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Search results for: CO2 adsorption isotherms
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Lanthanide metal–organic frameworks: Structural, thermal and sorption properties
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Diaryl Sulfide Derivatives as Potential Iron Corrosion Inhibitors: A Computational Study
PublicationThe present work aimed to assess six diaryl sulfide derivatives as potential corrosion inhibitors. These derivatives were compared with dapsone (4,4′-diaminodiphenyl sulfone), a common leprosy antibiotic that has been shown to resist the corrosion of mild steel in acidic media with a corrosion efficiency exceeding 90%. Since all the studied compounds possess a common molecular backbone (diphenyl sulfide), dapsone was taken as the...
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ACTIVATED BIOCHAR AS AN ADSORBENT OF ORGANIC POLLUTANTS FOR WATER AND WASTEWATER TREATMENT
PublicationThe use of biomass, especially waste biomass, as an alternative energy source is a very important issue today. Pyrolysis is a process of thermal degradation of raw material and one of its products is biochar. This product is mainly distinguished by its high carbon content, and by improving its quality through activation, it can be more widely used. Activated biocarbon has a strongly developed surface and porous structure, and as...
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Impact of trajectory simplification methods on modeling carbon dioxide emissions from ships
PublicationModels of ship fuel consumption and emissions play an essential role in estimating global shipping’s greenhouse gas emissions. They are also widely used for verification of reported CO2 emissions for systems like EU MRV (Monitoring, Reporting and Verification) or IMO DCS (Data Collection System). Such models achieve high accuracy using historical spatiotemporal information about each ship from AIS data. However, this approach requires substantial...
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Chemically reduced graphene oxide based aerogels - Insight on the surface and textural functionalities dependent on handling the synthesis factors
PublicationEfficient adjusting of reduced graphene oxide aerogels properties requires information about experimental factor-aerogel property relationship. In this work, the reduced graphene oxide aerogels surface and textural functionalities in relation to precursor concentration, gelation time and hydrogel freezing temperature were studied in detail, with the use of dynamic adsorption method of gaseous organic probes and experimental design....
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Cellulose and its derivatives, coffee grounds, and cross-linked, β-cyclodextrin in the race for the highest sorption capacity of cationic dyes in accordance with the principles of sustainable development
PublicationIn this study, seven different materials were analyzed and includes coffee grounds (CG), two types of cellulose (CGC and CC), two types of modified cellulose (CT and CTCD), and cross-linked β-cyclodextrin (CD-1 and CD-2) were tested as adsorbents for the removal of dyes from the wastewater. The composition, morphology, and presence of functional groups in the obtained sorption materials were characterized by elemental analysis,...
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Badania naprężeń własnych laserowo przetapianej stali C45.
PublicationPraca prezentuje badania wpływu parametrów laserowego przetapiania stali C45 za pomocą wiązki lasera CO2 o mocy 6 kW na wielkość naprężeń własnych.
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Wpływ fazy nagrzewania silnika samochodowego na zużycie paliwa
PublicationW referacie przedstawiono wybrane problemy wpływu parametrów rozgrzewania silnika na zużycie paliwa. Wymieniono przewidywane ograniczenia prawne Unii Europejskiej co do emisji CO2.
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Możliwość redukcji emisji C02 dzięki zastosowaniu geosyntetyków
PublicationZastosowanie geosystemów jako rozwiązania zamiennego do konstrukcji klasycznych. Wybór geosystemu - względy techniczne, ekonomiczne i środowiskowe. Metodologia obliczania emisji CO2. Geosyntetyki wsparciem zrównoważonego rozwoju
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Measurements of electron drift velocity in OCS
PublicationWykonano pomiary prędkości dryfu elektronów w funkcji zredukowanego pola elektrycznego E/N. Wyniki tych pomiarów porównano z wynikami pomiarów w CO2 i N2O.
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Synteza bio-cyklicznych węglanów z wykorzystaniem oligoeteroli różniących się masą molową
PublicationCykliczne węglany mogą być otrzymywane w wyniku cykloaddycji CO2 do eterów glicydylowych. Biorąc pod uwagę stopniowe wyczerpywanie się, a co za tym idzie, zauważalny wzrost cen substratów ropopochodnych należy wziąć pod uwagę zastąpienie surowców petrochemicznych przez związki pochodzenia naturalnego. Ponadto, wykorzystanie CO2 przyczynić się może do rozwoju perspektyw utylizacji tego gazu w syntezach organicznych. Otrzymanie węglanów...
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Utilization of ionic liquids for the enrichment of biogas
PublicationThis article discusses the dependence of biogas composition on organic feed material. High amounts of CO2 decrease the calorific value of biogas. Several technologies are reviewed which can be used to increase the calorific value. Special emphasis is laid on ionic liquids as a new absorbing material. ILs have a number of advantages due to their unique properties such as: low melting point, high thermal conductivity, no flammability,...
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Modelowanie systemów energetycznych wytwarzania energii elektrycznej i ciepła do celów planowania rozwoju - wybrane zagadnienia
PublicationSystemy energetyczne wymagają przemian technologicznych w kierunku neutralności klimatycznej. W Polsce, w której systemie elektroenergetycznym i systemach ciepłowniczych dominują przestarzałe elektrownie i ciepłownie węglowe, dążenie do minimalizacji wpływu na środowisko wiąże się z wysokimi kosztami. Dlatego należy szukać optymalnych ścieżek roz-woju energetyki, aby osiągnąć ambitne długoterminowe cele strategiczne, przy minimalizacji...
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Wpływ podatku węglowego na efektywność pracy elektrociepłowni.
PublicationArtykuł prezentuje metodę wprowadzania podatku węglowego z progiem emisji dopuszczalnej, zwolnionej od podatku i jedną z metod podziału emisji CO2 między energią elektryczną i ciepło wytwarzane w elektrociepłowni.
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A novel concept of enhanced direct-contact condensation of vapour- inert gas mixture in a spray ejector condenser
PublicationAn analytical model of direct steam condensation (DCC) in the novel idea of spray ejector condenser (SEC) in the presence of inert gas has been developed. It is based on continuity, momentum and energy equations for the steam-carbon dioxide mixture and direct contact condensation mechanisms due to heat transfer and concentration. Crucial in the process of DCC is atomisation of the motive fluid in the ejector. The effect of atomised...
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Diphosphinoboranes as Intramolecular Frustrated Lewis Pairs: P–B–P Bond Systems for the Activation of Dihydrogen, Carbon Dioxide, and Phenyl Isocyanate
PublicationHerein, we present the first example of the activation of small molecules by P-B-P bond systems. The reactivity study involves reactions of two selected diphosphinoboranes, (tBu2P)2BPh (1’) and (Cy2P)2BNiPr2 (2), that differ in terms of their structural and electronic properties for the activation of dihydrogen, carbon dioxide, and phenyl isocyanate. Diphosphinoborane 1’ activates H2 under very mild conditions in the absence of...
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Nowe czynniki chłodnicze i zmiany w instalacjach chłodniczych. Cz.2
PublicationW drugiej części artykułu kontynuowany jest temat związany z ograniczeniami stosowania syntetycznych czynników chłodniczych. W części pierwszej przedstawiono tendencje do zastępowania wycofywanych substancji czynnikami naturalnymi. Niniejszy artykuł traktuje natomiast o możliwości wykorzystywania nowych, syntetycznych czynników z grupy HFO, będących substancjami bezpiecznymi dla środowiska naturalnego, w kontekście ich wpływu na...
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Odporność kawitacyjna stali 2H13 przetapianej wiązką lasera i stopowanej niobem
PublicationPrzedstawiono badania odporności kawitacyjnej stali 2H13 po dwóch wariantach obróbki laserowej. W pierwszym wariancie powierzchnie stali przetapiano wiązką lasera CO2, a w drugim powierzchnie wzbogacano Nb w ilości 5% masowego.
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Photocatalysts for Solar Energy Conversion
PublicationPhotocatalytic oxidation over suspended solid photocatalysts (e.g., titanium dioxide) has been proposed as a sustainable process for treatment and purification of water and wastewater as well as the process for photoconversion of solar energy to hydrogen, methane, and other low hydrocarbons. Solar radiation could be used to drive heterogeneous electrochemical reactions at the surface of an optically active photocatalyst (e.g.,...
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Bile conjugation and its effect on in vitro lipolysis of emulsions
PublicationBile Salts (BS) are responsible for stimulating lipid digestion in our organism. Gut microbiota are responsible for the deconjugation process of primary conjugated to secondary unconjugated BS. We use two structurally distinct BS and characterize the rate of lipolysis as a compound parameter. A static in-vitro digestion model as well as meta-analysis of literature data has been performed to determine the most influential factors...
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A magnetic imprinted polymer nano-adsorbent with embedded quantum dots and mesoporous carbon for the microextraction of triazine herbicides
PublicationA magnetic molecularly imprinted polymer (MMIP) adsorbent incorporating amino-functionalized magnetite nanoparticles, nitrogen-doped graphene quantum dots and mesoporous carbon (MIP@MPC@NGQDs@ Fe3O4–NH2) was fabricated to extract triazine herbicides from fruit juice. The embedded magnetite nanoparticles simplified the isolation of the adsorbent from the sample solution. The N-GQDs and MPC enhanced adsorption by affinity binding...
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Corrosion Inhibition Mechanism and Efficiency Differentiation of Dihydroxybenzene Isomers Towards Aluminum Alloy 5754 in Alkaline Media
PublicationThe selection of efficient corrosion inhibitors requires detailed knowledge regarding the interaction mechanism, which depends on the type and amount of functional groups within the inhibitor molecule. The position of functional groups between different isomers is often overlooked, but is no less important, since factors like steric hinderance may significantly affect the adsorption mechanism. In this study, we have presented how...
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Emulsification alters simulated gastrointestinal proteolysis of β-casein and β-lactoglobulin
PublicationWe have studied the effect of the adsorption of milk proteins at the oil-water interface on their digestibility in simulated gastrointestinal environment. The investigations aimed to characterize how both the breakdown of the adsorbed proteins and the interactions with physiological surfactants, phosphatidylcholine (PC) and bile salts (BS), influence structural transformations of model, protein-stabilized food emulsions in the...
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Polysaccharide nanocomposites in wastewater treatment: A review
PublicationIn modern times, wastewater treatment is vital due to increased water contamination arising from pollutants such as nutrients, pathogens, heavy metals, and pharmaceutical residues. Polysaccharides (PSAs) are natural, renewable, and non-toxic biopolymers used in wastewater treatment in the field of gas separation, liquid filtration, adsorption processes, pervaporation, and proton exchange membranes. Since addition of nanoparticles...
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Lignocellulosic waste biosorbents infused with deep eutectic solvents for biogas desulfurization
PublicationThis paper introduces an innovative method for treating biogas streams, employing lignocellulosic biosorbents infused with environmentally friendly solvents known as deep eutectic solvents (DES). The primary focus of this study was the elimination of volatile organosulfur compounds (VSCs) from model biogas. Biosorbents, including energetic poplar wood, antipka tree, corncobs, and beech wood, were used, each with varying levels...
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Wpływ natężenia kawitacji na względną odporność kawitacyjną obrobionej laserowo stali 45
PublicationPrzedstawiono badania odporności kawitacyjnej stali 45 w początkowym okresie niszczenia po przetapianiu jej powierzchni wiązką lasera CO2 o mocy 6 kW. Stwierdzono spadek względnej odporności kawitacyjnej wraz ze wzrostem natężenia kawitacji.
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Sztuczna fotosynteza - utopia, czy szansa na tanie paliwa?
PublicationUwalnianie CO2 w procesach przemysłowych i inne czynniki wynikające z aktywności człowieka spowodowały, że naturalna równowaga między emisją tlenku węgla(IV) a pochłanianiem go przez rośliny i w owdach powierzchniowych została zakłócona
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Thermal visualization of Ostwald-de Waele liquid in wavy trapezoidal cavity: Effect of undulation and amplitude
PublicationThe present study is concerned with the numerical simulations of Ostwald-de Waele fluid flow in a wavy trapezoidal cavity in the presence of a heated cylinder situated at the center of the cavity. The work consists in characterizing the mixed convection as a function of the intensity of heat flow. The flow behaviour and temperature distribution in a cavity are the main focus of this study. The lower wall of the cavity is fixed...
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Charakterystyka kawitacyjna laserowo obrabianych napoin Fe-Cr-Mn
PublicationPrzedstawiono badania odporności kawitacyjnej napoin Fe-Cr-Mn w dwóch przypadkach: bez dodatkowej obróbki powierzchniowej oraz po przetapianiu powierzchni napoiny wiązką lasera CO2 o mocy 1000W. Oceniano głębokość i stopień umocnienia warstwy wierzchniej.
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High catalytic performance of laccase wired to naphthylated multiwall carbon nanotubes
PublicationThe direct electrical connection of laccase on the electrode surface is a key feature in the design of efficient and stable biocathodes. However, laccases can perform a direct electron transfer only when they are in the preferable orientation toward the electrode. Here we report the investigation of the orientation of Laccase from Amano on multi-walled carbon nanotube surface modified with naphthalene group. Naphthylated multi...
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Numerical investigations of effect of indoor air quality on thermal comfort in residential buildings.
PublicationArtykuł przedstawia wyniki numeryczne MES odnośnie wpływu koncentracji CO2 w lokalnej strefie powietrza w budynkach mieszkalnych naturalnie wentylowanych na zachowanie mieszkańców. Obliczenia wykonano w 2 wymiarach. Zbadano wpływ położenia mieszkańców i prędkości wchodzącego powietrza.
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The Quality of the Outflow from Conventional WWTPs and Treatment Wetlands
PublicationUntil recently the humic substances were considered to have no negative impact on human health. Therefore elimination of these substances from potable water was only performed due to aesthetic reasons. In the recent years, however, it was found out that humic substances may cause unacceptable smell of water or cumulate toxic substances by complexing metal ions and adsorption of persistent organic pollutants such as pesticides,...
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Sustainable recovery of plant essential Nitrogen and Phosphorus from human urine using industrial coal fly ash
PublicationCoal-based thermal power plants play a pivotal role in meeting global energy demand. The amount of fly ash generated from these plants increases every year, and its successful use has posed a significant environmental risk in the last decade. In this study, coal fly ash was packed in a fixed-bed adsorption column to remove Urea–N from synthetic human urine. To assess the efficacy of fly ash in the removal of Nitrogen, various process...
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New laser-enhanced surface treatment of Ti bioalloy
PublicationPrzedstawiono wyniki badan mikrostruktury i korozji w roztworze Ringera stopu Ti6Al4V, który był poddawany nadtapianiu laserem CO2 w powietrzu, wodzie i ciekłym azocie. Stwierdzono znaczący wpływ warunków obróbki na mikrostrukturę, mikrotwardość i głębokość zmodyfikowanej warstwy wierzchniej.
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Photoelectrochemically Active N‐Adsorbing Ultrathin TiO2 Layers for Water‐Splitting Applications Prepared by Pyrolysis of Oleic Acid on Iron Oxide Nanoparticle Surfaces under Nitrogen Environment
PublicationHighly performing photocatalytic surfaces are nowadays highly desirable in energy fields, mainly due to their applicability as photo water‐splitting electrodes. One of the current challenges in this field is the production of highly controllable and efficient photoactive surfaces on many substrates. Atomic layer deposition has allowed the deposition of photoactive TiO2 layers over wide range of materials and surfaces. However,...
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Removal of persistant organic pollutants from landfill leachates treated in three constructed wetland systems
PublicationThe objective of the study was assessment of occurrence and removal of two groups of persistent organic pollutants: polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) in landfill leachate (LL) treated in three constructed wetland systems (CWs) of different construction and flow regime. Two subsurface flow systems (SSF) were analyzed: one with horizontal flow and the second one consisting of two vertical...
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Silica Gel Impregnated by Deep Eutectic Solvents for Adsorptive Removal of BTEX from Gas Streams
PublicationThe paper presents the preparation of new adsorbents based on silica gel (SiO2) impregnated with deep eutectic solvents (DESs) to increase benzene, toluene, ethylbenzene, and p-xylene (BTEX) adsorption efficiency from gas streams. The DESs were synthesized by means of choline chloride, tetrapropylammonium bromide, levulinic acid, lactic acid, and phenol. The physico-chemical properties of new sorbent materials, including surface...
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Rapid and Green Separation of Mono- and Diesters of Monochloropropanediols by Ultrahigh Performance Supercritical Fluid Chromatography–Mass Spectrometry Using Neat Carbon Dioxide as a Mobile Phase
PublicationThis study demonstrates the effect of column selectivity and density of supercritical carbon dioxide (SC-CO2) on the separation of monochloropropanediol (MCPD) esters, known as food toxicants, using SC-CO2 without addition of cosolvent in ultrahigh performance supercritical fluid chromatography–mass spectrometry (UHPSFC-MS). This study shows that over 20 2-monochloropropanediol (2-MCPD) and 3-monochloropropanediol (3-MCPD) mono-...
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Chitosan-coated coconut shell composite: A solution for treatment of Cr(III)-contaminated tannery wastewater
PublicationTannery industry generates a large amount of Cr(III)-contaminated wastewater daily. Unless properly treated, not only this effluent contaminates the water body, but also damages the environment and threatens public health. This batch study investigates the feasibility of chitosan-coated coconut shells as a low-cost material for removing Cr(III) from tannery wastewater. Both chitosan and coconut shell (CS) waste are abundantly available...
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Recent Advancements in Cyclodextrin-Based Adsorbents for the Removal of Hazardous Pollutants from Waters
PublicationWater is an essential substance for the survival on Earth of all living organisms. However, population growth has disturbed the natural phenomenon of living, due to industrial growth to meet ever expanding demands, and, hence, an exponential increase in environmental pollution has been reported in the last few decades. Moreover, water pollution has drawn major attention for its adverse effects on human health and the ecosystem....
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Process Control of Biogas Purification Using Electronic Nose
PublicationNowadays, biogas produced from landfills and wastewater treatment plants or lignocellulosic biomass is important sustainable and affordable source of energy. Impurities from biogas stream can cause a serious odor problem, especially for residents of areas immediately adjacent to production plants. Therefore, biogas pre-treatment is necessary to protect engines that convert biogas into energy and in order to increase the specific...
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Modelling of the Polish Electricity Generation Subsystem in MARKAL Program with Emphasis on the EU Emissions Trading Scheme
PublicationThis paper addresses issues related to greenhouse gas emissions in the European Union and measures to reduce them, in particular the European Emissions Trading Scheme (EU ETS). A model of the Polish electricity generation subsystem, taking into account EU ETS mechanisms, has been developed using the MARKAL optimization package. Data collected on the basis of available projects, regulations and statistics were entered into the model....
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Carbon dioxide potential reduction using Start-Stop system in a car
PublicationOperating fuel consumption increases significantly when the vehicle stops frequently while driving or when the engine is idling during braking. In such cases, the internal combustion engine consumes the fuel but the mechanical energy is not used by the drive system. The amount of fuel that is consumed in this time by the engine can potentially be saved if the car is equipped with a Stop-Start system. Start-Stop system automatically...
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Catalytic activity of Ni-MgAl2O4 modified with transition metal (Ti, Mo, W) carbides as potential catalysts for resource recovery via dry reforming of waste plastics
PublicationThe growing amounts of plastic waste and CO2 emissions are two environmental threats that require urgent attention. Pyrolysis combined with dry reforming (PCDR) is a technology that allows both CO2 utilization and resource recovery from waste plastic. New catalysts for PCDR are crucial for developing efficient and stable processes that can be widely implemented in the industry. In this study, Ni/MgAl2O4 catalysts modified using different...
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Biodegradability of simulant fluids and crude oil in aquatic environment
PublicationBiodegradowalność symulantów płynów była oceniana poprzez pomiar CO2 (EPA 560/6-82-003). Badaniu poddawane były emulsyjne i nieemulsyjne symulanty ropy oraz lekka ropa naftowa typu A z Północnej Ameryki. Uzyskane wyniki wskazują na łatwą biodegradowalność obu symulantów w porównaniu do badanej ropy naftowej.
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Badania naprężeń własnych laserowo przetopionej stali X20Cr13
PublicationPrzedstawiono badania naprężeń własnych stali X20Cr13 przetopionej wiązką lasera CO2 o dwóch różnych energiach liniowych. Przetapianie wiązką lasera o energii liniowej 16,7 Ws/m3 powodowało większe naprężenia w kierunku prostopadłym do kierunku przetopienia podczas gdy przetapianie z energią 70,8 Ws/m3 powoduje sytuację odwrotną.
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Evaluation of citric acid corrosion inhibition efficiency and passivation kinetics for aluminium alloys in alkaline media by means of dynamic impedance monitoring
PublicationA novel approach is proposed for constructing the adsorption isotherm in corrosion studies, based on a well-known interaction between citric acid and aluminium in alkaline electrolytes. Our approach utilizes the instantaneous impedance measurements via Dynamic Electrochemical Impedance Spectroscopy in galvanostatic mode (g-DEIS). Unlike other common tools, g-DEIS delivers exact information about the concentration required for full...
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Effective assessment of biopolymer-based multifunctional sorbents for the remediation of environmentally hazardous contaminants from aqueous solutions
PublicationPersistent contaminants in wastewater effluent pose a significant threat to aquatic life and are one of the most significant environmental concerns of our time. Although there are a variety of traditional methods available in wastewater treatment, including adsorption, coagulation, flocculation, ion exchange, membrane filtration, co-precipitation and solvent extraction, none of these have been found to be significantly cost-effective...
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Adsorptive Removal of Aqueous Phase Crystal Violet Dye by Low-Cost Activated Carbon Obtained from Date Palm (L.) Dead Leaflets
PublicationUp to now, water pollution is still one of the important issues and challenges worldwide, due to its environmental, economic and human life impacts. It is also remains a challenge to environment scientists and technologists. Nowadays, the textile dyeing industry is considered one of the largest water consuming industries and produces large volumes of colored wastewater in its dyeing and finishing process. In this study, date palm...
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Advanced super-hydrophobic polymer-based porous absorbents for the treatment of oil-polluted water
PublicationThe threat of environmental pollution caused by spilled oil is rapidly increasing along with the expansion of oil exploration, the development of maritime activities and industrial growth. Oil spill incidents usually affect seriously the ecosystem and human life. Therefore, the treatment and recovery of the oil spill have been considered as an ultra-important issue to protect the environment and to minimize its negative impacts...