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Wyniki wyszukiwania dla: POROUS POLYURETHANE THIN LAYER
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Microporous Polyurethane Thin Layer as a Promising Scaffold for Tissue Engineering
PublikacjaThe literature describes that the most efficient cell penetration takes place at 200–500 µm depth of the scaffold. Many different scaffold fabrication techniques were described to reach these guidelines. One such technique is solvent casting particulate leaching (SC/PL). The main advantage of this technique is its simplicity and cost efficiency, while its main disadvantage is the scaffold thickness, which is usually not less than...
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Improved performance of LaNi0.6Fe0.4O3 solid oxide fuel cell cathode by application of a thin interface cathode functional layer
PublikacjaIn this work, novel functional layers were prepared by a low temperature spray pyrolysis method on the oxygen side of the solid oxide cells. Thin layers of Ce0.8Gd0.2O2 and LaNi0.6Fe0.4O3 are prepared between the electrolyte and the porous oxygen electrode. Additionally the influence of the sprayed ceria barrier layer on the zirconia based electrolyte with the new layers is evaluated. Impedance spectroscopy results show improvement...
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Investigation of thin perovskite layers between cathode and doped ceria used as buffer layer in solid oxide fuel cells
PublikacjaIn this paper, thin perovskite layers between cathode material of solid oxide fuel cells and gadolinia-doped ceria buffer layer are investigated. Thin layers made of LaNi0.6Fe0.4O3-δ (LNF), La0.6Sr0.4Co0.2Fe0.8O3-δ (LSCF), or SrTi0.65Fe0.35O3-δ (STF) were symmetrically deposited by spin coating method from metallo-organic polymer precursors on a Ce0.8Gd0.2O2-δ (CGO) substrate. Porous and about 40-μm-thick LNF cathodes were deposited...
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A review: Fabrication of porous polyurethane scaffolds
PublikacjaThe aim of tissue engineering is the fabrication of three-dimensional scaffolds that can be used for the reconstruction and regeneration of damaged or deformed tissues and organs. A wide variety of techniques have been developed to create either fibrous or porous scaffolds from polymers, metals, composite materials and ceramics. However, the most promising materials are biodegradable polymers due to their comprehensive mechanical...
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Warstwy funkcjonalne tlenkowych ogniw paliwowych
PublikacjaIn this paper, results describing current research on solid oxide fuel cells conducted at Gdańsk University of Technology, Faculty of Electronics, Telecommunications and Informatics are presented. The results are related to three kinds of functional layers: a thin cathode layer between the porous cathode layer and the electrolyte to improve the cathode performance, a buffer layer between the electrolyte and the cathode to slow...
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Influence of Surface-Modified Montmorillonite Clays on the Properties of Elastomeric Thin Layer Nanocomposites
PublikacjaIn recent years, polyurethane nanocomposites have attracted more attention due to the massive demand for materials with increasingly exceptional mechanical, optical, electrical, and thermal properties. As nanofillers have a high surface area, the interaction between the nanofiller and the polymer matrix is an essential issue for these materials. The main aim of this study is to validate the impact of the montmorillonite nanofiller...
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Shape memory thin films of Polyurethane: Does graphene content affect the recovery behavior of Polyurethane nanocomposites?
PublikacjaThin nanocomposite films of polyurethane have received remarkable attention due to their shape memory properties. As most of the reports focus on the beneficial aspects of the presence of nanofillers such as graphene nanoplatelets (GNPs) introduced into shape memory polymers, some research results reveal the opposite trend. The polyether/polyester-based polyurethane was synthesized through a condensation polymerization and the...
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Antibacterial polyurethanes, modifed with cinnamaldehyde, as potential materials for fabrication of wound dressings
PublikacjaThe epidermis is a skin layer, which protects an organism from the different factors of external environment. Therefore, the fast and effective regeneration of epidermis is important. Potential materials used for epidermis regeneration may be polyurethane scaffolds in form of the thin permeable layers. One and main disadvantage of such polyurethane scaffolds are their lack of antibacterial and antifungal properties. The great proposition...
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Polyurethane porous scaffolds (PPS) for soft tissue regenerative medicine applications
PublikacjaTissue engineering requires suitable polymeric scaffolds, which act as a physical support for regenerated tissue. A promising candidate might be polyurethane (PUR) scaffold, due to the ease of the PUR properties design, which can be adjusted directly to the intended purpose. In this study, we report a successful fabrication of porous polyurethane scaffolds (PPS) using solvent casting/particulate leaching technique combined with...
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THE ROLE OF THIN FUNCTIONAL LAYERS IN SOLID OXIDE FUEL CELLS
PublikacjaWidespread commercialization of solid oxide fuel cells requires lowering its cost. It is generally accepted that to lower the cost of solid oxide fuel cells it is necessary to use metal alloys as interconnectors and, consequently, lower its operating temperature to slow down interconnectors degradation. As a result the area specific resistance of the cathodes should be lowered to sustain the performance of the cells. In order to...
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Development of conductive porous media as packing materials for biotrickling filter – microbial fuel cell system (BTF-MFC system)
Dane BadawczeDataset presents values of electrical resistance measured for three developed conductive packimg materials for the application in a BTF-MFC system.
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Pavement ageing influence on tyre/road noise
PublikacjaRoad surface should be constructed in a way that ensures safe and comfortable traffic conditions, not only when it is newly paved but also during its entire lifetime. An important factor in the asphalt mixture design process is also the expected pavement durability and stability of pavement properties over time. In many countries, road surface starts to play a significant role in traffic noise reduction actions. Selecting a particular...
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Morphology of the sol-gel derived LTO:Cu films
Dane BadawczeMorphology of the lithium titanate doped by Cu thin films were investigated by SEM microscope. Films were deposited by spin-coater from sol-gel derived sol. SEM images showed a high porous structure, tipaciall for sol-gel based films. For measurements samples with a various content of Cu were selected.
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Preparation, characterization, and manufacturing of new polymeric materials for 3D printing for medical applications
PublikacjaThis work concerns the synthesis, formation, and characteristics of new filaments for 3D printing in FDM™/FFF technology for medical purposes. Two types of filaments were developed, i.e. degradable polyurethane and biodegradable polylactide-starch. The influence of the 3D printing process on selected filament properties was investigated. A detailed analysis of the filament formation process by the extrusion method was carried out,...
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Fabrication of Composite Polyurethane/Hydroxyapatite Scaffolds Using Solvent-Casting Salt Leaching Technique
PublikacjaScaffolds are porous three-dimensional structures which are used to fill bone losses and make them possible to cells to grow. Many different structural and biological properties are required from them: porosity, mechanical strength and biocompability. The present research is aimed at development of composite polyurethane/hydroxyapatite scaffolds by using the solvent-casting salt leaching method. The SEM examinations were applied...
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Experimentation, material modelling and simulation of bonded joints with a flexible adhesive
PublikacjaThe paper deals with material parameters identification of a flexible adhesive and the numerical simulation of its behaviour in a single lap bonded joint. The material modelling was based on the simple shear and tensile-shear laboratory tests of the bonded joints made of thin aluminium and polyurethane plates with the flexible adhesive Terostat MS 9360 manufactured by Henkel AG & Co. The adhesive was considered as a hyperelastic...
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Risks related to car fire on innovative Poroelastic Road Surfaces-PERS
PublikacjaTo reduce tyre/road noise, the concept of poroelastic road surfaces (PERS) was invented. PERS is a road surface material that is porous, and at the same time, it is flexible because of the substantial amount of rubber granulate content (from 20% to 85%). The rubber and stone particles are bound by polyurethane resin instead of bitumen. It was feared that in case of fire, because of the high content of rubber and polyurethane, there...
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Low Noise Poroelastic Road Pavements Based On Bituminous Binder
PublikacjaTire/road noise is the dominant source of traffic noise. It depends both on the tire design and on the characteristics of road pavements as well as on the vehicles’ operating conditions. Due to the fact that conventional (pneumatic) car tires have almost reached the limits of their ability to further reduce their noisiness, it is widely believed that the additional reduction of tire noise will be possible mainly through modifications...
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The porosity and morphology of PU foams prepared by solvent casting/salt leaching method with different solvents
PublikacjaIn this study, the polyurethane (PU) system based on poly(ethylene-butylene) adipate diol, 1,6-hexamethylene diisocyanate, 1,4-butanediol and ascorbic acid is used to prepare a foamed material. Polymer foams were created using solvent casting/salt-particle leaching (SC/PL) method. The influence of the PU concentration in different solutions [either in a DMF or in DMF with THF as a co-solvent] on the morphology and porosity of the...
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Processing of Polyester-Urethane Filament and Characterization of FFF 3D Printed Elastic Porous Structures with Potential in Cancellous Bone Tissue Engineering
PublikacjaThis paper addresses the potential of self-made polyester-urethane filament as a candidate for Fused Filament Fabrication (FFF)-based 3D printing (3DP) in medical applications. Since the industry does not provide many ready-made solutions of medical-grade polyurethane filaments, we undertook research aimed at presenting the process of thermoplastic polyurethane (TPU) filament formation, detailed characteristics, and 3DP of specially...
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Nickel Oxide Thin Film Sensor for Fluctuation-Enhanced Gas Sensing of Formaldehyde
PublikacjaNanocrystalline nickel-oxide-based thin films were prepared by advanced reactive gas deposition, and the response of these films to formaldehyde was studied by fluctuationenhanced sensing. Morphological and structural analyses showed porous deposits of nickel oxide particles with face-centered cubic structure. Resistance fluctuations were measured upon exposure to ethanol, formaldehyde and methane at 200 °C. Power density spectra...
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Structural evaluation of percolating, self-healing polyurethane–polycaprolactone blends doped with metallic, ferromagnetic, and modified graphene fillers
PublikacjaComposites with differently shaped micro- and nanofillers show various, unique thermal, and physicochemical properties when mixed with carefully chosen polymer matrix. Selected composition holds strategic value in achieving desired properties that is biodegradability, thermoelectric conductivity, and shape memory for organic coating. The main aim of this work is to briefly examine structural changes after reaching percolation...
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Structural evaluation of percolating, self-healing polyurethane–polycaprolactone blends doped with metallic, ferromagnetic, and modified graphene fillers
PublikacjaComposites with differently shaped micro- and nanofillers show various, unique thermal, and physicochemical properties when mixed with carefully chosen polymer matrix. Selected composition holds strategic value in achieving desired properties that is biodegradability, thermoelectric conductivity, and shape memory for organic coating. The main aim of this work is to briefly examine structural changes after reaching percolation threshold...
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The importance of the bottom layer in double-layer porous asphalt for noise reduction
PublikacjaDouble-layer porous asphalt concrete (DPAC) surfaces are generally considered to be the acoustically most effective low noise road surfaces ready for implementation. While DPAC used on highways in warm climates may have an average life of around 8 years, in Scandinavia with severe winter climate DPAC usually survive only about 3 years; partly due to wear of studded tyres. An ongoing project in Sweden, applying DPAC and single-layer...
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Fluctuation-enhanced and conductometric gas sensing with nanocrystalline NiO thin films: A comparison
PublikacjaNanocrystalline thin films of NiO were prepared by advanced reactive gas deposition, and their responses to formaldehyde, ethanol and methane gases were studied via fluctuation-enhanced and conductometric methods Thin films with thicknesses in the 200–1700-nm range were investigated in as-deposited form and after annealing at 400 and 500 °C. Morphological and structural analyses showed porous deposits with NiO nanocrystals having...
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A Simple Replica Method as the Way to Obtain a Morphologically and Mechanically Bone-like Iron-Based Biodegradable Material
PublikacjaPorous iron-based scaffolds were prepared by the simple replica method using polyurethane foam as a template and applying the sintering process in a tube furnace. Their surface morphology was characterized using scanning electron microscopy (SEM) and phase homogeneity was confirmed using X-ray diffraction (XRD). Corrosion behavior was determined using immersion and potentiodynamic polarization methods in phosphate buffered saline...
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Preparation of porous TiO2 films by means of pulsed laser deposition for photocatalytic applications
PublikacjaIn this work the preparation and structure properties of porous thin films of TiO2 were investigated. The films were produced by means of the pulsed laser deposition technique using laser pulses at 266nm (10Hz) and at fluencies of 1-3.5J/cm2. The process was performed in vacuum using O2 buffer gas and films were deposited on the SiO2 glass or Si substrate. X-ray diffraction (XRD) and Raman analysis of the structure and chemical...
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YSZ Thin film deposited on porous substrate by spray pyrolysis
PublikacjaIn this work the results of deposition of YSZ layer on a porous substrate using an ultrasonic Spray Pyrolysis are presented.
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Porosity and swelling properties of novel polyurethane–ascorbic acid scaffolds prepared by different procedures for potential use in bone tissue engineering
PublikacjaIn this work, a novel polyurethane (PU) system based on poly(ethylene-butylene) adipate diol, 1,6-hexamethylene diisocyanate, 1,4-butanediol, and ascorbic acid was used to prepare scaffolds with potential applications in bone tissue engineering. Two fabrication methods to obtain porous materials were chosen: phase separation (PS)/salt particle leaching (PL) and solvent casting (SC)/salt PL. The calculated porosity demonstrated...
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Modelling hydraulic and capillary-driven two-phase fluid flow in unsaturated concretes at the meso-scale with a unique coupled DEM-CFD technique
PublikacjaThe goal of the research was to demonstrate the impact of thin porous interfacial transition zones (ITZs) between aggregates and cement matrix on fluid flow in unsaturated concrete caused by hydraulic/capillary pressure. To demonstrate this impact, a novel coupled approach to simulate the two-phase (water and moist air) flow of hydraulically and capillary-driven fluid in unsaturated concrete was developed. By merging the discrete...
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On-line measurement of wood surface smoothness
PublikacjaThe latest progress in the field of optics and microelectronics resulted in development of new generation vision systems capable of scanning surface topography with very high sampling frequencies. The blue color of illuminating light as well as novel systems for controlling ultra-thin laser line thickness allows measurement of the porous surface of wood with a triangulation method. Three alternative sensors were tested here in...
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Spectroscopic Optical Coherence Tomography for Thin Layer and Foil Measurements
PublikacjaThe main goal of this research was to assess if it is possible to evaluate the thickness of thin layers (both thin films on the surface and thin layers below the surface of the tested object) and foils using optical coherence tomography (OCT) for thickness assessment under the resolution of the standard commercially available OCT measurement system. In the proposed solution, light backscattered from the evaluated thin layer has...
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Surface quality control of a thin SiN layer by optical measurements
PublikacjaFiber optic interferometers have a wide range of applications, including biological and chemical measurements. Nevertheless, in the case of a reflective interferometer setup, standard silver mirrors cannot be used in every measurement, due to their chemical activity. This work investigates the surface quality of a thin optical layer of silicon nitride (SiN), which can serve as an alternative material for silver mirrors. We present...
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Analysis of magnetic field inside thin-layer ferromagnetic objects
PublikacjaResults of the numerical analysis of the magnetic field inside an infinitely long, thin-layer ferromagnetic pipe with and without a barrier were presented in this paper. Two wires with current symmetrically placed on two sides of the pipe are the sources of magnetic field. Numerical calculations for the quasi-steady state for chosen frequency band were carried out in the Flux 2D.
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Poroelastic Low Noise Road Surfaces
PublikacjaNoise is one of the most important problems related to road traffic. During the last decades, noise emitted by engine and powertrain of vehicles was greatly reduced and tyres became a clearly dominant noise source. The paper describes the concept of low noise poroelastic road surfaces that are composed with mineral and rubber aggregate bound by polyurethane resin. Those surfaces have a porous structure and are much more flexible...
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Ultra Low Noise Poroelastic Road Surfaces
PublikacjaNoise is one of the most important environmental problems related to road traffic. During the last decades, the noise emitted by the engines and powertrains of vehicles was greatly reduced and tires became a clearly dominant noise source. The article describes the concept of low noise poroelastic road surfaces that are composed of mineral and rubber aggregate bound by polyurethane resin. Those surfaces have a porous structure and...
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Production and Properties of the Porous Layer Obtained by the Electrochemical Method on the Surface of Austenitic Steel
Publikacja: The growing demand for implants has seen increasing interest in the introduction of new technologies and surface modification methods of metal biomaterials. This research aimed to produce and characterize a porous layer grown on austenitic stainless steel 316L, obtained via the anodization process near the micro-arc oxidation, i.e., low voltage micro-arc oxidation (LVMAO). The discussed layer significantly influences the properties...
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Plasma-Based Deposition and Processing Techniques for Optical Fiber Sensing
PublikacjaPlasma-based techniques are widely applied for well-controlled deposition, etching or surface functionalization of a number of materials. It is difficult to imagine fabrication of novel microelectronic and optoelectronic devices without using plasma-enhanced deposition of thin films, their selective etching or functionalization of their surfaces for subsequent selective binding of chemical or biological molecules. Depending on...
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Dielectric properties of modified graphene oxide filled polyurethane nanocomposites and its correlation with rheology
PublikacjaThis study aims at investigating the dynamic mechanical, dielectric and rheological properties of reinforced polyurethane (PU) nanocomposites containing hydrophilic graphene oxide (GO) and/or hydrophobic modified graphene oxide (mGO) sheets. The organic modification of GO was performed with 4,4′-methylenebis (phenyl isocyanate) (MDI) and the samples were prepared by solvent mixing. We found that addition of mGO provides a more...
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Biophotonic low-coherence sensors with boron-doped diamond thin layer
PublikacjaLow-coherence sensors using Fabry-Perot interferometers are finding new applications in biophotonic sensing, especially due to the rapid technological advances in the development of new materials. In this paper we discuss the possibility of using boron-doped nanodiamond layers to protect mirror in a Fabry-Perot interferometer. A low-coherence sensor using Fabry-Perot interferometer with a boron-doped nanodiamond (B-NCD) thin protective...
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Study of the Layer-Type BST Thin Film with X-ray Diffraction and X-ray Photoelectron Spectroscopy
PublikacjaIn the present paper, results of X-ray photoelectron studies of electroceramic thin films of barium strontium titanate, Ba1xSrxTiO3 (BST), composition deposited on stainless-steel substrates are presented. The thin films were prepared by the sol-gel method. A spin-coating deposition of BST layers with different chemical compositions was utilized so the layer-type structure of (0-2) connectivity was formed. After the deposition,...
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One More Step Towards a Circular Economy for Thermal Insulation Materials—Development of Composites Highly Filled with Waste Polyurethane (PU) Foam for Potential Use in the Building Industry
PublikacjaThe rapid development of the building sector has created increased demand for novel materials and technologies, while on the other hand resulting in the generation of a severe amount of waste materials. Among these are polyurethane (PU) foams, which are commonly applied as thermal insulation materials. Their management is a serious industrial problem, due to, for example, their complex chemical composition. Although some chemical...
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Acoustic lifecycle study of the double-layer porous asphalt on E4 in Huskvarna, Sweden
PublikacjaIn 2010 a double-layer porous asphalt concrete (DPAC) pavement was constructed on the E4 motorway through the Swedish city Huskvarna. Earlier experience in Sweden indicated that it was feasible to obtain a high initial noise reduction but due to the widespread use of studded tires in winter, clogging and ravelling created losses of around 2 dB per year, with an expected acoustical lifetime of only 3 years. However, the improved...
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Modelling of elastic wave propagation in a bolted joint using a thin layer of shell elements
PublikacjaThere are many mathematical models describing the propagation of elastic waves through the imperfect boundary of two media. They were successfully applied to modelling of high frequency bulk waves and their interaction with local defects. On the other hand, the existing literature models of bolted connections ignore the aspect of imperfect connection between elements. Therefore, this paper presents the concept of application of...
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High - voltage thin - layer fuses
PublikacjaZaprezentowano nową technologię i konstrukcję bezpieczników wysokonapięciowych wykorzystując technologie stosowane w mikroelektronice. Cienką warstwę topika naniesiono na quasiceramiczne podłoże. Wykonane modele bezpieczników charakteryzują się wysoką pewnością działania oraz małymi stratami I2t.
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Improving the Performance of a Graphite Foil/Polyaniline Electrode Material by a Thin PEDOT:PSS Layer for Application in Flexible, High Power Supercapacitors
PublikacjaIn this study, we present a novel strategy for enhancing polyaniline stability and thus obtaining an electrode material with practical application in supercapacitors. A promising (graphite foil/polyaniline/poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) GF/PANI/PEDOT:PSS) electrode material was characterized and used in the construction of a symmetric supercapacitor that provides an outstanding high power density. For this...
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Thin layer chromatography in drug discovery process
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Random height of thin layer of rheological liquids
PublikacjaPraca prezentuje nowe modele funkcji gęstości w rozkładach Gaussa, opisujących losowo zmieniającą się wysokość szczeliny w stawie biodrowym człowieka przy uwzględnieniu właściwości reologicznych synowialnej cieczy smarującej.
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Properties of humidity sensors with porous Al2O3 as a dielectric layer
PublikacjaPrzedstawiono wpływ wartości wilgotności względnej na charakterystki ceramicznego czujnika z porowatą warstwą Al2O3. Pokazano wpływ wybranych parametrów technologicznych na właściwości czujnika. Wyniki pomiarów dla dwóch grup czujników poddano analizie wykorzystując znane z literatury układy zastępcze.
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Polyurethane based hybrid ciprofloxacin-releasing wound dressings designed for skin engineering purpose
PublikacjaPurpose Even in the 21st century, chronic wounds still pose a major challenge due to potentially inappropriate treatment options, so the latest wound dressings are hybrid systems that enable clinical management, such as a hybrid of hydrogels, antibiotics and polymers. These wound dressings are mainly used for chronic and complex wounds, which can easily be infected by bacteria. Materials and methods Six Composite Porous Matrices...