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Search results for: BIT KWANTOWY
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Topochemical, Single‐Crystal‐to‐Single‐Crystal [2+2] Photocycloadditions Driven by Chalcogen‐Bonding Interactions
PublicationThe face-to-face association of (E)-1,2-di(4-pyridyl)ethylene (bpen) molecules into rectangular motifs stabilized for the first time by chalcogen bonding (ChB) interactions is shown to provide photoreactive systems leading to cyclobutane formation through single-crystal-to-single-crystal [2+2] photodimerizations. The chelating chalcogen bond donors are based on original aromatic, ortho-substituted bis(selenocyanato)benzene derivatives...
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Chromogenic amides of pyridine-2,6-dicarboxylic acid as anion receptors
PublicationThe synthesis of simple, chromogenic pyridine-2,6-dicarboxylic acid amides, derivates of isomeric nitroanilines and aminonitrophenols, and their ion binding properties are described. The ligands' response to ionic species was examined by naked eye and was studied with the use of UV-Vis spectroscopy in DMSO and its mixture with water. The effect of the localisation and the type of the substituents in aromatic rings were discussed....
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Molecular structure and electrochemical properties of alkyldithiocarbamates.
PublicationZastosowano klasyczne metody elektroanalityczne do badania właściwości redoks ditiokarbaminianów litu w środowisku dimetylosulfotlenku. Użyto elektrody z platyny i węgla szklistego. Badane związki zsyntezowano z N,N'-dimetyloetylenodiaminy, do której podstawiono jedną lub dwie grupy ditiokarbonylowe na drodze reakcji z CS2 w środowisku alkalicznym. Stwierdzono, że elektrochemiczne utlenianie ditiokarbaminianów przebiega z udziałem...
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Otrzymywanie i charakterystyka TiO2 modyfikowanego nanocząstkami Au oraz Pd
PublicationDitlenek tytanu jest intensywnie badany od wielu lat, ze względu na jego właściwości fotokatalityczne, nietoksyczność oraz niski koszt. Ograniczeniem w zastosowaniu TiO2 jest jego niska wydajność kwantowa konwersji energii słonecznej, ze względu na szybką rekombinację nośników oraz konieczność zastosowania promieniowania UV. TiO2 absorbuje tylko 3-4% promieniowania słonecznego, ponieważ może być wzbudzony tylko promieniowaniem...
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Emilia Dębińska-Bis
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Tomasz Wit Kozłowski dr inż.
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Hanna Obracht-Prondzyńska dr inż. arch.
PeopleHanna Obracht-Prondzyńska, PhD MArch, Eng. Assistant Professor at the University of Gdańsk, Department of Spatial Management, academic teacher of urban design and spatial data analyses. Architect and urban planner experienced in data driven urban design and planning. She defended her PhD with distinction in engineering and technical sciences in the discipline of architecture and urban planning in 2020 at the Faculty of Architecture...
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Biocementacja – ekologiczna alternatywa dla stabilizacji gruntów.
PublicationPrzedstawienie badań wytrzymałości na ścinanie dla gruntu niespoistego stabilizowanego bio-cementacją bakteryjną. Omówienie charakterystyki drobnoustrojów wraz z podziałem badań na dwie części: mikrobiologiczną oraz geotechniczną. Potwierdzenie możliwości wykorzystania cementacji bakteryjnej jako alternatywnej metody stabilizacji podłoża gruntowego.
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Wpływ rodzaju kwaśnego dodatku do eluentu oraz właściwości fazy stacjonarnej na rozdzielanie średnio i nisko hydrofobowych kwaśnych organicznych związków chemicznych w odwróconych układach faz kolumnowej elucyjnej wysokosprawnej chromatografii cieczowej - RP HPLC
Publicationedna z serii prac badawczych nad opracowaniem optymalnych warunków rozdzielania, identyfikacji i oznaczania względnie, średnio i nisko polarnych składników mieszanin organicznych związków chemicznych otrzymywanych z procesu konwersji biomasy lignocelulozowej, lub suszu roślinnego z wykorzystaniem wysokosprawnej kolumnowej elucyjnej chromatografii cieczowej w odwróconych układach faz (RP-HPLC) z elucją izokratyczną, a wówczas gdy...
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Open-Source Coprocessor for Integer Multiple Precision Arithmetic
PublicationThis paper presents an open-source digital circuit of the coprocessor for an integer multiple-precision arithmetic (MPA). The purpose of this coprocessor is to support a central processing unit (CPU) by offloading computations requiring integer precision higher than 32/64 bits. The coprocessor is developed using the very high speed integrated circuit hardware description language (VHDL) as an intellectual property (IP) core. Therefore,...
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Nano-particle doped hydroxyapatite material evaluation using Spectroscopic Polarization Sensitive Optical Coherence Tomography
PublicationBio-ceramics such as hydroxyapatite (HAp) are widely used materials in medical applications, especially as an interface between implants and living tissues. There are many ways of creating structures from HAp like electrochemical assisted deposition, biomimetic, electrophoresis, pulsed laser deposition or sol-gel processing. Our research is based on analyzing the parameters of the sol-gel method for creating thin layers of HAp....
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Rengel Cane Sia Doctoral Candidate
PeopleI’m Rengel, born and raised in the Philippines. As an undergraduate I did kinetic modeling on Copper-catalyzed atom transfer radical addition (ATRA). Then I was inspired to do both theoretical and experimental studies, which led me to propose my master’s thesis on Synthesis, Computational, Electrochemical, and Photoconductivity Studies on Naphthalene and its derivatives. This led to a master’s degree in Chemistry in the Mindanao...
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Frequency Response Functions for Sandvik CoroBore 825 XL boring tool, 733 mm
Open Research DataFrequency Response Functions (FRF) obtained for Sandvik CoroBore® 825 XL mounted at WHN 13-15 TOS VARNSDORF CNC machine at the minimum extension of the spindle adaptor. Tool set to bore a hole with a diameter 733mm
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Sterowane elektrycznie pojemności stosowane w mikroelektronice
PublicationPraca prezentuje aktualny stan wiedzy o stosowanych w mikroelektronice elektrycznie sterowanych zmiennych pojemnościach. Omawiana jest budowa i podstawowe charakterystyki trzech rodzajów takich pojemności: diodowych (złączowych), MEMS i BST na podstawie przeglądu publikacji naukowych z lat 1964-2004.
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Experimental Investigation of the Properties of Laminated Nonwovens Used for Packaging of Powders in Mineral Warmers
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Otrzymywanie i właściwości poliuretanowo-stalowych elementów sandwiczowych
PublicationCelem pracy było wykonanie elementów warstwowych z rdzeniem poliuretanowym opracowanym według własnych technologii i okładzinami stalowymi jako układy SPS (Sandwich Plate System) oraz zbadanie wytrzymałości na zginanie połączonych elementów.
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Mössbauer Spectroscopy and Magnetoelectric Effect Studies of Multiferroic Ceramics Based on BiFeO<sub>3</sub>
PublicationIn this work the results of investigations for (BiFeO3)x(BaTiO3)1-x and Bi1-xNdxFeO3 solid solutions are described. Samples were prepared by the conventional solid-state sintering method. X-ray diffraction, 57Fe Mössbauer spectroscopy, and magnetoelectric effect measurements were applied as complementary methods to determine the structure and magnetic properties of materials. For (BiFeO3)x(BaTiO3)1-x solid solutions Mössbauer...
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Hydraulic conductivity of a biopolymer treated sand
PublicationThis paper presents results of laboratory assessment of creating seepage barriers in a sandy soil using biopolymer additives (bio substance), which consist of polysaccharides and water. Polysaccharides strongly interact with water to produce a viscous suspension. The aim of the conducted work was to investigate the influence of a biosubstance employed in a highly permeable sandy soil. The amount of the biopolymer used in a sample...
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Photophysics of a Ruthenium 4H-Imidazole Panchromatic Dye in Interaction with Titanium Dioxide
PublicationThe photophysics of bis(4,4′-di-tert-butyl-2,2′-bipyridine-κ2N,N′)[2-(4-carboxyphenyl)-4,5-bis(p-tolylimino-κN)imidazolato]ruthenium(II) hexafluorophosphate is investigated, both in solution and attached to a nanocrystalline TiO2 film. The studied substitution pattern of the 4H-imidazole ligand is observed to block a photoinduced structural reorganization pathway within the 4H-imidazole ligand that has been previously investigated....
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Progress in non-isocyanate polyurethanes synthesized from cyclic carbonate intermediates and di- or polyamines in the context of structure–properties relationship and from an environmental point of view
PublicationCommercially, polyurethanes are produced by the reaction of diisocyanates, polyols (polyester or polyether) and low molecular weight chain extender. Toxicity, moisture sensitivity and phosgene-based synthesis of diisocyanates resulted in investigations focused on obtaining the non-isocyanate polyurethanes (NIPUs). This work presents the review of synthesis and structure–properties relationship of non-isocyanate polyurethanes obtained...
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The scope of fiscal decentralisation in EU countries: a comparative analysis
PublicationMotivation: Decentralization is one of the main challenges in public sector reform. In democratic countries the level of decentralisation in individual countries is not identical. The varying scope of decentralization affects the quality, quick and efficient decision-making by public leaders. Aim: Comparison of the extent of fiscal decentralisation in EU Member States; creation of groups of states with similar levels of decentralisation;...
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Low-Power Receivers for Wireless Capacitive Coupling Transmission in 3-D-Integrated Massively Parallel CMOS Imager
PublicationThe paper presents pixel receivers for massively parallel transmission of video signal between capacitive coupled integrated circuits (ICs). The receivers meet the key requirements for massively parallel transmission, namely low-power consumption below a single μW, small area of less than 205 μm2, high sensitivity better than 160 mV, and good immunity to crosstalk. The receivers were implemented and measured in a 3-D IC (two face-to-face...
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Fabrication of La-Doped Bi4Ti3O12 Ceramics
PublicationLa-modified Bi4Ti3O12 is a typical ferroelectric, piezoelectric and electro-optic material, having relatively low coercive field, low dielectric constant, high Curie temperature and high breakdown strength. Goal of the present research was to apply mixed oxide method for fabrication of BiTLax ceramics, study its chemical composition, crystalline structure and microstructure. The compound BiTLax for x=0, 0.25, 0.5, 0.75 ceramic...
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Using wavelet techniques for multibeam sonar bathymetry data compression
PublicationMultibeam sonars are widely used in applications like high resolution bathymetry measurements or underwater object imaging. One of the significant problems in multibeam sensing of the marine environment is large amount of data which must be transmitted from the sonar processing unit to an operator station using a limited bit rate channel. For instance, such a situation would be in the case when the multibeam sonar was mounted on...
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On the compression of multibeam sonar raw bathymetry data
PublicationMultibeam sonars are widely used in applications like high resolution bathymetry measurements or underwater object imaging. One of the significant problems in multibeam sensing of the marine environment is large amount of data which must be transmitted from the sonar processing unit to an operator station using a limited bit rate channel. For instance, such a situation would be in the case when the multibeam sonar was mounted on...
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A CMOS Pixel With Embedded ADC, Digital CDS and Gain Correction Capability for Massively Parallel Imaging Array
PublicationIn the paper, a CMOS pixel has been proposed for imaging arrays with massively parallel image acquisition and simultaneous compensation of dark signal nonuniformity (DSNU) as well as photoresponse nonuniformity (PRNU). In our solution the pixel contains all necessary functional blocks: a photosensor and an analog-to-digital converter (ADC) with built-in correlated double sampling (CDS) integrated together. It is implemented in...
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AN ALTERNATIVE WAY OF DETERMINING MECHANICAL PROPERTIES OF WOOD BY MEASURING CUTTING FORCES
PublicationThe cutting force is an energetic effect of splitting material, and might be therefore considered from a point of view of modern fracture mechanics. The dedicated mathematical model developed for description of the wood cutting has been developed here on the base of fracture theory, and includes work of separation (fracture toughness) in addition to the material plasticity and friction. The effect of the cutting edge dullness is...
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Koncepcja wartościowania działania urządzeń energetycznych siłowni okrętowych
PublicationPrzedstawiono propozycję wartościowania (ilościowego określenia) działania dowolnego urządzenia siłowni okrętowych, w którym zachodzą oddziaływania energetyczne w określonym czasie. Działanie to rozumiane jest jako przekazywanie energii w ustalonym czasie, w którym zachodzi przetwarzanie lub przenoszenie energii w formie pracy bądź ciepła. Zaproponowana ilościowa interpretacja działania urządzeń energetycznych, jest podobna do...
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State of the art electronic nose technology and future trends
PublicationThis chapter briefly reviews the progress in field of artificial olfaction and demonstrates future trends in electronic nose technology. The discussion about e-nose concern also a big challenge for the pattern recognition (PARC) systems due to several particular problems they involve. Finally, the application of e-nose in different areas of life is given.
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Analiza oddziaływań w kryształach związków zawierających w strukturze pierścień pirydynowy
PublicationMożliwość tworzenia się wiązań wodorowych jest kluczowym parametrem z punktu widzenia inżynierii kryształu, ponieważ wiązania wodorowe mają bezpośredni wpływ na strukturę oraz trwałość sieci krystalicznej. Głównym celem niniejszej rozprawy doktorskiej była analiza porównawcza wiązań wodorowych występujących w układach, zawierających w strukturze pierścień pirydynowy. Badane układy podzielono na: (1) układy ze związkami krzemosiarkowymi...
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Teoretyczne badanie struktury oscylacyjno-elektronowej cząsteczki NaRb z uwzględnieniem efektów relatywistycznych
PublicationZ wykorzystaniem kwantowo-chemicznych metod opartych na pseudopotencjałach opisujących oddziaływanie elektronów walencyjnych z atomowymi rdzeniami zostały policzone krzywe adiabatyczne energii potencjalnej. Na ich podstawie wyznaczono parametry spektroskopowe cząsteczki NaRb w ujęciu nierelatywistycznym i relatywistycznym. Policzyłem osiemnaście stanów nierelatywistycznych w symetrii Σ+, dziesięć stanów symetrii Π oraz cztery stany...
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Eugeniusz Kozaczka prof. dr hab. inż.
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Results of research on the SME sector in the context of applying tax reliefs
Open Research DataThis dataset presents the quantitative results of the survey conducted in the period June 2019 - April 2020. In total, 274 completed survey questionnaires were obtained.
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Tailor-Made Polysaccharides for Biomedical Applications
PublicationPolysaccharides (PSAs) are carbohydrate-based macromolecules widely used in the biomedical field, either in their pure form or in blends/nanocomposites with other materials. The relationship between structure, properties, and functions has inspired scientists to design multifunctional PSAs for various biomedical applications by incorporating unique molecular structures and targeted bulk properties. Multiple strategies, such as...
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A Monte Carlo Strategy to simulate Positrons and Positronium in biological Materials
PublicationWe present an algorithm for Monte Carlo simulations of positron tracks in biological materials. The algorithm takes into account the cross-section data for elastic and inelastic collisions between positrons and molecules and processes like direct annihilation, ionization and positronium formation. In the case of positronium formation, the algorithm considers the interactions of positronium with molecules. The algorithm can be used...
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Green Polymer Nanocomposites for Skin Tissue Engineering
PublicationFabrication of an appropriate skin scaffold needs to meet several standards related to the mechanical and biological properties. Fully natural/green scaffolds with acceptable biodegradability, biocompatibility, and physiological properties quite often suffer from poor mechanical properties. Therefore, for appropriate skin tissue engineering and to mimic the real functions, we need to use synthetic polymers and/or additives as complements...
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Proteomic profiling of exosomes derived from pancreatic beta-cells cultured under hyperglycemia
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Biomedical Engineering at Gdansk University of Technology
PublicationShort history of education in Biomedical Engineering at Gdansk University of Technology is presented. The last initiative- implementation of the new programme, Biomedical Engineering - an interfaculty direction of study, supported by a grantfinanced by the European Social Fund is presented. Curricula of four specializations: Chemistry in Medicine, run by the Facultyof Chemistry; Electronics in Medicine and Informatics in Medicine,...
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Improved Performance of 1-Ethyl-3-Methylimidazolium Tetrafluoroborate at Steel/HCl Interface by Iodide Ions
PublicationThe corrosion and corrosion inhibition of St37 steel in 0.1 M HCl solution by 1-ethyl-3-methylimidazolium tetrafluoroborate (EMITFB) and the effect of addition of KI on the inhibitive performance of EMITFB have been examined by electrochemical [electrochemical impedance spectroscopy, potentiodynamic polarization, and dynamic electrochemical impedance spectroscopy (DEIS)] and surface examination [scanning electron microscope (SEM)...
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Modernization of historic healthcare buildings
PublicationThe practice of transforming and adapting the existing healthcare facilities to meet the growing demands of modern medicine applies not only to buildings of historical value. Of course, one can set a time point from which hospitals, erected mostly with industrialized technologies, undergo upgrades for better or worse effect. Existing healthcare buildings or facilities, including historic ones, have to be refurbished and adapted...
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Modernisation of existing hospitals
PublicationProgress in medicine and development of medical technologies directly affect the evolution of methods for treating patients in hospitals. The main task of 19th-century hospitals was patient care and nursing, while the aim of hospitals today is to diagnose and treat patients effectively in the shortest time possible. The changes which are taking place in methods of treatment affect the functional-spatial layout of hospitals. This...
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The Mott-Schottky characteristics of microwave pulsed-plasma polymerized allylamine by DEIS analysis
Open Research DataThe dataset contains the results obtained for the Mott-Schottky analysis of the microwave pulsed-plasma polymerized allylamine using the multifrequency perturbation signal with Dynamic Electrochemical Impedance Spectroscopy (DEIS) technique. The results were obtained using the perturbation composed of the elementary signals with a frequency range between...
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The Issues of Reactive Power Compensation in High-voltage Transmission Lines
PublicationThis paper discusses the selection of compensation shunt reactors for a double-circuit 400 kV transmission line using the example of the newly built Elk Bis – Alytus transmission line. The analysis takes into account various conditions of the power system. The published results relate to voltage levels in steady states and during switching processes and short circuits.
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Wdrożenia komercyjne chatter-botów
PublicationCelem artykułu jest ocena przydatności wdrożenia systemów chatter-bot, czyli tzw. wirtualnych konsultantów - systemów informatycznych, które potrafią odpowiadać na pytania zadawane w języku naturalnym. Przedstawiono główne czynniki wpływające na funkcjonalność systemu, analizę kosztów wdrożenia i efektywności inwestycji oraz przykłady komercyjnych zastosowań.
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System zarządzania złożonym przedsięwzięciem na przykładzie Igrzysk Olim-pijskich w Barcelonie. W: Inżynieria zarządzania przedsięwzięciami. Pod red. L. Zawadzkiej. Gdańsk: Wydaw. P. Gdań.** 2003 s. 75-90, 3 rys. 8 tab. bi-bliogr. 20 poz.
PublicationCelem niniejszej publikacji jest przedstawienie wpływu Igrzysk Olimpijskichw Barcelonie na rozwój miasta. W niniejszej publikacji przedstawione zostanądwa aspekty tego wpływu - techniczno- organizacyjny oraz ekonomiczny.
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Nowe urządzenia fotoniczne i kwantowe wykorzystujące nieliniowe i koherencyjne zjawiska w centrach barwnych w diamencie
ProjectsProject realized in Department of Metrology and Optoelectronics according to UMO-2016/21/B/ST7/01430 agreement from 2017-04-20
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Enhancement of PUR/PIR foam thermal stability after addition of Zostera marina biomass component investigated via thermal analysis and isoconversional kinetics
PublicationIn the present work, a thorough thermogravimetric (TG) analysis of bio-based polyurethane–polyisocyanurate (PUR–PIR) foams in both nitrogen and oxygen atmosphere is performed. A sustainable element of the foam is a biopolyol obtained via acid-catalyzed liquefaction of Zostera marina and Enteromorpha Algae biomass. Based on isoconversional analysis and apparent activation energies, several conclusions are obtained. In contradiction...
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Comparison of the Efficiency of Hetero- and Homogeneous Catalysts in Cellulose Liquefaction
PublicationBiomass liquefaction is a well-known and extensively described process. Hydrothermal processes are well understood and can be used in the fuel industry. The use of organic solvents can result in full-fledged products for use in the synthesis of polyurethanes. The plastics industry, including polyurethanes, is targeting new, more environmentally friendly solutions. One of these is the replacement of petrochemical polyols with compounds...
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Ion-selective electrodes based on p-tert-butyl-homooxacalixarene di(ethyl) amides
PublicationPochodne dietyloamidowe p-tert-butylodihomooksakaliks[4]arenu (1), p-tert-butyloheksahomotrioksakaliks[3]arenu (2) oraz p-tert-butylokaliks[4]arenu (3) były wykorzystane jako materiał aktywny w membranach elektrod jonoselektywnych w celu sprawdzenia detekcji kationów różnych rodzajów (Na+, K+, Cs+, Mg2+, Ca2+, Mn2+, Cu2+, Zn2+, Cd2+, Pb2+ oraz kation tetrametyloammoniowy). Wyznaczono charakterystyki elektrod oraz współczynniki...
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Influence of Ionic Liquid Structure on Supported Ionic Liquid Membranes Effectiveness in Carbon Dioxide/Methane Separation
PublicationThis paper indicates the possibility of application of imidazolium ionic liquids immobilized in polymeric supports—supported ionic liquid membranes—in CO2 separation from gaseous streams (e.g., biogas). Imidazolium salts containing alkyl fluoride anions, bis(trifluoromethylsulfonyl)imide and trifluoromethanesulfonate, selectively separating CO2 were used. The permeability of CO2 through membranes was investigated under gas pressure...