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Search results for: ESTRY ETYLOWE KWASÓW TŁUSZCZOWYCH . GC-MS . MECONIUM . LC-MS/MS
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Thermal analysis of bis(tetraethylammonium) tetrachloroferrate(II)
PublicationBadano dekompozycję termiczną związków bis(tetraethylammonium) tetrachloroferrate(II). Stosowano następujące metody badawcze: TG-FTIR, TG-MS i DTA. Pomiary przeprowadzono w atmosferze obojętnej w zakresie temperatur od 293 K do 1073 K. Stałe produkty dekompozycji identyfikowano metodą spektroskopii w podczerwieni, spektroskopii Mössbauera oraz metodą dyfrakcji promieniowania rentgenowskiego. Przedyskutowano wpływ stopnia utlenienia...
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Some advances in environmental analytics and monitoring
PublicationW pracy przedstawiono wkład Katedry Chemii Analitycznej w rozwój analityki środowiskowej i monitoringu, ze szczególnym uwzględnieniem analityki pozostałości leków w próbkach wodnych ( w układzie on-line i off-line), badań nad identyfikacją produktów degradacji organicznych zanieczyszczeń, analizy toksyn w wodach za pomocą techniki HPLC-DAD-MS, wykorzystania dozymetrii pasywnej do izolacji analitów z wody oraz jednoczesnego oznaczania...
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Radio Link Measurement Methodology for Location Service Applications
PublicationThe aim of this paper is the methodology of measurements executed in a radio link for the realization of radiolocation services in radiocommunication networks, particularly in cellular networks. The main results of the measurements obtained in the physical layer of the universal mobile telecommunications system (UMTS) are introduced. A new method for the utilization of the multipath propagation phenomenon to improve the estimation...
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Wnioskowanie w wielowymiarowej statystyce (semestr letni 2022/2023)
e-Learning Courseswykład, seminarium, laboratorium: dr inż. Anna Szafrańska Specjalność: Analityk danych, II stopnia, Matematyka, WFTiMS, stacjonarne, 2021/2022 - letni (obecnie sem. 2)
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A fast and convenient method for analysis of collagen hydrolysis products Szybka i dogodna metoda analizy produktów hydrolizy kolagenu
PublicationPolypeptides produced by hydrolysis of collagen from minced animal hide and skin scraps were studied by mass spectrometry (MS) in conjunction with electrophoresis to det. their mol. mass. The degree of peptides ionisation was ca 50+. This allowed for observation of the large polypeptide chains with mass analyzers with a relatively low m/z range. The electrospray and atm. pressure photoionization techniques were used. The polypeptide...
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Ultrasound-Assisted Solvent Extraction of a Porous Membrane Packed Sample for the Determination of Tobacco-Specific Nitrosamines in the Replacement Liquids for E-Cigarettes
PublicationThe content of tobacco-specific nitrosamines (TSNAs) possessing carcinogenic properties has been an important area of research since replacement liquids were introduced for e-cigarettes. A method for determining N′-nitrosonornicotine (NNN), 4-(methylnitrosamino)-1-(3-pyridyl)-1-butanone (NNK), N′-nitrosoanatabine (NAT), and N′-nitrosoanabasine (NAB) in replacement liquids for electronic cigarettes was developed using liquid chromatography–tandem...
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Multi-Technique Investigation of Grave Robes from 17th and 18th Century Crypts Using Combined Spectroscopic, Spectrometric Techniques, and New-Generation Sequencing
PublicationThe textile fragments of the funeral clothes found in the 17th and 18th century crypts were subjected to spectroscopic, spectrometric, and microbial investigation. The next-generation sequencing enabled DNA identification of microorganisms at the genus and in five cases to the species level. The soft hydrofluoric acid extraction method was optimized to isolate different classes of dyes from samples that had direct contact with...
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Boron-doped carbon nanowalls for fast and direct detection of cytochrome C and ricin by matrix-free laser desorption/ionization mass spectrometry
PublicationDetecting proteins via surface assisted laser desorption/ionization mass spectrometry (SALDI-MS) method is still highly challenging, and only few examples of nanomaterials have been demonstrated to perform such detection so far. In this study, carbon nanowalls (CNWs), vertically aligned graphene sheet-based materials, presenting specific morphology, dimensions, and boron doping levels have shown improved performances for both qualitative...
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A Closed Bipolar Electrochemical Cell for the Interrogation of BDD Single Particles: Electrochemical Advanced Oxidation
PublicationA closed bipolar electrochemical cell containing two conductive boron-doped diamond (BDD) particles of size 250 – 350 m, produced by high-pressure high-temperature (HPHT) synthesis, has been used to demonstrate the applicability of single BDD particles for electrochemical oxidative degradation of the dye, methylene blue (MB). The cell is fabricated using stereolithography 3D printing and the BDD particles are located at either...
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Carbon nanowalls: A new versatile graphene based interface for laser desorption/ionization-mass spectrometry detection of small compounds in real samples.
PublicationCarbon nanowalls, vertically aligned graphene nanosheets, attract attention owing to their tunable band-gap, high conductivity, high mechanical robustness, high optical absorbance and other remarkable properties. In this paper, we report for the first time, the use of hydrophobic boron-doped carbon nanowalls (CNWs) for laser desorption/ionization of small compounds and their subsequent detection by mass spectrometry (LDI-MS). The...
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Convenient identification of desulfoglucosinolates on the basis of mass spectra obtained during liquid chromatography-diode array-electrospray ionisation mass spectrometry analysis: Method verification for sprouts of different Brassicaceae species extracts
PublicationOver the past decade, glucosinolates (GLs) present in different tissues of Brassicaceae and their breakdown products, especially isothiocyanates formed after myrosinase catalyzed hydrolysis, have been regarded as not only environment friendly biopesticides for controlling soilborne pathogens, but most importantly as promising anticarcinogenic compounds. For these reasons, the identification and quantitative determination of the...
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Red Kale (Brassica oleracea L. ssp. acephala L. var. sabellica) Induces Apoptosis in Human Colorectal Cancer Cells In Vitro
PublicationThis article presents the results of studies investigating the effect of red kale (Brassica oleracea L. ssp. acephala L. var. sabellica) extract on cancer cells (HT-29). The cytotoxicity of the red kale extract was assessed using MTT and LDH assays, while qRT-PCR was employed to analyze the expression of genes associated with the p53 signaling pathway to elucidate the effect of the extract on cancer cells. Furthermore, HPLC-ESI-QTOF-MS/MS...
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The Impact of Different Drying Methods on the Metabolomic and Lipidomic Profiles of Arthrospira platensis
PublicationDrying is an inseparable part of industrial microalgae production. In this work, the impacts of eight different drying methods on the metabolome and lipidome of Arthrospira platensis were investigated. The studied drying methods were freeze drying (FD), sun drying (SD), air drying at 40 and 75 °C (AD′ and AD″), infrared drying at 40 and 75 °C (IRD′ and IRD″), and vacuum drying at 40 and 75 °C (VD′ and VD″). Results gathered by...
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Analytical methods for exhaustive characterization of Brassica plants and dietary products based on them
PublicationGlucosinolates (GLs), and particularly two classes of their degradation products - isothiocyanates (ITC) and indoles - released upon myrosinase catalyzed hydrolysis, belong to the most promising chemopreventive dietary components. Despite their wide use in plant research, studies on chemopreventive mechanisms and industrial utilization in the production of e.g. dietary supplements, the methods of reliable characterization of myrosinase-GLs...
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Ocena narzędzi wspomagających zarządzanie przedsięwzięciami informatycznymi na przykładzie IBM Rational Method Composer
PublicationRozdział przedstawia zalety i wady oprogramowania wspomagającego zarządzanie przedsięwzięciami informatycznymi. Skupia się na ocenie technologii informatycznej spopularyzowanej na rynku przez firmę IBM jako Rational Method Composer. W rozdziale zostały zaproponowane kryteria oceny z punktu widzenia menedżera zarządzającego przedsięwzięciem oraz oceny w zależności od stopnia spełnienia tego kryterium. Ponadto przeprowadzona została...
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Funcionality assessment of Citrus Hysteria peel as a protective barrier using gas chromatography
PublicationThe aim of this study was to analyse the volatile fractions of fruit peel and pulp using two-dimensional gas chromatography technique coupled with mass spectrometry. The isolation of the compounds was achieved by microextraction to the stationary phase from the headspace of the sample (HS-SPME). Mass spectrometry with time-of-flight analyser (TOF-MS) was used to identify the chemical compounds. There are no reports in the literature...
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Arsalan Muhammad Soomar Doctoral Student
PeopleHi, I'm Arsalan Muhammad Soomar, an Electrical Engineer. I received my Master's and Bachelor's Degree in the field of Electrical Engineering from Mehran University of Engineering and Technology, Jamshoro, Sindh, Pakistan. Currently enrolled as a Doctoral student at the Gdansk University of Technology, Gdansk, Poland. Also worked in Yellowlite. INC, Ohio as a Solar Design Engineer. HEADLINE Currently Enrolled as a Doctoral...
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An in situ derivatization – dispersive liquid–liquid microextraction combined with gas-chromatography – mass spectrometry for determining biogenic amines in home-made fermented alcoholic drinks
PublicationA novel dispersive liquid–liquid microextraction (DLLME) gas chromatography mass-spectrometry(GC–MS) method was developed for the determination of 13 biogenic amines in home-made wine sam-ples. The method allows to simultaneous extraction and derivatization of the amines providing a simpleand fast mode of extract enrichment. During the study, two different procedures were examined. Sta-tistical analysis was performed to choose...
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The content of biogenic amines in Rondo and Zweigelt wines and correlations between selected wine parameters
PublicationThe purpose of this study was to evaluate the content of biogenic amines (BAs) in wines using dispersive liquid–liquid microextraction–gas chromatography–mass spectrometry (DLLME-GC–MS). An additional objective was to assess the correlations between selected parameters characterizing the samples such as the content of BAs, sugars, and organic acids, pH, and total acidity. Wines produced from the same grape variety in which alcoholic...
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Combination of air-dispersion cathode with sacrificial iron anode generating Fe2+Fe3+2O4 nanostructures to degrade paracetamol under ultrasonic irradiation
PublicationIn the present study, ultrasound (US) was coupled with an electrochemical process (ECP) consisting of a novel cathode of carbon cloth (CC)-carbon black (CB) as the nano-composite air-dispersion cathode (NADC) for the degradation of paracetamol (APAP) in an aquatic medium. The NADC favored in situ production of H2O2 by the cathodic reduction. The implementation of iron sacrificial anode instead of dimensionally stable anodes resulted...
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GP III sem: Oświetlenie w projektowaniu przestrzennym (2022/23) przedmiot do wyboru
e-Learning CoursesPrzedmiot do wyboru: Oświetlenie w projektowaniu przestrzennym Zajęcia we piątki 10:15 do 13:00 spotkania w sali 357 w razie spotkań online MS Teams
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Ultrasonic wave propagation and digital image correlation measurements of polyolefin fibre-reinforced concrete beams under 3-point bending (beam B-002)
Open Research DataThe DataSet contains the results of the mechanical behaviour of a concrete beam under a 3-point bending test. The beams had dimensions 15 x 15 x 70 cm3. The beam B-Con was made of concrete without fibres (as the reference beam), while beams B-002, B-004, and B-006 were manufactured from the concrete mix containing 2 kg/m3, 4 kg/m3 and 6 kg/m3 of fibres,...
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Ultrasonic wave propagation and digital image correlation measurements of polyolefin fibre-reinforced concrete beams under 3-point bending (beam B-Con)
Open Research DataThe DataSet contains the results of the mechanical behaviour of a concrete beam under a 3-point bending test. The beams had dimensions 15 x 15 x 70 cm3. The beam B-Con was made of concrete without fibres (as the reference beam), while beams B-002, B-004, and B-006 were manufactured from the concrete mix containing 2 kg/m3, 4 kg/m3 and 6 kg/m3 of fibres,...
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Ultrasonic wave propagation and digital image correlation measurements of polyolefin fibre-reinforced concrete beams under 3-point bending (beam B-004)
Open Research DataThe DataSet contains the results of the mechanical behaviour of a concrete beam under a 3-point bending test. The beams had dimensions 15 x 15 x 70 cm3. The beam B-Con was made of concrete without fibres (as the reference beam), while beams B-002, B-004, and B-006 were manufactured from the concrete mix containing 2 kg/m3, 4 kg/m3 and 6 kg/m3 of fibres,...
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Ultrasonic wave propagation and digital image correlation measurements of polyolefin fibre-reinforced concrete beams under 3-point bending (beam B-006)
Open Research DataThe DataSet contains the results of the mechanical behaviour of a concrete beam under a 3-point bending test. The beams had dimensions 15 x 15 x 70 cm3. The beam B-Con was made of concrete without fibres (as the reference beam), while beams B-002, B-004, and B-006 were manufactured from the concrete mix containing 2 kg/m3, 4 kg/m3 and 6 kg/m3 of fibres,...
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20 lat dydaktyki: próby, błędy i dylematy
EventsProwadzący: dr inż. Marek Augustyniak (Wydział Fizyki Technicznej i Matematyki Stosowanej, Instytut Nanotechnologii i Inżynierii Materiałowej) Nagrania z poprzednich spotkań można znaleźć na kanale YouTube CNE PG.
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Uproszone modelowanie sieci dystrybucyjnej na potrzeby analiz przyłączeniowych
PublicationW artykule przedstawiono rozważania na temat sposobu modelowania sieci średniego (SN) i niskiego (nn) napięcia na potrzeby wykonywania analiz przyłączeniowych przez operatorów sieci dystrybucyjnej. Przeprowadzono dyskusję na temat możliwych do wykonania uproszczeń w modelowaniu sieci, które są do zaakceptowania z punktu widzenia uzyskiwanego wyniku końcowego. Głównym elementem wymuszającym uproszenia w modelowaniu jest środowisko...
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Uproszczone modelowanie sieci dystrybucyjnej na potrzeby analiz przyłączeniowych
PublicationW artykule przedstawiono rozważania na temat sposobu modelowania sieci średniego (SN) i niskiego (nn) napięcia na potrzeby wykonywania analiz przyłączeniowych przez operatorów sieci dystrybucyjnej. Przeprowadzono dyskusję na temat możliwych do wykonania uproszczeń w modelowaniu sieci, które są do zaakceptowania z punktu widzenia uzyskiwanego wyniku końcowego. Głównym elementem wymuszającym uproszenia w modelowaniu jest środowisko...
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Lower rim substituted tert-butylcalix[4]arenes (II). Complexing ability of5,11,17,23-tetra-tert-butyl-25,26,27,28-tetrakis-O-(piperidinylcarbonyl)me- thylenecalix[4]arene. The crystal structures of the ligand and its sodium complex
PublicationSyntezowano kompleksy wymienionego w tytule liganda z chlorkiem sodu i azotanami itru(III), lantanu(III), samaru(III) i gadolinu(III) w reakcji liganda i odpowiedniej soli, które charakteryzowano za pomocą widm IR, UV-vis,1H NMR, FAB-MS, a także za pomocą analizy elementarnej. W reakcji wymiany z kompleksu z sodem otrzymywano kompleksy z lantanowcami. Określono strukturę krystaliczną wolnego liganda i jego kompleksu z sodem za...
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Diagnostyka i identyfikacja procesu przy użyciu AdMS-PCA
PublicationArtykuł dotyczy diagnostyki i identyfikacji procesu przy użyciu adaptacyjnego, wieloskalowego rozszerzenia PCA - Adaptive Multiscale Principal Component Analysis (AdMS-PCA). Przeprowadzona została analiza własności AdMS-PCA istotnych dla diagnostyki i identyfikacji. Zauważono wadę części adaptacyjnej metody, która ogranicza jej praktyczne zastosowanie. Zaproponowano modyfikację poprzez wprowadzenie algorytmu nadzorującego adaptację....
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Pogłosowości wnętrza sakralnego na przykładzie kościoła pw. Niepokalanego Serca Maryji w Gdyni
PublicationWalory słuchowe stanowią obok walorów wizualnych istotny element w postrzeganiu przestrzeni sakralnej. Dlatego dobrze zaprojektowana akustyka wnętrza (lub chociażby uniknięcie podstawowych błędów akustycznych) jest na równi ważna z projektem architektonicznym. Zasadniczym kryterium w ocenie własności akustycznych wnętrz jest jego pogłosowość. W niniejszym referacie przedstawiono analizę i ocenę pogłosowośći wnętrza kościoła przeprowadzoną...
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Intensification of catechin extraction from the bark of Syzygium cumini using ultrasonication: Optimization, characterization, degradation analysis and kinetic studies
PublicationCatechin is a prominent polyphenolic component that possesses various medicinal properties. Present work communicates the intensification and optimization of catechin extraction from the bark of Syzygium cumini tree using stirred reactor, soxhlet, ultrasonic bath, and ultrasonic horn technique. The optimization of several parameters such as type of solvent, solid to solvent ratio (1:100 w/v), speed of agitation (300 RPM), extraction...
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Identification and characterization of the Indian Yellow dyestuff and its degradation products in historical oil paint tube by liquid chromatography mass spectrometry
PublicationAn analytical protocol for identification of dyes using reversed phase liquid chromatography-mass spectrometry with atmospheric pressure electrospray ionization (LC-ESI/MS) is presented. The developed method has been successfully applied in identification of euxanthic acid and euxanthone, the main components of the Indian Yellow dye in a historical oil paint tube produced by Richard Ain`es, a recognizable French company supplying...
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Występowanie surfaktantów w próbkach środowiskowych
PublicationOd czasu wytworzenia pierwszego syntetycznego surfaktantu naukowcy wprowadzali wiele zmian w ich składzie, które miały na celu poprawę działania preparatów oraz zmniejszanie ich negatywnego oddziaływania na poszczególne elementy środowiska. Obecnie surfaktanty stosowane są zarówno jako środki piorące, myjące, czyszczące (chemia gospodarcza, kosmetyki) oraz w przemyśle spożywczym,włókienniczym, metalurgicznym, rafineryjnym, petrochemicznym,...
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Philosophy and Aesthetics
e-Learning CoursesHello, welcome to our classes page. We will be working via MS Teams. Link below: https://teams.microsoft.com/l/meetup-join/19%3ameeting_MjE4NmI0M2QtM2UzYi00MTM1LWFkYjEtZTA3MWY0MjZlZDYx%40thread.v2/0?context=%7b%22Tid%22%3a%2286760356-0022-486f-b793-a2d470bba5a5%22%2c%22Oid%22%3a%22744d498a-011e-4d0b-8a3d-08b49c9156ff%22%7d
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Filozofia i estetyka
e-Learning CoursesDzień dobry, witamy na stronie naszego kursu. Będziemy zajęcia prowadzić przez platformę MS Teams: https://teams.microsoft.com/l/meetup-join/19%3ameeting_NmJkZTczMTEtN2FkNy00OTE4LWE1YWItN2MyNzk4NWRiZTQ3%40thread.v2/0?context=%7b%22Tid%22%3a%2286760356-0022-486f-b793-a2d470bba5a5%22%2c%22Oid%22%3a%22744d498a-011e-4d0b-8a3d-08b49c9156ff%22%7d
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GP III sem: Przedmiot do wyboru - Oświetlenie w projektowaniu przestrzennym (23/24)
e-Learning CoursesPrzedmiot do wyboru: ćwiczenia Oświetlenie w projektowaniu przestrzennym Zajęcia we wtorki 13:15 do 15:00 spotkania w sali 352 w razie spotkań online MS Teams
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Singlet oxygen in the removal of organic pollutants: An updated review on the degradation pathways based on mass spectrometry and DFT calculations
PublicationThe degradation of pollutants by a non-radical pathway involving singlet oxygen (1O2) is highly relevant in advanced oxidation processes. Photosensitizers, modified photocatalysts, and activated persulfates can generate highly selective 1O2 in the medium. The selective reaction of 1O2 with organic pollutants results in the evolution of different intermediate products. While these products can be identified using mass spectrometry...
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Engineering boron and nitrogen codoped carbon nanoarchitectures to tailor molecularly imprinted polymers for PFOS determination
PublicationPer- and polyfluoroalkyl substances (PFAS) have gained significant attention as emerging contaminants due to their persistence, abundance, and adverse health effects. Consequently, the urgent need for ubiquitous and effective sensors capable of detecting and quantifying PFAS in complex environmental samples has become a priority. In this study, we present the development of an ultrasensitive molecularly imprinted polymer (MIP)...
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Comparison of hydrophilic interaction and reversed phase liquid chromatography coupled with tandem mass spectrometry for the determination of eight artificial sweeteners and common steviol glycosides in popular beverages
PublicationHydrophilic interaction liquid chromatography (HILIC) coupled with tandem mass spectrometry (MS/MS) was used to separate artificial and natural sweeteners approved for use in European Union (EU). Among three tested HILIC columns (BlueOrchid PAL-HILIC, Ascentis Express Si and Acclaim™ Trinity™ P2) the last one was selected for the development of HILIC method due to the best results obtained with it. Early eluting and coeluting compounds...
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In vivoevaluation of the CB1allosteric modulator LDK1258 reveals CB1-receptor independent behavioral effects
PublicationIn the present study, we examined whether LDK1258, which produces strong CB1receptor allosteric effects ininvitroassays, would elicitin vivoeffects consistent with allosteric activity. In initial studies, LDK1258 reducedfood consumption and elicited delayed antinociceptive effects in the chronic constrictive injury of the sciaticnerve (CCI) model of neuropathic pain, which unexpectedly emerged 4 h post-injection. UPLC-MS/MS analysisquantified...
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Studies on Silver Ions Releasing Processes and Mechanical Properties of Surface-Modified Titanium Alloy Implants
PublicationDispersed silver nanoparticles (AgNPs) on the surface of titanium alloy (Ti6Al4V) and titanium alloy modified by titania nanotube layer (Ti6Al4V/TNT) substrates were produced by the chemical vapor deposition method (CVD) using a novel precursor of the formula [Ag5(O2CC2F5)5(H2O)3]. The structure and volatile properties of this compound were determined using single crystal X-ray diffractometry, variable temperature IR spectrophotometry...
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Pharmaceuticals and another groups of emerging contaminants: Occurrence and sources in Admiralty Bay (King George Island, Maritime Antarctica)
PublicationEveryday live activities may introduce a wide range of chemicals into wastewater systems. In this study presence of selected types of pharmaceuticals from cardiovascular system group, nervous and muscolo-skeleton system group, antimicrobial agents, genitourinary and sex hormones were tested in the wastewater from H. Arctowski Antarctic station. Moreover, the receiver of discharged wastewater (Admiralty Bay) were also studied. Considering...
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Stabilities of bisphenol A diglycidyl ether, bisphenol F diglycidyl ether, and their derivatives under controlled conditions analyzed using liquid chromatography coupled with tandem mass spectrometry
PublicationBisphenol A diglycidyl ether (BADGE), bisphenol F diglycydyl ether (BFDGE), and their related compounds are widely used as precursors in production of epoxy resins. The high reactivity of these compounds makes the development of analytical methodologies that ensure appropriate metrological accuracy crucial. Consequently, we aimed to determine whether and to what extent the composition of the solution and storage conditions affect...
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Decyzje optymalne z Solverem
PublicationNa rynku można odnaleźć wiele podręczników pomocnych w rozwijaniu kompetencji związanych z posługiwaniem się arkuszem kalkulacyjnym w praktyce menedżerskiej. Niewiele jest natomiast pozycji literaturowych pokazujących możliwości wykorzystania MS Solver do wspomagania decyzji. Niniejsza książka ma za zadanie wypełnić tę lukę. Jej celem jest przedstawienie możliwości dodatku Solver w procesie podejmowania decyzji optymalnych. Intencją...
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Determination of robenidine in animal feeds by liquid chromatography coupled with diode-array detection and mass spectrometry after accelerated solvent extraction
PublicationRobenidyna (chlorowodorek 1,3-bis[(4-chlorobenzylideno)amino]guanidyny) jest stosowana w celu zapobiegania i leczenia kokcydiozy - pasożytniczej choroby układu pokarmowego wielu zwierząt hodowlanych (kozy, owce, króliki, drób) wywoływanej przez pierwotniaki należące do rzędu Eimeria tenella, E. Necatrix, E. Acervulina, E. Maxima, E. Brunetti, and E. Mivati. Robenidyna wykazuje stosunkowo wysoką skuteczność terapeutyczną, przy niewielkiej...
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Direct solid phase microextraction combined with gas chromatography – Mass spectrometry for the determination of biogenic amines in wine
PublicationA direct method based on immersion solid phase microextraction (DI-SPME) gas chromatography mass-spectrometry (GC-MS) was optimized and validated for the determination of 16 biogenic amines in Polish wines. In the analysis two internal standards were used: 1,7-diaminoheptane and bis-3-aminopropylamine. The method allows for simultaneous extraction and derivatization, providing a simple and fast mode of extraction and enrichment....
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Synthesis of conjugates of muramyl dipeptide and nor-muramyl dipeptide derivatives with adenosine as potential immunosuppressant
PublicationZaprezentowano syntezę koniugatów adenozyny z pochodnymi muramylo- i nor-muramylodipeptydów zawierających w części peptydowej D-aminokwasy (D-Ala, D-Val, D-Ser, D-Pro, D-2-ABA). Jako substrat zastosowano rybozyd 6-chloropuryny, który łączono poprzez 1,2-diaminoetan z odpowiednimi pochodnymi MDP lub nor-MDP w obecności EDCI i HOBt. Struktury otrzymanych związków zostały potwierdzone widmami 1H i 13C NMR (500 MHz), widmami MS oraz...
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Experimentation, material modelling and simulation of bonded joints with a flexible adhesive
PublicationThe paper deals with material parameters identification of a flexible adhesive and the numerical simulation of its behaviour in a single lap bonded joint. The material modelling was based on the simple shear and tensile-shear laboratory tests of the bonded joints made of thin aluminium and polyurethane plates with the flexible adhesive Terostat MS 9360 manufactured by Henkel AG & Co. The adhesive was considered as a hyperelastic...
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Synthesis of conjugates of muramyl dipeptide and nor-muramyl dipeptide derivatives with adenosine as potential immunosuppressants
PublicationPrzedstawiono syntezę koniugatów pochodnych muramylodipeptydu (MDP) i nor-MDP z adenozyną jako potencjalnych związków o działaniu immunosupresyjnym. Jako substrat zastosowano rybozyd 6-chloropuryny, który łączonp poprzez 1,2-diaminoetan z pochodną MDP lub nor-MDP. Do syntezy wykorzystano pochodne MDP zawierające w części peptydowej D-aminokwasy (D-Ala, D-Val, D-Ser, D-Pro, D-2-ABA). Jako odczynniki sprzęgające zastosowano EDCI...