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Effect of coarse grain aggregate on strength parameters of two-stage concrete
Publikacja. Two-stage concrete (TSC) is a special type of concrete that the method of its construction and implementation is different from conventional one. In TSC, coarse aggregate particles are first placed in the formwork and voids between them are subsequently injected with a special cementations mixture. TSC has been successfully used in many applications, such as underwater construction, casting concrete sections congested with reinforcement...
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A new tool for the evaluation of the analytical procedure: Green Analytical Procedure Index
PublikacjaA new means for assessing analytical protocols relating to green analytical chemistry attributes has been developed. The new tool, called GAPI (Green Analytical Procedure Index), evaluates the green character of an entire analytical methodology, from sample collection to final determination, and was created using such tools as the National Environmental Methods Index (NEMI) or Analytical Eco-Scale to provide not only general but...
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Green Chemistry in Higher Education: State of the Art, Challenges, and Future Trends
PublikacjaNowadays, there is increasing interest in global sustainability, and thus, university students would like to know how human actions affect the health status of our planet. This is mainly due to their basic knowledge of problems such as global warming and greenhouse gases. Students would like to gain knowledge on how to safeguard the earth for future generations. This must involve changes in education programs at interested institutions...
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Pre-selection and assessment of green organic solvents by clustering chemometric tools
PublikacjaThe study presents the result of the application of chemometric tools for selection of physicochemical parameters of solvents for predicting missing variables – bioconcentration factors, water-octanol and octanol-air partitioning constants. EPI Suite software was successfully applied to predict missing values for solvents commonly considered as “green”. Values for logBCF, logKOW and logKOA were modelled for 43 rather nonpolar solvents...
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Bioassays as one of the Green Chemistry tools for assessing environmental quality: A review
PublikacjaFor centuries, mankind has contributed to irreversible environmental changes, but due to the modern science of recent decades, scientists are able to assess the scale of this impact. The introduction of laws and standards to ensure environmental cleanliness requires comprehensive environmental monitoring, which should also meet the requirements of Green Chemistry. The broad spectrum of Green Chemistry principle applications should...
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Green aspects of techniques for the determination of currently used pesticides in environmental samples
PublikacjaPesticides are among the most dangerous environmental pollutants because of their stability, mobility and long-term effects on living organisms. Their presence in the environment is a particular danger. It is therefore crucial to monitor pesticide residues using all available analytical methods. The analysis of environmental samples for the presence of pesticides is very difficult: the processes involved in sample preparation are...
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Packing [1,Delta]-factors in graphs of small degree
PublikacjaRozważano problem znalezienia w grafie zadanej liczby k krawędziowo rozłącznych [1,Delta]-faktorów, gdzie Delta oznacza stopień grafu. Problem ten można rozwiązać w czasie liniowym dla k=2, jest on jednak NP-trudny dla każdego k>=3. Pokazano, że wariant minimalizacjny problemu dla k=2 jest NP-trudny dla grafów planarnych podkubicznych, jednak w ogólności istnieje algorytm (42 Delta - 30) / (35 Delta - 21) - aproksymacyjny.
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Role of composite cathodes in single chamber SOFC.
PublikacjaZbadano wpływ składu katody na napięcie oraz wydajność ogniw paliwowych pracujących w konfiguracji jednokomorowej. W związku z tym, że takie ogniwo pracuje w mieszanienie powietrza i paliwa, napięcie jest określone przez różnice aktywności katalitycznej anody i katody. Typowy cermet na bazie niklu oraz związki perovskitów pracują dobrze odpowiednio jako anoda i katoda. Jednakże perowskity mają również właściwości katalityczne,...
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Interaction of HLA-DRB1 Alleles with CTLA-4 in the Predisposition to Graves' Disease: The Impact of DRB1*07
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Geometrically Nonlinear Analysis of Functionally Graded Shells Based on 2-D Cosserat Constitutive Model
PublikacjaIn this paper geometrically nonlinear analysis of functionally graded shells in 6-parameter shell theory is presented. It is assumed that the shell consists of two constituents: ceramic and metal. The mechanical properties are graded through the thickness and are described by power law distribution. Formulation based on 2-D Cosserat constitutive model is used to derive constitutive relation for functionally graded shells. Numerical...
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Modelowanie problemów strażniczych jako grafów dynamicznych - przykładowy sposób analizy skuteczności systemów strażniczych
PublikacjaW problemach strażniczych rozważamy przestrzeń (graf), w której znajduje się intruz i pewna liczba agentów przechwytujących, zaś celem większości algorytmów jest jak najszybsze przechwycenie intruza lub też uniknięcie przez niego detekcji.Zaprezentowany model pozwala na praktyczne rozważanie problemów z życia wziętych przez matematyczne przedstawienie różnorodnych agentów przechwytujących (kamery mobilne i stacjonarne, strażnicy...
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Nonlocal elasticity analysis of moderately thick porous functionally graded plates in a hygro-thermal environment
PublikacjaThis work performs a novel quasi three-dimensional (3D) bending analysis for a moderately thick functionally graded material (FGM) made of nanoceramics and metal powders, in presence of porosities due to some incorrect manufacturing processes. Such porosities can appear within the plate in two forms, namely, even and uneven distributions. The modeled system assumes a polymer matrix where both shear and transverse factors coexist....
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Edge ranking and searching in partial orders
PublikacjaArtykuł jest poświęcony problemowi konstrukcji optymalnej (wymagającej minimalnej ilości porównań/zapytań) strategii wyszukiwania elementu w częściowym porządku. W pracy wskazano związki pomiędzy tym problemem oraz uporządkowanym kolorowaniem krawędzi grafów, co implikuje liniowy algorytm dla częściowych porządków o strukturze drzewa. Pokazano również, że znalezienie optymalnej strategii jest problemem obliczeniowo trudnym dla...
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Efficient list cost coloring of vertices and/or edges of some sparse graphs
PublikacjaRozważane jest kolorowanie wierzchołków i krawędzi grafów w modelach klasycznym, totalnym i pseudototalnym z uwzględnieniem dodatkowego ograniczenia w postaci list dostępnych kolorów. Proponujemy wielomianowy algorytm oparty na paradygmacie programowania dynamicznego dla grafów o strukturze drzewa. Wynik ten można uogólnić na grafy o liczbie cyklomatycznej ograniczonej z góry przez dowolnie wybraną stała.
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Energy optimisation in resilient self-stabilizing processes
PublikacjaW pracy rozważa się rozproszony model obliczeń, w którym struktura systemu jest reprezentowana przez graf bezpośrednich połączeń komunikacyjnych. W tym modelu podajemy nowy samostabilizujący algorytm kolorowania grafów oparty na konstrukcji drzewa spinającego. Zgodnie z naszą wiedzą jest to pierwszy algorytm z gwarantowaną wielomianową liczbą ruchów, który dokładnie koloruje grafy dwudzielne.
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Self-Organization of Graft Copolymers and Retortable iPP-Based Nanoporous Films Thereof
PublikacjaPolyolefins might become inexpensive alternatives to the existing membranes based on polyethersulfone. Here we disclose the production of retortable, well-defined PP-based nanoporous membranes derived from amphiphilic graft copolymer precursors. The graft copolymers, containing a polypropylene backbone and polyester grafts, were obtained by grafting lactones, specifically δ-valerolactone and ε-caprolactone, from well-defined randomly...
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Bilans ekonomiczny produkcji biopaliwa rzepakowego (biodiesla) w indywidualnym gospodarstwie rolnym
PublikacjaEstry metylowe oleju rzepakowego (ang. RME - Rapeseed Methyl Esters), znane szerzej jako biopaliwo rzepakowe lub biodiesel są alternatywnym paliwem służącym do zasilania silników z zapłonem samoczynnym (silników Diesla). Uzyskuje się je w wyniku reakcji transestryfikacji oleju rzepakowego za pomocą metanolu w obecności alkalicznego katalizatora, czego wynikiem jest mieszanina, rozdzielająca się po pewnym czasie na warstwę estrową...
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Self-stabilizing algorithm for edge-coloring of graphs
PublikacjaReferat ten poświęcony jest kolorowaniu grafów w modelu rozproszonym.Podano samostabilizujący się algorytm kolorowania krawędzi grafu wraz z dowodem poprawności oraz oszacowaniem jego czasu działania.
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Green tea protects against ethanol-induced lipid peroxidation in rat organs
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Green Tea Protection Against Age-Dependent Ethanol-Induced Oxidative Stress
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Uptake, tissue distribution, and metabolism of malachite green in the channel catfish (Ictalurus punctatus)
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Wheat Bread with Grape Seeds Micropowder: Impact on Dough Rheology and Bread Properties
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New Screening Protocol for Effective Green Solvents Selection of Benzamide, Salicylamide and Ethenzamide
PublikacjaNew protocol for screening efficient and environmentally friendly solvents was proposed and experimentally verified. The guidance for solvent selection comes from computed solubility via COSMO-RS approach. Furthermore, solute-solvent affinities computed using advanced quantum chemistry level were used as a rationale for observed solvents ranking. The screening protocol pointed out that 4-formylomorpholine (4FM) is an attractive...
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Green method of conversion of geraniol to value-added products in the presence of selected minerals
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A Multicriteria Analysis for the Green VRP: A Case Discussion for the Distribution Problem of a Spanish Retailer
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Effect of Sieve Unit Inclination Angle in a Rotary Cleaning Device for Barley Grain
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Effect of Grain Husk Microfibers on Physicochemical Properties of Carboxymethyl Polysaccharides-Based Composite
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Research on flue gas flow measurement and modelling in the moving grate biomass boiler
PublikacjaThe aim of this research was to determine the nature of gas flow in a grate boiler model by the method of Particle Image Velocimetry (PIV) and CFD. The paper presents the comparison of the PIV results with numerical simulations made in the environment of ANSYS Fluent. The main goal of the experiment was to describe the phenomena occurring on the grate. Methodology of modelling solid fuel combustion on the moving grate was proposed...
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A Green Chemistry "environmentally friendly" approach to the synthesis of chloro-intermediates of ephedrine/pseudoephedrine
PublikacjaMethylamphetamine is an addictive stimulant drug that strongly activates certain systems in the brain. It is closely related chemically to amphetamine, but the central nervous system effects of methamphetamine are greater. There is much interest in methylamphetamine among scientists and therefore the synthesizes of methylamphetamine and its metabolites are carried out on a large scale in chemical laboratories. Globally, ephedrine...
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Green engineered biomaterials for bone repair and regeneration: Printing technologies and fracture analysis
PublikacjaDespite the exceptional self-regeneration properties of bone, severe injuries often require additional surgical intervention such as using artificial bone constructs. These structures need to meet a number of criteria regarding their structure, performance, alongside the rate and the mechanism of erosion and fracture when implanted, for stimulating the regeneration of defected bone and, more critically providing support in the...
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Efficient Extraction of Fermentation Inhibitors by Means of Green Hydrophobic Deep Eutectic Solvents
PublikacjaThe methods for hydrogen yield efficiency improvements, the gaseous stream purification in gaseous biofuels generation, and the biomass pretreatment are considered as the main trends in research devoted to gaseous biofuel production. The environmental aspect related to the liquid stream purification arises. Moreover, the management of post-fermentation broth with the application of various biorefining techniques gains importance....
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Enhanced aging resistance of poly(ε-caprolactone)/brewers’ spent grain composites
PublikacjaThe presented paper investigated the influence of brewers’ spent grain (BSG) extrusion pa-rameters on the photo-oxidative resistance of poly(ε-caprolactone)-based wood polymer composites. Filler samples characterized by the higher melanoidin content were more efficient in hindering of poly-mer degradation, inhibiting the decomposition of the polymer amorphous phase. As aresult, deteriora-tion of mechanical performance was limited,...
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Grafo-mania, czyli rzecz o grafach i algorytmach. Liczby Ramseya
PublikacjaZdefiniowano liczby Ramseya i wskazano na trudności obliczeniowe ich wyznaczania już przy niewielkich wartościach takich liczb.
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Grafo-ania, czyli rzecz o grafach i algorytmach. Drzewa Steinera
PublikacjaProblem: na płaszczyźnie leżą 3 punkty. Znajdź czwarty, taki że jego sumaryczna odległość od 3 pozostałych jest minimalna, Pokazujemy jak rozwiązać ten problem i jego uogólnienie.
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Structurally well-defined functionalized polyolefins and graft copolymers thereof as bitumen modifiers
PublikacjaHere we demonstrate the application of hydroxyl-functionalized propylene-based copolymers, poly(propylene-co-1-hexene-co-10-undecen-1-ol) (FPP) and poly(styrene-co-maleic anhydride) (SMA) graft copolymers derived thereof, poly(propylene-co-1- hexene-graft-styrene-co-maleic anhydride) (FPP-g-SMA) as bitumen modifiers. The FPP samples were synthesized via solution copolymerization, while FPP-g-SMA products were obtained via transesterification...
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Application of multivariate statistics in assessment of green analytical chemistry parameters of analytical methodologies
PublikacjaThe study offers a multivariate statistical analysis of a dataset, including the major metrological, “greenness” and methodological parameters of 43 analytical methodologies applied for aldrin determination (a frequently analyzed organic compound) in water samples. The variables (parameters) chosen were as follows: metrological (LOD, recovery, RSD), describing the “greenness” (amount of the solvent used, amount of waste generated)...
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Coffee Silverskin as a Multifunctional Waste Filler for High-Density Polyethylene Green Composites
PublikacjaThis work aims to describe the coffee silverskin effect as a lignocellulosic waste filler for high-density polyethylene (HDPE) composites development. The main task was to determine various modification effects resulting from the complex chemical composition of coffee silverskin containing compounds with potential antioxidative properties, including caffeine, polyphenols, tannins, or melanoidins. The processing, thermal, physicochemical,...
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Locust bean gum as green and water-soluble binder for LiFePO4 and Li4Ti5O12 electrodes
PublikacjaLocust Bean Gum (LBG, carob bean gum) was investigated as an environmentally friendly, natural, and water-soluble binder for cathode (LFP) and anode (LTO) in lithium-ion batteries (Li-ion). For the frst time, we show LBG as an electrode binder and compare to those of the most popular aqueous (CMC) and conventional (PVDF) binders. The electrodes were characterized using TGA/DSC, the galvanostatic charge–discharge cycle test, cyclic...
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Functionalized nanodiamonds as a perspective green carbo-catalyst for removal of emerging organic pollutants
PublikacjaRapid industrial and urban development jointly with rising global population strongly affect the large-scale issues with drinking, groundwater, and surface water pollution. Concerns are not limited to environmental issues but also human health impact becoming serious global aspect. Organic pollution becomes a primarily serious hazard, therefore, the novel sophisticated approaches to treat them are thoroughly investigated. Among...
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Developing the Urban Blue-Green Infrastructure as a Tool for Urban Air Quality Management
PublikacjaUrban structure is an important factor that shapes the process of urban ventilation and pollution dispersion. With proper planning of the urban spatial layout, city breathability can be effectively regulated, contributing to urban air quality improvement. This paper investigates the development and current management of urban systems of green and open spaces in four Polish cities: Gda ´nsk, Warsaw, Pozna ´n and Wrocław, with a...
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Weldability of pipe grade polyethylenes as realized from thermal and mechanical properties assessments
PublikacjaSince polyethylene (PE) has been widely accepted for the production of high-pressure fluid conveying pipelines, studies devoted to weldability of PE connections were always of major importance. In this study, two industrial PE grades designed for pipe production, namely PE80 and PE100, were injection molded, cut, and then welded as PE100-PE100, PE100-PE80, and PE80-PE80. The heat-welded joints were assessed by differential scanning...
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A Panel Analysis of the Impact of Green Transformation and Globalization on the Labor Share in the National Income
PublikacjaThis study aims to examine the impact of green transition and globalization processes on changes in the labour share. The study covers 76 national economies diversified in development, global production share and energy transition stage from 2000 to 2018. Based on the Total Economy Database data, panel models of the relationship between green transition, globalization and the labour share in the national income were estimated....
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Optimization of liquid chromatographic separation of pharmaceuticals within green analytical chemistry framework
PublikacjaThe contribution is aimed at the development of methodology that allows to consider green analytical chemistry criteria during optimization of liquid chromatographic separation with design of experiment. The objectives of the optimization are maximization of peak areas of five non-steroid anti-inflammatory drugs, maximization of resolution between peaks, with simultaneous shortening of chromatographic separation time and minimization...
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Planning of the green road system as an element of spatial management in suburbs and small towns
PublikacjaThe premise for the development of sustainable forms of road infrastructure in small towns is the appropriate plan at an early stage or modifi cation in the case of existing spaces. A multi-directional approach is extremely important, which takes into account the specifi city of the regional (country) road system, availability, and capacity of traffi c network, but also social and environmental factors. Effi cient management...
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Green analytical chemistry introduction to chloropropanols determination at no economic and analytical performance costs?
PublikacjaIn this study we perform ranking of analytical procedures for 3-monochloropopane-1,2-diol determination in soy sauces with PROMETHEE method. Multicriteria decision analysis was performed for three different scenarios – metrological, economic and environmental, by application different weights to decision making criteria. All three scenarios indicate capillary electrophoresis – based procedure as the most preferable. Apart from...
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Spawalność tytanu Grade 2 na przykładzie płaszczowo-rurowego wymiennika ciepła
PublikacjaW artykule scharakteryzowano właściwości, obszary zastosowania i problemy związane ze spawalnością tytanu i jego stopów. Opracowano technologię spawania metodą TIG płaszczowo-rurowego wymiennika ciepła typu JAD B z tytanu Grade 2, zaprezentowano wyniki badań nieniszczących i niszczących złączy spawanych. Szczególną uwagę zwrócono na trudności związane z przygotowaniem krawędzi elementów do spawania i wynikające z nich niezgodności...
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Grabe J.:Recommendations of the "Committee for Waterfront Structures Harbours and Waterways" EAU 2012
PublikacjaRecenzja - Grabe J.: Recommendations of the "Committee for Waterfront Structures Harbours and Waterways" EAU 2012. Ernst & Sohn, Berlin 2015
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Highly sensitive large strain cellulose/multiwalled carbon nanotubes (MWCNTs)/thermoplastic polyurethane (TPU) nanocomposite foams: From design to performance evaluation
PublikacjaAerogel-based polymer composite foams are promising for large strain piezoresistive sensors, but their aerogel skeleton is partially destroyed during the foaming process, limiting their sensitivity. Herein, the thermoplastic polyurethane was synthesized on the aerogel skeleton to obtain cellulose/multiwalled carbon nanotubes (MWCNTs)/thermoplastic polyurethane (TPU) nanocomposite materials foamed with the aid of supercritical carbon...
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Histological evaluation of age-related variations in saphenous vein grafts used for coronary artery bypass grafting
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Microstructure and Mechanical Properties of Carboxylated Nitrile Butadiene Rubber/Epoxy/XNBR-grafted Halloysite Nanotubes Nanocomposites
PublikacjaThe effect of various amounts of carboxylated nitrile butadiene rubber (XNBR) functionalized halloysite nanotubes (XHNTs) on the cure characteristics, mechanical and swelling behavior of XNBR/epoxy compounds was experimentally and theoretically investigated. The morphology of the prepared XNBR/epoxy/XHNTs nanocomposites was imaged using scanning electron microscopy (SEM). The effects of various XNBR-grafted nanotubes on the damping...