Wyniki wyszukiwania dla: PHOTO‐CROSSLINKING
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Study of the Effect of Filling Thermoplastic Medical Polyurethane with PVA, PLA or Diatomite on the Relaxation Times Distributions of 1H NMR
PublikacjaIn this work, to characterize the mobility of diferent sections of the macromole‑ cules of polyurethane (PUR), polyvinyl alcohol (PVA), and polylactic acid (PLA), as well as the density of crosslinks of the polymer chains when using fllers, we used the distributions of spin–lattice and spin–spin relaxation times for the protons. It is shown that the rigidity of the thermoplastic polymers depends on the sizes of the granules of...
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Do Phenyl Substituents Affect the Properties of Azobenzocrown Derivatives?
PublikacjaNew products of photo- and thermal rearrangements of 19-membered azoxybenzocrown with phenyl substituents in benzene rings in the para positions to oligooxyethylene fragments are characterized. The yields of photochemical transformations depend on the solvent. Para-hydroxyazocrown is formed with yields over 50% in propan-2-ol. Ortho-hydroxyazobenzocrown is obtained with yields up to 70% in toluene/acetic acid mixture. Macrocyclic...
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Ag modified ZnO microsphere synthesis for efficient sonophotocatalytic degradation of organic pollutants and CO2 conversion
PublikacjaThe synthesis and design of non-precious and efficient sonophotocatalyts by an environment friendly technique are requisites for solar energy conversion and environmental remediation. This work reports the preparation of Ag/ZnO microspheres with different Ag contents through deposition–precipitation method for pollutant degradation and CO2 conversion. Detail structural investigation reveals that ZnO microspheres and Ag-ZnO microspheres...
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Hydrogen migration in formation of NH(A3Π) radicals in photodissociations of isoxazole and pyridine molecules
PublikacjaIn the present study, the H atom migration was observed in the photodissociation processes of the isoxazole and pyridine molecules in the gas-phase, applying the photon-induced fluorescence spectroscopy (PIFS).
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Comparison of selected off-the-shelf solutions for emotion recognition based on facial expressions
PublikacjaThe paper concerns accuracy of emotion recognition from facial expressions. As there are a couple of ready off-the-shelf solutions available in the market today, this study aims at practical evaluation of selected solutions in order to provide some insight into what potential buyers might expect. Two solutions were compared: FaceReader by Noldus and Xpress Engine by QuantumLab. The performed evaluation revealed that the recognition...
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Enhanced aging resistance of poly(ε-caprolactone)/brewers’ spent grain composites
PublikacjaThe presented paper investigated the influence of brewers’ spent grain (BSG) extrusion pa-rameters on the photo-oxidative resistance of poly(ε-caprolactone)-based wood polymer composites. Filler samples characterized by the higher melanoidin content were more efficient in hindering of poly-mer degradation, inhibiting the decomposition of the polymer amorphous phase. As aresult, deteriora-tion of mechanical performance was limited,...
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Chitosan, Collagen and Gelatin in the design of novel materials with antimicrobial acticity
PublikacjaMedical devices containing and releasing antiinfective agents directly on the site of injury are a common group of materials available and widely used in treating difficult to heal wounds. Sustained contact of the active agent to the damaged tissue, needed to inhibit infection and preservation of microbiological purity of the wound, is provided by the immobilization antimicrobial agents on the surface of the matrix material or...
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Monte-Carlo Modeling of Optical Sensors for Postoperative Free Flap Monitoring
PublikacjaThis work aims to develop a numerical tissue model and implement software to simulate photon propagation using the Monte Carlo method to determine design guidelines for a physical measurement system. C++ was used for the simulation program, and Python as a programming environment to create an interface that allows the user to customize individual simulation elements, allowing for increased accuracy and flexibility when simulating...
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O 1s excitation and ionization processes in the CO2 molecule studied via detection of low-energy fluorescence emission
PublikacjaOxygen 1s excitation and ionization processes in the CO2 molecule have been studied with dispersed and non-dispersed fluorescence spectroscopy as well as with the vacuum ultraviolet (VUV) photon-photoion coincidence technique. The intensity of the neutral O emission line at 845 nm shows particular sensitivity to core-to-Rydberg excitations and core-valence double excitations, while shape resonances are suppressed. In contrast,...
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Monte-Carlo Modeling of Optical Sensors for Postoperative Free Flap Monitoring
PublikacjaThis work aims to develop a numerical tissue model and implement software to simulate photon propagation using the Monte Carlo method to determine design guidelines for a physical measurement system. C++ was used for the simulation program, and Python as a programming environment to create an interface that allows the user to customize individual simulation elements, allowing for increased accuracy and flexibility when simulating...
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Elimination and migration of hydrogen in the vacuum-ultraviolet photodissociation of pyridine molecules
PublikacjaElimination of the excited hydrogen atoms H(n), n = 4–7, and hydrogen migration in formation of the excited NH(A 3Π) free radicals in the photodissociation of pyridine, C5H5N, molecules have been studied over the 17.5–70 eV photon energy range. In the measurements the photon-induced fluorescence spectroscopy technique has been applied. Both fragments are produced through excitation of pyridine molecules into higher-lying superexcited...
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Ocena stanu technicznego rurociągu przesyłowego zawiesiny popiołów w Elektrowni Ostrołęka B
PublikacjaPrzedmiotem pracy był rurociąg przesyłowy zawiesiny popiołów przesyłanych z Elektrowni Ostrołęka B. Celem pracy było potwierdzenie przynależności próbek yvyciętych z rurociągu do określonego gatunku stali i ocena stanu materiału po eksploatacji. Dla zrealizowania tego celu wykonano: - analizę składu chemicznego materiału pobranego ze stalowych rur, - mikroanalizę warstw wierzchnich na powierzchni wewnętrznej i zewnętrznej, -...
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Epoxy/Ionic Liquid-Modified Mica Nanocomposites: Network Formation–Network Degradation Correlation
PublikacjaWe synthesized pristine mica (Mica) and N-octadecyl-N’-octadecyl imidazolium iodide (IM) modified mica (Mica-IM), characterized it, and applied it at 0.1–5.0 wt.% loading to prepare epoxy nanocomposites. Dynamic differential scanning calorimetry (DSC) was carried out for the analysis of the cure potential and kinetics of epoxy/Mica and epoxy/Mica-IM curing reaction with amine curing agents at low loading of 0.1 wt.% to avoid particle...
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Measurements of photoionization of mercury atoms into the 6s 2S1/2, 5d96s2 2D5/2 and 5d96s2 2D3/2 ionic states over the energy range from 10.5 eV to 18.7 eV
PublikacjaPhotoionization of mercury atoms into the three lowest ionic states, 5d106s 2S1/2, 5d96s2 2D5/2 and 5d96s2 2D3/2 has been studied in the photon energy ranges from their respective thresholds to 18.7 eV. The photoionization spectra were obtained with high energy resolution at an angle of 0° with respect to the polarization vector of the photon beam. The high energy resolution and sensitivity achieved in the measurements permitted...
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Mirosław Andrusiewicz prof. dr hab. n. med. i n. o zdr.
OsobyPosiadane dyplomy, stopnie naukowe lub artystyczne ̶ stopień doktora habilitowanego nauk medycznych (dyscyplina biologia medyczna) z dnia 4 grudnia 2017 r. Tytuł osiągnięcia naukowego: „Analiza wybranych genów związanych z przebiegiem zmian patologicznych w komórkach wywodzących się z żeńskich wewnętrznych narządów płciowych”; Uniwersytet Medyczny im. Karola Marcinkowskiego w Poznaniu, Wydział Lekarski II; recenzenci: Prof....
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Lighting conditions in Home Office and occupant’s perception: an international study
PublikacjaThe global pandemic and physical distancing restrictions are forcing us to rethink how residential buildings are used regarding the visual environment. This paper describes home office lighting conditions within different countries and continents. The aim is to define the current limitations of home offices in providing a resilient visual environment. The work was developed by a team of international experts working together on...
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The study on application of biopolyols obtained by cellulose biomass liquefaction performed with crude glycerol for the synthesis of rigid polyurethane foams
PublikacjaIn this work rigid polyurethane foams (PUR) were obtained by replacement of 0–70 wt% of petrochemical polyol with bio-polyol obtained via cellulose liquefaction in presence of crude glycerol. The foams with different content of a bio-polyol were prepared by single step method for NCO/OH ratio equals 1.5. The prepared materials were analyzed in terms of their morphology, chemical structure, thermal stability and basic physical and...
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Azo group(s) in selected macrocyclic compounds
PublikacjaAzobenzene derivatives due to their photo- and electroactive properties are an important group of compounds finding applications in diverse fields. Due to the possibility of controlling the trans–cis isomerization, azo-bearing structures are ideal building blocks for development of e.g. nanomaterials, smart polymers, molecular containers, photoswitches, and sensors. Important role play also macrocyclic compounds well known for...
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Yields and Time-of-Flight Spectra of Neutral High-Rydberg Fragments at the K Edges of the CO2 Molecule
PublikacjaWe have studied the production of neutral fragments in high-Rydberg (HR) states at the C 1s and O 1s edges of the CO2 molecule by performing two kinds of experiments. First, the yields of neutral HR fragments were measured indirectly by ionizing such fragments in a static electric field and by collecting resulting singly charged positive ions as a function of the photon energy. Such measurements reveal not only excitations below...
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Processing of Biomass Prior to Hydrogen Fermentation and Post-Fermentative Broth Management
PublikacjaUsing bioconversion and simultaneous value-added product generation requires purifica- tion of the gaseous and the liquid streams before, during, and after the bioconversion process. The effect of diversified process parameters on the efficiency of biohydrogen generation via biological pro- cesses is a broad object of research. Biomass-based raw materials are often applied in investigations regarding biohydrogen generation using...
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CMOS implementation of an analogue median filter for image processing in real time
PublikacjaAn analogue median filter, realised in a 0.35 μm CMOS technology, is presented in this paper. The key advantages of the filter are: high speed of image processing (50 frames per second), low-power operation (below 1.25 mW under 3.3 V supply) and relatively high accuracy of signal processing. The presented filter is a part of an integrated circuit for image processing (a vision chip), containing: a photo-sensor matrix, a set of...
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Analog CMOS processor for early vision processing with highly reduced power consumption
PublikacjaA new approach to an analog ultra-low power visionchip design is presented. The prototype chip performs low-levelconvolutional image processing algorithms in real time. Thecircuit is implemented in 0.35 μm CMOS technology, contains64 x 64 SIMD matrix with embedded analogue processors APE(Analogue Processing Element). The photo-sensitive-matrix is of2.2 μm x 2.2 μm size, giving the density of 877 processors permm2. The matrix dissipates...
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5-Thiocyanato-2′-deoxyuridine as a possible radiosensitizer: electron-induced formation of uracil-C5-thiyl radical and its dimerization
PublikacjaIn this work, we have synthesized 5-thiocyanato-2′-deoxyuridine (SCNdU) along with the C6-deuterated nucleobase 5-thiocyanatouracil (6-D-SCNU) and studied their reactions with radiation-produced electrons. ESR spectra in γ-irradiated nitrogen-saturated frozen homogeneous solutions (7.5 M LiCl in H2O or D2O) of these compounds show that electron-induced S–CN bond cleavage occurs to form a thiyl radical (dU-5-S˙ or 6-D-U-5-S˙) and...
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Superexcited states in the vacuum-ultraviolet photofragmentation of isoxazole molecules
PublikacjaThe photofragmentation of isoxazole molecules producing excited atomic and molecular fragments has been investigated over the energy range 16-50 eV, using photon-induced fluorescence spectroscopy. The following fragments have been identified by their fluorescence: the excited hydrogen atoms H(n), n = 3-7 and the diatomic CH(A2Δ, B2Σ−), CN(B2Σ+) and C2(d3Πg) fragments. The diatomic fragments are vibrationally and highly rotationally...
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Tagged images with LEGO bricks
Dane BadawczeThe data set conatins tagged images conatining LEGO bricks used for traning LEGO bricks detecting network. The dataset contains two types of images:
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Quantum randomness protected against detection loophole attacks
PublikacjaDevice and semi-device-independent private quantum randomness generators are crucial for applications requiring private randomness. However, they are vulnerable to detection inefficiency attacks and this limits severely their usage for practical purposes. Here, we present a method for protecting semi-device-independent private quantum randomness generators in prepare-and-measure scenarios against detection inefficiency attacks....
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An Overview of Treatment Approaches for Octahydro-1, 3, 5, 7-tetranitro-1, 3, 5, 7-tetrazocine (HMX) Explosive in Soil, Groundwater, and Wastewater
PublikacjaOctahydro-1, 3, 5, 7-tetranitro-1, 3, 5, 7-tetrazocine (HMX) is extensively exploited in the manufacturing of explosives; therefore, a significant level of HMX contamination can be encountered near explosive production plants. For instance, up to 12 ppm HMX concentrations have been observed in the wastewater effluent of a munitions manufacturing facility, while up to 45,000 mg/kg of HMX has been found in a soil sample taken from...
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On the mechanism of photocatalytic reactions on CuxO@TiO2 core–shell photocatalysts
PublikacjaTitania (titanium(IV) oxide) is a highly active, stable, cheap and abundant photocatalyst, and is thus commonly applied in various environmental applications. However, two main shortcomings of titania, i.e., charge carrier recombination and inactivity under visible-light (vis) irradiation, should be overcome for widespread commercialization. Accordingly, titania has been doped, surface modified and coupled with various ions/compounds,...
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LEGO bricks for training classification network
Dane BadawczeThe data set contains images of 447 different classes of LEGO bricks used for training LEGO bricks classification network. The dataset contains two types of images: photos (10%) and renders (90%) aggregated into respective directories. Each directory (photos and renders) contains 447 directories labeled as the official brick type number. The images...
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Płyty przedprożowe z elewacji dawnego budynku jatek mięsnych w Gdańsku?
PublikacjaPodczas badań archeologicznych prowadzonych w latach 2004-2005 na terenie historycznych jatek mięsnych głównomiejskiego cechu rzeźników w Gdańsku, kierujący badaniami Robert Krzywdziński postawił tezę, że fragmenty płaskorzeźbionej dekoracji ściany szczytowej od strony ulicy Mariackiej, zniszczonego w 1945 roku budynku jatek, zostały wykorzystane jako elementy dekoracyjnych płyt przedprożowych podczas powojennej odbudowy kamienicy...
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An Analog Sub-Miliwatt CMOS Image Sensor With Pixel-Level Convolution Processing
PublikacjaA new approach to an analog ultra-low power medium-resolution vision chip design is presented. The prototype chip performs low-level image processing algorithms in real time. Only a photo-diode, MOS switches and two capacitors are used to create an analog processing element (APE) that is able to realize any convolution algorithm based on a full 3x3 kernel. The proof-of-concept circuit is implemented in 0.35 µm CMOS technology,...
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Fixed Pattern Noise Reduction and Linearity Improvement in Time-Mode CMOS Image Sensors
PublikacjaIn the paper, a digital clock stopping technique for gain and offset correction in time-mode analog-to-digital converters (ADCs) has been proposed. The technique is dedicated to imagers with massively parallel image acquisition working in the time mode where compensation of dark signal non-uniformity (DSNU) as well as photo-response non-uniformity (PRNU) is critical. Fixed pattern noise (FPN) reduction has been experimentally validated...
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Novel Polyurethanes as Antifouling Paint Matrices
PublikacjaThe new poly(ester-ether urethane)s (PEEUR) were prepared in two stage synthesis from formerly obtained oligo(alkylene ester-ether)diols (OAEE) and 4,4‘-diphenylmethane diisocyanate (MDI). PEEUR samples were subjected to crosslinking with styrene in the presence of radical polymerization initiators: methyl ethyl ketone peroxide (MEKPO) or cobalt 2-ethyl cyclohexanoate (EtHCo). Crosslinked PEEUR were characterized by their physicochemical...
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Fiber optic low-coherence Fabry-Pérot interferometer with ZnO layers in transmission and reflective mode: comparative study
PublikacjaA construction of a low-coherence fiber-optic Fabry-Pérot interferometer using a thin ZnO layer as a reflective surfaces was proposed and examined. In the investigated setup, the ZnO layer of thickness 200 nm were deposited on the face of the standard telecommunication single-mode optical fiber (SMF-28). Measurements of interference signal were performed for the interferometer working in the transmission and reflective mode, as...
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The Use of Photographs in the Teaching/Learning of Descriptive Geometry
PublikacjaThe article presents the concept of enriching the Descriptive Geometry course with photographs and several simplified real-life engineering tasks. The photographic images used for the exercises are tightly linked to engineering structures, the given specialization and the surrounding world. The photo image as a record of central projection of a real space can be useful for presentation and analysis of the properties of perspective....
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Experimental study of the use of electric car powered with stationary solar and electrochemical batteries in Northern Poland
PublikacjaThe subject of this paper is an experimental analysis of a Nissan LEAF electric car equipped with 24 kWh battery, powered from the standalone photo-voltaic (PV) charging station in Gdańsk, Poland. The calculations of charging process efficiency and range of test drives were conducted in two extreme situations (winter and summer) of sunlight and road conditions. Experiments were performed in the Laboratory of Innovative Power Technologies...
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Epitaph of Bartholomew Wagner in St. Mary's Church in Gdańsk
Dane BadawczeThe data set concerns epigraphy. It refers to the epitaph placed in St. Mary’s Church in Gdańsk, that is dedicated to Bartholomew Wagner, city physician from 1562, who came to Gdańsk from Konigsberg. Data set contains one general photo of the epitaph, transcription of its text in Latin, its translation in Polish, and the biography of the deceased, also...
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Foundation text of St. Mary's Church in Gdańsk
Dane BadawczeThe data set concerns epigraphy. It refers to the medieval foundation preserved on the wall above the sacristy entrance in St. Mary’s Church in Gdańsk, which confirms that the foundation stone of the temple was laid on 28th of March 1343. The data set contains one general photo of the foundation text, transcription of its text in Latin and its Polish...
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Epitaph of John Schroeder in St. Mary's Church in Gdańsk
Dane BadawczeThe data set concerns epigraphy. It refers to the epitaph placed in St. Mary’s Church in Gdańsk, that is dedicated to John Schröder, son of Simon. John, as he was a single, erected this epitaph for himself. Data set contains one general photo of the epitaph, transcription of its text in Latin, its translation in Polish, and the biography of the deceased,...
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Organic pollutants photodegradation increment with use of TiO2 nanotubes decorated with transition metals after pulsed laser treatment
PublikacjaAmong various titanium(IV) oxide (TiO2, titania) structures, 1D nanotubes (TiO2 NTs) produced during the two-electrode anodization process, are extensively utilized in sensors or supercapacitors as well as in photo(electro)catalytic water splitting. However, due to wide bandgap and fast electron-hole recombination additional modifications, mostly concerned on materials surface, are required. According to the recent research, TiO2...
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Epitaph of Henry Giese in St. Mary's Church in Gdańsk
Dane BadawczeThe data set concerns epigraphy. It refers to the epitaph placed in St. Mary’s Church in Gdańsk, that is dedicated to Henry Giese, a member of merchant family that came from Germany and settled down in Gdańsk in XVI century. Data set contains one general photo of the epitaph, transcription of its text in Latin, its translation in Polish, and the biography...
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Epitaph of Oehm family in St. Mary's Church in Gdańsk
Dane BadawczeThe data set concerns epigraphy. It refers to the epitaph placed in St. Mary’s Church in Gdańsk, that is dedicated to Öhm family, rather unknown to Gdańsk. The epitaph was erected by two latest representatives of family – John and Andrew. Data set contains one general photo of the epitaph, transcription of its text in Latin, its translation in Polish,...
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MXene-based materials for removal of antibiotics and heavy metals from wastewater– a review
PublikacjaAs a novel family of 2D materials, MXenes provide an extensive variety of applications in water and effluent treatment due to their distinctive properties and attractive applicability, including superior electrical conductivity, higher thermal stability, hydrophilicity, and high sorption-reduction capacity. Their excellent sorption selectivity makes them perfect for removing hazardous contaminants. Currently, MXene-based materials...
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New approaches for improving selectivity and sensitivity of resistive gas sensors: A review
PublikacjaResistive gas sensors are very popular and reliable but suffer from low selectivity and sensitivity. Various methods have been suggested to improve both features without increasing the number of sensors in gas detection systems. Fluctuation enhanced gas sensing was proposed to improve gas detection efficiency by analyzing low-frequency resistance fluctuations, and noise parameters can be more informative than the single DC resistance...
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Photofragmentation of tetrahydrofuran molecules in the vacuum-ultraviolet region via superexcited states studied by fluorescence spectroscopy
PublikacjaPhotofragmentation of tetrahydrofuran molecules in the vacuum-ultraviolet region, producing excited atomic and molecular fragments, has been studied over the energy range 14-68 eV using photon-induced fluorescence spectroscopy. Excited hydrogen atoms H(n), n = 3-11, have been detected by observation of the Hα to Hı lines of the Balmer series. The diatomic CH(A2Δ), CH(B2Σ-) and C2(d3Πg) fragments, which are excited to low vibrational...
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A piece of corporate finance
PublikacjaThe handbook presents the subject of financial liquidity and CVP analysis. The handbook uses different types of information: definitions of the issues; “real life” examples illustrating a given theoretical issue in practice; mathematical formulas necessary to calculate a certain value; types of method used. In addition to traditional resources such as drawings, diagrams, tables and photos, the handbook also includes resources of...
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Alms-panel of Anton Moeller in St. Mary's Church in Gdańsk
Dane BadawczeThe data set concerns epigraphy. It refers to the Alms-panel placed in St. Mary’s Church in Gdańsk, that is the work of Gdańsk painter Antoni Moller, made in 1607, or rather – to be more specific – to lower part of this work, which are the verses from Holy Bible. Data set contains one general photo of the inscription, transcription of its text in Latin...
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Epitaph of Anna Loitz in St. Mary's Church in Gdansk
Dane BadawczeThe data set concerns epigraphy. It refers to the epitaph placed in St. Mary’s Church in Gdańsk which is dedicated to Anna Loitz, daughter of the well-known merchant Michał Loitz, wife of the juror and councilor Jan Konnert the Younger. The data set contains one general photo of the epitaph, transcription of its text in Latin, its Polish translation,...
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Epitaph of Martin Ramus in St. Mary's Church in Gdańsk
Dane BadawczeThe data set concerns epigraphy. It refers to the epitaph placed in St. Mary’s Church in Gdańsk which is dedicated to Martin Ramus, teacher of the parochial school at the St. Mary church in Gdansk who died on 24th of June 1631 in Gdańsk. The data set contains one general photo of the epitaph, transcription of its text in Latin, its Polish translation,...
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Epitaph of Guldenstern family in St. Mary's Church in Gdańsk
Dane BadawczeThe data set concerns epigraphy. It refers to the epitaph placed in St. Mary’s Church in Gdańsk, that is dedicated to family Guldenstern, very noble family that came to Poland with the king of Sweden and Poland – Sigismund III Vasa, and to representatives of Swedish emigration. Data set contains one general photo of the epitaph, transcription of its...