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Search results for: Q-ORBITRAP-HRMS
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Comparative Analysis of Metabolic Variations, Antioxidant Profiles and Antimicrobial Activity of Salvia hispanica (Chia) Seed, Sprout, Leaf, Flower, Root and Herb Extracts
PublicationThe purpose of this study was to evaluate the phytochemical profiles of the seeds, sprouts, leaves, flowers, roots and herb of Salvia hispanica and to demonstrate their significant contribution to antioxidant and antimicrobial activities. Applied methods were: HPLC-DAD coupled with post-column derivatization with ABTS reagent, untargeted metabolomics performed by LC-Q-Orbitrap HRMS, and two-fold micro-dilution broth method, which...
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Comparative evaluation of different methods for determining phytochemicals and antioxidant activity in products containing betalains - Verification of beetroot samples
PublicationThis study presents methods that can be used to assess the health quality of products containing betalains. The paper compares and verifies data on the phytochemical composition of three different pigmented beetroot cultivars using spectrophotometric, HPLC-DAD, HPTLC and LC-Q-Orbitrap-HRMS techniques. Additionally, we compared the total antioxidant activity in both the cell-free and cellular systems. Betalain contribution to antioxidant...
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The Action Mechanisms, Anti-Cancer and Antibiotic-Modulation Potential of Vaccinium myrtillus L. Extract
PublicationHerbal medicinal products containing Vaccinium myrtillus L. (bilberry) fruits and fruit extracts are widely available in the market. Although bilberry leaves and stems are considered as bio-waste, they contain much higher levels of phenolic compounds than fruits. The study aimed to investigate the antimicrobial and anticancer potential of aerial part extracts from Vaccinium myrtillus L. (V. myrtillus, VM) plants harvested at high...
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Hypericum alpestre extract exhibits in vitro and in vivo anticancer properties by regulating the cellular antioxidant system and metabolic pathway of L‐arginine
PublicationConventional treatment methods are not effective enough to fight the rapid increase in cancer cases. The interest is increasing in the investigation of herbal sources for the development of new anticancer therapeutics. This study aims to investigate the antitumor capacity of Hypericum alpestre (H. alpestre) extract in vitro and in vivo, either alone or in combination with the inhibitors of the L‐arginine/polyamine/nitric oxide...
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Advances in mass spectrometry for iron speciation in plants
PublicationIron is an important nutrient essential for plants and critical for human health. The state-of-the art of methods for iron speciation in cereal grains and plant fluids is critically reviewed. Particular attention is given to the latest developments in the coupling of HPLC with the parallel ICP MS and electrospray ionization (ESI) MS/MS detection, usually QTOF MS or Q-Orbitrap MS, for the identification and quantification of iron...
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The Impact of Different Drying Methods on the Metabolomic and Lipidomic Profiles of Arthrospira platensis
PublicationDrying is an inseparable part of industrial microalgae production. In this work, the impacts of eight different drying methods on the metabolome and lipidome of Arthrospira platensis were investigated. The studied drying methods were freeze drying (FD), sun drying (SD), air drying at 40 and 75 °C (AD′ and AD″), infrared drying at 40 and 75 °C (IRD′ and IRD″), and vacuum drying at 40 and 75 °C (VD′ and VD″). Results gathered by...
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Estimators of covariance matrices in Msplit(q) estimation
PublicationThis paper proposes methods for the determination of covariance matrices of Msplit(q) estimators. The solutions presented here allow Msplit(q) estimation to be supplemented by the operations from the domain of accuracy analysis (especially that concerning estimators of parameters). Theoretical forms of covariance matrices of Msplit(q) estimators were established using the empirical influence functions and the equivalent covariance...
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Matrix representation of the ARMA(p, q) process spectrum
PublicationPraca dotyczy szeregów czasowych i ich modelowania scałkowanymi procesami autoregresji i średniej ruchomej ARIMA(p,q). Dla dowolnych parametru modelu p i q, zaproponowano opis spektrum wykorzystując zapis macierzowy. Takie podejście pozwoliło na znaczne uproszczenia przy różnego rodzaju wyprowadzeniach, a w efekcie i obliczeniach.
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Instrumenty ekonomiczne właściwej realizacji sterowania U i Q.
PublicationJest to jeden z referatów prezentujących wyniki obszernej pracy badawczej obejmującej złożoną problematykę sterowania poziomami napięć i rozpływem mocy biernej w systemie elektroenergetycznym (sterowanie U i Q). Założenia ogólne: Jest to jeden z referatów prezentujących wyniki obszernej pracy badawczej obejmującej złożoną problematykę sterowania poziomami napięć i rozpływem mocy biernej w systemie elektroenergetycznym (sterowanie...
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Instrumenty ekonomiczne realizacji sterowania U i Q
PublicationCelem tworzenia instrumentów ekonomicznych w gospodarce rynkowej jest uaktywnienie zainteresowanych podmiotów gospodarczych do działań ukierunkowanych na zamierzony cel. W rozważanej pracy celem tym jest właściwe sterowanie poziomami napięć i rozpływem mocy biernej w krajowym systemie elektroenergetycznym, prowadzące do poprawy jakości jego pracy. W referacie omówiono lub wspomniano o następujących instrumentach, które powinny...
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Blok wytwórczy w hierarchicznej strukturze sterowania U i Q.
PublicationIstotną rolę w procesie regulacji napięć w systemie elektroenergetycznym pełni generator synchroniczny. W referacie przedstawiono wymagania dla układów regulacji generatorów synchronicznych jako elementów hierarchicznej struktury sterowania U i Q.
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The complexity of the L(p,q)-labeling problem for bipartite planar graphs of small degree
PublicationW pracy pokazano, że problem L(p,q)-kolorowania przy użyciu ''t'' kolorów jest NP-zupełny nawet w wersji ograniczonej do grafów planarnych dwudzielnych małego stopnia, nawet dla stosunkowo niewielkich wartości ''t''. Jako wniosek z uzyskanych wyników stwierdzono, że problem L(2,1)-kolorowania grafów planarnych przy użyciu 4 kolorów jest NP-zupełny, a także że problem L(p,q)-kolorowania grafów o maksymalnym stopniu 4 jest NP-zupełny...
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Low-Voltage Low-Power Filters with Independent ω0 and Q Tuning for Electronic Cochlea Applications
PublicationAn acoustic second-order low-pass filter is proposed for filter banks emulating the operation of a human cochlea. By using a special filter structure and an innovative quality (Q)-factor tuning technique, an independent change of the cutoff frequency (ω0) and the Q-factor with unchanged gain at low frequencies is achieved in this filter. The techniques applied result in a simple filter design with low Q-factor sensitivity to component...
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A nontargeted approach to determine the authenticity of Ginkgo biloba L. plant materials and dried leaf extracts by liquid chromatography-high-resolution mass spectrometry (LC-HRMS) and chemometrics
PublicationThe lack of stringent regulations regarding raw materials for herbal supplements used for medicinal purposes has been a constant challenge in the industry. Ginkgo biloba L. leaf extracts attract consumers because of the supposed positive effect on mental performance and memory. Supplements are produced using dried leaf materials and standardized leaf extracts such as EGb 761. Adulteration of Ginkgo biloba L. plants and extracts...
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Matrix Strengthening the Identification of Observations with Split Functional Models in the Squared Msplit(q) Estimation Process
PublicationThis article addresses the issue of raising the level of identification of observations with either single or more split functional models in the squared Msplit(q) estimation process. The theoretical part of the study presents the theoretical grounds for the classical method for estimating parameters in a split functional model and proposes a modification of the computational algorithm to increase the quality of the determinations...
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Celowość wykorzystania źródeł mocy biernej zainstalowanych w sieci SN do regulacji U i Q
PublicationW artykule zawarto uwagi dotyczące celowości, możliwości oraz ewentualnego sposobu wykorzystania źródeł mocy biernej w celu regulacji U i Q w sieci SN. Wskazano również na celowość weryfikacji jakości sterowania transformatorów zasilających sieć 110 kV/SN.
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The use of HPLC-Q-TOF-MS for comprehensive screening of drugs and psychoactive substances in hair samples and several “legal highs” products
PublicationNon-targeted screening of drugs present in herbal products, known as “legal high” drugs and in hair as a biological matrix commonly used in toxicological investigations was accomplished with the use of high pressure liquid chromatography coupled with quadrupole time-of-flight mass spectrometry (HPLC-Q-TOF-MS). In total, 25 and 14 therapeutical drugs and psychoactive substances/metabolites were detected in investigated hair samples...
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Efficient optimization approaches for microwave assisted extraction of high-quality antioxidant compounds from Salvia officinalis L.: UHPLC-HRMS differential analysis of phenolic profiles obtained by ultrasound and microwave extraction
PublicationThe study aims to optimize MAE of total phenolic compounds (TPC) and antioxidant capacity from Salvia officinalis L. leaves using a definitive screening design (DSD) and I-optimal design. UHPLC-HRMS analysis was used to identify and compare the composition of MAE and UAE optimal extracts. The results showed that DSD and I-optimal design were successfully applied for the optimization of MAE targeting phenolics and other antioxidants...
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Wykorzystanie źródeł rozproszonych zainstalowanych w sieci SN do celów regulacji U i Q - praca w stanie ustalonym
PublicationW artykule przedstawiono i omówiono przykładowe wyniki badań pokazujące potencjalne możliwości wykorzystania źródeł rozproszonych zainstalowanych w sieci SN, w procesie sterowania U i Q.
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Error analysis of calculating average d-q current components using Regular Sampling and Park transformation in FOC drives
PublicationIn electric drives using voltage source inverters, motor currents contain ripple component resulting from pulse-width modulated (PWM) voltage. The frequency range of the ripples is much higher than the bandwidth of current control. Therefore the control is performed on the basis of a fundamental current component, i.e. average value with the averaging time being the PWM period. In majority of cases the average current is measured...
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Provisional model technique in the FDTD analysis of high-q resonators.
PublicationW artykule zaproponowano nową metodą wyznaczania wartości współczynnika dobroci oraz częstotliwości rezonansowych rezonatorów dużej dobroci na podstawie odpowiedzi układów w dziedzinie czasu. Przebiegi czasowe, będące rezultatem symulacji pełnofalowej układów, modelowane są dwukrotnie. Pierwszy model, tzw. model prowizoryczny, wykorzystywany jest do przedłużenia oryginalnego ciągu czasowego w celu zapobieżenia zniekształceniu wspomnianego...
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Optimization of a novel procedure for determination of VOCs in water and human urine samples based on SBSE coupled with TD-GC-HRMS.
PublicationPodczas ozanczania lotnych związków chlorowcoorganicznych (t.j. bromodichlorometanu, dibromochlorometanu, bromoformu I tetrachloroetylenu) z próbek wody I moczu ludzkiego wykorzystano technikę ekstrakcji za pomocą ruchomego elementu sorpcyjnego typu Twister połączonego z desorpcją termiczną analitów do kolumny chromatografu gazowego wyposażonego w wysokosprawny spektrometr mas. Przeprowadzono optymalizację czasu (30 min) i prędkości...
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Narratives on cutting down trees on private land. A comparison of urban and rural municipalities in Poland using the Q-deliberation method
PublicationIncreased development in rural and urban areas leads to a decrease in tree cover and reduces the ecosystem services that trees provide. Municipal authorities must consider managing trees on private land to ensure that residents have access to trees and green spaces. In doing so, they must frequently confront conflicting stakeholder views, which are driven by diverse public and private interests and impacted by the type of landscape...
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High Q-factor Microwave Fabry-Perot Resonator With Distributed Bragg Reflectors
PublicationZrealizowany został rezonator Fabry-Perot pracujący na częstotliwości 39 GHz i wykorzystujący dwie pary ćwierćfalowych kwarcowych reflektorów Bragga. Dla fali o długości 98.26 mm otrzymano dobroć ok. 560,000, co oznacza 4.3-krotny wzrost w porównaniu z identycznym rezonatorem bez reflektorów Bragga. Analizę problemu wykonano przy pomocy metody różnic skończonych w dziedzinie częstotliwości (FDFD) i porównano z uproszczonym rozwiązaniem...
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A method for a comprehensive lipidomic analysis of flaxseed (Linum usitatissimum) with the use of LC–Q-TOF-MS and dispersive micro-solid-phase (μDSPE) extraction
PublicationFlaxseed (FS) is one of the richest sources of α-linolenic acid oil and lignans, and it is suggested that the consumption of flaxseed may contribute to the prevention of certain chronic diseases such as many types of cancer, diabetes, cardiovascular diseases and cerebrovascular stroke. Here, we demonstrate a new method for comprehensive FS lipidome profiling with the use of LC–Q-TOF-MS and dispersive micro-solid-phase extraction....
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The use of RP-HPLC–Q-TOF–MS as a powerful tool for wastewater composition profiling and selection of water pollution marker specific to wastewater contamination
PublicationLimited drinking water resources and water pollution are one of the main worldwide problems. To reduce the consumption of fresh water resources, the use of treated wastewater has been proposed. The farmlands have been irrigated with wastewater for centuries, but the composition of used sewage has changed over the years. Recent research has revealed the presence of hundreds of new organic contaminants in many environmental waters,...
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Założenia do zasad rozliczeń za świadczenie usług systemowych U i Q
PublicationPrzedstawiono przyjęte założenia do rozliczeń za świadczenie usług w zakresie regulacji napięć i mocy biernej w systemie energetycznym. Uwzględniono złożone wzajemne relacje zachodzące pomiędzy podmiotami gospodarczymi na rynkach energii i rynkach usług, w obecnych uwarunkowaniach organizacyjnych polskiej elektroenergetyki. Zaproponowano rynkowe zasady rozliczeń za świadczone usługi.
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Characterization of Multimodal Silicas Using TG/DTG/DTA, Q-TG, and DSC Methods
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Evaluation of VSC Impact on Power System Using Adequate P-Q Capability Curve
PublicationRenewable energy sources, which are becoming increasingly popular, often use a voltage source converter (VSC) for connection to the power system. Assessing the effects of connecting such a source to the power system is essential to ensure the proper operation of the power system and the connected source. For this purpose, it is necessary to know the range of active and reactive power generation by the converter. The authors indicate...
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Theoretical treatment of charge-transfer processes induced by collision of C^q+ ions with uracil
PublicationWychwyt ładunku został opisany teoretycznie przy użyciu podstawowych metod chemii kwantowej, uzupełnionych półklasycznym opisem dynamiki zachodzącego procesu. Otrzymane przekroje czynne pokazują zróżnicowane zachowanie pod wpływem struktury elektronowej badanego jonu i mogą służyć do wyjaśniania prowadzonych badań doświadczalnych.
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A comprehensive lipidomic analysis of oilseeds using LC-Q-TOF-MS and dispersive micro-solid phase (D-μ-SPE) extraction techniques
PublicationGrowing public health awareness increased the demand for natural products with positive health benefits. Vegetable oils containing omega-3 fatty acids (FA) such as alpha-linolenic acid (ALA) has been proposed as a possible source of eicosapentaenoic acid (EPA) and docosahexaenoic acid (DHA). In this work, a comprehensive lipidome analysis and comparison of seven oilseeds, including flaxseed, chia, hemp, black cumin, white sesame,...
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Matrix Strengthening the Identification of Observations with Split Functional Models in the Squared Msplit(q) Estimation Process
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Discussion of “Development of an Accurate Time integration Technique for the Assessment of Q-Based versus h-Based Formulations of the Diffusion Wave Equation for Flow Routing” by K. Hasanvand, M.R. Hashemi and M.J. Abedini
PublicationThe discusser read the original with great interest. It seems, however, that some aspects of the original paper need additional comments. The authors of the original paper discuss the accuracy of a numerical solution of the diffusion wave equation formulated with respect to different state variables. The analysis focuses on nonlinear equations in the form of a single transport equation with the discharge Q (volumetric flow rate)...
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The Non-Lantibiotic Bacteriocin Garvicin Q Targets Man-PTS in a Broad Spectrum of Sensitive Bacterial Genera
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Oral coenzyme Q 10 administration prevents the development of ischemic brain lesions in a rabbit model of symptomatic vasospasm
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Lipidomic characteristics of three edible cold-pressed oils by LC/Q-TOF for simple quality and authenticity assurance
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Determination of an adequate number of competitive functional models in the square Msplit(q) estimation with the use of a modified Baarda’s approach
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Wdrażanie zorientowanego procesowo systemu zarządzania jakością w małej organizacji - studium przypadku.
PublicationW artykule podano na przykładzie małej organizacji informacje dotyczące praktycznego zastosowania opisanej w dwóch poprzednich numerach Q jakości metodyki wdrażania podejścia procesowego do zarządzania jakością wg normy ISO 9001:2000.
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Struktura techniczna układu sterowania U i Q. Systemy elektroenergetyczne: eksploatacja, stabilność, niezawodność, awarie i restytucje, modelowanie i symulacje.
PublicationW przypadku hierarchicznej struktury sterowania konieczne jest zapewnienie we wszystkich węzłach systemu nowoczesnych, w pełni automatycznych układów regulacji i sterowania. W referacie przedstawiono propozycję realizacji poszczególnych szczebli hierarchicznej struktury sterowania napięciami i rozpływem mocy biernej.
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Chemical and biological characterization of Ocimum basilicum L. phenolic extract and essential oil derived through ultrasound and microwave-assisted extraction techniques
PublicationPlant-derived bioactive molecules are increasingly utilized in food processing as natural additives, driven by a growing interest in healthier lifestyles. This trend has spurred industries to reformulate products to meet the demands of health-conscious consumers. This study investigates the phenolic extract and essential oil of O. basilicum L. obtained via ultrasound-assisted extraction and microwave-assisted extraction, respectively. Characterization...
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Linear-scaling calculation of Hartree-Fock exchange energy with Non-orthogonal Generalised Wannier Functions
PublicationWe present a method for the calculation of four-centre two-electron repulsion integrals in terms of localised non-orthogonal generalised Wannier functions (NGWFs). Our method has been imple- mented in the ONETEP program and is used to compute the Hartree-Fock exchange energy component of Hartree-Fock and Density Functional Theory (DFT) calculations with hybrid exchange-correlation functionals. As the NGWFs are optimised in situ...
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Green capsule phase microextraction employing hydrophobic monolithic sol-gel octadecyl siloxane platforms for the monitoring of organophosphorus pesticides in environmental water samples
PublicationIn this study, a novel, facile and green capsule phase microextraction (CPME) method is presented for the extraction and preconcentration of organophosphorus pesticides (i.e., chlorpyrifos, disulfoton, ethoprophos, fenchlorphos, prothiofos, and parathion-methyl) from environmental water samples. Monolithic sol-gel octadecyl siloxane (sol-gel C18) sorbent encapsulated within porous polypropylene capsules was synthesized, characterized,...
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Monolithic capsule phase microextraction prior to gas chromatography-mass spectrometry for the determination of organochlorine pesticides in environmental water samples
PublicationIn this study, a capsule phase microextraction (CPME) protocol followed by gas chromatography-mass spectrometry is proposed for the accurate and sensitive monitoring of organochlorine pesticides (OCPs) in environmental water samples. Different monolithic sol–gel encapsulated sorbents were compared and monolithic sol–gel poly(ethylene glycol)-based sorbent incorporated into porous microextraction capsules resulted in the highest...
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Identification of novel psychoactive substances 25B-NBOMe and 4-CMC in biological material using HPLC-Q-TOF-MS and their quantification in blood using UPLC–MS/MS in case of severe intoxications
PublicationThis paper describes cases of poisoning caused by new psychoactive substances such as: 25BNBOMe (2-(4-bromo-2,5-dimethoxyphenyl)-N-[(2-methoxyphenyl)methyl]ethanamine) and 4-CMC (1-(4-chlorophenyl)-2-(methylamino)-1-propanone). The analytical procedure includes rapid and selective method for the extraction and determination of 4-CMC and 25B-NBOMe in blood samples using UPLC–MS/MS technique. To the best of our knowledge,this is...
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Stoichiometry, spin fluctuations, and superconductivity in LaNiPO
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Superconductivity in noncentrosymmetricMg10Ir19B16
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Successive Orbital Ordering Transitions inNaVO2
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Analysing selection of low-temperature medium for cogeneration micro power plant
PublicationThe article analyses the ORC system working with dry and wet low-boiling media which are most frequently used in installations of this type. Two types of cycles were examined, which were the cycle with heat regeneration for dry media: fc72, hfe7100, R227ea, R245fa, R423a and R600a, and the cycle without heat regeneration for wet media: R11, R12, R134a, R718 and 507a. The calculations were performed for the assumed required thermal...
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Modeling the pH effects on nitrogen removal in the anammox-enriched granular sludge
PublicationThe aim of the study was to determine the pH effects on nitrogen removal in the anammox-enriched granular sludge. The experimental data were extracted from a 4L completely-mixed batch reactor with the granular sludge at different initial pH values (6.5, 7, 7.5, 8, 8.5, 9, 9.5, 10, 10.5) and constant temperature T=30℃. Simulations were run in GPS-X 6.4 using a comprehensive mechanistic model Mantis2. Two kinetic parameters, including...
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Magnetism and structure ofLixCoO2and comparison toNaxCoO2
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