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Search results for: c-h methylene compounds
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Możliwości energetycznego wykorzystania osadów ściekowych jako paliwa
PublicationObecnie szeroko dyskutowana jest efektywność energetyczna oczyszczalni, stąd istotnym zagadnieniem staje się prawidłowe wykorzystanie potencjału energetycznego osadów ściekowych (CHP i ITPO). Realizacja termicznej przeróbki osadów ściekowych wymaga znajomości właściwości energetycznych (ciepło spalania, wartość opałowa, zawartość wody) oraz składu pierwiastkowego, wskazującego na zawartość substancji lotnych i mineralnych osadów...
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Aluminum-TiO2 NPs Composites as Non-precious Catalysts for Efficient Electrochemical Generation of Hydrogen
PublicationIn this paper, we demonstrated, for the first time, aluminum titania nanoparticle (Al-TiO2 NP) composites with variable amounts of TiO2 NPs as nonprecious active catalysts for the electrochemical generation of H2. These materials were synthesized by mixing desired amounts of hydrogen titanate nanotubes (TNTs), fabricated here by a cost-effective approach at moderate hydrothermal conditions, with aluminum powder (purity 99.7%; size...
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Porous carbon derived from rice husks as sustainable bioresources: insights into the role of micro-/mesoporous hierarchy in hosting active species for lithium–sulphur batteries
PublicationThe exploration of natural resources as sustainable precursors affords a family of green materials. Exploring highly abundant and available biowaste precursors remaining from food processing throughout a scalable and cost-effective material synthesis path is highly important especially for new materials discovery in emerging energy storage technologies such as lithium–sulphur (Li–S) batteries. Herein, we have produced a series...
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Biopolyols obtained via crude glycerol-based liquefaction of cellulose: their structural, rheological and thermal characterization
PublicationIn this work lignocellulose biomass liquefaction was used to produce biopolyols suitable for the manufacturing of rigid polyurethane foams. In order to better evaluate the mechanism of the process, pure cellulose was applied as a raw material. The effect of time and temperature on the effectiveness of liquefaction and the parameters of resulting biopolyols were characterized. The prepared materials were analyzed in terms of their...
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Enhanced hydrogen evolution reaction on highly stable titania-supported PdO and Eu2O3 nanocomposites in a strong alkaline solution
PublicationIn this work, PdO/TiO2 and Eu2O3/TiO2 nanocomposites (NCs), were synthesized using a new facile, template-free and one-step solvothermal approach, and characterized by several instrumentation techniques. X-ray photoelectron spectroscopy (XPS) studies revealed the presence of oxidised form of the Pd and Eu nanoparticles within the nanocomposite materials (PdO and Eu2O3). The two catalysts exhibited remarkable activity for the HER...
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Organochlorine pesticides and polichlorinated biphenyls concentrations in fresh snowfall or top layer of snow from Hornsund region, Svalbard, in the spring 2019
Open Research DataThe dataset contains concentration of organochlorine persistent organic pollutants in snow samples collected from top layer of snow, which corresponded to fresh snowfall in most cases (except DS location, where these are 20 cm top layer sampled weekly). All snow samples have been collected within one month during spring 2019, in the vicinity of the...
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Influence of Cement Replacement with Sewage Sludge Ash (SSA) on the Heat of Hydration of Cement Mortar
PublicationThe amount of fly ash from the incineration of sewage sludge is increasing all over the world, and its utilization is becoming a serious environmental problem. In the study, a type of sewage sludge ash (SSA) collected directly from the municipal sewage treatment plant was used. Five levels of cement replacement (2.5%, 5%, 7.5%, 10% and 20%) and unchanged water-to-binder (w/b) ratio (0.55) were used. The purpose of the study was...
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Solvent Screening for Solubility Enhancement of Theophylline in Neat, Binary and Ternary NADES Solvents: New Measurements and Ensemble Machine Learning
PublicationTheophylline, a typical representative of active pharmaceutical ingredients, was selected to study the characteristics of experimental and theoretical solubility measured at 25 °C in a broad range of solvents, including neat, binary mixtures and ternary natural deep eutectics (NADES) prepared with choline chloride, polyols and water. There was a strong synergistic effect of organic solvents mixed with water, and among the experimentally...
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Development and evaluation of thermosensitive hydrogels with binary mixture of Scutellariae baicalensis radix extract and chitosan for periodontal diseases treatment.
PublicationScutellaria baicalensis root displays anti-inflammatory and antibacterial properties due to the presence of flavonoids, particularly baicalin, baicalein, and wogonin. Our work aimed at developing thermosensitive hydrogels containing a binary mixture of S. baicalensis radix lyophilized extract and chitosan as a novel approach for periodontal diseases treatment....
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An investigation on the chemistry of the R2P=P ligand: reactions of a phosphanylphosphinidene complex of tungsten(VI) with electrophilic reagents
PublicationThe nucleophilic properties of the title compound [(2,6-i-Pr2C6H3N)2(Cl)W(η2-t-Bu2PvP)]Li·3DME (1) were investigated in reactions with selected electrophilic reagents such as MeI, M(CO)5THF (M = Cr, Mo, W), AlCl3, and GaCl3. Methylation of 1 by MeI yields phosphanylphosphido complexes [(2,6-i-Pr2C6H3N)2W(X)(1,2-η-t-Bu2PvP–CH3)] (X = Cl, I) (2-Cl/2-I) with the formation of a new P–C bond. Moreover, 1 reacts with electrophilic compounds...
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Microcrystalline Cellulose Management in the Production of Poly(ether-urethane)s- Structure, Morphology, and Thermal Characteristic
PublicationIn response to the demand of polymer industry for reducing the use of synthetic chemicals, eco-friendly materials are investigated. In the presented study, bio-based poly(ether-urethane)s were prepared by using microcrystalline cellulose (MCC) and polyether polyol and 1,3-propanediol derived from corn sugar. A step towards sustainability was taken by incorporating bio-based compounds and cellulose, consequently, bio-waste are utilized...
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Bioactive and bioavailability of minerals in rats loaded with cholesterol and kiwi fruit
PublicationThe aim of this study was to compare the content of polyphenols (TP), minerals, ascorbic acid (AA) and total antioxidant capacities (TAC) of conventional and organic kiwifruit ‘Hayward’ treated with ethylene after harvest and to determine their influence on plasma TAC, mineral content in the liver and bioavailability (RBV — relative bioavailability value) in rats fed diet containing cholesterol. Organic and conventionally grown...
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A Series of Novel 3D Coordination Polymers Based on the Quinoline-2,4-dicarboxylate Building Block and Lanthanide(III) Ions—Temperature Dependence Investigations
PublicationA series of novel 3D coordination polymers [Ln2(Qdca)3(H2O)x]yH2O (x = 3 or 4, y = 0–4) assembled from selected lanthanide ions (Ln(III) = Nd, Eu, Tb, and Er) and a non-explored quinoline- 2,4-dicarboxylate building block (Qdca2 = C11H5NO4 2) were prepared under hydrothermal conditions at temperatures of 100, 120, and 150 C. Generally, an increase in synthesis temperature resulted in structural transformations and the formation...
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Similarities and differences in d6 low-spin ruthenium, rhodium and iridium half-sandwich complexes: synthesis, structure, cytotoxicity and interaction with biological targets
PublicationIn this paper, we discussed the similarities and diferences in d6 low-spin half-sandwich ruthenium, rhodium and iridium complexes containing 2,2′-biimidazole (H2biim). Three new complexes, {[RuCl(H2biim)(η6 -p-cymene)]PF6}2·H2O (1), [(η5 - Cp)RhCl(H2biim)]PF6 (2), and [(η5 -Cp)IrCl(H2biim)]PF6 (3), were fully characterized by CHN, X-ray difraction analysis, UV–Vis, FTIR, and 1 H, 13C and 15N NMR spectroscopies. The complexes exhibit...
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From structure to luminescence investigation of oxyfluoride transparent glasses and glass-ceramics doped with Eu3+/Dy3+ ions
PublicationGlasses and glass-ceramics with nominal composition 73 TeO2– 4BaO– 3Bi2O3–18SrF2-2RE2O3 (where RE = Eu, Dy) have been synthesized by conventional melt-quenching technique and subsequent heat treatment at 370 °C for 24 h in air atmosphere. Various Eu3+ to Dy3+ molar ratio have been applied to investigate luminescence properties in both glass and glass-ceramic matrices. Especially, white light emission through simultaneous excitation...
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Transport deficiency is the molecular basis of Candida albicans resistance to antifungal oligopeptides
Publication(FMDP), an inhibitor of glucosamine-6-phosphate synthase, exhibited growth inhibitory activity against Candida albicans, with minimal inhibitory concentration values in the 0.05–50 mg/L range. Uptake by the peptide permeases was found to be the main factor limiting an anticandidal activity of these compounds. Di- and tripeptide containing FMDP (F2 and F3) were transported by Ptr2p/Ptr22p peptide transporters (PTR) and FMDP-containing...
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Antibiotic-Based Conjugates Containing Antimicrobial HLopt2 Peptide: Design, Synthesis, Antimicrobial and Cytotoxic Activities
PublicationRecent studies have shown that modified human lactoferrin 20−31 fragment, named HLopt2, possesses antibacterial and antifungal activity. Thus, we decided to synthesize and evaluate the biological activity of a series of conjugates based on this peptide and one of the antimicrobials with proven antibacterial (ciprofloxacin, CIP, and levofloxacin, LVX) or antifungal (fluconazole, FLC) activity. The drugs were covalently connected...
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Magnetically recyclable TiO2/MXene/MnFe2O4 photocatalyst for enhanced peroxymonosulphate-assisted photocatalytic degradation of carbamazepine and ibuprofen under simulated solar light
PublicationIn this study, a novel TiO2/Ti3C2/MnFe2O4 magnetic photocatalyst with dual properties, enabling (i) improved photocatalytic degradation with PMS activation under simulated solar light and (ii) magnetic separation after the degradation process in an external magnetic field was developed and applied for the efficient photodegradation pharmaceutically active compounds (PhACs) frequently present in wastewater and surface waters worldwide. MXene...
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Density functional theory-based simulations of sum frequency generation spectra involving methyl stretching vibrations: effect of the molecular model on the deduced molecular orientation and comparison with an analytical approach
PublicationThe knowledge of the first hyperpolarizability tensor elements of molecular groups is crucial for a quantitative interpretation of the sum frequency generation (SFG) activity of thin organic films at interfaces. Here, the SFG response of the terminal methyl group of a dodecanethiol (DDT) monolayer has been interpreted on the basis of calculations performed at the density functional theory (DFT) level of approximation. In particular,...
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Conversion of waste biomass to designed and tailored activated chars with valuable properties for adsorption and electrochemical applications
PublicationWaste biomass, a renewable energy source, is inexpensive material that has great potential in sorp-tion and electrochemical application. The selected waste materials (corncobs, coconut shells, wal-nuts, and pistachio husks) allow to close the production cycle and enable material recycling, which are important aspects in the hierarchy of waste management. The proposed methodology for pro-duction and activation of biochars can be...
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Fusion of Taq DNA polymerase with single-stranded DNA binding-like protein of Nanoarchaeum equitans—Expression and characterization
PublicationDNA polymerases are present in all organisms and are important enzymes that synthesise DNA molecules. They are used in various fields of science, predominantly as essential components for in vitro DNA syntheses, known as PCR. Modern diagnostics, molecular biology and genetic engineering need DNA polymerases which demonstrate improved performance. This study was aimed at obtaining a new NeqSSB-TaqS fusion DNA polymerase from the...
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Chemiczne Źródła Prądu
e-Learning CoursesPrzedmiot przeznaczony dla Studentów I stopnia FTiMS kierunek KE, Obejmuje wykład 15 h - obecność wskazana Laboratoria 15 h - obecność obowiązkowa Treści przedmiotu I. Podstawy elektrochemiiJonika- Transport ładunku w elektrolitach: elektrolity wodne,elektrolity aprotyczne, elektrolity polimerowe,elektrolity żelowe, elektrolity stałe.Elektrodyka - Granica faz metal /elektrolit, półprzewodnik /elektrolit, membrane elektrolit....
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Chemiczne Źródła Prądu
e-Learning CoursesPrzedmiot przeznaczony dla Studentów I stopnia FTiMS kierunek KE, Obejmuje wykład 15 h - obecność wskazana Laboratoria 15 h - obecność obowiązkowa Treści przedmiotu I. Podstawy elektrochemiiJonika- Transport ładunku w elektrolitach: elektrolity wodne,elektrolity aprotyczne, elektrolity polimerowe,elektrolity żelowe, elektrolity stałe.Elektrodyka - Granica faz metal /elektrolit, półprzewodnik /elektrolit, membrane elektrolit....
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THE GENE CLONING, OVEREXPRESSION, PURIFICATION AND BIOCHEMICAL CHARACTERISATION OF A NEW COLD-ADAPTED β–GALACTOSIDASE FROM ARTHROBACTER SP. VII-4
PublicationINTRODUCTION. β-Galactosidase [EC 3.2.1.23] is an enzyme that catalyzes the hydrolysis of O-glycosidic linkages in galactosides. It is commercially used in dairy industry for the production of milk with reduced lactose content. Potentially, the best method for lactose removal under cooling conditions should be carried out with a cold-adapted enzyme. AIM. The aim of this study was to determine the taxonomic affiliation of the isolate...
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Hydrothermal synthesis of vanadium ammonium compounds – the crucial role of the pressure
PublicationDue to the structural diversity and chemical activity, vanadium oxides and their derivatives are continuingly in the great interest of scientist. In a large family of vanadium compounds, one of the most interesting are ammonium vanadates (with the general formula (NH4)xVyOz). They have received much attention because of their promising application as cathode material in mono- and multivalent-ion batteries [1]. Hydrothermal synthesis...
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Hydration of Carboxylate Anions: Infrared Spectroscopy of Aqueous Solutions
PublicationHydratacja anionów karboksylanowych w roztworach wodnych ich soli sodowych została zbadana przy wykorzystaniu spektroskopii FTIR z zastosowaniem cząsteczki HDO jako sondy molekularnej. Do wyznaczenia widm wody zaburzonej przez rozpuszczalnik wykorzystano ilościową wersję metody widm różnicowych. Widma te wykazują dwa pasma składowe przy ok. 2550 i ok. 2420 cm-1. Pasma te przypisano grupie -COO- anionu R-COO- (R = H, CH3, C2H5),...
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Cathodic Activation of Titania-Fly Ash Cenospheres for Efficient Electrochemical Hydrogen Production: A Proposed Solution to Treat Fly Ash Waste
PublicationFly ash (FA) is a waste product generated in huge amounts by coal-fired electric and steam-generating plants. As a result, the use of FA alone or in conjunction with other materials is an intriguing study topic worth exploring. Herein, we used FA waste in conjunction with titanium oxide (TiO2) to create (FA-TiO2) nanocomposites. For the first time, a cathodic polarization pre-treatment regime was applied to such nanocomposites...
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Dataset of phase portraits of the fractional prey-predator model with Holling type-II interaction (without predator harvesting)
Open Research DataThe need for a fractional generalization of a given classical model is often due to new behaviors which cannot be taken into account by the model. In this situation, it can be useful to look for a fractional deformation of the initial system, trying to fit the fractional exponent of differentiation in order to catch properly the data.
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Prediction of Overall In Vitro Microsomal Stability of Drug Candidates Based on Molecular Modeling and Support Vector Machines. Case Study of Novel Arylpiperazines Derivatives
PublicationOther than efficacy of interaction with the molecular target, metabolic stability is the primary factor responsible for the failure or success of a compound in the drug development pipeline. The ideal drug candidate should be stable enough to reach its therapeutic site of action. Despite many recent excellent achievements in the field of computational methods supporting drug metabolism studies, a well-recognized procedure to model...
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Cathodic activation of synthesized highly defective monoclinic hydroxyl‐functionalized ZrO2 nanoparticles for efficient electrochemical production of hydrogen in alkaline media
PublicationThe high electrochemical stability of Zirconia (ZrO2) at high potentials strongly suggested it as an alternative to carbon supports, which experience reduced efficiency due to some corrosion problems particularly during prolonged electrocatalysis activity. However, the use of ZrO2 was limited by its low electrical conductivity and surface area. In this work, we developed a methodology for synthesizing monoclinic ZrO2 NPs with increased...
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A geophysical, geochemical and microbiological study of a newly discovered pockmark with active gas seepage and submarine groundwater discharge (MET1-BH, central Gulf of Gdańsk, southern Baltic Sea)
PublicationHigh-resolution bathymetric data were collected with a multi-beam echosounder in the southern part of the Baltic Sea (region MET1, Gulf of Gdańsk) revealing the presence of a 10 m deep and 50 m in diameter pockmark (MET1-BH) on the sea bottom (78.7 m). To date, no such structures have been observed to reach this size in the Baltic Sea. The salinity of the near-bottom water in the pockmark was about 2 PSU (about 31.22 mmol/l...
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A set of data constituting the basis for the publication entitled "Mitochondria dysfunction is one of the causes of diclofenac toxicity in the green alga Chlamydomonas reinhardtii"
Open Research DataNon-steroidal anti-inflammatory drugs (NSAIDs), such as diclofenac (DCF), form a significant group of environmental contaminants. When the toxic effects of DCF on plants are analyzed, authors often focus on photosynthesis, whilemitochondrial respiration is usually overlooked. Therefore, an in vivo investigation of plant mitochondria functioning under...
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18th European Symposium on Radiopharmacy and Radiopharmaceuticals
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Long-term hindcast simulation of water temperature and salinity in the Baltic Sea
Open Research DataThe dataset contains the results of numerical modelling of water temperature and salinity over a period of 50 years (1958-2007) in the Baltic Sea. A long-term hindcast simulation was performed using a three-dimensional hydrodynamic model PM3D (Kowalewski and Kowalewska-Kalkowska, 2017), a new version of the M3D model (Kowalewski, 1997). The hydrodynamic...
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AVHRR Level1CD covering Baltic Sea area year 2006
Open Research DataThe product level is the NOAA AVHRR Level 1C that is result of processing the AVHRR data from the HRPT stream based on ancillary information like sensing geometry and calibration data. Then converted into geophysical variables: top-of-the atmosphere (TOA) albedo or brightness temperature. Additionally, information like geolocation has been added. Other...
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AVHRR Level1CD covering Baltic Sea area year 2010
Open Research DataThe product level is the NOAA AVHRR Level 1C that is result of processing the AVHRR data from the HRPT stream based on ancillary information like sensing geometry and calibration data. Then converted into geophysical variables: top-of-the atmosphere (TOA) albedo or brightness temperature. Additionally, information like geolocation has been added. Other...
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AVHRR Level1CD covering Baltic Sea area year 2007
Open Research DataThe product level is the NOAA AVHRR Level 1C that is result of processing the AVHRR data from the HRPT stream based on ancillary information like sensing geometry and calibration data. Then converted into geophysical variables: top-of-the atmosphere (TOA) albedo or brightness temperature. Additionally, information like geolocation has been added. Other...
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AVHRR Level1CD covering Baltic Sea area year 2011
Open Research DataThe product level is the NOAA AVHRR Level 1C that is result of processing the AVHRR data from the HRPT stream based on ancillary information like sensing geometry and calibration data. Then converted into geophysical variables: top-of-the atmosphere (TOA) albedo or brightness temperature. Additionally, information like geolocation has been added. Other...
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AVHRR Level1CD covering Baltic Sea area year 2012
Open Research DataThe product level is the NOAA AVHRR Level 1C that is result of processing the AVHRR data from the HRPT stream based on ancillary information like sensing geometry and calibration data. Then converted into geophysical variables: top-of-the atmosphere (TOA) albedo or brightness temperature. Additionally, information like geolocation has been added. Other...
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AVHRR Level1CD covering Baltic Sea area year 2008
Open Research DataThe product level is the NOAA AVHRR Level 1C that is result of processing the AVHRR data from the HRPT stream based on ancillary information like sensing geometry and calibration data. Then converted into geophysical variables: top-of-the atmosphere (TOA) albedo or brightness temperature. Additionally, information like geolocation has been added. Other...
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AVHRR Level1CD covering Baltic Sea area year 2009
Open Research DataThe product level is the NOAA AVHRR Level 1C that is result of processing the AVHRR data from the HRPT stream based on ancillary information like sensing geometry and calibration data. Then converted into geophysical variables: top-of-the atmosphere (TOA) albedo or brightness temperature. Additionally, information like geolocation has been added. Other...
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AVHRR Level1CD covering Baltic Sea area year 2001
Open Research DataThe dataset contains data derived from recordings of the AVHRR/3 radiometer operating on board the NOAA POES (Polar Orbiting Environmental Satellites) Series - 5th Generation Satellites covering the Baltic Sea area. The satellite data was recorded in the years 2000-2012 directly by the HRPT station installed at the University of Gdańsk. The registration...
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Karol Grębowski dr inż.
PeopleKarol Grębowski (M.Sc.) works as an assistant at the Department of Technical Fundamentals of Architecture Design of the Faculty of Architecture at Gdansk University of Technology. His scientific research deals with dynamic phenomena occurring during the vibration of structures, bridges, and studies the design methodology of the elements forming passive protection system of the vehicles degraded by struck or explosion in the context...
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AVHRR Level1CD covering Baltic Sea area year 2005
Open Research DataThe dataset contains data derived from recordings of the AVHRR/3 radiometer operating on board the NOAA POES (Polar Orbiting Environmental Satellites) Series - 5th Generation Satellites covering the Baltic Sea area. The satellite data was recorded in the years 2000-2012 directly by the HRPT station installed at the University of Gdańsk. The registration...
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AVHRR Level1CD covering Baltic Sea area year 2004
Open Research DataThe dataset contains data derived from recordings of the AVHRR/3 radiometer operating on board the NOAA POES (Polar Orbiting Environmental Satellites) Series - 5th Generation Satellites covering the Baltic Sea area. The satellite data was recorded in the years 2000-2012 directly by the HRPT station installed at the University of Gdańsk. The registration...
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Long-term measurements from a photovoltaic power plant and meteorological stations at the Laboratory LINTE^2 of Gdańsk University of Technology
Open Research Data1) The Laboratory LINTE^2 is a large research infrastructure operated by the Faculty of Electrical and Control Engineering at Gdańsk University of Technology, to be found in Gdańsk, Poland (54.3690 N, 18.6130 E). 2) The measurements have been collected from a photovoltaic power plant located on the roof of the laboratory, having total capacity...
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AVHRR Level1CD covering Baltic Sea area year 2003
Open Research DataThe dataset contains data derived from recordings of the AVHRR/3 radiometer operating on board the NOAA POES (Polar Orbiting Environmental Satellites) Series - 5th Generation Satellites covering the Baltic Sea area. The satellite data was recorded in the years 2000-2012 directly by the HRPT station installed at the University of Gdańsk. The registration...
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AVHRR Level1CD covering Baltic Sea area year 2002
Open Research DataThe dataset contains data derived from recordings of the AVHRR/3 radiometer operating on board the NOAA POES (Polar Orbiting Environmental Satellites) Series - 5th Generation Satellites covering the Baltic Sea area. The satellite data was recorded in the years 2000-2012 directly by the HRPT station installed at the University of Gdańsk. The registration...
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Supplementary material for: Fungal Planet description sheets: 1478–1549
Open Research DataNovel species of fungi described in this study include those from various countries as follows: Australia, Bolivia, Brazil, Bulgaria, Canada, China, Denmark, Ecuador (Galapagos), Finland, France, India, Iran, Israel, Italy, Namibia, Netherlands, Norway, Pakistan, Poland, Portugal, Qatar, South Africa, South Korea, Spain, Sweden, Thailand, Taiwan region...
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Elective surgery system strengthening: development, measurement, and validation of the surgical preparedness index across 1632 hospitals in 119 countries
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