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Niedzielny odpoczynek przed stu laty.
PublicationArtykuł ukazuje zwyczaje dotyczące pracy i odpoczynku w dni świąteczne w Gdańsku na przełomie XIX i XX wieku - jako odniesienie do przedmiotowych dyskusji w dniu dzisiejszym.
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Dla niepalących.
PublicationArtykuł przywołuje sprawy palenia papierosów w miejscach publicznych na przykładzie zdarzenia opisanego w prasie gdańskiej w r. 1921 - jako tła do odpowiedniej dyskusji prowadzonej współcześnie.
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Comparative study of operation of condensing and traditional boilers equipped with ORC module for electricity generation
PublicationThe study analyzed the operation of the "traditional" boiler equipped with the ORC module as the similar arrangement but with the condensing boiler. In the case of a conventional boiler there is noted a greater fuel consumption and the greater power generated than in the case of the unit with the condensing boiler. Postulated is the indicator in the form of a ratio of turbine power to the mass flow rate of fuel, which in turn gives...
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Cobalt(II) tri-tert-butoxysilanethiolates: in search of models for catalytic metal site of liver alcohol dehydrogenase
PublicationPrzeprowadzono syntezę trzech kompleksów: [Co{SSi(OBut)3}2(NH3)(L-pic)],[Co{SSi(OBut)3}2(NH3)2]xMeCN i [Co{SSi(OBut)3}3(H2O)][NHEt3]. Kompleksy są monomeryczne, dla nich wyznaczono strukturę krystalograficzną. Kompleks [Co{SSi(OBut)3(NH3)(L-pic)] o rdzeniu CoN2OS2 posiada dwa różne ligandy azotowe, zaś [Co{SSi(OBut)3(L-pic)] stanowi substrat do syntezy związku modelującego centrum katalityczne LADH.
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A Five-Leg Three-Level Dual-Output Inverter
PublicationClassical 3-level dual-output inverter, 3-L DOI, involves two similar 3-level inverters that provides a pair of 3-phase output voltages with same or different frequencies from common input voltage source. Flexibility of either operation of the constituting inverters is evident in this DOI; but total duplication of power switches is a major drawback. State of the art coupled 3-L DOIs reduce this drawback by providing series-shared...
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Badania doświadczalne segmentu walidacyjnego kompozytowej kładki pieszo-rowerowej
PublicationW artykule przedstawiono zakres badań zrealizowanych na segmencie walidacyjnym o długości ~3 m będącym wycinkiem docelowej kompozytowej, powłokowej kładki pieszo-rowerowej. Wykonane testy statyczne i dynamiczne pozwoliły na ocenę pracy konstrukcji i potwierdziły przyjęte na etapie projektowania założenia teoretyczne.
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One dimensional coordination polymers generated from Cd(II) tri-tert-butoxysilanethiolates and flexible aliphatic diamines.
PublicationPraca ta dotyczy chemii koordynacyjnej tri-tert-butoksysilanotiolanu kadmu(II) z diaminami alifatycznymi. Reakcja dwucentowego [Cd{SSi(OtBu)3}2]2 z poszczególnymi diaminami pozwala otrzymać pięć nowych obojętnych jednowymiarowych polimerów koordynacyjnych o różnej topologii łańcuchów [Cd{SSi(OtBu)3}2(μ-C4H12N2)(CH3OH)]n (1), [Cd{SSi(OtBu)3}2(μ-C5H14N2)(CH3OH)]n (2) [Cd{SSi(OtBu)3}2(μ-C6H16N2)(CH3OH)]n (3), [Cd{SSi(OtBu)3}2(μ-C7H18N2)]n...
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Młode Miasto Gdańsk (1380-1455) i jego patrymonium
PublicationW monografii ustalono m.in.: 1) położenie strefy osadniczej Młodego Miasta i zasięg jego patrymonium, 2) liczbę i (w miarę możliwości) lokalizację obiektów sakralnych w tym ośrodku, 3) zmiany w statusie parafialnym kościoła św Bartłomieja, 4) przemiany demograficzne ośrodka młodomiejskiego, 5) związki elity politycznej Młodego Miasta z Głównym Miastem oraz ich kontakty z Zakonem, 6) rolę portu Młodego Miasta jako ośrodka pomocniczego...
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Novel tetrahedral cobalt(II) silanethiolates: structures and magnetism
PublicationThree heteroleptic complexes of Co(II) tri-tert-butoxysilanethiolates have been synthesized with piperidine [Co{SSi(OtBu)3}2(ppd)2] 1, piperazine [Co{SSi(OtBu)3}2(NH3)]2(μ-ppz)·2CH3CN 2, and N-ethylimidazole [Co{SSi(OtBu)3}2(etim)2] 3. The complexes have been characterized by a single-crystal X-ray, revealing their tetrahedral geometry on Co(II) coordinated by two nitrogen and two sulfur atoms. Complexes 1 and 3 are mononuclear,...
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Phosphorescence response to excitonic interactions in Ir organic complex-based electrophosporescent emitters
PublicationSpadek kwantowej wydajności fosforescencji ze wzrostem natężenia światła wzbudzajacego w Ir(ppy)3 tworzącym 100% warstwę naparowaną próżniowo oraz w Ir(ppy)3 umieszczonym w matrycy polimerowej PC:TPD, jest wywołany odziaływaniami między ekscytonami trypletowymi. Stała oddziaływania tryplet-tryplet wynosi (1-3)x 10-12 cm3/s i tylko nieznacznie zależy od stężenia Ir(ppy)3 w warstwie.
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Synteza, badania strukturalne i spektroskopowe kompleksów cynku i kadmu z ligandem tris(2,6-diizopropylofenoksy)silanotiolanowym
PublicationW pracy doktorskiej przedstawiono nowy związek krzemo-siarkowy tris(2,6-diizopropylofenoksy)silanotiolanowy (TDST) zastosowany do syntezy modelowych kompleksów cynku i kadmu, które modelują bezpośrednio środowisko jonu metalu w β anhydrazie węglanowej oraz dehydrogenazie alkoholowej. Zastosowanie związku krzemo-siarkowego tris(2,6-diizopropylofenoksy)silanotiolanowy (TDST) jako liganda do syntezy modelowych kompleksów cynku i kadmu...
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Mono- and polynuclear Co(II) silanethiolates with aliphatic diamines
PublicationFour Co(II) complexes, [Co{SSi(OtBu)3}2(dmpda)] 1, [Co{SSi(OtBu)3}2(bda)2]n2 [Co{SSi(OtBu)3}2(pda)2]n3 and [Co{SSi(OtBu)3}2(hda)2]n4 [dmpda = 3-(dimethylamino)-1-propylamine; bda = 1.4-butanediamine; pda = 1.5-pentanediamine; had = 1.6-hexanediamine] have been synthesized and characterized using X-ray diffraction. Complex 1 is mononuclear and contains Co(II) coordinated by dmpda molecule in chelating mode, whereas compounds 3 and...
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Micellar aggregation of Triton X-100 surfactant in imidazolium ionic liquids
PublicationIn this work we investigated aggregation behavior of a nonionic surfactant Triton X-100 in eighteen imidazolium ionic liquids (ILs) with two to eight carbon atoms in cations alkyl chain, namely 1-ethyl-3-methylimidazolium, [EMIM], 1-butyl-3-methylimidazolium, [PrMIM], 3-methyl-1-propylimidazolium, [BMIM], 1-hexyl-3-methylimidazolium, [PMIM], 3-methyl-1-pentyl-imidazolium, [HMIM], and 1-octyl-3-methylimidazolium, [OMIM], and with...
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Przyczynek do poznania grzybów wielkoowocnikowych (macromycetes) w dawnej Puszczy Sztumskiej (województwo pomorskie).
PublicationNa obszarze dawnej Puszczy Sztumskiej wstępnie stwierdzono 85 gatunków grzybów wielkoowocnikowych (macromycetes). Jeden gatunek jest na liście grzybów wymierających, 3 gatunki są zagrożone wymarciem, 3 gatunki są rzadkie, a 3 o nieustalonym zagrożeniu. Duża różnorodność gatunkowa jest następstwem proekologicznej gospodarki leśnej oraz różnorodności siedlisk i biotopów.
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Crystal and electronic structures of Ni(II) silanethiolates containing flexible diamine ligands
PublicationFive nickel(II) complexes containing aliphatic diamines and tri-tert-butoxysilanethiolate ligand have been synthesized for the purpose of studying their structural, spectral (IR, UV–Vis, HF EPR) and thermal properties. Complexes (1)–(5) have been prepared in high yield by reactions of [Ni{SSi(OtBu)3}2(NH3)(H2O)] with 1.3-propanediamine (L1), 1,6-hexanediamine (L2), or 1,7-heptanediamine (L3). The X-ray structures were determined...
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Zn(II) and Cd(II) coordination polymers with tri-tert-butoxysilanethiol and bipyridines. Synthesis, crystal structure and spectroscopy
PublicationTrzy nowe silanotiolany cynku(II) I kadmu(II) [Zn{SSi(OtBu)3}2(μ-bpea) •CH3CN]n 1, [Cd{SSi(OtBu)3}2(μ -bpea) •2CHCl3]n 2 oraz [Cd{SSi(OtBu)3}2(μ -bpey)•C7H8]n 3 otrzymane z użyciem pochodnych bipirydylu [bpea = 1,2-bis(4-pyridyl)etan and bpey = 1,2-bis(4-pyridyl)etylen] zostały zsyntetyzowane i strutkualnie scharakteryzowane przy użyciu rentgenografii strukturalnej XRD. Ich budowa krystaliczna została dodatkowo potwierdzona przy...
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CO2 EMISSION TO THE ATMOSPHERE FROM CARBONATE WATERS: THE STUDY CASE OF THE LUBLIN UPLAND AND ROZTOCZE REGIONS
PublicationThe concentration of carbon dioxide dissolved in water (CO2(aq)) was measured in consecutive phases of the hydrological cycle. Its potentially possible degassing from groundwaters to the atmosphere was also assessed. The research was conducted in the area of occurrence of carbonate rocks of the Lublin Upland and Roztocze (SE Poland). The results of the measurements of CO2(aq) concentration varied as follows (min-max/mean): precipitation...
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Selection of Electrode Material for Inconel 617/P92 Steel SMAW Dissimilar Welds
PublicationThe present work aimed to investigate the microstructure and mechanical properties of the dissimilar shielded metal arc welded (SMAW) joint of Alloy 617 and P92 steel for advanced ultrasupercritical boilers. The SMAW joint was produced using three different types of electrodes, namely, ENiCrFe-3, ENiCrMo-3, and ENiCrCoMo-1. During microstructural observation of the welded joints, no possible cracking was detected in the weldments....
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Tight bounds on the complexity of semi-equitable coloring of cubic and subcubic graphs
PublicationWe consider the complexity of semi-equitable k-coloring, k>3, of the vertices of a cubic or subcubic graph G. In particular, we show that, given a n-vertex subcubic graph G, it is NP-complete to obtain a semi-equitable k-coloring of G whose non-equitable color class is of size s if s>n/3, and it is polynomially solvable if s, n/3.
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Monitoring of organic pollutants in coastal waters of the Gulf of Gdańsk, Southern Baltic.
PublicationPrzedstawiono zmiany zawartości zanieczyszczeń organicznych (np. VOC, PAH, PCB, chlorofenoli) w wodach Zatoki Gdańskiej na przestrzeni 5-ciu lat. Zawartość VOX i VOC zmieniała się od kilku ngdm-3 do kilkuset ngdm-3, podczas gdy zawartość chlorofenoli fenoksykwasów była na poziomie kilku ngdm-3. W większości próbek nie wykryto PCB.
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Heteroleptic tri-tert-butoxysilanethiolate complexes of manganese(II) - thermal studies
PublicationThe thermal behavior of Mn(II) silanethiolate series [Mn(SR)2L(MeOH)n], where R=SSi(OBut)3, L=heterocyclic nitrogen base and n=0, 1 or 2 has been comparatively investigated using differential scanning calorimetry (DSC), thermogravimetry (TG) and TG-infrared spectoscopy (IR) techniques. The TG curves indicate the differences in the thermal decomposition due to presence of distinct N-donor ligands and labile MeOH molecules coordinated...
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Grafo-ania, czyli rzecz o grafach i algorytmach. Drzewa Steinera
PublicationProblem: na płaszczyźnie leżą 3 punkty. Znajdź czwarty, taki że jego sumaryczna odległość od 3 pozostałych jest minimalna, Pokazujemy jak rozwiązać ten problem i jego uogólnienie.
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Tuning of photocatalytic activity by creating a tridentate coordination sphere for palladium
PublicationThe synthesis and characterisation of an asymmetric potential bridging ligand bmptpphz (bmptpphz = 2,17-bis(4-methoxyphenyl)tetrapyrido[3,2-a:2’,3’-c:3’’,2’’-h:2’’’,3’’’-j] phenazine) is presented. This ligand contains a 1,10-phenanthroline (phen) and a 2,9-disubstituted phen sphere and possesses a strong absorbance in the visible. Facile coordination of the phen sphere to a Ru(tbbpy)2 core leads to Ru(bmptpphz) ([(tbbpy)2Ru(bmptpphz)](PF6)2;...
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Adsorption behavior and corrosion inhibitive characteristics of newly synthesized cyano-benzylidene xanthenes on copper/sodium hydroxide interface: Electrochemical, X-ray photoelectron spectroscopy and theoretical studies
PublicationElegant process for synthesis of 3-(7H-dibenzo[c,h]xanthen-7-yl)benzaldehyde (3), as new starting material to create a set of novel xanthene analogues, 2-(3-(7H-dibenzo[c,h]xanthen-7-yl)benzylidene)malononitrile (4), 3-(3-(7H-dibenzo[c,h]xanthen-7-yl)phenyl)-2-cyanoacrylic acid (5), and Ethyl-3-(3-(7H-dibenzo[c,h]xanthen-7-yl)phenyl)-2-cyanoacrylate (6), was achieved starting with available materials under mild conditions. Various...
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Electrochemical sensor for measurement of volatile organic compounds employing square wave perturbation voltage
PublicationThe paper presents the results of investigation on a prototype sensor for measurement of benzaldehyde in air. Sensitivity and limit of quantification of the sensor were determined for different internal electrolyte using the square wave voltammetry (SWV) as a detection technique. The working and counter electrodes were made of platinum. Ionic liquids 1-hexyl, 3-methylimidazolium chloride,1-hexyl, 3-methylimidazolium bis (trifluoromethanesulfonyl)...
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Stereoselective Alkylation of Indole with 5-Arylidene-Meldrum’s Acids in the Presence of Organocatalysts
PublicationBackground: Indole motif is frequently present in biologically active compounds. Enantiomerically pure or enriched 2,2-dimethyl-5-(aryl(1H-indol-3-yl)methyl)-1,3-dioxane-4,6-diones can be considered as a convenient starting point for the synthesis of a indole ring fused with cyclic ketones with biological activity. Preparation of chiral 2,2-dimethyl-5-(aryl(1H-indol-3-yl)methyl)-1,3-dioxane- 4,6-diones requires the reaction of...
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Structural, spectral and magnetic properties of Ni(II), Co(II) and Cd(II) compounds with imidazole derivatives and silanethiolate ligands
PublicationA series of new metal heteroleptic complexes have been obtained in simple reactions of 1-(3-aminopropyl)-imidazole (api) and 1,4-bis(imidazol-1-yl)-butane (bbi) ligands with metal silanethiolates or acetylacetonates. The obtained complexes are the coordination polymers [Ni{SSi(tBuO)3}2(μ-api)]n1, [Co{SSi(tBuO)3}2(μ-api)]n2, [Cd{SSi(tBuO)3}2(μ-api)·2CH3OH]n3, [Cd{SSi(tBuO)3}2(μ-bbi)·CHCl3]n4 and the dimer [Co{SSi(tBuO)3}2(μ-bbi)·3CH3OH]25....
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Comparison of the Efficiency of Deammonification under Different DO Concentrations in a Laboratory-Scale Sequencing Batch Reactor
PublicationThe efficiency of deammonification depends on the cooperation of ammonium oxidizing bacteria and archaea (AOB/AOA), anaerobic ammonium oxidizing bacteria (AnAOB) and the effective suppression of nitrite oxidizing bacteria (NOB) that compete with AnAOB for nitrite (NO2 -N). One of the effective NOB suppression strategies is intermittent aeration. However, it is important to have a good understanding of the optimum dissolved oxygen...
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Structural, magnetic and spectral properties of tetrahedral cobalt(II) silanethiolates: a variety of structures and manifestation of field-induced slow magnetic relaxation
PublicationBlue crystals of five heteroleptic cobalt(II) silanethiolates 1–5 have been obtained by the reaction of [Co{SSi (tBuO)3}2(NH3)]2 with aminopyridines and aminomethylpyridines at an appropriate molar ratio and their structural, spectral, thermal and magnetic properties have been established and described. All complexes 1–5 contain Co(II) ions in a tetrahedral CoN2S2 environment formed by (tBuO)3SiS− residues and pyridines and present...
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Synthesis and structure determination of 2,3-diaryl-9,9-dioxo-1H-9-thia-1,4,4a,7,10-pentaazaphenanthrene-2-ols
Publication3-Amino-1,1-dioxopyrido[4,3-e]-1,4,2-dithiazine has been synthesized and applied to the synthesis of 3-amino-2-(4-thioxo-1,4-dihydropyridin-3-ylsulfonyl)guanidine. The reaction of the aminoguanidine with the appropriate 1,2-diarylethane-1,2-diones afforded 2,3-diaryl-9,9-dioxo-1H-9-thia-1,4,4a,7,10-pentaazaphenanthrene-2-ol derivatives. The structure of these compounds, which represent a novel heterocyclic ring system, was confirmed...
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Corrosion of AISI1018 and AISI304 steel exposed to sulfates
PublicationThis research analyses the behavior of corrosion, durability, and quality of reinforced concrete samples coated with two different materials when exposed to contaminated soil with sulfates. The initial assessment involved evaluating the water absorption rate of the coating materials before and after exposure to a solution containing 3%푁푎2푆푂4+3%푀푔푆푂4+3%퐾2푆푂4+3%퐶푎푆푂4to determine their durability. the corrosion...
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Comparison of the coordination geometries of Zn(II) and Cd(II) ions in complexes with water, methanol and bulky aryloxysilanethiolate ligands
PublicationZinc and cadmium complexes containing silanethiolate anions and methanol or water were synthesized and characterized by X-ray diffraction, FT-IR and NMR spectroscopy, and DFT calculations. Contrary to zinc, the cadmium ion utilizes very weak donors to complete its coordination sphere; it forms contacts to phenyl rings of the silanethiolate ligand. Two zinc analogs of the general formula [Zn{SSi(OAr)3}2(L)2] where L = CH3OH (2)...
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Nitrogen mass balance and mathematical model of a Structured- Bed Reactor (SBRRIA)
PublicationAn up-flow structured-bed reactor subjected to recirculation and intermittent aeration (SBRRIA) was operated under varying influent conditions. The influent COD/N ratio was adjusted by maintaining a stable organic loading rate (average of 1.07 kgCOD m-3 d-1) and changing the nitrogen loading rate from 0.1 to 0.4 kg N m-3. Therefore, three different COD/N ratios were tested: 9.7±1 (Scenario 1); 7.6±1 (Scenario 2) and 2.9±1 (Scenario...
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Bounds on the vertex-edge domination number of a tree
PublicationA vertex-edge dominating set of a graph $G$ is a set $D$ of vertices of $G$ such that every edge of $G$ is incident with a vertex of $D$ or a vertex adjacent to a vertex of $D$. The vertex-edge domination number of a graph $G$, denoted by $\gamma_{ve}(T)$, is the minimum cardinality of a vertex-edge dominating set of $G$. We prove that for every tree $T$ of order $n \ge 3$ with $l$ leaves and $s$ support vertices we have $(n-l-s+3)/4...
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Problemy komunikacji międzykulturowej w warunkach konkurencji na rynku globalnym
PublicationCelem referatu jest identyfikacja barier komunikacji międzykulturowej. Praca składa się z 3 części:1. Istota i znaczenie komunikacji międzykulturowej w warunkach konkurowania na rynku międzynarodowym 2. Bariery komunikacji międzykulturowej 3. Problemy komunikacji międzykulturowej werbalnej i niewerbalnej.
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Functional Bi2O3/Gd2O3 Silica-Coated Structures for Improvement of Early Age and Radiation Shielding Performance of Cement Pastes
PublicationThis study presents a new approach towards the production of sol-gel silica-coated Bi2O3/Gd2O3 cement additives towards the improvement of early mechanical performance and radiation attenuation. Two types of silica coatings, which varied in synthesis method and morphology, were used to coat Bi2O3/Gd2O3 structures and evaluated...
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Analysis of floor-to-column pounding of buildings founded on different soil types
PublicationThe aim of this study is to investigate the effect of the soil type on buildings experiencing floor-to-column pounding during earthquakes. Five buildings with 4-storeys, 6-storeys, and 7-storeys were considered. Three types of the 4-storey building with different total heights were taken into account which leads to floor-to-column pounding at 1/3, 1/2 and 2/3 of the height of the impacted column. Two pounding scenarios were considered,...
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Fungal co-culture improves the biodegradation of hydrophobic VOCs gas mixtures in conventional biofilters and biotrickling filters
PublicationThe present study systematically evaluated the potential of Candida subhashii, Fusarium solani and their consortium for the abatement of n-hexane, trichloroethylene (TCE), toluene and α-pinene in biofilters (BFs) and biotrickling filters (BTFs). Three 3.2 L BFs packed with polyurethane foam and operated at a gas residence time of 77 s with an air mixture of hydrophobic volatile organic compounds (VOCs) were inoculated with C. subhashii,...
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System Weryfikacji Autentyczności Podpisu Odręcznego
PublicationW referacie przedstawiono system statycznej i dynamicznej weryfikacji autentyczności podpisu odręcznego, składanego piórem biometrycznym, wyposażonym w 2 akcelerometry, 2 żyroskopy i 3 czujniki ścisku, na rezystancyjnej powierzchni dotykowej, łączącym się bezprzewodowo z urządzeniami komputerowymi. We wstępie przedstawiono architekturę sieciową wielomodalnego systemu biometrii. Przedstawiono warstwę sprzętową systemu weryfikacji...
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Triplet energy exchange between fluorescent and phosphorescent organic molecules in a solid state matrix.
PublicationW pracy przedstawiono model wymiany energii trypletów na podstawie mechanizmu Dextera i zweryfikowano go w układzie dwuamina TPD : organiczny komleks Ir(ppy)3: matryca poliwęglanowa, mierząc czasy życia emisji Ir(ppy)3 przy różnych koncentracjach molekuł TPD.
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Application of passive sampling technique in monitoring research on quality of atmospheric air in the area of Tczew, Poland.
PublicationThis paper presents the results of atmospheric air quality research in Tczew (adjacent to the Vistula River) on the content of BTEX compounds. Analytical procedure applied during the sampling of the analytes from the air used the passive sampling technique (diffusive passive sampler, Radiello®). For determination of BTEX compounds in atmospheric air, two-stage thermal desorption technique combined with gas chromatography (TD-GC-FID)...
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Design of Compact and Wideband Groove Gap Waveguide-Based Directional Couplers
PublicationThis paper proposes a compact cross-shaped groove gap waveguide structure for creating wideband and compact directional couplers with different coupling levels. Groove gap waveguide technology is applied to overcome fabrication challenges of printed and hollow waveguide structures in high frequency bands. The validity of the novel concept is demonstrated through the design and evaluation of several compact broadband directional...
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Synthesis and Structure of Novel Copper(II) Complexes with N,O- or N,N-Donors as Radical Scavengers and a Functional Model of the Active Sites in Metalloenzymes
PublicationToevaluatetheantioxidantactivityofpotentialsyntheticenzymemimetics,wepreparednewfivecopper(II)complexesviaaself‐assemblymethodandnamedthem[Cu(2‐(HOCH2)py)3](ClO4)2(1),[Cu(2‐(HOCH2)py)2(H2O)2]SiF6(2),[Cu2(2‐(HOCH2CH2)py)2(2‐(OCH2CH2)py)2](ClO4)2(3),[Cu(pyBIm)3](BF4)2∙1.5H2O(4)and[Cu(py2C(OH)2)2](ClO4)2(5).ThesyntheticprotocolinvolvedN,O‐ orN,N‐donors:2‐(hydroxymethyl)pyridine(2‐(HOCH2)py),2‐(hydroxyethyl)pyridine(2‐(HOCH2CH2)py),2‐(2‐pyridyl)benzimidazole(pyBIm),di(2‐pyridyl)ke‐tone(py2CO).TheobtainedCu(II)complexeswerefullycharacterisedbyelementalanalysis,FTIR,EPR,UV‐Vis,single‐crystalX‐raydiffractionandHirshfeldsurfaceanalysis.Crystallographicandspectroscopicanalysesconfirmedchromophoresofbothmonomeric({CuN3O3}(1),{CuN2O4}(2),{CuN6}(4),{CuN4O2}(5))anddimericcomplex({CuN2O3}(3)).Mostoftheobtainedspeciespos‐sessedadistortedoctahedralenvironment,exceptdimer3,whichconsistedoftwocoppercentreswithsquarepyramidalgeometries.Thewater‐solublecompounds(1,3and5)wereselectedforbiologicaltesting.Theresultsofthestudyrevealedthatcomplex1insolutionsdisplayedbetterradicalscavengingactivitythancomplexes3,5andfreeligands.Therefore,complex1hasbeenselectedforfurtherstudiestotestitsactivityasanenzymemimetic.Thechosencompoundwastestedontheerythrocytelysateoftwogroupsofpatientsafterundergoingchemotherapyandchemoradiotherapy.Theeffectofthetestedcompound(1)onenzymeactivitylevels(TAS,SODandCAT)suggeststhattheselectedcomplexcanbetreatedasafunctionalmimeticoftheenzymes.
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Wykorzystanie technik chemometrycznych
Publication-------STRESZCZENIE 2-3 ZDANIA------------
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Revised structure of the repeating unit of the O-specific polysaccharide from Azospirillum lipoferum strain SpBr17
PublicationO-polisacharyd otrzymany poprzez delikatną kwasową hydrolizę lipopolisacharydu wyizolowanego z Azospirillum lipoferum SpBr17 był badany metodami spektroskopii NMR jak również metodą analizy metylacyjnej połączonej z elektroforezą SDS-PAGE. Stwierdzono, że nie jest on liniowym homopolimerem złożonym wyłącznie z (1->3) [alfa]-glikozydowo połączonych cząsteczek L-ramnopiranozy (jak proponowano wcześniej) lecz sekwencją kolejnych bloków...
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Fracture simulations in concrete beam under bending using a mesoscopic model with cohesive elements
PublicationThe main aim of this paper was to investigate a complex fracture process in a concrete beam subjected to 3-point bending test by means of the 2D meso-scale FEM with 4-node cohesive elements embedded in the initial mesh of 3-node solid elements. The material heterogeneity was taken into account by considering 3 different phases (aggregate, cement matrix, ITZs) on the basis of randomly generated internal structure of concrete and...
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Estimation of the minimal number of periodic points for smooth self-maps of odd dimensional real projective spaces
PublicationLet f be a smooth self-map of a closed connected manifold of dimension m⩾3. The authors introduced in [G. Graff, J. Jezierski, Minimizing the number of periodic points for smooth maps. Non-simply connected case, Topology Appl. 158 (3) (2011) 276-290] the topological invariant NJD_r[f], where r is a fixed natural number, which is equal to the minimal number of r-periodic points in the smooth homotopy class of f. In this paper smooth...
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Transition-Metal-Promoted Oxidative Cyclization To Give 1,2,4-Trisubstituted Carbazole Scaffolds
PublicationHerein, we describe the synthesis of a 1,2,4-trisubstituted carbazole core from 5-(1H-indol-3-yl)-3-oxopentanoic acid esters or amides. For oxidative cyclization, we tested two different approaches. First, we used manganese triacetate as a conventional moderate oxidizer to ensure the radical course of the reaction. Second, we examined the use of a more complex oxidizing agent I2/Me(OTf)3. In both cases, formation of a fused-ring...
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Badania nośności na zginanie innowacyjnego kształtownika giętego na zimno typu GEB
PublicationLekkie konstrukcje metalowe wytwarzane z kształtowników giętych na zimno to jedna z najszybciej rozwijających się dyscyplin w zakresie budownictwa. Do niedawna profile gięte na zimno stosowano wyłącznie jako elementy drugorzędne, czyli płatwie oraz rygle. Nowo opatentowany przekrój typu GEB ma być wykorzystywany jako element nośny konstrukcji ramowych. Jednak jego zaistnienie na rynku budowlanych konstrukcji metalowych jest uwarunkowane...
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Packing Three-Vertex Paths in 2-Connected Cubic Graphs
PublicationW pracy rozważano problem rozmieszczanie ścieżek P3 w 2-spójnych grafach 3-regularnych. Pokazano, że w 2-spójnym grafie 3-regularnym o n wierzchołkach można zawsze pokryć 9/11 n wierzchołków przez ścieżki P3; podano także odpowiednie oszacowania górne.