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Search results for: hydrogen production and combustion
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Signal filtering method of the fast-varying diesel exhaust gas temperature
PublicationThe paper presents the problem of the impact of external distortions originating on laboratory test stands on the results of measurements of fast-varying diesel exhaust gas temperature. It has been stressed how significant the aspect of the test stand adaptation is during an experiment to ensure the smallest possible impact. This paper, however, focuses on the methods of mathematical processing of a signal recorded during experimental...
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Adoption of the F-statistic of Fisher-Snedecor distribution to analyze importance of impact of modifications of injector opening pressure of a compression ignition engine on specific enthalpy value of exhaust gas flow
PublicationThis article analyzes the effect of modifications of injector opening pressure on the operating values of a compression ignition engine, including the temperature of the fumes. A program of experimental investigation is described, considering the available test stand and measurement capabilities. The structure of the test stand on which the experimental measurements were conducted is presented. The method of introducing real modifications...
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Research on the effect of low-sulphur marine fuels on the dynamic characteristics of a CI engine
PublicationThe implementation of low-sulphur, so-called modified marine fuels into operation requires prior labora- tory engine tests to assess the energy, emission and structural effects of their usage. This type of research are carried out on the test bed of a diesel engine as a small-scale physical model that reproduces the adequate design and process (parametric) features of a full-size marine engine. Their key stage is to determine the energy...
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Analysis of the structure of the atomized fuel spray with marine diesel engine injector in the early stage of injection
PublicationThis paper presents the results of the experimental research of the atomized fuel spray with the marine diesel engine injector in the constant volume chamber. The specificity of the phenomena occurring in the marine engine cylinder was the reason to use the optical visualisation method in the studies – the Mie scattering technique. This work presents an analysis of the influence of different geometry of outlet orifice and opening...
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Crystallographic study of self-organization in the solid state including quasi-aromatic pseudo-ring stacking interactions in 1-benzoyl-3-(3,4-dimethoxyphenyl)thiourea and 1-benzoyl-3-(2-hydroxypropyl)thiourea
Publication1-Benzoylthioureas contain both carbonyl and thiocarbonyl functional groups and are of interest for their biological activity, metal coordination ability and involvement in hydrogen-bond formation. Two novel 1-benzoylthiourea derivatives, namely 1-benzoyl-3-(3,4-dimethoxyphenyl)thiourea, C₁₆H₁₆N₂O₃S, (I), and 1-benzoyl-3-(2-hydroxypropyl)thiourea, C₁₁H₁₄N₂O₂S, (II), have been synthesized and characterized. Compound (I) crystallizes...
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Determination of moisture resistance of covered electrodes according to PN-EN ISO 14372
PublicationMoisture present in the electrode covering is one of the sources of diffusible hydrogen in welded joints. In order to study the diffusible hydrogen content in deposited metal, a stand for moisturizing covered electrodes, in accordance with the PN-EN ISO 14372 standard, was built. After the stand was completed, a test of moisturizing the electrodes was carried out and measurements of the diffusible hydrogen content in deposited...
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Correlation between structural and electrical properties in highly porous (Y,Sr)(Ti,Nb)O3-delta SOFC anodes
PublicationIn order to find a relationship between structural and electrical properties, niobium and yttrium doped SrTiO3 ceramics were prepared via solid-state reaction. The samples were sintered in hydrogen and air conditions. The samples were also fabricated with a pore-former to obtain highly porous specimens. The electrical properties of Nb-doped SrTiO3 samples and yttrium and niobium co-doped SrTiO3 were compared. The comparable electrical...
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Weakly Hydrated Solute of Mixed Hydrophobic–Hydrophilic Nature
PublicationInfrared (IR) spectroscopy is a commonly used and invaluable tool in studies of solvation phenomena in aqueous solutions. Concurrently, density functional theory calculations and ab initio molecular dynamics simulations deliver the solvation shell picture at the molecular detail level. The mentioned techniques allowed us to gain insights into the structure and energy of the hydrogen bonding network of water molecules around methylsulfonylmethane...
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Effective method of treatment of industrial effluents under basic pH conditions using acoustic cavitation – a comprehensive comparison with hydrodynamic cavitation processes
PublicationThe use of acoustic cavitation in advanced oxidation processes (AOPs) is a promising trend in research for treatment of industrial effluents. The paper presents the results of investigations on the use of acoustic cavitation aided by additional oxidation processes (ozonation/H2O2 oxidation/Peroxone/UV-C) for the treatment of effluents from the production of bitumens. Under these conditions, the total contaminant load, expressed...
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Tuning of food wastes bioavailability as feedstock for bio-conversion processes by acoustic cavitation and SPC, SPS, or H2O2 as external oxidants
PublicationThe growing amount of food wastes makes them a suitable source for the generation of bioproducts through anaerobic digestion. Appropriate hydrolysis of the feedstock can enhance the efficiency of production of desired products. In this work, acoustic cavitation (AC) was employed as a pretreatment method to enhance hydrolysis stage by the modification of model (potato-based) food waste for increase in soluble chemical oxygen demand...
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Alternative methods for dark fermentation course analysis
PublicationDark fermentation course analysis is crucial, as complexed matrix of gaseous components may be formed and revealed during the process. The paper considers key issues related to the microbiological process in which complex organic substances are transformed into hydrogen. For the purposes of hydrogen generation, the application of wastewater mixed sludge pre-treated according to Faloye method (Faloye et al. in Int J Hydrog Energy...
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Elementary analysis and energetic potential of the sludge from the Gdynia Dębogórze and Lębork wastewater treatment plants
PublicationThe paper aims to show the results of the elementary analysis of the sewage sludges from wastewater treatment plants in Gdynia Dębogórze and Lębork as well as measurements of the heat of combustion and the calculated calorific values according to regulation PN-93/Z-15008, taking into account water content and the composition of sewage sludge at different utilisation stages. The results presented in this paper are based on the analysis...
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USEFULNESS OF SEMI-MARKOV PROCESSES AS MODELS OF THE OPERATION PROCESSES FOR MARINE MAIN ENGINES AND OTHER MACHINES OF SHIP POWER PLANTS
PublicationThe paper describes the properties of semi-Markov processes and the opportunities and benefits from their use as models of the operation processes for marine combustion engines and other machines of ship power plants. The emphasis is put on the importance of the theory of semi-Markov processes for development of the theory of marine combustion engines and other machines of ship power plants, as well as for development of the operational...
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Design and distribution of air nozzles in the biomass boiler assembly
PublicationDue to energy crisis as well as increasing pollution of the environment, renewable energy sources usage increases all over the world. These facts encouraged authors to start research over developing a uniform biomass boiler calculation model. This paper presents a design of biomass boiler assembly created for ORC (Organic Rankine Cycle) unit since these systems could achieve strong position in energy industry....
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Zaawansowane utlenianie odcieków składowiskowych - przegląd metod
PublicationPrzedstawiono rozwiązania unieszkodliwiania odcieków składowiskowych metodami zaawansowanego utleniania, takimi jak: reakcja Fentona, utlenienie ozonem i nadtlenkiem wodoru, utlenienie elektrochemiczne, utlenienie w warunkach nadkrytycznych oraz mokre utlenienie powietrzem. Podstawy teoretyczne tych metod, ich efektywność oraz stosowane reagenty. Uwarunkowania stosowania poszczególnych metod.
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Preparation and X-ray structures of selected aminium thiosulfates
PublicationVarious types of aminium thiosulfates (1–6), including hydrates and mixed salts, have been obtained by the reaction of ammonium thiosulfate with amines. Tertbutylamine, cyclo-hexylamine and 1,6-diaminohexane gave crystals of (t-BuNH3)2S2O3·H2O (1), (c-C6H11NH3)2S2O3 (3) and {(NH4)2(H3NC6H12NH3)(S2O3)2} (6), respectively, which were investigated by X-ray structural analysis. Extensive hydrogen bonding of the N-H…O and N-H…S type...
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EMISJA AKUSTYCZNA JAKO SYGNAŁ DIAGNOSTYCZNY ODWZOROWUJĄCY ZMĘCZENIOWE ZUŻYCIE WARSTW ŚLIZGOWYCH PANWI ŁOŻYSK GŁÓWNYCH I KORBOWYCH SILNIKÓW O ZAPŁONIE SAMOCZYNNYM
PublicationW artykule przedstawiono wyniki badań laboratoryjnych, z których wynika, że emisja akustyczna (EA) może być uznana za sygnał diagnostyczny, przydatny do identyfikacji stanu technicznego łożysk głównych i korbowych okrętowych silników o zapłonie samoczynnym. Wykazano w nim bowiem, że parametry emisji akustycznej takie jak: czas rejestracji, energia sygnału, amplituda sygnału, ilość przekroczeń poziomu dyskryminacji, czas narastania,...
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Diagnostyka eksploatacyjna okrętowych silników spalinowych - tłokowych i turbinowych
PublicationW monografii przedstawiono wybrane zagadnienia diagnostyki technicznej silników spalinowych dużej mocy, zarówno tłokowych, jak i turbinowych, ukierunkowane na eksploatację okrętowych (i nie tylko) systemów energetycznych, w których występują tego typu silniki. W początkowej części opracowania zaproponowano koncepcję systemowego ujęcia diagnostyki eksploatacyjnej silników okrętowych w aspekcie obowiązujących standardów światowych...
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Effect of Nanohydroxyapatite on Silk Fibroin–Chitosan Interactions—Molecular Dynamics Study
PublicationFibroin–chitosan composites, especially those containing nanohydroxyapatite, show potential for bone tissue regeneration. The physicochemical properties of these biocomposites depend on the compatibility between their components. In this study, the intermolecular interactions of fibroin and chitosan were analyzed using a molecular dynamics approach. Two types of systems were investigated: one containing acetic acid and the other...
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Structural and electrical transport properties of Pr-doped SrTi0.93Co0.07O3-δ a novel SOEC fuel electrode materials
PublicationSolid Oxide Electrolyzer Cells (SOECs) are very promising electrochemical devices for the production of syngas (H2/CO) by H2O and CO2 co-electrolysis. The structure, microstructure and electrical properties of the fuel electrode material play a crucial role in the performance of the whole cell and efficiency of electrocatalytic reduction of steam into hydrogen. In the present work, a novel Co and Pr co-doped SrTiO3-δ material attracted...
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Process Control and Investigation of Oxidation Kinetics of Postoxidative Effluents Using Gas Chromatography with Pulsed Flame Photometric Detection (GC-PFPD)
PublicationThis article presents the results of investigations on the use of headspace analysis and gas chromatography with pulsed flame photometric detection (HSA-GC-PFPD) to evaluate the effectiveness of oxidation of postoxidative effluents from the production of bitumens. Samples of effluents from the bitumen oxidation unit were used in the experiments. In addition, the kinetics of effluent oxidation was also investigated. The content...
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Tailoring a low-energy ball milled MnCo2O4 spinel catalyst to boost oxygen evolution reaction performance
PublicationThe development of cost-efficient oxygen evolution reaction (OER) catalysts is one of the most important tasks facing modern techniques for hydrogen production. In this work, for the first time, a low-energy ball milling process of MnCo2O4 (MCO) spinel powders, with a mechanical modification time exceeding 1 day was used. After 6 days of ball-milling, the obtained overpotential of the electrocatalyst reached the value of 375 mV...
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Thermodynamic Analysis of Negative CO2 Emission Power Plant Using Aspen Plus, Aspen Hysys, and Ebsilon Software
PublicationAbstract: The article presents results of thermodynamic analysis using a zero-dimensional mathematical models of a negative CO2 emission power plant. The developed cycle of a negative CO2 emission power plant allows the production of electricity using gasified sewage sludge as a main fuel. The negative emission can be achieved by the use this type of fuel which is already a “zeroemissive” energy source. Together with carbon capture...
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Corrosion and Cavitation Resistances of Low Alloy Steel After Frictional-Mechanical Treatment
PublicationPaper presents the results of the studies of wear, corrosion and cavitation resistances of the S355J2 low alloy medium carbon steel subjected to surface modification by friction-mechanical treatment, as tested in sea water simulated solution. To evaluate the effect of the surface treatment, the comparative studies of the corrosive properties of the steel before and after treatment have been considered. The treatment due to a severe...
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Dimethyl ether (DME) as potential environmental friendly fuel
PublicationIn recent years, there has been a growing interest in replacing petroleum fuels with so-called second generation environmental friendly fuels. Compared to traditional petroleum fuels dimethyl ether (DME) could be used as a clean high-efficiency compression ignition fuel with reduced particulate matter (PM), sulfur oxides (SOx), hydrocarbons (HC), carbon monoxide (CO) as well as combustion noise. Compared to some of the other leading...
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Carbon dioxide potential reduction using Start-Stop system in a car
PublicationOperating fuel consumption increases significantly when the vehicle stops frequently while driving or when the engine is idling during braking. In such cases, the internal combustion engine consumes the fuel but the mechanical energy is not used by the drive system. The amount of fuel that is consumed in this time by the engine can potentially be saved if the car is equipped with a Stop-Start system. Start-Stop system automatically...
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WYBRANE WŁAŚCIWOŚCI FIZYCZNO-CHEMICZNE MIKROSFER I MOŻLIWOŚĆ ICH WYKORZYSTANIA W KOMPOZYTACH CEMENTOWYCH : The selected physico-chemical properties of microspheres and possibility of their use in cement composites
PublicationMicrospheres are formed during the mineral transformation stage in coal combustion. Their content in fly ashes from the combustion of different types of coals varies over a rather wide range from 0.01 to 4.8 wt.%. The microspheres have three main elements, silicon, aluminum and iron, the oxides of which account for about 89.0 wt.% of the material. Mineralogical analysis using XRD shows that microspheres mainly contain mullite and...
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Why is the cubic structure preferred in newly formed ice?
PublicationMolecular dynamics was employed to explain the preference for the cubic structure in newly formed crystals of ice. The results showed that in supercooled liquid water the molecules connected by hydrogen bonds are more likely to adopt relative orientations similar to the ones characteristic for cubic ice. The observed preference for certain relative orientations of molecules in the hydrogen-bonded pairs results in the higher probability...
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The role of robotisation in improving bakery product quality
PublicationThe article aims to present the role of robotisation in increasing bakery product quality, as it is closely linked to machine reliability, as well as hygienic and sanitary conditions. All machines employed in the production process ought to be maintained at full production potential and reliability, which also has a fundamental influence on the final product’s quality. While participating in the 2014-2020 Smart Growth Operational...
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Research on flue gas flow measurement and modelling in the moving grate biomass boiler
PublicationThe aim of this research was to determine the nature of gas flow in a grate boiler model by the method of Particle Image Velocimetry (PIV) and CFD. The paper presents the comparison of the PIV results with numerical simulations made in the environment of ANSYS Fluent. The main goal of the experiment was to describe the phenomena occurring on the grate. Methodology of modelling solid fuel combustion on the moving grate was proposed...
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Selected Problems of Cogeneration Energy Systems Designing, Fueled with Landfill Biogas
PublicationThe article discusses the impact of the quality of biogas fuel for operation of generating sets with internal combustion engines. There are presented selected investigation results of landfill biogas fueled gensets operation. The article includes also discussion of the possibility of increasing the efficiency of biogas fuelled cogeneration systems. It also presents guidelines for the optimal design of landfill biogas fueled engines,...
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Self-assembly of secondary aryl amides in cocrystals with perfluoroaryl coformers: structural analysis and synthon preferences
PublicationCooperation of aryl⋯perfluoroaryl stacking interactions and hydrogen bonds was utilized in the construction of six novel cocrystals of aromatic cis-amides with pentafluorobenzoic acid (pfba) and pentafluorophenol (pfp). They were obtained by crystallization from solution and structurally characterized. In four instances, the components form heterotetrameric motifs, in which amide:amide homodimer interacts symmetrically on two sides...
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HIERARCHICAL CYCLES IN MODERN POWER SYSTEMS – EXERGY ANALYSIS UNDER PART LOADS
PublicationThe aim of the paper is to investigate thermodynamic efficiency of advanced hierarchic power cyclesunder partial loads by using of exergy analyze. Advanced hierarchical power systems arecomposed of few energy conversion cycles, most common are steam and gas cycles in various configurations, but they may contain fuel cells, ORC, lithium bromide absorption chillers and others. Moreover hierarchical cycles can be powered by several...
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On the Use of Selected 4th Generation Nuclear Reactors in Marine Power Plants
PublicationThis article provides a review of the possibility of using different types of reactors to power ships. The analyses were carried out for three different large vessels: a container ship, a liquid gas carrier and a bulk carrier. A novelty of this work is the analysis of the proposal to adapt marine power plants to ecological requirements in shipping by replacing the conventional propulsion system based on internal combustion engines...
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The evaluation of the vibration measurement usability of electronic indicator lemag "premet C"
PublicationThe measuring possibilities of modern compression and combustion pressure analyzers are extended with additional functions. One of them is parallel to the pressure measurement, the measurement of vibrations in the region of the cylinder head. The paper presents a general assessment of the vibration measurement function of the electronic indicator LEMAG "PREMET C". This feature is very rarely offered by manufacturers of these devices....
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1,3-Di-<i>n</i>-butylthiourea
PublicationIn the title compound, C9H20N2S, the n-butyl groups are in syn and anti positions in relation to the C=S bond. In the crystal, two molecules are connected by two N-H···S=C hydrogen bonds into a centrosymmetric dimer. Another N-H···S=C hydrogen bond links the dimers, forming layers with a hydrophilic interior and a hydrophobic exterior, which spread across the (100) plane. Interlacing of the...
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Thermal Energy Development in Magnetohydrodynamic Flow Utilizing Titanium Dioxide, Copper Oxide and Aluminum Oxide Nanoparticles: Thermal Dispersion and Heat Generating Formularization
PublicationThe main aim of this article heat transfer in thermal engineering deals with the production, use, transformation, and transfer of thermal energy. Engineering and industrial fields including food packaging, the production of food additives, electronic cooling, microturbines, etc. heavily rely on heat transmission. Due to its intriguing potential in industries like the production of polymers, paper, crystal glass, etc., scientists...
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Effect of temperature and composition on physical properties of deep eutectic solvents based on 2-(methylamino)ethanol – measurement and prediction
PublicationNovel deep eutectic solvents were synthesized using 2-(methylamino)ethanol as hydrogen bond donor with tetrabutylammonium bromide or tetrabutylammonium chloride or tetraethylammonium chloride as hydrogen bond acceptors. Mixtures were prepared at different molar ratios of 1:6, 1:8 and 1:10 salt to alkanolamine and then Fourier Transform Infrared Spectroscopy measurements were performed to confirm hydrogen bonds interactions between...
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Możliwości zamiany elektrycznych przepływomierzy powietrza stosowanych w silnikach spalinowych samochodów
PublicationW artykule przedstawiono podstawowe typy przepływomierzy powietrza, stosowane w silnikach spalinowych samochodów: z klapąspiętrzającą, HLM, HFM, Vortex i MAP. Przedstawiono wyniki badania tych przepływomierzy na specjalnie przygotowanym stanowisku pomiarowym. Przeanalizowano możliwość ich zamiany i zweryfikowano taką możliwość w praktyce.
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Synthesis of Trehalose by the Erythritol-Producing Yeast Yarrowia lipolytica Co-Displaying Maltooligosyltrehalose Synthase and Maltooligosyltrehalose Trehalohydrolase
PublicationIndustrial trehalose production faces economic challenges with costly enzyme preparations, prompting the exploration of eco-friendly alternatives. Here, we established a coupled functional sugar production line leveraging erythritolproducing cells as an innovative enzyme preparation for trehalose synthesis. The erythritol-producing Yarrowia lipolytica was modified to express a fusion protein consisting of maltooligosyltrehalose synthase...
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ENVIRONMENTAL DEGRADATION OF DISSIMILAR AUSTENITIC 316L AND DUPLEX 2205 STAINLESS STEELS WELDED JOINTS
PublicationThe paper describes structure and properties of dissimilar stainless steels welded joints between duplex 2205 and austenitic 316L steels. Investigations were focused on environmentally assisted cracking of welded joints. The susceptibility to stress corrosion cracking (SCC) and hydrogen embrittlement was determined in slow strain rate tests (SSRT) with the strain rate of 2.2 × 10–6 s–1. Chloride-inducted SCC was determined in the...
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Application of H2O2 to optimize ammonium removal from domestic wastewater
PublicationThe paper presents the results of application of hydrogen peroxide (H2O2) for the optimization of the effects of ammonia nitrogen removal from domestic wastewater. The investigations were carried out at a model wastewater treatment plant consisting of a preliminary sedimentation tank and a sand filter with a horizontal flow of wastewater at a constant hydraulic load of 1.44 L/day. The efficiency of ammonia nitrogen removal was...
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Wodór jako paliwo cz. 1
PublicationW artykule przedstawiono wodór jako nowoczesny nośnik energii oraz jego zastosowanie techniczne w ujęciu konwersji energii. Przybliżono jego odkrycie, właściwości oraz jego wykorzystanie od odkrycia do współczesności. Dokonano opisu budowy i zasady działania ogniw paliwowych. Omówiono ich podział przedstawiając zalety i wady każdego rozwiązania oraz ich zastosowanie techniczne w zależności od typu ogniwa.
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Selected Issues of Hybrid Outboard Motors
PublicationThe aim of the research reported in the article was designing a hybrid drive system based on an outboard internal combustion engine offered by a selected producer and testing its operating characteristics. The article presents different designs of this type of drive which can be found in the literature and are available in the market. The designed hybrid outboard drive system was tested both on the laboratory test rig and in real...
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Influence of Rock Dust Additives as Fine Aggregate Replacement on Properties of Cement Composites—A Review
PublicationConcrete production consumes enormous amounts of fossil fuels, raw materials, and is energy intensive. Therefore, scientific research is being conducted worldwide regarding the possibility of using by-products in the production of concrete. The objective is not only to identify substitutes for cement clinker, but also to identify materials that can be used as aggregate in mortar and concrete productions. Among the potential alternative...
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Configurational and Conformational Preferences in Stereoselective Acylations of N-Methyl-1,3-diaminopropane with Acyl Chlorides
PublicationEvidence for a stereoinduction profile of the reaction of N-methyl-1,3-diaminopropane with acyl chlorides was provided. A possibility to engage in intramol. CH2···HN and Cl···H-N interactions and the proton migration process to the methylamino group leads to the E secondary amides carrying the N···H+···N or N-H···N bridges, that show unusual spectroscopic images. Empirical relations between the ΔδC chem. shift differences,...
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Wet H2S corrosion and degradation of pipeline in amine regeneration system
PublicationThe paper presents the results of NDT examinations, metallographic tests and risk assessment of degradation related to corrosion of amine regeneration unit in a desulphurisation system. Intensive corrosion resulting from acid gases environment upon water condensation causes perforation of the pipeline. Detailed analysis reveals cracking related to the mechanism of wet H2S. Hydrogen penetration, resulting from the wet H2S process,...
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Feasibility of combined diesel engine - steam turbine in power station operating in the maritime
PublicationCompression-ignition engines used in ship technology as main propulsion engines are large units reaching even to 50-60 MW. Currently, the efficiency of such engines amounts to 45-50%. With such a large power unit, exhaust gases leaving the engine contain very large quantities of heat available for further treatment. Exhaust gases from the piston engine contain about 25% of the heat supplied to the engine in the fuel. Using the...
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Application of Thermo-chemical Technologies for Conversion of Associated Gas in Diesel-Gas Turbine Installations for Oil and Gas Floating Units
PublicationThe paper considers the issue of thermo-chemical recovery of engine’s waste heat and its further use for steam conversion of the associated gas for oil and gas floating units. The characteristics of the associated gas are presented, and problems of its application in dual-fuel medium-speed internal combustion engines are discussed. Various variants of combined diesel-gas turbine power plant with thermo-chemical heat recovery are...
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Thermal utilization of meat-and-bone meal using the rotary kiln pyrolyzer and the fluidized bed boiler – The performance of pilot-scale installation
PublicationThermal utilization of meat-and-bone meal (MBM) is subject to stringent regulations that are meant to provide elimination of any potential pathogens. Incineration as well as other possible routes for thermal conversion of MBM are still at the research state. The universal technology was developed that allows to combust various types of waste organic materials, including animal waste, municipal solid waste and sludge, mixed at any...