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Wyniki wyszukiwania dla: TRAPPED IONS

  • A Framework of a Ship Domain-based Collision Alert System

    Publikacja

    The paper presents a framework of a planned ship collision alert system. The envisaged system is compliant with IMO Resolution MSC.252 (83) “Adoption of the revised performance standards for Integrated Navigation Systems (INS)”. It is based on a ship domain-oriented approach to collision risk and introduces a policy of alerts on dangerous situations. The alerts will include cautions, warnings and alarms, which will be triggered...

  • Wielokrotność stosowania katalizatorów miedziowych podczas uwodornienia oleju sojowego i rzepakowego

    Publikacja

    Określono kinetykę i chemizm uwodornienia oleju sojowego i rzepakowego na katalizatorach miedziowych INS 1011red i G99B13, stosowanych 3-krotnie. Proces prowadzono w szklanym reaktorze laboratoryjnym, wyposażonym w układ do pomiaru ilości pochłoniętego wodoru. Stężenie katalizatorów wynosiło 1% Cu, a temperatura reakcji 200 st.C. Stwierdzono, że przy kolejnym użyciu kontaktu spada jego aktywność, powodując przedłużenie czasu reakcji,...

  • Wybrane aspekty oceny jakości produktów żywnościowych

    Przedstawiono wybrane aspekty oceny jakości produk tów żywnościo- wych: pojęcie jakości, wybrane metody oceny jakości ze szczególnym uwzględ- nieniem sztucznych potencjometrycznych sensorów sma ku składających się z szeregu elektrod typu ISE (Ion Selective Electrodes ) oraz ASSE (All Solid State Electrodes). Omówiono działanie sztucznych sensorów smaku. Przedstawiono 10 potencjometryczny sensor wprowadzony do obrotu hand lowego....

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  • Limitations of Emotion Recognition in Software User Experience Evaluation Context

    This paper concerns how an affective-behavioural- cognitive approach applies to the evaluation of the software user experience. Although it may seem that affect recognition solutions are accurate in determining the user experience, there are several challenges in practice. This paper aims to explore the limitations of the automatic affect recognition applied in the usability context as well as...

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  • Adaptacyjny system sterowania ruchem drogowym

    Publikacja

    - Rok 2024

    Adaptacyjny system sterowania ruchem drogowym to rodzaj systemu sterowania, który dynamicznie, w czasie rzeczywistym, dostosowuje swoje parametry w oparciu o bieżące warunki ruchu drogowego. Celem niniejszej rozprawy jest sprawdzenie wpływu wybranych cech systemu, zbudowanego w oparciu o zaprojektowane i zbudowane z udziałem autora inteligentne znaki drogowe, na wybrane parametry mające wpływ na bezpieczeństwo i płynność ruchu....

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  • Green and Sustainable Membranes: A review

    Publikacja
    • N. Rabiee
    • R. Sharma
    • S. Foorginezhad
    • M. Jouyandeh
    • M. Asadnia
    • M. Rabiee
    • O. Akhavan
    • E. C. Lima
    • K. Formela
    • M. Ashrafizadeh... i 4 innych

    - ENVIRONMENTAL RESEARCH - Rok 2023

    Membranes are ubiquitous tools for modern water treatment technology that critically eliminate hazardous materials such as organic, inorganic, heavy metals, and biomedical pollutants. Nowadays, nano-membranes are of particular interest for myriad applications such as water treatment, desalination, ion exchange, ion concentration control, and several kinds of biomedical applications. However, this state-of-the-art technology suffers...

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  • Bias-Dependent Dynamics of Degradation and Recovery in Perovskite Solar Cells

    Publikacja
    • M. Prete
    • M. V. Khenkin
    • D. Głowienka
    • B. R. Patil
    • J. S. Lissau
    • I. Dogan
    • J. Hansen
    • T. Leißner
    • J. Fiutowski
    • H. Rubahn... i 6 innych

    - ACS Applied Energy Materials - Rok 2021

    Degradation of perovskite solar cells (PSCs) is often found to be partially or fully reversible when the cells are allowed to recover in the dark. Unlike the dynamics of degradation, knowledge about the dynamics of PSC cell recovery is very limited. Here, we demonstrate that the PSC recovery strongly depends on the electrical bias conditions during the light-induced degradation and that it can be manipulated by applying an external...

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  • Nanodiamonds Doped with Manganese for Applications in Magnetic Resonance Imaging

    Publikacja
    • S. Kunuku
    • B. Lin
    • C. Chen
    • C. Chang
    • T. Chen
    • T. Hsiao
    • H. Yu
    • Y. Chang
    • L. Liao
    • F. Chen... i 2 innych

    - ACS Omega - Rok 2023

    Nanodiamonds (NDs) are emerging with great potential in biomedical applications like biomarking through fluorescence and magnetic resonance imaging (MRI), targeted drug delivery, and cancer therapy. The magnetic and optical properties of NDs could be tuned by selective doping. Therefore, we report multifunctional manganese-incorporated NDs (Mn-NDs) fabricated by Mn ion implantation. The fluorescent properties of Mn-NDs were tuned...

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  • Finding the Right Solvent: A Novel Screening Protocol for Identifying Environmentally Friendly and Cost-Effective Options for Benzenesulfonamide

    Publikacja

    - MOLECULES - Rok 2023

    This study investigated the solubility of benzenesulfonamide (BSA) as a model compound using experimental and computational methods. New experimental solubility data were collected in the solvents DMSO, DMF, 4FM, and their binary mixtures with water. The predictive model was constructed based on the best-performing regression models trained on available experimental data, and their hyperparameters were optimized using a newly...

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  • E-Technologies in Teaching Research Methodology for Engineers – a Case Study of the Course for International Postgraduate Students

    The Research Methodology course for postgraduate students is challenging, even for an experienced academic teacher. The primary objective of this course is to prepare participants to conduct scientific research and publish the results. This case study presents an original teaching method applied to Research Methodology with Emphasis on Engineering Science, for international engineering students at...

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  • Kompleksowa analiza symulacyjna układu napędowego zespołu trakcyjnego

    Publikacja

    - Czasopismo Techniczne - Rok 2011

    The paper describes an approach to comprehensive analysis of traction electric drive. The drivetrain of ED-74 electric unit equipped with four inverter-fed induction motors was modeled in Matlab/Simulink. The model consists of functional blocks as: motors, inverters, drive controllers, filters. Structure and operation of the model was described. Chosen simulation results were presented and discussed. Two methods of modeling the...

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  • Experimental study on the behaviour of steel columns under seismic-induced axial impact load

    Publikacja

    - Rok 2010

    It has been observed during major earthquakes that the so called soft-storey failure of an upper floor of a structure results in large impact load acting on structural members of the lower storeys. It may further lead to progressive collapse of the whole structure substantially intensifying human and material losses. Therefore, the aim of this paper is to investigate experimentally the behaviour of columns under bending (observed...

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  • Comparison of Selected Neural Network Models Used for Automatic Liver Tumor Segmentation

    Publikacja

    Automatic and accurate segmentation of liver tumors is crucial for the diagnosis and treatment of hepatocellular carcinoma or metastases. However, the task remains challenging due to imprecise boundaries and significant variations in the shape, size, and location of tumors. The present study focuses on tumor segmentation as a more critical aspect from a medical perspective, compared to liver parenchyma segmentation, which is the...

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  • Automatic audio signal mixing system based on one-dimensional Wave-U-Net autoencoders

    Publikacja

    - Rok 2023

    The purpose of this dissertation is to develop an automatic song mixing system that is capable of automatically mixing a song with good quality in any music genre. This work recalls first the audio signal processing methods used in audio mixing, and it describes selected methods for automatic audio mixing. Then, a novel architecture built based on one-dimensional Wave-U-Net autoencoders is proposed for automatic music mixing. Models...

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  • The passive operating mode of the linear optical gesture sensor

    The study evaluates the influence of natural light conditions on the effectiveness of the linear optical gesture sensor, working in the presence of ambient light only (passive mode). The orientations of the device in reference to the light source were modified in order to verify the sensitivity of the sensor. A criterion for the differentiation between two states - "possible gesture" and "no gesture" - was proposed. Additionally,...

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  • Applying molecular dynamics simulation to take the fracture fingerprint of polycrystalline SiC nanosheets

    Publikacja
    • F. Molaei
    • M. Zarghami Dehaghani
    • A. Salmankhani
    • S. Fooladpanjeh
    • S. M. Sajadi
    • M. Esmaeili Safa
    • O. Abida
    • S. Habibzadeh
    • A. Hamed Mashhadzadeh
    • M. Saeb

    - COMPUTATIONAL MATERIALS SCIENCE - Rok 2021

    Graphene-like nanosheets are the key elements of advanced materials and systems. The mechanical behavior of the structurally perfect 2D nanostructures is well documented, but that of polycrystalline ones is less understood. Herein, we applied molecular dynamics simulation (MDS) to take the fracture fingerprint of polycrystalline SiC nanosheets (PSiCNS), where monocrystalline SiC nanosheets (MSiCNS) was the reference nanosheet....

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  • Information Extraction from Polish Radiology Reports using Language Models

    Publikacja

    Radiology reports are vital elements of directing patient care. They are usually delivered in free text form, which makes them prone to errors, such as omission in reporting radiological findings and using difficult-to-comprehend mental shortcuts. Although structured reporting is the recommended method, its adoption continues to be limited. Radiologists find structured reports too limiting and burdensome. In this paper, we propose...

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  • Labeler-hot Detection of EEG Epileptic Transients

    Publikacja

    - Rok 2019

    Preventing early progression of epilepsy and sothe severity of seizures requires effective diagnosis. Epileptictransients indicate the ability to develop seizures but humansoverlook such brief events in an electroencephalogram (EEG)what compromises patient treatment. Traditionally, trainingof the EEG event detection algorithms has relied on groundtruth labels, obtained from the consensus...

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  • Recovering Evaluation of Narrow-Kerf Teeth of Mini Sash Gang Saws

    Publikacja

    - Materials - Rok 2021

    Sash gang saws with narrow-kerf saw blades are used in the production of glued laminate flooring elements in plants where dry technology is applied. This means that boards or friezes are sawn into top layer lamellae in dry conditions (moisture content of about 10–12%) from expensive wood species, often exotic. The object of this research was stellite-tipped teeth of narrow kerf saw blades sharpened under industrial conditions....

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  • Real estate investment trusts in Turkey: Structure, analysis, and strategy

    Publikacja

    - Journal of Business, Economics and Finance - Rok 2017

    Purpose-Aim of this study is to make the determinations related to the problems mentioned in the REIT sector in Turkey, to offer a solution for this issue, and to ensure the classification in the sector by adhering to the financial data of the REITsMethodology-Financial data set of the REITs was firstly standardized by using median instead of mean. Then, the scoring was performed according to defined coefficients....

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  • Synthesis and properties of new 'N,'N-phenyltetrazole podand

    Publikacja

    - CHEMICAL PAPERS - Rok 2016

    The synthesis of a new chromogenic N,N-phenyltetrazole receptor is reported here. The cationbinding properties of this receptor in solution were investigated by naked-eye colour change, electrochemical methods and UV-Vis spectroscopy in various solvents (CH3CN, dimethylsulphoxide (DMSO), DMSO/H2O, CH3CN/H2O and CH3CN/MeOH). In addition, the receptor was used as a sensing material in ion-selective membrane electrodes. The selectivity...

  • Imidazolium silanethiolates relevant to the active site of cysteineproteases. A cooperative effect in a chain of NH(+)...S(-) hydrogenbonds

    Three imidazolium silanethiolates relevant to the active site of cysteine proteases have been synthesized and investigated by X-ray diffraction, IR spectroscopy and computational methods. As indicated by crystallographic and FT-IR data in the solid state, the transfer of proton from thiol to imidazole takes place and a thiolato-imidazolium ion pair is formed. The FT-IR spectra of crystalline imidazolium silanethiolates exhibit...

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  • Architektura rozproszonego systemu udostępniającego wyniki numerycznych prognoz pogody

    W artykule przedstawiono architekturę systemu udostępniania wyników numerycznych prognoz pogody do którego należą m.in. serwer, portal internetowy oraz mobilne aplikacje klienckie, które wizualizują na różne sposoby dane pogodowe pobrane z serwera. Oprogramowanie mobilne przeznaczone jest na najpopularniejsze platformy mobilne, czyli iOS (min. iPhone, iPad, iPod) oraz Android. Prototyp systemu funkcjonuje operacyjnie w ramach...

  • Influence of Operation Conditions on Temperature Hazard of Lithium-Iron-Phosphate (LiFePO4) Cells

    Publikacja
    • W. Kurpiel
    • B. Polnik
    • Ł. Orzech
    • K. Lesiak
    • B. Miedziński
    • M. Habrych
    • G. Debita
    • M. Zamłyńska
    • P. Falkowski-Gilski

    - ENERGIES - Rok 2021

    The article presents and discusses the results of research on hazard, especially temperature, for selected lithium-ion-phosphate cells operated in accordance with the manufacturer’s recommendations but used under onerous mining conditions. This applies to the performance of cells in battery sets without the application of any management system (BMS). On the basis of the obtained test results, first of all, the influence of the...

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  • 9 - Solid oxide fuel and electrolysis cells

    Publikacja
    • C. Lenser
    • D. Udomsilp
    • N. Menzler
    • P. Holtappels
    • T. Fujisaki
    • L. Kwati
    • H. Matsumoto
    • A. Sabato
    • F. Smeacetto
    • A. Chrysanthou
    • S. Molin

    - Rok 2019

    In this chapter, the fundamental reactions, the geometrical designs, the material requirements, and the status of SOFCs and SOECs are presented. In the following seven chapters, the most important components of an SOC are described and the chapter ends with a summary and outlook. The described components are: (i) oxygen-ion conductors (electrolyte), (ii) anode materials for SOFCs (cathode in SOEC mode), (iii) cathode materials...

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  • Iron(III)-selective materials based on a catechol-bearing amide for optical sensing

    The synthesis and ion-binding properties of a new amide L derived from 3,4-dihydroxybenzoic acid are described. Due to the presence of a catechol unit, the compound interacts selectively with iron(III) in organic solvent (dimethyl sulfoxide, DMSO) to produce a color change from pale yellow to green. The incorporation of the ligand L into polymeric matrices or its encapsulation into surfactant-based spheres enables analyte detection...

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  • Analogues of trypsin inhibitor SFTI-1 modified in the conserved P1′ position by synthetic or non-proteinogenic amino acids retain their inhibitory activity

    Publikacja
    • Ł. Rafał
    • Ł. Anna
    • W. Magdalena
    • D. Dawid
    • L. Adam
    • R. Krzysztof
    • A. Lesner

    - JOURNAL OF PEPTIDE SCIENCE - Rok 2011

    A series of linear and monocyclic (with a disulfide bridge only) analogues of trypsin inhibitor SFTI-1 modified in the P-1 and/or P-1' positions were synthesized by the solid-phase method. In the substrate specificity P-1 position, Phe or N-benzylglycine (Nphe) were introduced, whereas the conserved Ser6 in Bownam-Birk (BBI) inhibitors was replaced by Hse (L-homoserine), Nhse [N-(2-hydroxyethyl)glycine], Sar, and Ala. Kinetic studies...

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  • Designing drainage systems – possible application of advanced calculations and hydrodynamical modeling

    Publikacja

    - Rok 2015

    Nowadays we can observe a faster development of drainage systems than ever. This gives us an opportunity to de- sign more efficient systems that can cope with the rapid growth of cities and, what comes with it, impervious surfaces. Here the question arises, whether traditional methods used in drainage system design are potent enough to cope with the emerging prob- lems and difficulties. In this paper we will make...

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  • Design of a Distributed System using Mobile Devices and Workflow Management for Measurement and Control of a Smart Home and Health

    Publikacja

    - Rok 2013

    The paper presents design of a distributed system for measurements and control of a smart home including temper- atures, light, fire danger, health problems of inhabitants such as increased body temperature, a person falling etc. This is done by integration of mobile devices and standards, distributed service based middleware BeesyCluster and a workflow management system. Mobile devices are used to measure the parameters and are...

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  • Toward Safe and Efficient Recovery of Gas Munitions Dumped at Sea

    Publikacja

    - Polish Maritime Research - Rok 2023

    The proposal of a system for the safe recovery of unexploded ordnance (UXO), chemical weapons (CW) and chemicalwarfare agents (CWA) dumped at sea mainly after WWI and WWII is described in this work. The proposed solutionaddresses the tasks required to neutralise thousands of tons of dumped material and the currently available solutionsand proposed ideas. Requirements concerning the features of a recovery system are defined and...

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  • Magnetoacoustic Heating of Plasma Caused by Periodic MagnetosoundPerturbations with Discontinuities in a Quasi-Isentropic Magnetic Gas

    Publikacja

    The magnetoacoustic heating of plasma by harmonic or periodic saw-tooth perturbations at a trans-ducer is theoretically studied. The planar fast and slow magnetosound waves are considered. The wavevector may form an arbitrary angleθwith the equilibrium straight magnetic field. In view of variableθand plasma-β, the description of magnetosound perturbations and appropriate magnetosound heatingis fairly difficult. The scenario of...

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  • Solubility of carbon dioxide in water: Some useful results for hydrate nucleation

    Publikacja
    • J. Algaba
    • I. M. Zerón
    • J. M. Míguez
    • J. Grabowska
    • S. Blazquez
    • E. Sanz
    • C. Vega
    • F. J. Blas

    - JOURNAL OF CHEMICAL PHYSICS - Rok 2023

    In this paper, the solubility of carbon dioxide (CO2) in water along the isobar of 400 bar is determined by computer simulations using the well-known TIP4P/Ice force field for water and the TraPPE model for CO2. In particular, the solubility of CO2 in water when in contact with the CO2 liquid phase and the solubility of CO2 in water when in contact with the hydrate have been determined. The solubility of CO2 in a liquid–liquid...

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  • Innowacje jako przedmiot obrotu rynkowego

    W artykule podjęto problem cech innowacji jako produktów, które na świecie, coraz częściej również w Polsce, stają się przedmiotem obrotu rynkowego. Różnią się zdecydowanie od produktów, oferowanych przez przedsiębiorstwa produkcyjno-usługowe na rynkach dóbr konsumpcyjnych, także gotowych dóbr przemysłowych. Kluczowe różnice wynikają z tego, że innowacja może być produktem - przedmiotem obrotu rynkowego już jako idea i koncepcja,...

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  • Ionization and fragmentation of furan molecules by electron collisions

    Cation mass spectra obtained by electron impact were measured to investigate the ionization and ionic fragmentation of furan, C4H4O, molecules in the gas phase. The most abundant cations, with comparable intensities in the mass spectra, were the parent, C4H4O+, cation (68 amu) and the C3H3+ fragment (39 amu). The appearance energies of most of the observed ionic fragments were determined and the possible fragmentation processes...

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  • Monitoring Trends of Land Use and Land Cover Changes in Rajang River Basin

    Publikacja

    - Rok 2021

    In this study, the spatiotemporal changes in land use and land cover (LULC) were evaluated from 1992 to 2015 for the Rajang River Basin (RRB) located in the Sarawak State of Malaysia. The changes in water bodies cropped lands, and forests were assessed based on the available remotely sensed satellite data. Supervised classification with the Maximum-Likelihood-Algorithm technique was adopted for monitoring the LULC changes using...

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  • Efficient algorithm for blinking LED detection dedicated to embedded systems equipped with high performance cameras

    Publikacja

    This paper presents the concept and implementation of an efficient algorithm for detection of blinking LED or similar signal sources. Algorithm is designed for embedded devices equipped with high performance cameras being a part of an indoor positioning embedded system. An algorithm to be implemented in such a system should be efficient in terms of computational power what is hard to be achieved when large amount of data from camera...

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  • Clothes Detection and Classification Using Convolutional Neural Networks

    Publikacja

    In this paper we describe development of a computer vision system for accurate detection and classification of clothes for e-commerce images. We present a set of experiments on well established architectures of convolutional neural networks, including Residual networks, SqueezeNet and Single Shot MultiBox Detector (SSD). The clothes detection network was trained and tested on DeepFashion dataset, which contains box annotations...

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  • Position Estimation in Mixed Indoor-Outdoor Environment Using Signals of Opportunity and Deep Learning Approach

    To improve the user's localization estimation in indoor and outdoor environment a novel radiolocalization system using deep learning dedicated to work both in indoor and outdoor environment is proposed. It is based on the radio signatures using radio signals of opportunity from LTE an WiFi networks. The measurements of channel state estimators from LTE network and from WiFi network are taken by using the developed application....

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  • An Intelligent Approach to Short-Term Wind Power Prediction Using Deep Neural Networks

    Publikacja

    - Journal of Artificial Intelligence and Soft Computing Research - Rok 2023

    In this paper, an intelligent approach to the Short-Term Wind Power Prediction (STWPP) problem is considered, with the use of various types of Deep Neural Networks (DNNs). The impact of the prediction time horizon length on accuracy, and the influence of temperature on prediction effectiveness have been analyzed. Three types of DNNs have been implemented and tested, including: CNN (Convolutional Neural Networks), GRU (Gated Recurrent...

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  • Semantic segmentation training using imperfect annotations and loss masking

    One of the most significant factors affecting supervised neural network training is the precision of the annotations. Also, in a case of expert group, the problem of inconsistent data annotations is an integral part of real-world supervised learning processes, well-known to researchers. One practical example is a weak ground truth delineation for medical image segmentation. In this paper, we have developed a new method of accurate...

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  • Diagnosing wind turbine condition employing a neural network to the analysis of vibroacoustic signals

    It is important from the economic point of view to detect damage early in the wind turbines before failures occur. For this purpose, a monitoring device was built that analyzes both acoustic signals acquired from the built-in non-contact acoustic intensity probe, as well as from the accelerometers, mounted on the internal devices in the nacelle. The signals collected in this way are used for long-term training of the autoencoder...

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  • Effect of Functionalization of Reduced Graphene Oxide Coatings with Nitrogen and Sulfur Groups on Their Anti-Corrosion Properties

    Publikacja

    Electrophoretic production of anticorrosion carbonaceous coatings on copper could be successfully performed by anodic oxidation of negatively charged graphene platelets suspended in an aqueous solution. The various platelets were synthesized by Hummer’s method followed by a hydrothermal reduction in the presence of NH4SCN which was expected to substitute some parts of graphene structure with nitrogen and sulfur groups. X-ray photoelectron...

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  • A review on application of artificial neural network (ANN) for performance and emission characteristics of diesel engine fueled with biodiesel-based fuels

    Publikacja
    • A. Tuan Hoang
    • S. Nižetić
    • H. Chyuan Ong
    • W. Tarełko
    • V. Viet Pham
    • T. Hieu Le
    • M. Quang Chau
    • X. Phuong Nguyen

    - Sustainable Energy Technologies and Assessments - Rok 2021

    Biodiesel has been emerging as a potential and promising biofuel for the strategy of reducing toxic emissions and improving engine performance. Computational methods aiming to offer numerical solutions were inevitable as a study methodology which was sometimes considered the only practical method. Artificial neural networks (ANN) were data-processing systems, which were used to tackle many issues in engineering and science, especially...

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  • Mobile satellite measurements in designing and exploitation of rail roads

    Publikacja

    - Rok 2016

    The article presents a summary of several years (2009-2015) of studies on the application of mobile satellite Global Navigation Satellite Systems (GNSS) measurements in the field of designing and operation of railways. These studies have been conducted by an interdisciplinary research team from the Gdansk University of Technology and the Gdynia Maritime University. Mobile satellite GNSS measurements are taken during a ride (through...

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  • Knowledge base views

    Publikacja

    - Rok 2008

    The paper introduces an extension to the NeeK language. In the current shape NeeK allows for selection of fragments of a given ontology. The selected part is automatically mapped to a database schema by Data Views implementation. Experience with a real system using Data Views has shown that the resulting database schema does not necessarily reflect the needs of the business logic of an application that uses a specific Data View....

  • Efficient Multi-Fidelity Design Optimization of Microwave Filters Using Adjoint Sensitivity

    A simple and robust algorithm for computationally efficient design optimiza-tion of microwave filters is presented. Our approach exploits a trust-region (TR)-based algorithm that utilizes linear approximation of the filter response obtained using adjoint sensitivity. The algorithm is sequentially executed on a family of electromagnetic (EM)-simulated models of different fidelities, starting from a coarse-discretization one, and...

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  • EE-ISAC—Practical Cybersecurity Solution for the Energy Sector

    Publikacja

    - ENERGIES - Rok 2022

    A recent survey of cybersecurity assessment methods proposed by the scientific community revealed that their practical adoption constitutes a great challenge. Further research that aimed at identifying the reasons for that situation demonstrated that several factors influence the applicability, including the documentation level of detail, the availability of supporting tools, and the continuity of support. This paper presents the...

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  • Spinon excitations in the quasi-one-dimensional S=12 chain compound Cs4CuSb2Cl12

    Publikacja

    - PHYSICAL REVIEW B - Rok 2020

    The spin−1/2 Heisenberg antiferromagnetic chain is ideal for realizing one of the simplest gapless quantum spin liquids (QSLs), supporting a many-body ground state whose elementary excitations are fractional fermionic excitations called spinons. Here we report the discovery of such a one-dimensional (1D) QSL in Cs4CuSb2Cl12. Compared to previously reported S=1/2 1D chains, this material possesses a wider temperature range over...

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  • The role of organic and mineral constituents on kerogen transformation ratio

    Publikacja

    - Rok 2015

    The main aim of this dissertation is to determine the role of mineral and organic matter constituents in kerogen transformation ratio. Practical aspects of the work include application of the results in the assessment of hydrocarbon production potential; to make process of hydrocarbon recovery more predictable consistent and efficient. The work used shale from the Vaca Muerta formation from the Nequen basin in Argentina. The formation...

  • Crystal and electronic structures of Ni(II) silanethiolates containing flexible diamine ligands

    Publikacja

    Five nickel(II) complexes containing aliphatic diamines and tri-tert-butoxysilanethiolate ligand have been synthesized for the purpose of studying their structural, spectral (IR, UV–Vis, HF EPR) and thermal properties. Complexes (1)–(5) have been prepared in high yield by reactions of [Ni{SSi(OtBu)3}2(NH3)(H2O)] with 1.3-propanediamine (L1), 1,6-hexanediamine (L2), or 1,7-heptanediamine (L3). The X-ray structures were determined...

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