akcelerator realizuje predykcję typu „intra” dla makrobloków luminancji o wymiarach 4x4 i 16x16. Akcelerator wstępnie zaimplementowano w układzie FPGA, gdzie został on pomyślnie zweryfikowany, a następnie zaimplementowano go w układzie ASIC w technologii UMC 90 nm. Szczegółowe wyniki testów...
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Akcelerator predykcji wewnątrzramkowej H.264 do kompresji obrazu w sensorach wizyjnych
PublikacjaW artykule przedstawiono konfigurowalny cyfrowy akcelerator predykcji wewnątrzramkowej przeznaczony dla enkodera wideo standardu H.264. Akcelerator realizuje predykcję typu „intra” dla makrobloków luminancji o wymiarach 4x4 i 16x16. Akcelerator wstępnie zaimplementowano w układzie FPGA, gdzie został on pomyślnie zweryfikowany, a następnie zaimplementowano go w układzie ASIC w technologii UMC 90 nm. Szczegółowe wyniki testów akceleratora...
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Comparison of extraction techniques of robenidine from poultry feed samples
PublikacjaW publikacji opisano wykorzystanie różnych technik ekstrakcji kokcydistatyków (na przykładzie robenidyny) z próbek pasz zwierzęcych. W trakcie badań porównano wpływ różnych parametrów ekstrakcji na współczynniki odzysku analitu. Wśród wykorzystanych technik ekstrakcji wymienić należy: ekstrakcję za pomocą rozpuszczalnika wspomaganą ultradźwiękami oraz mikrofalami, ekstrakcję w aparatach Soxhleta i Soxteca a także ekstrakcję przez...
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Functional safety and human factors
PublikacjaRozdział przedstawia istotny problem uwzględnienia czynników ludzkich (H&OF) w analizie bezpieczeństwa funkcjonalnego, które wpływają istotnie na bezpieczeństwo przemysłowych obiektów podwyższonego ryzyka, nie ujęty jednak w normach bezpieczeństwa funkcjonalnego. Przedstawia się metody analizy niezawodności człowieka (HRA) w kontekście tych czynników, które wpływają na błędy człowieka. Czynniki ludzkie i organizacyjne powinny być...
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Investigation of noises in the EPN weekly time series
PublikacjaThe constantly growing needs of permanent stati ons’ velocities users cause their stability level to increase. To this research we included more than 150 stations located across Europe operating within the EUREF Permanent Network (EPN) w ith weekly changes in the ITRF2005 reference frame. The obvious long-range dependencies in the stochastic part of GPS time series were p roven by Ljung-Box...
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Video content analysis in the urban area telemonitoring system
PublikacjaThe task of constant monitoring of video streams from a large number of cameras and reviewing the recordings in order to find a specified event requires a considerable amount of time and effort from the system operators and it is prone to errors. A solution to this problem is an automatic system for constant analysis of camera images being able to raise an alarm if a predefined event is detected. The chapter presents various aspects...
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The role of the One-Belt One-Road initiative in China's exports and global value chains
PublikacjaResearch background: China is regarded as the “world factory” highly involved in international trade and plays an increasingly important role in the global value chains (GVC). Additionally, the “One-Belt One-Road” (OBOR) initiative was proposed by the Chinese government to further promote China in the international market. Purpose of the article: The article explores the role of the OBOR in China’s exports and global value...
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Lipopolysaccharides: regulated biosynthesis and structural diversity
PublikacjaThe cell envelope of Gram-negative bacteria contains two distinct membranes, an inner (IM) and an outer (OM) membrane, separated by the periplasm, a hydrophilic compartment that includes a thin layer of peptidoglycan. The most distinguishing feature of such bacteria is the presence of an asymmetric OM with phospholipids located in the inner leaflet and lipopolysaccharides (LPSs) facing the outer leaflet. The maintenance of this...
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Tribo-Environment Dependent Chemical Modification of Sliding Interfaces in Ultrananocrystalline Diamond Nanowall Film: A Correlation with Friction and Wear
PublikacjaTribological properties of ultrananocrystalline diamond nanowall (UNCD NW) films were investigated quantitatively in three different and controlled tribo-environmental conditions, proposing the passivation and graphitization mechanisms. However, these mechanisms are rather complicated and possibly can be understood in well-controlled tribological conditions. It was shown that the friction and wear of these films were high in highPage 1...
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Performance-Driven Surrogate Modeling of High-Frequency Structures
PublikacjaThe development of modern high-frequency structures, including microwave and antenna components, heavily relies on full-wave electromagnetic (EM) simulation models. Notwithstanding, EM-driven design entails considerable computational expenses. This is especially troublesome when solving tasks that require massive EM analyzes, parametric optimization and uncertainty quantification be-ing representative examples. The employment of...
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A novel concept of negative CO2 emission power plant for utilization of sewage sludge
PublikacjaCarbon Capture and Storage (CSS) technology is considered an important “bridge technology”, allowing effective abatement of CO2 emissions for power units using fossil fuels. However, if biomass is used in a power plant, equipped with CCS system, negative CO2 emissions can be achieved. In practice, wide development of such technologies would enable not only reduction of CO2 emissions, but also reversal of the harm done so far. In...
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Akcelerator transformacji DCT do kompresji obrazu w sensorach wizyjnych
PublikacjaW komunikacie przedstawiono konfigurowalny cyfrowy akcelerator transformacji DCT przeznaczony dla enkodera wideo standardu H.264. Akcelerator realizuje także odwrotnątransformacjęDCT oraz kwantyzacjęi dekwantyzację. Akcelerator początkowo zaimplementowano w układzie FPGA. Zostałon pomyślnie zweryfikowany, a następnie zaimplementowany w układzie ASIC w technologii UMC 90 nm. Szczegółowe wyniki testów akceleratora ASIC zostały...