Wyniki wyszukiwania dla: STRUT BEARINGS - MOST Wiedzy

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Wyniki wyszukiwania dla: STRUT BEARINGS

Wyniki wyszukiwania dla: STRUT BEARINGS

  • The Influence of External Additional Loading on the Muscle Activity and Ground Reaction Forces during Gait

    Publikacja

    - Applied Bionics and Biomechanics - Rok 2021

    Asymmetrical external loading acting on the usculoskeletal system is generally considered unhealthy. Despite this knowledge, carrying loads in an asymmetrical manner like carrying on one shoulder, with one hand, or on the strap across the torso is a common practice. This study is aimed at presenting the effects of the mentioned load carrying methods on muscle activity assessed by using thermal field and ground reaction forces....

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  • Measurement of the tram rail profile during a year of operation - supplementary data

    Dane Badawcze
    embargo

    The aim of the work was to analyze the wear of rails during operation and to analyze the supplementation of heavy metals in the soil around the tram route, originating from wearing out rails and tram wheels.The dataset contains measurements of rail head coordinates in 9 research sections made in 8 measurement series. The wear of the rails in selected...

  • An inclination in Thermal Energy Using Nanoparticles with Casson Liquid Past an Expanding Porous Surface

    Publikacja

    - ENERGIES - Rok 2021

    Physical aspects of inclined MHD nanofluid towards a stretching sheet embedded in a porous medium are visualized. Two types of nanoparticles are used named as copper and alumna dioxide with water as base fluid. Similarity transformations are used to convert the partial differential equations into the set of ordinary differential equation. Closed solutions are found to examine the velocity and the temperature profiles. It is examined...

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  • Sensitivity of the Baltic Sea level prediction to spatial model resolution

    Publikacja

    - Rok 2017

    he three-dimensional hydrodynamic model of the Baltic Sea (M3D) and...

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  • IATUL Fall Seminar - Connecting in a disconnected world.

    Wydarzenia

    15-12-2021 12:00 - 15-12-2021 15:45

      We invite both current community members and other people interested in IATUL's activities to the online seminar on December 15, 2021. During the meeting, we will talk about the mission and activities of the organisation, as well as the benefits of belonging to the IATUL community. In addition, Special Interest Groups (SIGs), analysing...

  • Migracje ludności we współczesnej rzeczywistości globalnej

    Publikacja

    - Rok 2009

    Za globalne zwykło uważać się procesy które swoim zasięgiem bądź w zakresie występowania czy oddziaływania dotyczą całego świata. Znaczącym zmianom ulegają procesy ekonomiczne, społeczne i polityczne. Podlegają one przeobrażeniom jakościowym i ilościowym, tworząc nierzadko nową jakość. Jedną ze znamiennych cech rozwoju społeczeństw od zarania tworzenia się struktur organizacji społecznych i politycznych była i jest ruchliwość przestrzenna...

  • Dynamic Bayesian Networks for Symbolic Polyphonic Pitch Modeling

    Publikacja

    Symbolic pitch modeling is a way of incorporating knowledge about relations between pitches into the process of an- alyzing musical information or signals. In this paper, we propose a family of probabilistic symbolic polyphonic pitch models, which account for both the “horizontal” and the “vertical” pitch struc- ture. These models are formulated as linear or log-linear interpo- lations of up to fi ve sub-models, each of which is...

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  • The influence oil additives on spread cracks in silicon nitride

    Publikacja

    The paper presents an experimental study of the influence of oil additives (Cl, S, P, cerium dioxide (CeO2)) on spread cracks in silicon nitride. The additives Cl, S, P are bound in molecules in liquid form soluble in the base oil. The CeO2 is purely in powder form in suspension. The use of CeO2 powder was made based on the good results of polishing of silicon nitride. A ceramic angular contact ball bearing was modelled using a...

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  • Yerba Mate - A Long but Current History

    Publikacja

    Bearing in mind the growing interest in Yerba Mate, a comprehensive study has been prepared containing the most important aspects and possibilities of its use. The introduction of the work contains the species characteristics of Yerba Mate, as well as information about the origin and places of cultivation. The next part focuses on the analysis of the composition, pointing to purine alkaloids, polyphenols, saponins, and minerals...

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  • Palindromic carbazole derivatives: unveiling their antiproliferative effect via topoisomerase II catalytic inhibition and apoptosis induction

    Publikacja

    - JOURNAL OF ENZYME INHIBITION AND MEDICINAL CHEMISTRY - Rok 2024

    Human DNA topoisomerases are essential for crucial cellular processes, including DNA replication, transcription, chromatin condensation, and maintenance of its structure. One of the significant strategies employed in cancer treatment involves the inhibition of a specific type of topoisomerase, known as topoisomerase II (Topo II). Carbazole derivatives, recognised for their varied biological activities, have recently become a significant...

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  • Results of the “DPDT-Auger” Research Project on Screw Displacement Piles

    The main objective of the “DPDT-Auger” research project was to test the prototype DPDT auger for forming screw displacement piles in the ground (patented in Poland in 2020). An additional aim was to develop design methods and rules for the making of such piles. The augers and piles were first tested on a model scale, and then more extensively in the real scale on experimental field plots. The results found the overall functionality...

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  • Synthesis and Characterization of Poly(zwitterionic) Structures for Energy Conversion and Storage

    Publikacja

    - Rok 2021

    Zwitterions are unique class of molecules that possess two functional groups bearing electric charges, one positive and second negative. This setup results in peculiar properties such as high water retention and anti-fouling capability. Therefore, zwitterionic coatings and gels are commonly applied in e.g. biosensing and bioelectronic devices. Despite those applications, there are other perspectives for zwitterionic materials....

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  • Digital Gaps and Economic Inequalities in MENA Countries: An Empirical Investigation

    Publikacja

    - Rok 2022

    This research contributes to the present state of the art by examining changes in cross-country inequalities in digital technologies deployment and economic performance. Our empirical target builds on the hypothesis that rapid global diffusion of digital technologies unequivocally leads to gradual eradication of cross-country digital gaps and cross-country inequalities in terms of deployment of ICT; the technology convergence occurs....

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  • Thermal and technological aspects of double face grinding of Al2O3 ceramic materials

    Publikacja
    • M. Deja
    • M. List
    • L. Lichtschlag
    • E. Uhlmann

    - CERAMICS INTERNATIONAL - Rok 2019

    Double face grinding with planetary kinematics is a process to manufacture workpieces with plan parallel functional surfaces, such as bearing rings or sealing shims. In order to increase the economic efficiency of this process, it has to be advanced permanently. The temperature in the contact zone of most grinding processes has a huge influence on the process efficiency and the workpiece qualities. In contrast to most grinding...

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  • Powder metallurgy of the porous Ti-13Nb-13Zr alloy of different powder grain size

    The objective of the present project was to determine the effects of powder granulation (fraction of grain size) for the Ti-13Nb-13Zr alloy, produced by powder metallurgy, on its porosity, grain cohesion, compressive strength, and Young`s modulus. Two powder fractions, 45–105 µm, and 106–250 µm were applied. The 50 mass pct of NH4HCO3 was added as a space holder. The specimens were in compaction stage uniaxially pressed at pressure...

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  • Synthesis, Molecular Structure, Anticancer Activity, and QSAR Study of N-(aryl/heteroaryl)-4-(1H-pyrrol-1-yl)Benzenesulfonamide Derivatives

    Publikacja
    • B. Żołnowska
    • J. Sławiński
    • Z. Brzozowski
    • A. Kawiak
    • M. Belka
    • J. Zielińska
    • T. Bączek
    • J. Chojnacki

    - INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES - Rok 2018

    A series of N-(aryl/heteroaryl)-4-(1H-pyrrol-1-yl)benzenesulfonamides were synthesized from 4-amino-N-(aryl/heteroaryl)benzenesulfonamides and 2,5-dimethoxytetrahydrofuran. All the synthesized compounds were evaluated for their anticancer activity on HeLa, HCT-116, and MCF-7 human tumor cell lines. Compound 28, bearing 8-quinolinyl moiety, exhibited the most potent anticancer activity against the HCT-116, MCF-7, and HeLa cell lines,...

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  • GVC involvement and the gender wage gap: Micro -evidence on European countries

    We examine linkages between involvement in global value chains (GVCs) and gender wage inequalities. We use merged data from Structure of Earnings Survey and the World Input Output Database covering 18 European countries. We employ information on employees’ personal and company characteristics and a sectoral involvement in GVCs. In general, the wages of workers from sectors more involved in GVCs are lower. However, the relationship...

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  • Marek J. Siemek and His Interpretation of the Idea of Transcendentalism

    Publikacja

    The paper discusses in a concise manner and critical intent Marek J. Siemek’s conception of transcendental philosophy. Firstly, theory of knowledge does not belong to the epistemic level of reflection (Siemek’s stance) but it is precisely the other way around; namely, it is due to transcendental philosophy (critique of cognitive faculties) that it was possible to distinguish metaphysical, ontological and epistemological questions....

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  • Modeling and MANOVA studies on toxicity and endocrine potential of packaging materials exposed to different extraction schemes

    Publikacja

    - ENVIRONMENTAL RESEARCH - Rok 2018

    The stability of the linings of packaging that is in contact with the goods stored has been of major concern during decades of the development of packaging materials. In this work, an attempt was undertaken to assess the applicability of using two bioassays (Microtox® and XenoScreen YES/YAS) in estimating the stability of packaging (cans, caps, multilayer material) and the impact of their degradation on the toxicity of some simulated media....

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  • Calixthioamides as ionophores for transition and heavy-metal cations

    There is an increasing interest in applying p-tert-butylcalix[4]arenes as sensing materials in ion-selective electrodes(ISEs). Considerable efforts were made to design calixarenes that are selective for some heavy- or transitionmetal ions to be used in ISEs for controlling and monitoring the level of such pollutants in the environment. It has been reported that introduction of softer sulfur atoms instead of oxygen atoms in calix[4]arene...

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  • CM Voltage Compensators for Power Electronic Interfaces

    Publikacja
    • R. Smoleński
    • J. Bojarski
    • P. Leżyński
    • A. Kempski
    • J. Łuszcz

    - IEEE Electromagnetic Compatibility Magazine - Rok 2015

    The experimental results presented in the paper have shown that the application of the PEIs might cause EMC related problems, especially in the case of the application of a group of connected converters. The most convenient way to reduce EMI currents and prevent aggregation of EMI currents introduced by a group of converters is through passive compensation of voltage interference sources inside of the single converters. In the...

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  • Between Descriptive Geometry and CAD 3D

    Descriptive geometry provides methods to analyse three-dimensional space through two-dimensional drawings and prepares to create technical documentation. Geometric form of an engineering project is presented by the means of projection methods based on a 3D model, which is present in designer’s imagination. The forthcoming era of Building Information Modelling (BIM) brings changes in the way the engineer works, as the vision is...

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  • Nuclear power plant as a source of electrical energy and heat

    In this paper certain issues concerning usage of nuclear power plants as sources of not only electric power but also thermal energy will be discussed. For such a solution appeals most of all the need to limit harmful emissions of gases (including CO2) and ashes, which come from the process of burning fossil fuels, as well as the raising demand for network heat and chill. Additionally combined heat and power production brings measurable...

  • Cross-domain applications of multimodal human-computer interfaces

    Publikacja

    - Rok 2015

    Developed multimodal interfaces for education applications and for disabled people are presented, including interactive electronic whiteboard based on video image analysis, application for controlling computers with mouth gestures and audio interface for speech stretching for hearing impaired and stuttering people and intelligent pen allowing for diagnosing and ameliorating developmental dyslexia. The eye-gaze tracking system named...

  • Child-Robot Interaction Studies During COVID-19 Pandemic

    Publikacja
    • P. Uluer
    • H. Kose
    • A. Landowska
    • T. Zorcec
    • B. Robins
    • D. Erol Barkana

    - Rok 2020

    The coronavirus disease (COVID-19) pandemic affected our lives deeply, just like everyone else, the children also suffered from the restrictions due to COVID-19 affecting their education and social interactions with others, being restricted from play areas and schools for a long time. Although social robots provide a promising solution to support children in their education, healthcare, and social interaction with others, the precautions...

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  • Acoustic evaluation of road surfaces using different Close Proximity testing devices

    Publikacja

    - APPLIED ACOUSTICS - Rok 2023

    According to the valid standard, Close Proximity (CPX) method intends to evaluate the influence of road surfaces on traffic noise. Measurements may be carried out with the use of a self-powered vehicle or a special test trailer equipped with testing tyre towed by another vehicle. Two different testing devices took part in the research organized in Poland in order to determine the ranking of road surfaces in terms of acoustic parameters....

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  • Reduction of Tire Rolling Resistance by Optimization of Road Surfaces and Tires

    During interaction between tire and road surface three very important phenomena are always in effect. One of them (very desirable) is friction that is important for traction, braking and cornering. Two other phenomena are not desirable at all, that is rolling resistance and noise. This paper discusses relations between road surface and tire parameters versus tire rolling resistance. Road surface texture, porosity, impedance, strength...

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  • Loudness Scaling Test Based on Categorical Perception

    The main goal of this research study is focused on creating a method for loudness scaling based on categorical perception. Its main features, such as: way of testing, calibration procedure for securing reliable results, employing natural test stimuli, etc., are described in the paper and assessed against a procedure that uses 1/2-octave bands of noise (LGOB) for the loudness growth estimation. The Mann-Whitney U-test is employed...

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  • Nowe możliwości generowania zarysów satelitowych mechanizmów roboczych

    Publikacja

    - Rok 2012

    Planetary hydraulic gear motors have been well known since 70's . first motors were constructed for maritime industry by hydroster from gdansk. the evolution of this type of motors led to an increase of nominal pressure and durability. nowadays the industry needs reliable and efficient motor able to work with alternative hydraulic fluids like water, emulsion and vegetable oil. therefore a new type of motors are being developed...

  • Tinnitus Therapy Based on High-Frequency Linearization Principles - Preliminary Results

    Publikacja

    - Archives of Acoustics - Rok 2012

    The aim of this work is to present problems related to tinnitus symptoms, its pathogenesis, hypotheses on tinnitus causes, and therapy treatment to reduce or mask the phantom noise. In addition, the hypothesis on the existence of parasitic quantization that accompanies hearing loss has been recalled. Moreover, the paper describes a study carried out by the Authors with the application of high-frequency dither having specially formed...

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  • Mechanika Płynów i Hydraulika st. niest. IŚ inż. sem. IV 2022/2023

    Kursy Online
    • P. Zima

    ĆWICZENIA AUDYTORYJNE Wyznaczanie rozkładu ciśnienia oraz obliczanie naporu hydrostatycznego na ścianki płaskie i zakrzywione. Zastosowanie równania Bernoulliego dla strumienia cieczy rzeczywistej. Obliczanie strat hydraulicznych przy przepływie cieczy w przewodach pod ciśnieniem. Obliczanie parametrów ruchu ustalonego jednostajnego w korytach otwartych. Określanie oraz zastosowanie ruchu krytycznego w kanałach otwartych. Wyznaczanie...

  • Mechanika Płynów i Hydraulika st. niest. IŚ inż. sem. IV 2021/2022

    Kursy Online

    ĆWICZENIA AUDYTORYJNE Wyznaczanie rozkładu ciśnienia oraz obliczanie naporu hydrostatycznego na ścianki płaskie i zakrzywione. Zastosowanie równania Bernoulliego dla strumienia cieczy rzeczywistej. Obliczanie strat hydraulicznych przy przepływie cieczy w przewodach pod ciśnieniem. Obliczanie parametrów ruchu ustalonego jednostajnego w korytach otwartych. Określanie oraz zastosowanie ruchu krytycznego w kanałach otwartych. Wyznaczanie...

  • Mechanika płynów i hydraulika st. nstac. IŚ inż. sem. IV r.a. 23/24

    Kursy Online
    • P. Zima
    • P. Wielgat

    ĆWICZENIA AUDYTORYJNE Wyznaczanie rozkładu ciśnienia oraz obliczanie naporu hydrostatycznego na ścianki płaskie i zakrzywione. Zastosowanie równania Bernoulliego dla strumienia cieczy rzeczywistej. Obliczanie strat hydraulicznych przy przepływie cieczy w przewodach pod ciśnieniem. Obliczanie parametrów ruchu ustalonego jednostajnego w korytach otwartych. Określanie oraz zastosowanie ruchu krytycznego w kanałach otwartych. Wyznaczanie...

  • The influence of road surface unevenness on tyre rolling resistance

    The geometric characteristics of road surface substantially affect the interaction between tyre and road. Depending on pavement texture wavelength, the texture chiefly affects tyre/road friction, rolling resistance, interior and exterior noise, tyre wear, and ride comfort. The article presents results of investigations on the influence of road surface unevenness on the rolling resistance of passenger car and truck tyres. The tests...

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  • Badania mieszanek mineralno-asfaltowych w niskiej temperaturze

    Publikacja

    W artykule przedstawiono metody badań w niskiej temperaturze betonu asfaltowego przeznaczonego do warstwy ścieralnej. Przedstawione zostały wyniki badań dla 4 różnych metod badawczych: zginania, pełzania, pośredniego rozciągania oraz rozciągania termicznego przy ograniczonym odkształceniu (test TSRST). Próbki betonu asfaltowego były przygotowywane w laboratorium z wykorzystaniem 3 rodzajów asfaltów: asfaltu zwykłego, asfaltu modyfikowanego...

  • Rurociągi podmorskie. Zasady projektowania.

    Publikacja

    - Rok 2004

    Książkę poświęcono zasadom projektowania rurociągów podmorskich dalekiego zasięgu, transportujących ropę naftową lub gaz ziemny z podmorskich złóż do baz lądowych. W książce znajdują się rozdziały dotyczące: - podstawowych cech fizykochemicznych ropy naftowej i gazu ziemnego, - sposobów określania średnicy wewnętrznej i grubości ścianki rurociągu, - metod obliczania strat ciśnienia i zmian temperatury przesyłanego medium...

  • Oceny strategiczne elementem systemu łagodzenia w odniesieniu do krajobrazowych skutków komunikacji drogowej

    Publikacja

    - Rok 2005

    Artykuł prezentuje możliwości wykorzystania strategicznych ocen oddziaływania na środowisko jako jednego z elementów systemu łagodzenia negatywnych skutków rozwoju. Za wiodący aspekt wzmocnienia systemu SOOŚ/OOŚ uznano problem łagodzenia skutków środowiskowych, a najważniejszą w tym rolę przypisano krajobrazowi, określonemu jako nośnik informacji o skutkach w poszczególnych, współzależnych od siebie elementach środowiska i za wyznacznik...

  • Biochemical, Structural Analysis, and Docking Studies of Spiropyrazoline Derivatives

    Publikacja
    • A. Adamus-Grabicka
    • M. Daśko
    • P. Hikisz
    • J. Kusz
    • M. Malecka
    • E. Budzisz

    - INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES - Rok 2022

    In this study, we evaluated the antiproliferative potential, DNA damage, crystal struc‐ tures, and docking calculation of two spiropyrazoline derivatives. The main focus of the research was to evaluate the antiproliferative potential of synthesized compounds towards eight cancer cell lines. Compound I demonstrated promising antiproliferative properties, especially toward the HL60 cell line, for which IC50 was equal to 9.4 μM/L....

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  • Porównanie metod detekcji pierwszego prążka odpowiedzi impulsowej do celów radiolokalizacyjnych

    Publikacja

    Poprawność określania położenia terminali ruchomych w sieciach radiowych bazujących na pomiarach zależności czasowych pomiędzy odbieranymi sygnałami zależy od dokładności estymacji czasu nadejścia pierwszej składowej sygnału radiowego. W celu porównania efektywności działania metod detekcji pierwszego prążka odpowiedzi impulsowej zaimplementowano trzy metody działające w oparciu o detekcję maksimum oraz cztery metody progowe. W...

  • CZYNNIKI DECYDUJĄCE O PRZYDATNOŚCI KOMPUTEROWEGO MODELU PRZEPŁYWÓW W SIECI WODOCIĄGOWEJ

    Publikacja

    - Rok 2014

    W pracy poddano analizie wielozadaniowy proces tworzenia komputerowego modelu przepływów. W efekcie zidentyfikowano szereg czynników ograniczających obszar stosowania modelu w praktyce inżynierskiej. W zakresie pozyskiwania danych strukturalnych i operacyjnych wskazano potencjalne źródła błędów, które przyczyniają się do zmniejszenia dokładności odwzorowania stanu rzeczywistego. Specjalną rangę nadano specyfikacji czynników związanych...

  • The role and importance of total organic carbon (TOC) in production chain of KGHM Polska Miedż S.A. = Rola i znaczenie węgla organicznego w ciągu produkcyjnym realizowanym w KGHM Polska Miedź S.A.

    Publikacja

    - Rok 2014

    Węgiel organiczny ma szczególne znaczenie w procesach realizowanych w ciągu technologicznym KGHM Polska Miedź S.A. Obecność węgla organicznego i złożoność problemów z nim związanych wynika głównie z jego występowania we wszystkich fazach tworzenia się złoża, a obecnie ma znaczący wpływ zarówno na przebieg procesu wzbogacania, jakość koncentratu, jak również na procesy ogniowe w technologii pieca zawiesinowego. Jednocześnie forma...

  • Smooth least absolute deviation estimators for outlier-proof identification

    The paper proposes to identify the parameters of linear dynamic models based on the original implementation of least absolute deviation estimators. It is known that the object estimation procedures synthesized in the sense of the least sum of absolute prediction errors are particularly resistant to occasional outliers and gaps in the analyzed system data series, while the classical least squares procedure unfortunately becomes...

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  • Axial-Flux Permanent-Magnet Dual-Rotor Generator for a Counter-Rotating Wind Turbine

    Publikacja

    Coaxial counter-rotating propellers have been widely applied in ships and helicopters for improving the propulsion efficiency and offsetting system reactive torques. Lately, the counter-rotating concept has been introduced into the wind turbine design. Distributed wind power generation systems often require a novel approach in generator design. In this paper, prototype development of axial-flux generator with a counter-rotating...

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  • Mechanical and structural investigations of wings of selected insect species

    Publikacja

    - Acta of Bioengineering and Biomechanics - Rok 2020

    This paper presents research and measurements leading to obtaining the Young’s modulus of wing bearing structures of selected insect species. A small testing machine intended for three-point bending and equipped with instruments registering low forces was constructed for the needs of the experiment. The machine was used to perform numerous bending tests of wings of three species of insects (obtained from a breeding farm): Attacus...

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  • Experimental investigation of joint with positive eccentricity in CFS truss

    Due to technological restrictions, in the case of trusses made of CFS open cross-sections, positive eccentricities in the truss joints have become very frequent. Therefore studies concerning the load-bearing capacity of truss joints with positive eccentricity were undertaken. It was assumed that the resistance of cold-formed steel (CFS) open cross-section truss joints located on compression chords and with positive eccentricity...

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  • Study on some of the strength properties of soft clay stabilized with plastic waste strips

    It is well known that if plastic wastes are not well managed, it has a negative impact on the environment as well as on human health. In this study, recycling plastic waste in form of strips for stabilizing weak subgrade soil is proposed. For this purpose, a weak clay soil sample was mixed with 0.2%, 0.3%, and 0.4% of plastic strips by weight of soil, and the experimental results were compared to the control soil sample with 0%...

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  • Laboratory fatigue assessment of large geocomposite-reinforced double-layered asphalt concrete beams

    Publikacja

    - Rok 2022

    Geosynthetic reinforcement of asphalt layers has been used for several decades. Evaluation of the influence of these materials on pavement fatigue life is still ongoing, especially for new types of geocomposites. This paper presents the evaluation of fatigue performance of large asphalt concrete beams reinforced with a new type of composite in which square or hexagonal polypropylene stiff monolithic paving grid with integral junctions...

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  • The Idea of Using Adhesive Bonds in Shaping of Cold-formed Thin-walled Beam-columns

    The chapter concerns the idea of using adhesive bonds in the shaping of cold-formed thin-walled beam-columns. The idea of adhesive-bonded connections is not new but is unlikely to have been used in the design and shaping of thin-walled beam-columns in civil engineering up to date. Metal bar structures, including (due to economic reasons) thin-walled structures, are the most common and effective means to build engineering superstructures/loadbearing...

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  • Laboratory fatigue assessment of large geocomposite-reinforced double-layered asphalt concrete beams

    Publikacja

    - Rok 2022

    Geosynthetic reinforcement of asphalt layers has been used for several decades. Evaluation of the influence of these materials on pavement fatigue life is still ongoing, especially for new types of geocomposites. This paper presents the evaluation of fatigue performance of large asphalt concrete beams reinforced with a new type of composite in which square or hex­agonal polypropylene stiff monolithic paving grid with integral junctions...

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  • Reactivity of Diimido Complexes of Molybdenum and Tungsten towards Lithium Derivatives of Diphosphanes and Triphosphanes

    The reaction of R2P–P(SiMe3)Li (R = tBu, iPr) with the diimido molybdenum complex [(ArN)2MoCl2·dme] (Ar = 2,6-iPr2C6H3; dme = 1,2-dimethoxyethane) yielded the side-oncoordinated phosphanylphosphinidene anionic complexes [(2,6-iPr2C6H3N)2Mo(Cl)(η2-P=PR2)]– (7Mo, 8Mo). The thermal decomposition of [(2,6-iPr2C6H3N)2M(Cl)(η2-P=PR2)]–[M = Mo (7Mo), W (8W)] to [(2,6-iPr2C6H3N)2M(Cl)(1,2-η-tBu2P=P–PtBu2)] [M = Mo (3Mo), W (3W)] was investigated...

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