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Search results for: spektroskopia ramanowska
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Sposób modyfikacji rozdrobnionych odpadów gumowych
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Effects of Urea and Trimethylamine-N-oxide on the Properties of Water and the Secondary Structure of Hen Egg White Lysozyme
PublicationW celu określenia sposobu hydratacji mocznika i N-tlenku trimetyloaminy, wykorzystano spektroskopię oscylacyjną FTIR. Dane eksperymentalne, otrzymane z pomiarów widm oscylacyjnych wody półciężkiej (HDO) rozcieńczonej izotopowo w wodnych roztworach badanych związków, analizowane były za pomocą "metody widm różnicowych". Strukturalno-energetyczna charakterystyka wody zaburzonej przez cząsteczki osmolitów wskazuje, że woda zaburzona...
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Coexistence of HFE and rare UGT1A1 genes mutations in patients with iron overload related liver injury
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Waste tire rubber as low-cost and environmentally-friendly modifier in thermoset polymers – A review
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Liver steatosis correlates with iron overload but not with HFE gene mutations in chronic hepatitis C
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Association of Hepcidin mRNA Expression With Hepatocyte Iron Accumulation and Effects of Antiviral Therapy in Chronic Hepatitis C Infection
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Waste tire rubber as low-cost and environmentally-friendly modifier in thermoset polymers – a review
PublicationNowadays, waste tire rubber (WTR) management is a growing and serious problem. Therefore, research works focused on the development of cost-effective and environmentally-friendly methods of WTR recycling are fully justified. Incorporation of WTR into polymer matrices and composite materials attracts much attention, because this approach allows sustainable development of industrially applicable waste tires recycling technologies....
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Recent advances in compatibilization strategies of wood-polymer composites by isocyanates
PublicationWood-polymer composites technologies are gaining more and more attention in the scientific community, positively affecting the increase in their industrial applications, for example, automotive, building, 3D printing, etc. Many research works are focused on the improvement in matrix–lignocellulosic filler interactions to produce highly filled composites with satisfying performance properties. In this field of research, using isocyanates...
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Reclaimed Rubber/Poly(ε‐caprolactone) Blends: Structure, Mechanical, and Thermal Properties
PublicationThe amount of elastomeric waste, especially from tires is constantly increasing on a global scale. The recycling of these residua should be considered a priority. Compounding the waste rubbers with other polymers can be an excellent alternative to reuse waste materials. This procedure requires solving the issue of the lack of compatibility between the waste rubber particles and other polymers. Simultaneously, there is a claim for...
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Morphology, Thermo-Mechanical Properties and Biodegradibility of PCL/PLA Blends Reactively Compatibilized by Different Organic Peroxides
PublicationReactive blending is a promising approach for the sustainable development of bio-based polymer blends and composites, which currently is gaining more and more attention. In this paper, biodegradable blends based on poly(ε-caprolactone) (PCL) and poly(lactic acid) (PLA) were prepared via reactive blending performed in an internal mixer. The PCL and PLA content varied in a ratio of 70/30 and 55/45. Reactive modification of PCL/PLA...
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Influence of microwave treatment conditions of GTR on physico-mechanical and structural properties of NBR/NR/GTR composites
PublicationThe increasing amount of tires used in the industry induces the researchers to find alternatives to the recycling of the end-of-life tires. Several alternatives in order to application of ground tire rubber GTR include their incorporation as a filler in composites. The main issue in this approach is the lack of compatibility between GTR and polymer matrix. In order to solve this problem the devulcanization by microwaves has been...
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A Three-Step Approach to Estimation of Reduction Potentials of Natural Mixtures of Antioxidants Based on DPPH Test; Illustration for Catechins and Cocoa
PublicationThe aim of this study is to propose a methodology to assess electrochemical properties of complex mixtures of antioxidants, such as plant extracts, based on the results of simple and popular DPPH test. The first, most difficult step, involves determinations of standard reduction potentials (E0) for the series of purified compounds (here catechins). The next step is the calculation of stoichiometric values (n10) based on the results...
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DNA Methylation Changes Induced by Redox-Active Compounds—Choosing the Right PCR-Based Method
PublicationThe impact of catechins on the expression profile of redox-related genes in HT29 cell line has been studied recently by our group using Oxidative Stress RT2 Profiler PCR Array. Within the examined panel of 84 genes, the down-regulation of SRXN1 gene was unique among other up-regulated genes. We hypothesized that the observed down-regulation resulted from DNA methylation and have exploited this observation to choose the proper strategy...
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The relationship between standard reduction potentials of catechins and biological activities involved in redox control
PublicationRedox homeostasis involves factors that ensure proper function of cells. The excess reactive oxygen species (ROS) leads to oxidative stress and increased risk of oxidative damage to cellular components. In contrast, upon reductive stress, insufficient ROS abundance may result in faulty cell signalling. It may be expected that dietary antioxidants, depending on their standard reduction potentials (E°), will affect both scenarios....
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On the Correlation of Lignocellulosic Filler Composition with the Performance Properties of Poly(ε-Caprolactone) Based Biocomposites
PublicationIn this work, three types of agricultural waste: olive stones (OS), date seed (DS) and wheat bran (WB) were applied as potential lignocellulosic fillers in poly(ε-caprolactone) (PCL) based biocomposites. Differences in composites’ performance were related to the higher content of proteins, noted for WB comparing to other fillers applied, which enhanced plasticization of PCL matrix. The mechanical properties of biocomposites were...
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Power2Hcarbon Materials for Direct Power-to-Hydrocarbon Conversion
ProjectsProject realized in Department of Biomedical Engineering according to PL-TW/V/4/2018 agreement from 2018-08-23
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TROPSENSE PREMIA Development of a non-invassive breath test for early diagnosis of tropical diseases
ProjectsProject realized in Department of Metrology and Optoelectronics according to Umowa nr 329385/PnH/2016 agreement from 2016-11-04
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Productive4.0 Electronics and ICT as enabler for digital industry and optimized supply chain management covering the entire product lifecycle
ProjectsProject realized in Department of Microwave and Antenna Engineering according to 387341/PnH/2017 agreement from 2017-12-20
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FOODINTEGRITY Ensuring the Integrity of the European food chain
ProjectsProject realized in Department of Colloid and Lipid Science according to 613688 agreement from 2016-03-27
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FLOW Furthering Less Congestion by creating Opportunities for more Walking and cycling
ProjectsProject realized in Department of Transportation Engineering according to 635998 agreement from 2015-04-14
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BE OPEN European forum and oBsErvatory for OPEN science in transport
ProjectsProject realized in Main Library Office according to 824323 — BE OPEN — H2020-MG-2018-2019-2020/H2020-MG-2018-SingleStage-INEA agreement from 2018-12-03
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ISOESRE Innovative Solid Oxide Electrolyzers for Storage of Renewable Energy
ProjectsProject realized in Department of Biomedical Engineering according to PL-TW2/6/2015 agreement from 2015-04-27
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Quo vadis, Gdańsku? Mieszkańcy planują swoje miasto.
ProjectsProject realized in Faculty of Architecture according to Umowa o dotację dotycząca wniosku nr E2/0519 agreement from 2014-10-13
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FLOW Furthering Less Congestion by creating Opportunities for more Walking and cycling
ProjectsProject realized in Department of Transportation Engineering according to 331826/PnH/2016 agreement from 2016-11-28
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SCOTT Secure COnnected Trustable Things
ProjectsProject realized in Department of Microwave and Antenna Engineering according to 387192/PnH/2017 agreement from 2017-12-20
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ACCUS Adaptive Cooperative Control in Urban (sub) Systems
ProjectsProject realized in Faculty of Electronics, Telecommunications and Informatics according to 333020 agreement from 2013-12-18
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CRUNCH CRUNCH ─ Climate Resilient Urban Nexus Choices: Operationalising the Food-Water-Energy Nexus
ProjectsProject realized in Department of Urban Design and Regional Planning according to UMO-2017/25/Z/HS6/03050 agreement from 2018-06-13
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SoURCE Service of Utility Risk/Cost Evaluation (SoURCE)
ProjectsProject realized in Department of Geodesy according to 4000130203/20/UK/ND agreement from 2020-03-27
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Vibrational spectroscopic studies of N,N'-dimethylpropyleneurea-water system: Affected solvent spectra and factor analysis
PublicationZmierzono widma FT-IR układu N,N'-dimetylopropylenomocznik (DMPU) - woda w całym zakresie składów w zakresie 4000-500 cm-1 przy użyciu techniki całkowitego wewnętrznego odbicia (ATR). Hydratacja DMPU została dodatkowo zbadana przy pomocy transmisyjnej spektroskopii FT-IR izotopowo rozcieńczonej HDO w H2O. Widma zanalizowano przy użyciu ilościowej wersji metody widm różnicowych, prowadzącej do wyizolowania widma rozpuszczalnika...
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Thioamides and selenoamides with chirality solely due to hindered rotation about the C-N bond: enantioselective complexation with optically active hosts
PublicationBariera rotacji wokół wiązania C-N w tioamidach jest średnio o 3-5 kcal/mol wyższa niż w odpowiednich amidach, a w analogicznych selenoamidach wzrasta jeszcze o 1 kcal/mol. Dzięki temu związki te występują w dwu enancjomerycznych formach, których wzajemna przemiana zachodzi w wyniku rotacji wokół wiązań C-N. Bariera rotacji jest wystarczająco wysoka, aby można było podjąć próbę ich rozdziału na enancjomery w temperaturze pokojowej....
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Paweł Możejko dr hab.
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Behaviour of water in different types of goats' cheese
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The impact of land use and season on the riverine transport of mercury into the marine coastal zone
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Gluten-Free Bread with Cricket Powder—Mechanical Properties and Molecular Water Dynamics in Dough and Ready Product
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Water Behavior of Aerogels Obtained from Chemically Modified Potato Starches during Hydration
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Bifunctional Polymeric Carbon Nitride via Tuning Fabrication Conditions for Photocatalysis
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High efficiency protocol of DNA extraction from Micromys minutus mandibles from owl pellets: a tool for molecular research of cryptic mammal species
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Iron overload and HFE gene mutations in Polish patients with liver cirrhosis
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Identification of Polyphenols from Coniferous Shoots as Natural Antioxidants and Antimicrobial Compounds
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Chemical Characteristics and Thermal Oxidative Stability of Novel Cold-Pressed Oil Blends: GC, LF NMR, and DSC Studies
PublicationPlant oils contain a high content of unsaturated fatty acids. Studies of food products have revealed a considerable disproportion in the ratio of ω6 to ω3. This article presents information on the healthful qualities of eight new oil blends that contain a beneficial proportion of ω6 to ω3 fatty acids (5:1), as well as their degradation during heating at 170 and 200 °C. The fatty acid profile was analyzed by gas chromatography (GC),...
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The effect of new non-cross resistant antitumor agents on the energy state of human erythrocytes
PublicationPrzebadano pochodne benzoperimidynowe i antrapirydonowe odnośnie ich wpływu na stan energetyczny ludzkich erytrocytów. Stwierdzono, że poziom nukleotydów jak i wartość AEC erytrocytów nie zmienił się w ciągu 24 h inkubacji z powyższymi związkami. Jest to wynik obiecujący w odniesieniu do ich zastosowania jako związków aktywnych w pokonywaniu oporności wielolekowej.
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Investigation of matrix-free generation of methyl chloride as a reference material
PublicationW pracy opisano badania nad wykorzystaniem włókien szklanych do otrzymywania bezmatrycowych materiałów odniesienia zawierających chlorek metylu. Chlorek metylu jest uzyskiwany w wyniku termicznego rozkładu związku powierzchniowego. Przedstawiono wyniki badań dla trzech różnych włókien szklanych (o różnej grubości), pokrytych warstwą glinu.
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Metal-coated fused silica fibres as a support for immobilized compounds yielding a volatile analyte (C2H4)
PublicationPrzedstawiono wyniki badań dotyczących wykorzystania chemicznie modyfikowanych włókien szklanych pokrytych warstwą metalu (aluminium), jako nośników związków powierzchniowych. W trakcie procesu termicznego rozkładu z tak zmodyfikowanych włókien uwalnia się eten, który stanowi składnik mierzony uzyskiwanej gazowej mieszaniny wzorcowej. Ilość uwalnianego etenu zależy jedynie od długości danego rodzaju i typu modyfikowanego włókna...
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Photosensitive and pH-dependent activity of pyrazine-functionalized carbazole derivative as promising antifungal and imaging agent
PublicationCarbazole skeleton plays a significant role as a structural scaffold of many pharmacologically active compounds. Pyrazine-functionalized carbazole derivative was constructed by coupling 2-amino-5-bromo-3-methylaminepyrazine (ABMAP) into 3 and 6 positions of the carbazole ring. Multi-experimental methods were used, e.g., potentiometric, spectroscopic (ATR, UV, XRD powder,1H and13C NMR), electrochemical (cyclic voltammetry), and...
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ANTIOXIDANT POWER SERIES (APS) AS A TOOL FOR RATIONAL DESIGN AND ASSESSMENT OF HEALTH PROMOTING PROPERTIES OF FUNCTONAL FOODS BASED ON ANTIOXIDANT PHYTOCHEMICALS
PublicationOver past decades, plantborne antioxidants dominated so called "translational research" in the area of food, nutrition, and disease prevention. Among consumers and producers, such phytochemicals are synonyms of nutriceuticals. Popularity and commercial success of antioxidants stems from mechanistic studies suggesting the involvement of reactive oxygen species in etiology of chronic diseases. However, epidemiology failed to provide...
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Validated HPTLC method for determination of ledol and alloaromadendrene in the essential oil fractions of Rhododendron tomentosum plants and in vitro cultures and bioautography for their activity screening
PublicationRhododendron tomentosum (Ledum palustre) is a bog shrub used in traditional medicine for treatment of respiratory and rheumatic diseases. Due to the large variability of the chemical composition of its essential oil, depending on the habitat, the in vitro cultures were established as the alternative source of the volatile fraction. There is a need to monitor a quality of the field grown as well as in vitro plant material, especially...
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GeoSPAR Project. Validation and selection methods of geoinformation analysis using GIS for ranking and forecasting of terrorist threats and criminal events
PublicationThe paper presents the description of work activities which have already been done within the first two stages – WorkPackage 1 and WorkPackage 2 - of the GeoSPAR Project. In such a context the general conceptual design of the GIS system and associate web service was presented and analysed. In addition, the operational and technical requirements for the GeoSPAR system have been specified and discussed; with special emphasis on system...
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Ewa Romanowska
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Małgorzata Romanowska
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Metal-coated fused silica fibers as a support for immobilized compounds yielding a volatile analyte (C2H4)
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