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Wyniki wyszukiwania dla: Selective catalytic reduction
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Size Reduction of Microwave Couplers by EM-Driven Optimization
PublikacjaThis work addresses simulation-driven design optimization of compact microwave couplers that explicitly aims at circuit footprint area reduction. The penalty function approach allows us to minimize the area of the circuit while ensuring a proper power division between the output ports and providing a sufficient bandwidth with respect to return loss and isolation around the operating frequency. Computational cost of the optimization...
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Modification of structured bio‑carbon derived from spongin-based scaffolds with nickel compounds to produce a functional catalyst for reduction and oxidation reactions: Potential for use in environmental protection
PublikacjaThree different 3D fibrous-like NiO/Ni(OH)2/Ni‑carbonized spongin-based materials were prepared via a simple sorption–reduction method. Depending on the support used, the catalysts were composed of carbon, nickel oxide, nickel hydroxide and zero-valent nickel, with the surface content of the nickel-containing phase in the range 15.2–26.0 wt%. Catalytic studies showed promising activity in the oxidation of phenolic compounds in water...
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Quest for the Molecular Basis of Improved Selective Toxicity of All-Trans Isomers of Aromatic Heptaene Macrolide Antifungal Antibiotics
PublikacjaThree aromatic heptaene macrolide antifungal antibiotics, Candicidin D, Partricin A (Gedamycin) and Partricin B (Vacidin) were subjected to controlled cis-trans to all trans photochemical isomerization. The obtained all-trans isomers demonstrated substantially improved in vitro selective toxicity in the Candida albicans cells: human erythrocytes model. This effect was mainly due to the diminished hemotoxicity. The molecular modeling...
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Domain Reduction in Hybrid Technique for Electromagnetic Wave Scattering Problems
PublikacjaThis paper proposes a combination of the field matching technique, finite element method and generalized impedance matrix, the main idea of which is to reduce the computational domain by surrounding a scatterer with the smallest convex shape and applying the field matching technique. This approach can be applied for arbitrary shaped scatterers and types of materials and allows for the reduction of the computational domain. In order...
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Potentiometric sensor containing set of ion selective electrodes with lipid modified membranes for quality assessment of tested non-alcoholic beverages
PublikacjaPotentiometric sensors may be a good tool for fast quality control of commercial drinks. In this work, such a sensor, containing a set of ion-selective electrodes with lipid-modified membranes (benzylhexadecyldimethylammonium chloride monohydrate, hexadecylamine, 1-dodecanol, elaidic acid, cholesterol) was used for discrimination and quality control of non-alcoholic beverages, mainly composed of sugar and citric acid. It was found...
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Site-selective cation–π interaction as a way of selective recognition of the caesium cation using sumanene-functionalized ferrocenes
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A new phosphonium calix[4]arene for selective anion recognition: synthesis and studies in solution and in ion selective electrodes
PublikacjaZaprezentowana została synteza i charakteryzacja tetra (trifenylofosfoniowego) p-tert-butylkaliks[4]arenu 2. Oddziaływania z anionami były badane z użyciem (1)H oraz (31)P NMR i spektrofotometrii absorpcyjnej UV. Badania wykazały oddziaływania z anionami: CLO4-, I-, oraz SCN-. Selektywność jonoforu 2 badano również w membranowych elektrodach jonoselektywnych (ISE) PCV/o-NPOE. Elektroda zawierająca związek 2 generuje odpowiedź potencjometryczną...
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The reduction of auxiliaries power demand: The challenge for electromobility in public transportation
PublikacjaAn important role in the consumption of electric energy in urban transport are non-traction needs (auxiliaries), the main part of which is heating and air condition (HVAC). Auxiliaries are responsible for almost half of total energy consumption (normal weather conditions) and in the winter (or hot summer) it reaches up to 70% in daily scale. The reduction of energy used for non-traction needs is currently the main challenge related...
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Effect of Vascular Lumen Reduction on the Performance and Energy Consumption of an Innovative Implantable LVAD
PublikacjaThis paper presents the results of a study on the effect of vascular lumen reduction on the performance of an innovative implantable LVAD (left ventricular assist device). It details the pressures in the individual cardiac chambers as a function of device frequency. In addition, mass flow rates and energy consumption of the device are examined, varying with lumen reduction and operating frequency. While the lumen reduction of the...
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Improving Clairvoyant: reduction algorithm resilient to imbalanced process arrival patterns
PublikacjaThe Clairvoyant algorithm proposed in “A novel MPI reduction algorithm resilient to imbalances in process arrival times” was analyzed, commented and improved. The comments concern handling certain edge cases in the original pseudocode and description, i.e., adding another state of a process, improved cache friendliness more precise complexity estimations and some other issues improving the robustness of the algorithm implementation....
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Reliable Greedy Multipoint Model-Order Reduction Techniques for Finite-Element Analysis
PublikacjaA new greedy multipoint model-order reduction algorithm for fast frequency-domain finite-element method simulations of electromagnetic problems is proposed. The location of the expansion points and the size of the projection basis are determined based on a rigorous error estimator. Compared to previous multipoint methods, the quality of the error estimator is significantly improved by ensuring the orthogonality of the projection...
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Development of Microstructured Carbon Coatings by Substrate-Catalytic CVD
PublikacjaCarbon nanostructured films were synthesized by chemical vapor deposition (CVD) on H18 stainless steel (AISI 440C) sheets with an H2/CH4/N2 gas mixture at various substrate temperatures. During the synthesis, the iron and chromium oxide layer was formed between the steel and carbonaceous layer. The carbon films exhibited wall-like and spherical morphologies and structures, as characterized by scanning electron microscopy and Raman...
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Synthesis of Multiwalled Carbon Nanotubes by Catalytic Combustion of Polypropylene
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Heteropolyanions doped polyacetylene—Preparation, spectroscopic and catalytic properties
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The catalytic potential of high-κ dielectrics for graphene formation
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Preparation and characterization of TiO2 nanostructures for catalytic CO2 photoconversion
PublikacjaThe titanium dioxide target (99.7%) of 1 cm in dia was ablated in vacuum by laser pulses(6 ns) at 266 nm and at repetition rate of 10 Hz. During deposition the laser fluence between 1 and 3.5 J/cm2 and the O2 pressure from the range of 10-2 - 1 Pa were applied. The thin TiO2 films were deposited on glass substrate (1 × 1 cm2) heated up to 500 °C. The chemical composition of the film and samples produced by annealing were investigated...
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Surrogate-Assisted Design of Checkerboard Metasurface for Broadband Radar Cross-Section Reduction
PublikacjaMetasurfaces have been extensively exploited in stealth applications to reduce radar cross section (RCS). They rely on the manipulation of backward scattering of electromagnetic (EM) waves into various oblique angles. However, arbitrary control of the scattering properties poses a significant challenge as a design task. Yet it is a principal requirement for making RCS reduction possible. This article introduces a surrogate-based...
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Antifungal Effect of Penicillamine Due to the Selective Targeting of L-Homoserine O-Acetyltransferase
PublikacjaDue to the apparent similarity of fungal and mammalian metabolic pathways, the number of established antifungal targets is low, and the identification of novel ones is highly desirable. The results of our studies, presented in this work, indicate that the fungal biosynthetic pathway of L-methionine, an amino acid essential for humans, seems to be an attractive perspective. The MET2 gene from Candida albicans encoding L-homoserine...
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Low-Cost Behavioral Modeling of Antennas by Dimensionality Reduction and Domain Confinement
PublikacjaBehavioral modeling has been rising in importance in modern antenna design. It is primarily employed to diminish the computational cost of procedures involving massive full-wave electromagnetic (EM) simulations. Cheaper alternative offer surrogate models, yet, setting up data-driven surrogates is impeded by, among others, the curse of dimensionality. This article introduces a novel approach to reduced-cost surrogate modeling of...
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A Reduction Method for Bathymetric Datasets that Preserves True Coastal Water Geodata
PublikacjaWater areas occupy over 70 percent of the Earth’s surface and are constantly subject to research and analysis. Often, hydrographic remote sensors are used for such research, which allow for the collection of information on the shape of the water area bottom and the objects located on it. Information about the quality and reliability of the depth data is important, especially during coastal modelling. In-shore areas are liable...
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Reduction of measurement data before Digital Terrain Model generation vs. DTM generalisation
PublikacjaModern data acquisition technologies provide large datasets that are not always necessary in its entirety to properly accomplish the goal of the study. In addition, such datasets are often cumbersome for rational processing, and their processing is time and labour consuming. Therefore, methods that enable to reduce the size of the measurement dataset, such as the generalization of the Digital Terrain Model (DTM) or the reduction...
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The effectiveness of polymer adhesive in reduction of vibrations of structural members
PublikacjaIn this paper, the idea of using polymer adhesive as a damping layer is proposed. An experimental study of two aluminium cantilevered beams has been conducted. One of them presents a plain cantilevered beam, while the second one considers two aluminium beams bonded with a polymer adhesive of different thickness (0,5; 1,2; 1,75; 3,1 and 5 mm). The polymer adhesive considered in the study is a specially designed flexible...
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A Model-Order Reduction Approach for Electromagnetic Problems With Nonaffine Frequency Dependence
PublikacjaThe aim of this paper is to present a novel model-order reduction (MOR) technique for the efcient frequency-domain nite-element method (FEM) simulation of microwave components. It is based on the standard reduced-basis method, but the subsequent expansion frequency points are selected following the so-called sparsied greedy strategy. This feature makes it especially useful to perform a fast-frequency sweep of problems that lead...
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Fixed Pattern Noise Reduction and Linearity Improvement in Time-Mode CMOS Image Sensors
PublikacjaIn the paper, a digital clock stopping technique for gain and offset correction in time-mode analog-to-digital converters (ADCs) has been proposed. The technique is dedicated to imagers with massively parallel image acquisition working in the time mode where compensation of dark signal non-uniformity (DSNU) as well as photo-response non-uniformity (PRNU) is critical. Fixed pattern noise (FPN) reduction has been experimentally validated...
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Topological modifications for performance improvement and size reduction of wideband antenna structures
PublikacjaCompact antennas belong to the key components of modern communication systems. Their miniaturization is often achieved by introducing appropriate topological changes such as simple ground plane slots or tapered feeds. More sophisticated modifications are rarely considered in the literature because they normally lead to significant increase of the number of tunable parameters, which makes the antenna design process more challenging....
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Determinants of the surface quality, density and dimensional correctness in selective laser melting of the Ti-13Zr-13Nb alloy
PublikacjaSelective laser melting is widely used for custom-designed elements. Successful manufacturing depends on laser treatment parameters and material features. This research aimed to determine the effects of laser power, scan time and hatch distance on surface quality, relative density and dimensional precision for cuboids made of the Ti-13Zr-13Nb alloy. The influence of energy density, energy flux and pre-heating was seen to be decisive...
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Palindromic carbazole derivatives: unveiling their antiproliferative effect via topoisomerase II catalytic inhibition and apoptosis induction
PublikacjaHuman DNA topoisomerases are essential for crucial cellular processes, including DNA replication, transcription, chromatin condensation, and maintenance of its structure. One of the significant strategies employed in cancer treatment involves the inhibition of a specific type of topoisomerase, known as topoisomerase II (Topo II). Carbazole derivatives, recognised for their varied biological activities, have recently become a significant...
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Substrate Reduction Therapies for Mucopolysaccharidoses
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Distributed Learning with Data Reduction
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Multilevel model order reduction.
PublikacjaPrezentujemy wielopoziomowy algorytm redukcji rzędu modelu wykorzystany do zwiększenia efektywnosci analizy struktur mikrofalowych metodami siatkowymi.Schemat pozwala tworzyć makromodele zagniezdzone i laczyc te technike z szybkim przemiataniem częstotliwości (FFS). Implementacja metody pokazana jest na przukladzie różnic skończonych w dziedzinie częstotliwości i metody redukcji ENOR, lecz koncept moze być łatwo użyty w innych...
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Selective adsorption of BTEX on calixarene-based molecular coordination network determined by 13C NMR spectroscopy
PublikacjaBenzene, toluene, ethylbenzene, and xylenes (BTEX), a class of volatile organic compounds, are harmful pollutants but also very important precursors in organic industrial chemistry. Among different approaches used for the BTEX treatment, the adsorption technology has been recognized as an efficient approach because it allows to recover and reuse both adsorbent and adsorbate. However, the selective adsorption of the components is...
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Multilevel model order reduction with generalized compression of boundaries for 3-d FEM electromagnetic analysis
PublikacjaThis paper presents a multilevel Model Order Reduction technique for a 3-D electromagnetic Finite Element Method analysis. The reduction process is carried out in a hierarchical way and involves several steps which are repeated at each level. This approach brings about versatility and allows one to efficiently analyze complex electromagnetic structures. In the proposed multilevel reduction the entire computational domain is covered...
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Tyre/road noise reduction by a poroelastic road surface
PublikacjaLow noise road surfaces of existing types may in favourable cases and in new conditions provide up to 7 dB of noise reduction. For higher noise reductions, innovative solutions must be sought. Poroelastic road surfaces (PERS) may be such a solution, which currently is studied in the EU project PERSUADE. This paper presents results of trials with a PERS version prefabricated by one of the project partners. Tests were made in a laboratory...
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Site-selective magnetic order of neptunium inNp2Ni17
PublikacjaWe present the results obtained by superconducting quantum interference device (SQUID) magnetometry, specific heat, and Mossbauer spectroscopy measurements carried out on Np2Ni17 polycrystalline samples. We show that long-range magnetic order, with a moment mu((2b)) similar to 2.25 mu(B), occurs below T-N = 17.5 K on the Np (2b) sites. A nontrivial situation is observed in that the other Np sites (2d) do not take part to the order...
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Dipodal Tetraamide Derivatives of 1,10-Diaza-18-Crown-6 and Alkylmalonic Acids—Synthesis and Use as Ionophores in Ion Selective Membrane Electrodes
PublikacjaNovel dipodal derivatives of an 18-membered diaza-crown ether with two diamide chains featuring methylmalonic or butylmalonic acid residues were obtained and tested as ionophores in ion-selective plasticized membrane electrodes. The objective of the study was to identify measurement conditions which ensure the most favorable performance for magnesium ion-selective electrodes. The relationship between the molar lipophilic anion...
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General concept of reduction process for big data obtained by interferometric methods
PublikacjaInterferometric sonar systems apply the phase content of the sonar signal to measure the angle of a wave front returned from the seafloor or from a target. It collect a big data – datasets that are so large or complex that traditional data processing application software is inadequate to deal with them. The recording a large number of data is associated with the difficulty of their efficient use. So data have to be reduced. The main...
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Objective relaxation algorithm for reliable simulation-driven size reduction of antenna structure
PublikacjaThis letter investigates reliable size reduction of antennas through electromagnetic-driven optimization. It is demonstrated that conventional formulation of the design task by direct footprint miniaturization with imposing constraints on electrical performance parameters may not lead to optimum results. The reason is that—in a typical antenna structure—only a few geometry parameters explicitly determine the antenna footprint,...
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Solid-Contact Ion-Selective Electrodes with Highly SelectiveThioamide Derivatives of p-tert-Butylcalix[4]arene for theDetermination of Lead(II) in Environmental Samples
PublikacjaThioamide derivatives of p-tert-butylcalix[4]arene were used as ionophores in the development of solid-contact ion-selective electrodes based on conducting polymer poly(3,4-ethylenedioxythiophene)/polystyrene sulfonate (PEDOT/PSS) which was synthesized by electrodeposition on the glassy carbon electrodes. The typical ion-selective membranes with optionally two different plasticizers [bis(2-ethylhexyl)sebacate (DOS) and 2-nitrophenyl...
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The Influence of Articular Cartilage Thickness Reduction on Meniscus Biomechanics
PublikacjaObjective Evaluation of the biomechanical interaction between meniscus and cartilage in medial compartment knee osteoarthritis. Methods The finite element method was used to simulate knee joint contact mechanics. Three knee models were created on the basis of knee geometry from the Open Knee project. We reduced the thickness of medial cartilages in the intact knee model by approximately 50% to obtain a medial knee osteoarthritis...
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From ashes to porous hierarchical nanocarbon electrode: Upcycling secondary waste materials through self-catalytic chemical vapour deposition
PublikacjaMetal and metal oxide particles are abundant in various ash-based wastes. Utilizing these as catalyst sources for the fabrication of carbon nanomaterials could present a valuable approach to reduce our reliance on non-renewable and costly catalyst sources, thereby facilitating large-scale nanomaterial production. In this context, secondary waste materials (SWMs) are by-products resulting from the (complete or partial) combustion...
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Size-Reduction-Oriented Design of Compact CPW-Fed UWB Monopole Antenna
PublikacjaA structure and design optimization of compact CPW-fed UWB monopole antenna is presented. Explicit size reduction through constrained numerical optimization of all relevant geometry parameters of the structure leads to a very small footprint of only 321 mm2. At the same time, a very wide antenna bandwidth is achieved from 3.1 GHz to 17 GHz.
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Design of High-Performance Scattering Metasurfaces through Optimization-Based Explicit RCS Reduction
PublikacjaThe recent advances in the development of coding metasurfaces created new opportunities in realization of radar cross section (RCS) reduction. Metasurfaces, composed of optimized geometries of meta-atoms arranged as periodic lattices, are devised to obtain desired electromagnetic (EM) scattering characteristics. Despite potential benefits, their rigorous design methodologies are still lacking, especially in the context of controlling...
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Energy losses reduction in the medium voltage cable line – case study
PublikacjaThe paper presents an analysis of energy losses in a power cable system, which is composed of two 30 kV cable lines. This cable system is located at the seaside holiday area, so the load profile during a year is specific. Energy losses related to reactive power transmission, as well as to currents induced in the sheaths of the cables, are subject to analysis. Measurements were made in the system in order to prepare a computer model...
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Evolutionary sets of safe ship trajectories with speed reduction manoeuvres within traffic separation schemes
PublikacjaIn the previous paper the author presented the evolutionary ship trajectory planning method designed to support Traffic Separation Schemes (TSS). This time the extensions of this method are described which allow to combine evolutionary trajectory planning with speed reduction manoeuvres. On TSS regions with higher than usual density of traffic and smaller distances between ships, the course alterations alone are not always sufficient...
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THE INFLUENCE OF POLYMER STRIPS IN REDUCTION OF A STEEL GRANDSTAND VIBRATIONS
PublikacjaGrandstands are types of structures commonly used during sport events or music concerts. Dynamic loads generated by crowd movement may have significant influence on human perception as well as may lead to the destruction of a structure. Lighter and more slender structural steel members are more easily excitable by spectators. If the synchronized movement is tuned with the natural frequency of the affected part of the structure,...
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Frequency Selective Surface Based MIMO Antenna Array for 5G Millimeter-Wave Applications
PublikacjaAbstract: In this paper a radiating element consisting of a modified circular patch is proposed for MIMO arrays for 5G millimeter-wave applications. The radiating elements in the proposed 2×2 MIMO antenna array are orthogonally configured relative to each other to mitigate mutual coupling that would otherwise degrade the performance of the MIMO system. The MIMO array was fabri-cated on Rogers RT/Duroid high frequency substrate...
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Light-Dependent Protochlorophyllide Oxidoreductase: Phylogeny, Regulation, and Catalytic Properties
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Physicochemical and catalytic properties of ployaniline protonated with 12-molybdophosphoric acid
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The influence of synthesis method on the microstructure and catalytic performance of Y 0.07 Sr 0.93 Ti 0.8 Fe 0.2 O 3-δ in synthetic biogas operated solid oxide fuel cells
PublikacjaThe Y0.07Sr0.93Ti0.8Fe0.2O3-δ (YSTF) material was fabricated using three different synthesis methods: modified polymer precursor method (MPP), Pechini method and a solid state reaction method. It was applied as an anode catalytic material for biogas reforming in solid oxide fuel cells. Clear differences in the microstructure of fabricated catalytic layers were found, mainly with respect to a grain size and distribution of grains....
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Design space reduction and variable-fidelity EM simulations for feasible Pareto optimization of antennas
PublikacjaA computationally efficient procedure for multi-objective optimization of antenna structures is presented. In our approach, a response surface approximation (RSA) model created from sampled coarse-discretization EM antenna simulations is utilized to yield an initial set of Pareto-optimal designs using a multi-objective evolutionary algorithm. The final Pareto front representation for the high-fidelity model is obtained using surrogate-based...