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wszystkich: 2090
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- Publikacje 1637 wyników po odfiltrowaniu
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Wyniki wyszukiwania dla: N,N-DONOR LIGAND
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Nonlinear impedance of 50(2Bi2O3-V2O5)-50SrB4O7 glass-ceramic heat-treated at 613 K measured with impedance spectroscopy method at high temperature region
Dane BadawczeNonlinear electrcial properties of 50(2Bi2O3-V2O5)-50SrB4O7 glass-ceramic heat treated at 613 K was measured by impedance spectroscopy method.
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Copper(II) complexes of 7-amino-2-methylchromone and 7-aminoflavone: Magneto-structural, spectroscopic and DFT characterization
PublikacjaFour new complexes of copper(II) consisting of two different chromone derivatives with carbonyl and amine donor atoms: 7-aminoflavone (L1) and 7-amino-2-methylchromone (L2), were synthesized and characterized by X-ray diffraction, UV–Vis, FT-IR, EPR spectroscopy, MS and elemental analysis. In all four compounds, the chromone derivatives were found to act as monodentate O- or N-ligands. The structural characteristics of 1a and...
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A new optimal algorithm for a time-dependent scheduling problem
PublikacjaIn this article a single machine time-dependent scheduling problem with total completion time criterion is considered. There are n given jobs j_1, ..., j_n and the processing time pi of the i-th job is given by p_i = 1 + b_is_i, where si is the starting time of the i-th job, i = 1, ..., n. If all jobs have different and non-zero deterioration rates and bi > bj => bi >= (b_min+1)/(b_min) b_j + 1/b_min, where b_min = min{b_i}, then...
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ADAPTATION OF THE ACTIVATED SLUDGE TO THE DIGESTATE LIQUORS DURING THE NITRIFICATION AND DENITRIFICATION PROCESSES
PublikacjaThe activated sludge process of the digestate liquors after chemical separation was conducted using a 10 L lab-scale sequencing batch reactor (SBR) and a 0.50 m3 pilotscale SBR independently (with pH control). Due to the relatively high concentration of free ammonia (FA), clear inhibitory effects of the digestate liquors on the nitrifying bacteria were observed. The adaptation of the activated sludge to the toxicity was evaluated...
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One dimensional coordination polymers generated from Cd(II) tri-tert-butoxysilanethiolates and flexible aliphatic diamines.
PublikacjaPraca ta dotyczy chemii koordynacyjnej tri-tert-butoksysilanotiolanu kadmu(II) z diaminami alifatycznymi. Reakcja dwucentowego [Cd{SSi(OtBu)3}2]2 z poszczególnymi diaminami pozwala otrzymać pięć nowych obojętnych jednowymiarowych polimerów koordynacyjnych o różnej topologii łańcuchów [Cd{SSi(OtBu)3}2(μ-C4H12N2)(CH3OH)]n (1), [Cd{SSi(OtBu)3}2(μ-C5H14N2)(CH3OH)]n (2) [Cd{SSi(OtBu)3}2(μ-C6H16N2)(CH3OH)]n (3), [Cd{SSi(OtBu)3}2(μ-C7H18N2)]n...
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Stark effect of atomic helium singlet lines
PublikacjaWe present experimental and theoretical investigations of the He spectral series 2S1−nQ1 (n=3÷9, Q=S,P,D,…,n−1) and 2P1−nQ1 (n=3÷9, Q=S,P,D,…,n−1) in electric fields up to 1635 kV/cm. Apart from the allowed transitions with |ΔL|=1, the transitions with |ΔL|=0,2,3,…-without field strictly forbidden-were observed. Several He patterns become similar to hydrogen patterns, which means they are nearly symmetric and show in higher fields...
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Which is better in fat times and in lean times: the macho man vs. the nice guy? Study 1 dataset
Dane BadawczeThe dataset from cross-cultural study conducted in Poland and Norway in the area of gender stereotypes. Our study was conducted in two countries differing with regard to gender equality indices relating to the extent to which men are allowed to manifest gender-atypical behavior and influencing mate preferences of women. Polish (N = 106) and Norwegian...
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Chromium FTW dataset
Dane BadawczeThis dataset contains the results of chromium and nutrients (N and PO4-P) removal in floating treatment wetland microcosm experiment with two cosmopolitan species of parennials: Phragmites australis and Iris pseudacorus.
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Terrestrial Survey Images - Multispectral Exterior Model - Gdansk Church Pw. Św. Wojciecha - Micasense Dual
Dane BadawczeDataset description: Raw images from photogrammetric survey. Object: Kościół Rzymskokatolicki Pw. Św. WojciechaLocation: Gdansk, Pomerania, PolandDrone type: N/A (terrestrial images)Flight plan: Free - walk around the object with camera. 3 images taken at the point.Target Product: 3D Model - Multispectral ModelDate: 24.04.2022Direct georeferencing:...
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Compression test results of fused filamend fabricated polylactyde and polylactyde with carbon fiber filler
Dane BadawczeThe DataSet contains the results of the mechanical behaviour of cube specimens with dimensions 30 x 30 x 30 cm3. The specimens were additively manufactured with the fused filament fabrication (FFF) method. They used two different materials polylactide (PURE PLA) and polylactide with carbon fibre filler (PLA+CF). The specimens were segregated into three...
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Ellipsometric study of carbon nitride films deposited by DC-magnetron sputtering
PublikacjaWe report the optical properties of a carbon nitride (CNx) film as a function of nitrogen concentration (N/C) of the deposited film. As nitrogen concentration is increased (N/C ratio) in a CNx film, the refractive index and band gap also increase. The real and imaginary parts, n and k (refractive index and extinction coefficient) of the complex refraction index of carbon nitride films were determined by spectroscopic ellipsometry...
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Amyloid fibril formation in the presence of water structure-affecting solutes
PublikacjaThe impact of the differently hydrated non-electrolytes (protein structure destabilizers) on the fibrillation of hen egg white lysozyme (HEWL) was investigated. Two isomeric urea derivatives i.e. butylurea (BU) and N,N,N′,N′-tetramethylurea (TMU) were chosen as a tested compounds. The obtained results show that butylurea exerts greater impact on HEWL and its fibrillation than tetramethylurea. Both substances decrease the time of...
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Phonons at the Fe(110) Surface
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Sleep bruxism: An interdisciplinary concern
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The European Training Network ETUDE (Encompassing Training in fUnctional Disorders across Europe): a new research and training program of the EURONET-SOMA network recruiting 15 early stage researchers
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Impact of the anion and chalcogen on the crystal structure and properties of 4,6-dimethyl-2-pyrimido(thio)nium halides
PublikacjaBy the reaction of urea or thiourea, acetylacetone and hydrogen halide (HF, HBr or HI), we have obtained seven new 4,6-dimethyl-2-pyrimido(thio)nium salts, which were characterized by single-crystal X-ray diffraction, namely, 4,6-dimethyl-2-oxo-2,3-dihydropyrimidin-1-ium bifluoride, C₆H₉N₂O⁺·HF₂⁻ or (dmpH)F₂H, 4,6-dimethyl-2-oxo-2,3-dihydropyrimidin-1-ium bromide, C₆H₉N₂O⁺·Br⁻ or (dmpH)Br, 4,6-dimethyl-2-oxo-2,3-dihydropyrimidin-1-ium...
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Karolina Lademann Mgr
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The complete list of two-dimensional number-conserving ternary cellular automata
Dane BadawczeThis dataset contains a complete list of all 1327 two-dimensional number-conserving cellular automata with the state set {0,1,2} (the so-called ternary cellular automata) based on adjacent cells only, i.e. with the von Neumann neighborhood. The detailed definitions and the method of enumerating are given in the paper:
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Nonlinear impedance of 50Bi2VO5.5-50SrB4O7 glass measured with impedance spectroscopy method at low temperature region
Dane BadawczeThe nonlinear electrcial properties of 50(Bi2VO5.5)-50SrB4O7 glass was measured by impedance spectroscopy method.
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Nonlinear impedance of Bi2VO5.5 ceramic prepared by traditional melt quenching technique was measured with impedance spectroscopy method at low temperature region
Dane BadawczeThe nonlinear electrical properties of Bi2VO5.5 ceramic prepared by traditional melt quenching technique was measured by impedance spectroscopy method.
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Nonlinear impedance of 50Bi2VO5.5-50SrB4O7 annealed glass at 593 K measured with impedance spectroscopy method at high temperature region
Dane BadawczeThe nonlinear electrcial properties of 50Bi2VO5.5-50SrB4O7 annealed glass was measured by impedance spectroscopy method.
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Nonlinear impedance of 35Bi2VO5.5-65SrB4O7 glass measured with impedance spectroscopy method at high temperature region
Dane BadawczeThe nonlinear electrcial properties of 35Bi2VO5.5-65SrB4O7 glass was measured by impedance spectroscopy method.
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Nonlinear impedance of as-quenched 40Bi2VO5.5-60SrB4O7 glass measured with impedance spectroscopy method at high temperature region
Dane BadawczeThe nonlinear electrical properties of as-quenched 40Bi2VO5.5-60SrB4O7 glass was measured by impedance spectroscopy method.
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Nonlinear impedance of 30Bi2VO5.5-70SrB4O7 glass measured with impedance spectroscopy method at high temperature region
Dane BadawczeThe nonlinear electrcial properties of 30Bi2VO5.5-70SrB4O7 glass was measured by impedance spectroscopy method.
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Nonlinear impedance of 50Bi2VO5.5-50SrB4O7 glass measured with impedance spectroscopy method at high temperature region
Dane BadawczeThe nonlinear electrcial properties of 50(Bi2VO5.5)-50SrB4O7 glass was measured by impedance spectroscopy method.
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Nonlinear impedance of 45Bi2VO5.5-55SrB4O7 glass measured with impedance spectroscopy method at high temperature region
Dane BadawczeThe nonlinear electrcial properties of 45Bi2VO5.5-55SrB4O7 glass was measured by impedance spectroscopy method.
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Pochodne kwasu neopentylidenofosforoditiowego jako substraty do syntezy ugrupowania trisulfidowego
PublikacjaBadania przeprowadzone w Katedrze Chemii Organicznej Wydziału Chemicznego Politechniki Gdańskiej na przestrzeni ostatnich kilku lat, pokazały wszechstronność pochodnych kwasu neopentylidenofosforoditiowego [32] w syntezie symetrycznie i niesymetrycznie podstawionego ugrupowania disulfidowego. Wyniki powyższych badań doprowadziły do opracowania nowej strategii syntetycznej, umożliwiającej otrzymywanie...
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Generation of chirality in 4,4'-azopyridine by co-crystallization with optically active dicarboxylic acids
PublikacjaOtrzymano kokryształy anti-4,4'-azopirydyny z optycznie czynnymi kwasai: 9,10-dihydro-9,10-etanoantraceno-11,12-dikarboksylowym i trans-1,2-cykloheksnodikarboksylowym. Następnie pomierzono dichroizm kołowy otrzymanych kryształów. Dodatni znak efektu Cottona, odpowiadający niskoenergetycznemu wzbudzeniu elektronowemu n-pi*, został skorelowany z M helikalnością skręconego chromoforu Ar-N=N. Absolutna konfiguracja skręconej cząsteczki...
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Reconfiguring Minimum Dominating Sets in Trees
PublikacjaWe provide tight bounds on the diameter of γ-graphs, which are reconfiguration graphs of the minimum dominating sets of a graph G. In particular, we prove that for any tree T of order n ≥ 3, the diameter of its γ-graph is at most n/2 in the single vertex replacement adjacency model, whereas in the slide adjacency model, it is at most 2(n − 1)/3. Our proof is constructive, leading to a simple linear-time algorithm for determining...
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Geometric analogue of holographic reduced representation
PublikacjaHolographic reduced representations (HRRs) are distributed representations of cognitive structuresbased on superpositions of convolution-bound n-tuples. Restricting HRRs to n-tuples consisting of 1,one reinterprets the variable binding as a representation of the additive group of binary n-tupleswith addition modulo 2. Since convolutions are not defined for vectors, the HRRs cannot be directlyassociated with geometric structures....
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Understanding the interactions between protein stabilizers and the peptide bond through the analysis of the volumetric and compressibility properties for the model systems
PublikacjaThis work confirms our earlier supposition, that volumetric and acoustic parameters for simple model proposed by us are directly related to stabilizing/destabilizing effect of osmolytes on proteins structure. The apparent molar volumes, V and the apparent molar isentropic compressions, KS,, of glycine and N,N,N –trimethylglycine (betaine) were determined from densities and speed of sound measurements in aqueous solution of N-methylacetamide...
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Optical transmission of the Niobium thin films
Dane BadawczeNiobium thin films with a thickness of 200nm were deposited n a Corning glass substrate by magnetron sputtering method. The optical transmission spectra in a visible light range were.recorded. Investigations showed a good optical transmission thru the layers for each samples, annealed at various temperatures. For measurements samples annealed at 500,...
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Valence and ionic lowest-lying electronic states of ethyl formate as studied by high-resolution vacuum ultraviolet photoabsorption, He(I) photoelectron spectroscopy, and ab initio calculations
PublikacjaThe highest resolution vacuum ultraviolet photoabsorption spectrum of ethyl formate, C2H5OCHO, yet reported is presented over the wavelength range 115.0–275.5 nm (10.75–4.5 eV) revealing several new spectral features. Valence and Rydberg transitions and their associated vibronic series, observed in the photoabsorption spectrum, have been assigned in accordance with new ab initio calculations of the vertical excitation energies...
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Efficient synthesis of PMMA@Co0.5Ni0.5Fe2O4 organic-inorganic hybrids containing hyamine 1622 – Physicochemical properties, cytotoxic assessment and antimicrobial activity
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An Algorithm for Listing All Minimal 2-Dominating Sets of a Tree
PublikacjaWe provide an algorithm for listing all minimal 2-dominating sets of a tree of order n in time O(1.3248n) . This implies that every tree has at most 1.3248 n minimal 2-dominating sets. We also show that this bound is tigh.
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Discussion of “Axisymmetric Simulations of Cone Penetration in Saturated Clay” by Diane M. Moug, Ross W. Boulanger, Jason T. DeJong, and Robert A. Jaeger
PublikacjaN/A
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Effect of Aromatic System Expansion on Crystal Structures of 1,2,5-Thia- and 1,2,5-Selenadiazoles and Their Quaternary Salts: Synthesis, Structure, and Spectroscopic Properties
PublikacjaRational manipulation of secondary bonding interactions is a crucial factor in the construction of new chalcogenadiazole-based materials. This article reports detailed experimental studies on phenanthro[9,10-c][1,2,5]chalcogenadiazolium and 2,1,3-benzochalcogenadiazolium salts and their precursors. The compounds were synthesized, characterized employing NMR and UV-Vis spectroscopy. TD-DFT calculations were also performed. The influence...
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Nitrification, denitrification, and dephosphatation capability of activated sludge during co-treatment of intermediate-age landfill leachates with municipal wastewater
PublikacjaThis study focuses on the possible use and efficacy of the co-treatment of landfill leachate (intermediate-age) with municipal wastewater. The nitrification, denitrification, and dephosphatation capability of activated sludge acclimated with a mixture of raw municipal wastewater (RWW) with gradually increasing amounts of raw landfill leachate (RLL) (from 0.5 to 5% v/v) were tested. Biochemical tests were conducted simultaneously...
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Maciej Jaśkiewicz Dr n. farm.
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Sustainable nitrogen removal in anammox-mediated systems: Microbial metabolic pathways, operational conditions and mathematical modelling
PublikacjaAnammox-mediated systems have attracted considerable attention as alternative cost-effective technologies for sustainable nitrogen (N) removal from wastewater. This review comprehensively highlights the importance of understanding microbial metabolism in anammox-mediated systems under crucial operation parameters, indicating the potentially wide applications for the sustainable treatment of N-containing wastewater. The partial...
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Redox State Sensitive Spectroscopy of the Model Compound [(H-dcbpy)(2)Ru-II(NCS)(2)](2-) (dcbpy=2,2 '-Bipyridine-4,4 '-dicarboxylato)
PublikacjaThe charge transfer reaction mechanism in a ruthenium polypyridine model complex with isothiocyanato ligands, i.e., [(H-dcbpy)(2)Ru(NCS)(2)](2-) 2Bu(4)N(+) (Ru2H) (dcbpy = 2,2'-bipyridine-4,4'-dicarboxylato), has been investigated by combining UV-vis absorption, resonance Raman spectroscopy, and electrochemical methods. Understanding the photophysics of light-harvesting complexes of this class is an indispensable prerequisite to...
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An improved preparation of N2-tert-butoxycarbonyl- and N2-benzyloxycarbonyl-(S)-2,4-diaminobutanoic acids.
PublikacjaN-Benzyloksykarbonylo i N-tert-butoksykarbonylo-(S)-asparaginę przekształcono do odpowiednio chronionego kwasu (S)-2,4-diaminobutanowego z dobrą wydajnością, w reakcji z octanem jodobenzenu w temp. 0 st.C w mieszaninie tetrahydrofuranu i wody.
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Crystal and electronic structures of Ni(II) silanethiolates containing flexible diamine ligands
PublikacjaFive nickel(II) complexes containing aliphatic diamines and tri-tert-butoxysilanethiolate ligand have been synthesized for the purpose of studying their structural, spectral (IR, UV–Vis, HF EPR) and thermal properties. Complexes (1)–(5) have been prepared in high yield by reactions of [Ni{SSi(OtBu)3}2(NH3)(H2O)] with 1.3-propanediamine (L1), 1,6-hexanediamine (L2), or 1,7-heptanediamine (L3). The X-ray structures were determined...
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Reactions of cobalt(ii) chloride and cobalt(ii) acetate with hemisalen-type ligands: ligand transformation, oxidation of cobalt and complex formation. Preliminary study on the cytotoxicity of Co(ii) and Co(iii) hemisalen complexes
PublikacjaSeveral molecular cobalt(II) complexes, one Co(II) coordination polymer, and one ionic cobalt(III) complex with imine hemisalen ligands were synthesized. The hemisalen ligands were synthesized from o-vanillin (oVP) and diverse aminopyridines (compounds HL1–HL4) or aminophenol (compound HL5). It was observed that cobalt(II) chloride in dry acetonitrile catalyzes a transformation of HL1 and HL3 instead of complex formation. The conversion...
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Routing equal-size messages on a slotted ring
PublikacjaAnalizujemy problem routingu wiadomości w sieci slotted ring, biorąc pod uwagę dwa kryteria optymalizacyjne: długość uszeregowania oraz liczbę 'cykli' pracy sieci. Optymalny routing dla wiadomości o rozmiarze k jest silnie NP-trudny, natomiast dla k=q, gdzie q jest rozmiarem sieci, można obliczyć w czsie O(n^2log n) dla pierwszego kryterium. Podajemy również algorytm o czasie działania O(nlog n) oraz o stałym współczynniku dobroci....
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Superexcited states in the vacuum-ultraviolet photofragmentation of isoxazole molecules
PublikacjaThe photofragmentation of isoxazole molecules producing excited atomic and molecular fragments has been investigated over the energy range 16-50 eV, using photon-induced fluorescence spectroscopy. The following fragments have been identified by their fluorescence: the excited hydrogen atoms H(n), n = 3-7 and the diatomic CH(A2Δ, B2Σ−), CN(B2Σ+) and C2(d3Πg) fragments. The diatomic fragments are vibrationally and highly rotationally...
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Bezpieczeństwo elektroenergetyczne dla pokoleń
PublikacjaW artykule przeanalizowano źródła energii pierwotnej, ich wystarczalnośći dywersyfikację w skali lokalnej i globalnej, problem dekarbonizacji polskiej elektroenergetyki na tle europejskiej polityki klimatycznej, osiągalność źródeł gazu jako efektywnego paliwa dla energetyki, polski program energetyki jądrowej, bezpieczeństwo zasilania elektrycznych systemów trakcyjnych jako strategicznej alternatywy...
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Nondestructive Optical Sensing of Flavonols and Chlorophyll in White Head Cabbage ( Brassica oleracea L. var. capitata subvar. alba ) Grown under Different Nitrogen Regimens
PublikacjaA multiparametric optical sensor was used to nondestructively estimate phytochemical compounds in white cabbage leaves directly in the field. An experimental site of 1980 white cabbages (Brassica oleracea L. var. capitata subvar. alba), under different nitrogen (N) treatments, was mapped by measuring leaf transmittance and chlorophyll fluorescence screening in one leaf/cabbage head. The provided indices of flavonols (FLAV) and...
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Experimental and theoretical study of protonated water cluster
PublikacjaZa pomocą metody rojowej zbadano powstanie i dryf dodatnio naładowanych klastrów wody H+(H20)n n=1-7. Oszacowano energie dysocjacji. Prace uzupełniają obliczenia kwantowe konfiguracji wybranych klastrów. Dokonano obliczeń kilkunastu konfiguracji zjonizowanych klastrów.
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Reaction of thio and seleno phosphoric acid derivatives with O-thioacylated hydroxylamine
PublikacjaZbadano reakcję siarkowych i selenowych analogów kwasu O,O-neopentylidenofosforowego z O-tiopiwaloilo-N-tert-butylohydroksyloaminą, w której to następuje rozszczepienie wiązania N-O. Znaleziono korelację pomiędzy potencjałem utleniającym anionu pochodnej kwasu fosforowego a przebiegiem badanej reakcji.