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Search results for: chemia%20polimer%C3%B3w%20naturalnych
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Identification of chemical pollution problems and causes in the Baltic See in relation to socio-economic drivers
PublicationOpisano możliwość wykorzystania nowego narzędzia do zintegrowanej oceny stanu środowiska w akwenie Morza Bałtyckiego. Takie możliwości stwarza narzędzie znane jako DPSIR czyli Drivers (sfery działalności człowieka będące źródłem potencjalnych zznieczyszczeń)-Pressures (ksenobiotyki i specyficzne czynniki szkodliwe emitowane do środowiska)-Stata (stann środowiska)- Impact (efekty niekorzystego oddziaływania na część ożywioną i nieożywioną...
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Effect of glycols used as glycolysis agents on chemical structure and thermal stability of produced glycolysates
PublicationZaprezentowano warunki glikolizy poliuretanowych odpadów piankowych, przy użyciu różnych glikoli oraz wyniki badań budowy chemicznej glikolizatów oraz ich właściwości termicznych.
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Wystawa 34 rysunków i akwarel o tematyce architektonicznej pt.''świetlitość cienia''
Publicationarchitektura jako sztuka wumaga specyfi cznej reprezentacji jej elementami są rysunek, model i fotografia .zapis rysunkowy jest elementem procesu twórczego w powstawaniu, opisyw2aniu i percepcji dzieła architektury. rysunek jest jedna z podstawowych umiejetnosci zawodowych architekta.
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Quality Assurance and Quality Control in the Analytical Chemical Laboratory. A practical approach : Second edition
PublicationThe second edition defines the tools used in QA/QC, especially the application of statistical tools during analytical data treatment. Clearly written and logically organized, it takes a generic approach applicable to any field of analysis. The authors begin with the theory behind quality control systems, then detail validation parameter measurements, the use of statistical tests, counting the margin of error, uncertainty estimation,...
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Environmental characteristics of a tundra river system in Svalbard. Part 2: Chemical stress factors
PublicationBacterial communities in the Arctic environment are subject to multiple stress factors, including contaminants, although typically their concentrations are small. The Arctic contamination research has focused on persistent organic pollutants (POPs) because they are bioaccumulative, resistant to degradation and toxic for all organisms. Pollutants have entered the Arctic predominantly by atmospheric and oceanic long-range transport,...
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Storm petrels as indicators of pelagic seabird exposure to chemical elements in the Antarctic marine ecosystem
PublicationData on trace element bioavailability in the south-polar marine ecosystem is still scarce, compared to that relating to temperate zones. Seabirds can be used as indicators of ecosystem health and sentinels of environmental pollution, constituting a link between marine and terrestrial environments. Here, we analysed the concentration of 17 elements (with special emphasis on mercury, Hg) in feathers of adults and chicks of two pelagic...
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Green TPUs from Prepolymer Mixtures Designed by Controlling the Chemical Structure of Flexible Segments
PublicationThis study concerns green thermoplastic polyurethanes (TPU) obtained by controlling the chemical structure of flexible segments. Two types of bio-based polyether polyols—poly(trimethylene glycol)s—with average molecular weights ca. 1000 and 2700 Da were used (PO3G1000 and PO3G2700, respectively). TPUs were prepared via a two-step method. Hard segments consisted of 4,4?- diphenylmethane diisocyanates and the bio-based 1,4-butanodiol...
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Chemical, Physical, and Mechanical Properties of 95-Year-Old Concrete Built-In Arch Bridge
PublicationThis research aimed to determine the durability and strength of an old concrete built-in arch bridge based on selected mechanical, physical, and chemical properties of the concrete. The bridge was erected in 1925 and is located in Jagodnik (northern Poland). Cylindrical specimens were taken from the side ribs connected to the top plate using a concrete core borehole diamond drill machine. The properties of the old concrete were...
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Enzymatic and Chemical Cross-Linking of Bacterial Cellulose/Fish Collagen Composites—A Comparative Study
PublicationThis article compares the properties of bacterial cellulose/fish collagen composites (BC/Col) after enzymatic and chemical cross-linking. In our methodology, two transglutaminases are used for enzymatic cross-linking—one recommended for the meat and the other proposed for the fish industry—and pre-oxidated BC (oxBC) is used for chemical cross-linking. The structure of the obtained composites is characterized by scanning electron...
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The Impact of Long-Time Chemical Bonds in Mineral-Cement-Emulsion Mixtures on Stiffness Modulus
PublicationDeep cold in-place recycling is the most popular method of reuse of existing old and deteriorated asphalt layers of road pavements. In Poland, in most cases, the Mineral-Cement-Emulsion mixture technology is used, but there are also applications combining foamed bitumen and cement. Mineral-Cement-Emulsion mixtures contain two different binding agents – cement as well as asphalt from the asphalt emulsion. Asphalt creates asphalt...
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Bacterial presence in polar regions associated with environment modification by chemical compounds including contaminants
PublicationMicrobes are omnipresent and diverse members of all biological communities. In marine and freshwater ecosystems, microorganisms form the base of the food chain supporting higher trophic levels. Even though, microbes generally are thought to live in warm regions of Earth, many of them develop in cold climates. Polar regions remain relatively protected from widespread anthropogenic disturbances, which is a consequence of its remoteness...
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Investigation of the Efficiency of a Dual-Fuel Gas Turbine Combustion Chamber with a Plasma‒Chemical Element
PublicationThe study is devoted to the possibility of increasing the efficiency of the working process in dual-fuel combustion chambers of gas turbine engines for FPSO vessels. For the first time, it is proposed to use the advantages of plasma‒chemical intensification of the combustion of hydrocarbon fuels in the dual-fuel combustion chambers, which can simultaneously operate on gaseous and liquid fuels. A design scheme of a combustion chamber...
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Uwodornienie oleju rzepakowego i sojowego na katalizatorach miedziowych.Cz. 2. Chemizm reakcji.
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Victor Eremeev prof. dr hab.
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Ćwiczenia z Chemii Organicznej dla kierunku Chemia sem. IV
e-Learning CoursesĆwiczenia z chemii organicznej dla kierunku Chemia sem. IV - grupa dla powtarzających przedmiot. Prowadzący: dr inż. Monika Gensicka-Kowalewska
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SiC coating in ring-on-ring sliding with saline solution (0.9%) lubrication 5MPa, 0.1m/s specimn. #B37/#A35
Open Research DataWear tests in sliding friction of SiC coating on 1.4021 (EN 10088-1) heat treated stainless steel. Ring - on - ring contact in unidirectional sliding, SiC over SiC . Mean contact stress: 5MPa. Sliding velocity: 0,1 m/s. Mean friction radius: 9.5mm. Lubricant: SALINE SOLUTION (0.9%). Tribometer: PT-3. Overall test time till coating penetration 3 min.Secimen...
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SiC coating in ring-on-ring sliding with saline solution (0.9%) lubrication 5MPa, 0.1m/s specimn. #A35/#B37
Open Research DataWear tests in sliding friction of SiC coating on 1.4021 (EN 10088-1) heat treated stainless steel. Ring - on - ring contact in unidirectional sliding, SiC over SiC . Mean contact stress: 5MPa. Sliding velocity: 0,1 m/s. Mean friction radius: 9.5mm. Lubricant: SALINE SOLUTION (0.9%). Tribometer: PT-3. Overall test time till coating penetration 3 min.Secimen...
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Mariusz Marć dr hab. inż.
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Depth profile of the chemical composition of the Au-Ag multilayers
Open Research DataSilver and gold multilayers were deposited on a silicon substrate by magnetron sputtering method. Both type, Au and Ag thin films had 2 nm of thickness. Totally structure had thickness of 6 nm (Au-Ag-Au). That prepared multilayers were measured by XPS method. To obtain a depth profile of chemical composition, an Argon ion (Ar+) gun was used for etching...
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Polymers doped by Ca or P. Chemical composition investigations
Open Research DataThe calcium and phosphorus doped polyurethane polymers (PU) were analyzed by XPS method. A series of samples with various content of Ca and P dopand - from 0% up to 21%) were selected for measutements. The chemical composition and valence state of elements were measurements using OmicronNatechnology UHV system wih Argus hemispherical photoelectron...
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Influence of the annealing condictions on the chemical structure of LaBaGdCo ceramics
Open Research DataCeramic samples based on Barium, Lanthanum, Gadolinium and Cobaltium were produced by solid state reaction. After sintring in a furnance, samples were annealed at 300 Celsius degree in wet and dry atmosphere. Annealing takes 72h or 2h. Results of annealing were observed by X-Ray photoemission spectroscopy (XPS), OmicronNanotechnology. XPS analysis...
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Pisemna opinia biegłego z dziedziny chemii analitycznej na okoliczności szczegółowo wskazane w postanowieniu z dnia 27 lipca 2009.
PublicationEkspertyza dla Sądu Okręgowego w Toruniu - Wydział Drugi Karny, na okoliczność sfałszowania oleju napędowego.
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Pisemna opinia biegłego z dziedziny chemii analitycznej na okoliczności szczegółowo wskazane w postanowieniu z dnia 16 września 2009.
PublicationEkspertyza dla Sądu Rejonowego w Rawiczu - Wydział II Karny, na okoliczność sfałszowania benzyny.
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Molekularne aspekty aktywności biologicznej amfoterycyny B i jej pochodnych o podwyższonej selektywności - badania z zastosowaniem metod chemii obliczeniowej
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Ceria Based Protective Coatings for Steel Interconnects Prepared by Spray Pyrolysis
PublicationStainless steels can be used in solid oxide fuel/electrolysis stacks as interconnects. For successful long term operation they require protective coatings, that lower the corrosion rate and block chemical reactions between the interconnect and adjacent layers of the oxygen or the hydrogen electrode. One of the promising coating materials for the hydrogen side is ceria. Using standard sintering techniques, ceria sinters at around...
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PROBABILISTYCZNY MODEL PROCESU OBCIĄŻEŃ MOCĄ OKRĘTOWEGO TŁOKOWEGO SILNIKA GŁÓWNEGO I JEGO PRAKTYCZNA PRZYDATNOŚĆ
PublicationW artykule przedstawiono propozycję modelu widma obciążeń mocą okrętowego silnika głównego w formie czterostanowego procesu semi-Markoawa {D(t): t ≥0} ciągłego w stanach i czasie o zbiorze stanów C = {c1, c2, c3, c4} i następującej interpretacji elementów tego zbioru: c1 – obciążenie silnika mocą częściową, c2 – obciążenie silnika mocą trwałą, c3 – obciążenie silnika mocą znamionową, c4 – obciążenie silnika mocą maksymalną. Określono...
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Lidia Wolska prof. dr hab.
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Cold atmospheric plasma-induced chemical vapor generation in trace element analysis by spectrometric methods
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The impact of sediment, fresh and marine water on the concentration of chemical elements in water of the ice-covered lagoon
PublicationThe common use of chemical elements by man has been contributing to their extraction for centuries. As a consequence, they have been directly or indirectly introduced into the biogeochemical cycle. In the framework of many conventions, mining and processing of elements are currently subject to many restrictions. However, their large load that has already been deposited in the soil and bottom sediments can be remobilised and...
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Substituent effects on ^15N NMR chemical shifts in selected N-alkylthiohydroxamic acids. A comparative study
PublicationNa podstawie widm 15N NMR przeanalizowano wpływy podstawników wybranych kwasów tiohydroksamowych na przesunięcia chemiczne N-15. Analiza porównawcza z przesunięciami chemicznymi strukturalnie podobnych amidów, tioamidów i kwasów hydroksamowych pozwoliła na stwierdzenie, że nie zatłoczenie steryczne a grupa N-OH jest odpowiedzialna za osłabienie efektów odsłaniających zarówno podstawników bezpośrednio związanych z atomem azotu jak...
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Effect of applied standard wood machining fluid on colour and chemical composition of the machined wood surface
PublicationAppropriate monitoring of wood machining processes is a key issue to ensure the expected quality of the processed wood, expected efficiency and minimize energy consumption of production processes. A new trend is the design of environmentally friendly machining fluids. In this paper, as a preliminary study in this field, the effect of applied standard wood machining fluid on changes in the colour and chemical composition of the...
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An integrated assessment of the long-term impact of municipal sewage sludge on the chemical and biological properties of soil
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Fatty Acids Composition of Mustard Oil from Two Cultivars and Physico-chemical Characteristics of the Seeds
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Physico-chemical properties and possible photocatalytic applications of titanate nanotubes synthesized via hydrothermal method
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Green thermoplastic poly(ether-urethane)s – synthesis, chemical structure and selected properties investigation
PublicationThis work aimed to characterize the effect of the monomers chemical structure on the selected properties of the green thermoplastic poly(ether-urethane)s. During synthesis two types of polyether biopolyols, 4,4′-diphenylmethane diisocyanate and bio-based 1,3-propanediol were employed. Materials were synthesized with the use of two step method and two different prepolymers, which were mixed together in equimolar quantities. Obtained...
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Chemical Composition, In Vitro and In Situ Antimicrobial and Antibiofilm Activities of Syzygium aromaticum (Clove) Essential Oil
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Glycerolic Licorice Extracts as Active Cosmeceutical Ingredients: Extraction Optimization, Chemical Characterization, and Biological Activity
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Application of QSAR Analysis and Different Quantum Chemical Calculation Methods in Activity Evaluation of Selected Fluoroquinolones
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Influence of foliar fertilisation with calcium fertilisers on the firmness and chemical composition of two highbush blueberry cultivars
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Chemical and Enzymatic Changes of Different Soils during Their Acidification to Adapt Them to the Cultivation of Highbush Blueberry
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Biological and Physico-Chemical Characteristics of Arginine-Rich Peptide Gemini Surfactants with Lysine and Cystine Spacers
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Retro analog concept: comparative study on physico-chemical and biological properties of selected antimicrobial peptides
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<title>Novel matrix for fiber optic chemical sensors made of particle track polymer</title>
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Modelling of First- and Second-order Chemical Reactions on ARUZ – Massively-parallel FPGA-based Machine
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Synergistic effects of low-/medium-vacuum carbonization on physico-chemical properties and stability characteristics of biochars
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Does the chemical modification of Nystatin A1 affect the drug's ability to overcome the multidrug resistance of fungi?
PublicationAlthough the contemporary medicine keeps moving forward, disseminated infections caused by fungal pathogens are an emerging challenge. The dramatic rise of fungal diseases, especially the most life-threatening systemic mycoses is associated with a permanently growing number of immunodeficient patients. Undoubted difficulties in the treatment of fungal infections are caused by lack of highly effective and selective antifungal drugs,...
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Application of chiral chromatography for enantiomeric separation of currently used pesticides from various chemical groups
PublicationChiral pesticides account for more than 25 % of currently used pesticides and this ratio is still increasing. According to the number of chiral centers in the structure, a pesticide may consist of two or multiple enantiomers or stereoisomers. Studies into the stereoselective behaviour of pesticides started in the early 1990s and most research efforts focused on understanding the environmental fate and effects of these pesticides....
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Challenges in determination of pesticides from various chemical groups in fruits and vegetables applying QuEChERS method
PublicationPesticides are a large group of compounds with different physical and chemical properties, which place some of them among the most toxic, environmentally stable, and mobile substances. Nevertheless, their number, use, and application are continuously expanding. A consequence of their use is the possible presence of residues in treated food products. To protect consumers from exposure to unacceptable levels of pesticides Maximum...
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Release of selected chemical elements from shale drill cuttings to aqueous solutions of different pH
PublicationThe effect of pH changes on leachability of light and heavy metals from shale drill cuttings generated from unconventional shale gas production was investigated. Cuttings, being the primary byproduct generated from drilling operations, belong to the potentially hazardous type of wastes due to presence of heavy and radioactive elements and remains of drilling fluid. In this regard, assessment of potentially dangerous components...
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Experimental and Quantum Chemical Evaluation of 8-Hydroxyquinoline as a Corrosion Inhibitor for Copper in 0.1 M HCl
PublicationThe corrosion inhibition properties of 8-hydroxyquinoline (8-HQ) in 0.1 M HCl for copper have been investigated by using experimental (electrochemical impedance spectroscopy (EIS), dynamic electrochemical impedance spectroscopy (DEIS), and potentiodynamic polarization) and theoretical methods complemented by surface morphological examination with the aid of scanning electron microscopy (SEM) and electron dispersive X-ray spectroscopy...