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Search results for: ion-induced collision
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Impact response of novel layered two stage fibrous composite slabs with different support type
PublicationThe performance of novel Layered Two Stage Fibrous Composite slabs (LTSFC) was pioneered under falling mass collisions using a combined experimental and numerical study. Such LTSFC slabs consist of three layers with and without the insertion of glass fibre mesh between the layers. LTSFC techniques were used to fabricate the composite slabs with three layers including 3%, 1.5%, and 3% of fibre content for the top, middle, and...
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Binary-Encounter Model for Direct Ionization of Molecules by Positron-Impact
PublicationWe introduce two models for the computation of direct ionization cross sections by positron impact over a wide range of collision energies. The models are based on the binary-encounter-Bethe model and take into account an extension of the Wannier theory. The cross sections computed with these models show good agreement with experimental data. The extensions improve the agreement between theory and experiment for collision energies...
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Experimental Comparison of Straight Lines and Polynomial Interpolation Modeling Methods in Ship Evolutionary Trajectory Planning Problem
PublicationPaper presents the application of evolutionary algorithms and polynomial interpolation in ship evolutionary trajectory planning method and its comparison to classic approach, where trajectory is modeled by straight lines. Evolutionary algorithms are group of methods that allows\ to find a collision free trajectory in real time, while polynomial interpolation allows to model smooth trajectory, which keeps continuity of velocity...
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Równolegle przebiegające procesy separacji pianowej jonów Al(III), Cu(II) i Zn(II) z roztworów ich mieszanin
PublicationMetody flotacji jonowej i precypitacyjnej należą do procesów separacji pianowej, wykorzystujących zdolność selektywnej adsorpcji niektórych składników roztworu na powierzchni międzyfazowej gaz – ciecz. Do zalet separacji pianowej zalicza się m.in. niewysokie koszty inwestycyjne i eksploatacyjne oraz wysoką skuteczność w obróbce roztworów rozcieńczonych. Celem pracy jest ocena wpływu kluczowych parametrów na wydajność i przebieg...
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Depth XPS profile of vanadium pentoxide
Open Research DataVanadium pentoxide sample was manufactured by sol-gel method and deposited on a substrate by spin coating technique. To determine depth profile of chemical composition of thin film, etching by Argon ion gun was used. Thin film was etched three times. Chemical composition was measured by XPS method.
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The luminescence study of SrAl11.88−xGaxO19:0.12Cr3+ coumpounds.
Open Research DataPortable near-infrared (NIR) light sources are in high demand for applications in spectroscopy, night vision, bioimaging, and many others. Typical phosphor designs feature isolated Cr3+ ion centers, and it is challenging to design broadband NIR phosphors based on Cr3+–Cr3+ pairs. Here, we explore the solid-solution series SrAl11.88–xGaxO19:0.12Cr3+...
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Gracjana Klein-Raina dr hab.
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Mury oporowe z gruntu zbrojonego z przekładkami z keramzytu
PublicationW czerwcu 2019 r. nastąpiło otwarcie nowo budowanego wiaduktu na ulicy Drwęckiej w Ostródzie, który zastąpił jeden z trzech przejazdów kolejowo-drogowych znajdujących się w centrum miasta. Zakończenie budowy bezkolizyjnego przejazdu nad torami kolejowymi pozwoliło na bezpieczne oraz szybkie połączenie północnej i południowej części Ostródy. Zastosowanie materacy z keramzytu w konstrukcji z gruntu zbrojonego.
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Roman Śmierzchalski prof. dr hab. inż.
PeopleRoman Śmierzchalski born in 1956 in Gdynia. He received the M.Sc. degree in 1979, the Ph.D. degree in 1989, both from the Gdańsk University of Technology, and the D.Sc. (‘habilitation’) degree in 1999 from the Warsaw University of Technology. From 1980 to 2009 he was an academic teacher and researcher with the Gdynia Maritime University, and since 2009 he has been with the Gdansk University of Technology, where he is currently...
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Chromogenic derivatives of new bis(phenylhydrazono-1H-tetrazol-5-yl-acetonitriles) - synthesis and properties
PublicationDerivatives of bis(phenylhydrazono-1H-tetrazol-5-yl-acetonitriles) with oxygen and sulphur atoms in the structure of aliphatic chains were successfully synthesised. The correlation between the ligand structure and its complexation properties was investigated by absorption spectroscopy. The formation of complexes of presented compounds with metal cations (Cu2+, Ni2+, Zn2+, Co2+, Fe2+ and Pb2+) was studied. Ligands 5-8 were additionally...
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Advanced Ship Control Methods
PublicationThe chapter presents two main streams of research in vessel control at sea: dynamic positioning (DP) of the vessel and decision support in case of collision at sea. The control structure and basic requirements for the DP system are defined. Selected issues of automatic control of a dynamically positioned vessel are discussed. A review of advanced methods of controlling a DP ship is carried out, taking into account the tasks of...
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Selective detection of F- by chromogenic tetrazole receptor
PublicationA chromogenic anion host 4, containing two amide functionalities linked to azo dye and tetrazole rings was synthesized and its complexes with various anions were investigated. The results show that receptor 4 can recognize selectively biologically important F- ion. The binding affinity for F- was investigated by naked-eye colour change, UV-Vis and 1H NMR spectroscopy. Addition F- ion in CH3CN and DMSO to receptor 4 cause a colour...
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Analysis and Comparison of Safety of Children and Adult Passenger in Car Based on Crash Tests Results
PublicationMost important features of the child seat were presented. There was made analysis of selected dynamic loads acting on mannequins heads during a collision. Comparison of loads acting on the kid in a child seat and the other passengers in a car is presented. In analysis of the results particular attention has been paid on the children's secure in a car. The phenomena of collision child's occipital bone with seat backrest was described....
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MECONIUM SAMPLES USED TO ASSESS INFANT EXPOSURE TO THE COMPONENTS OF ETS DURING PREGNANCY
PublicationThe aim of the study was to use meconium samples to assess fetal exposure to compounds present in environmental tobacco smoke (ETS). Material and Methods: In order to assess fetal exposure to toxic tobacco smoke compounds, samples of meconium from the offspring of women with different levels of tobacco smoke exposure, and the samples of saliva from the mothers were analyzed. Thiocyanate ion as a biomarker of tobacco smoke exposure,...
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A general approach to study molecular fragmentation and energy redistribution after an ionizing event
PublicationWe propose to combine quantum chemical calculations, statistical mechanical methods, and photoionization and particle collision experiments to unravel the redistribution of internal energy of the furan cation and its dissociation pathways. This approach successfully reproduces the relative intensity of the different fragments as a function of the internal energy of the system in photoelectron–photoion coincidence experiments and...
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The Empirical Application of Automotive 3D Radar Sensor for Target Detection for an Autonomous Surface Vehicle’s Navigation
PublicationAvoiding collisions with other objects is one of the most basic safety tasks undertaken in the operation of floating vehicles. Addressing this challenge is essential, especially during unmanned vehicle navigation processes in autonomous missions. This paper provides an empirical analysis of the surface target detection possibilities in a water environment, which can be used for the future development of tracking and anti-collision...
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Framework of an Evolutionary Multi-Objective Optimisation Method for Planning a Safe Trajectory for a Marine Autonomous Surface Ship
PublicationThis paper represents the first stage of research into a multi-objective method of planning safe trajectories for marine autonomous surface ships (MASSs) involved in encounter situations. Our method applies an evolutionary multi-objective optimisation (EMO) approach to pursue three objectives: minimisation of the risk of collision, minimisation of fuel consumption due to collision avoidance manoeuvres, and minimisation of the extra...
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Dissociative photo-double-ionization of isoxazole
PublicationIn the present communication, we present results on the photo-double-ionization and fragmentation of the isoxazole molecules. The experiments were carried out at the CiPo beamline at the Elettra-Sincrotrone radiation facility exploiting the VUV excitation and the ion time-of-flight spectrometry combined with the PEPICO technique. The dissociative processes where only one electron is emitted are quite well known [1]. However, double...
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Synthesis and characterization of MoS2-carbon based materials for enhanced energy storage applications
PublicationThe article delves into the synthesis and characterization of MoS2-carbon-based materials, holding promise for applications in supercapacitors and ion batteries. The synthesis process entails the preparation of MoS2 and its carbon hybrids through exfoliation, hydrothermal treatment, and subsequent pyrolysis. Various analytical techniques were employed to comprehensively examine the structural, compositional, and morphological properties...
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Al(III) and Cu(II) simultaneous foam separation: Physicochemical problems
PublicationSimultaneous removal of Al(III) and Cu(II) from dilute aqueous solutions by ion and precipitate flotation methods is investigated. Influence of the pH of the initial solution, the surface active collector concentration and the gas flow rate on the final removal ratio and the course of ion and precipitate flotations is presented. Results show that simultaneous flotations of Al(OH)3 and Cu(OH)2 insoluble species occur allowing to...
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Comparison of Single and Multi-Population Evolutionary Algorithm for Path Planning in Navigation Situation
PublicationIn this paper a comparison of single and multi-population evolutionary algorithm is presented. Tested algorithms are used to determine close to optimal ship paths in collision avoidance situation. For this purpose a path planning problem is defined. A specific structure of the individual path and fitness function is presented. Principle of operation of single-population and multi-population evolutionary algorithm is described....
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COLREGS compliance in Evolutionary Sets of Cooperating Ship Trajectories
PublicationIn general, Evolutionary Sets of Cooperating Ship Trajectories combine some of the assumptions of game theory with evolutionary programming and aim to find optimal set of cooperating trajectoriesof all ships involved in an encounter situation. In a two-ship encounter situation the method enables the operator of an on-board collision-avoidance system to predict the most probable behaviour of atarget and to plan the own manoeuvres...
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Simulation Environment in Python for Ship Encounter Situations
PublicationTo assess the risk of collision in radar navigation distance-based safety measures such as Distance at the Closest Point of Approach and Time to the Closest Point of Approach are most commonly used. Also Bow Crossing Range and Bow Crossing Time measures are good complement to the picture of the meeting situation. When ship safety domain is considered then Degree of Domain Violation and Time to Domain Violation can be applied. This...
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Data set generation at novel test-rig for validation of numerical models for modeling granular flows
PublicationSignificant effort has been exerted on developing fast and reliable numerical models for modeling particulate flow; this is challenging owing to the complexity of such flows. To achieve this, reliable and high-quality experimental data are required for model development and validation. This study presents the design of a novel test-rig that allows the visualization and measurement of particle flow patterns during the collision...
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Electron-impact ionization cross section of formic acid
PublicationExperimental electron-impact ionization cross sections of one of the simplest carboxylic acids, formic acid, are presented. The molecular target was studied in two independent experimental setups applying different methods: the total ion collection and the electron–impact mass spectrometry methods. Experimental data were taken at incident electron energies ranging from ionization threshold [11.31 eV; J.C. Traeger, Int. J. Mass...
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Positron Scattering and Annihilation in Organic Molecules
PublicationIn this paper, we address the problem of connecting positron lifetimes in liquids with collision cross sections in gases. We present the analyses of annihilation lifetime spectra of positrons in the liquid benzene, c-hexane, n-hexane, methanol and ethanol and calculations of scattering cross sections of positrons with benzene and c-hexane in the gas phase.
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Raman studies of 3D printed CB-PLA samples after microwave treatment
Open Research DataThis dataset contains Raman spectroscopy analyses of microwave-activated carbon-black doped polylactic acid 3D printed electrodes.
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X-ray Photoelectron Spectroscopy (XPS) results of bulk boron and borophene after the ball-milling process
Open Research DataThese data contain X-ray Photoelectron Spectroscopy (XPS) results of boron and borophene nanoflakes induced during ball milling at rotation speed of 450 rpm, 6 h and mass loading of 1g.
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Inhibition of impurities formation in the synthesis of N-alkyltheobromines stimulated by microwave irradiation. Cationic and anionic response of membrane electrodes
PublicationN-Alkyltheobromine (1-9) derivatives were obtained by reacting theobromine with appropriate alkyl halide under microwave irradiation at 100-150 W and by conventional synthesis. Formation of by-products of oxygen atom alkylation and 1-N-alkyltheobromine ring opening were considered. The presented compounds 1-5 have been studied as ion carriers in ion-selective membrane electrodes. Selectivity of these membranes was studied towards...
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A System for Cooling Electronic Elements with EHD Coolant Flow
PublicationA system for cooling electronic components where the liquid coolant flow is forced with ion-drag type EHD micropumps was tested.
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Jednoelektronowy atom Diraca w słabym polu magnetycznym
PublicationW rozprawie przedstawiono opis wpływu zewnętrznego stałego, słabego, jednorodnego pola magnetycznego na jednoelektronowy atom Diraca. Wykorzystując funkcje gęstości ładunku elektrycznego oraz gęstości prądu elektrycznego, rozważono procesy indukowania się w atomie dodatkowych elektromagnetycznych momentów multipolowych. Dokonano analizy indukowanego momentu dipolowego, w wyniku której uzyskano wyrażenie dla magnetyzowalności atomu....
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Lower rim substituted p-tert-butyl-calix[4]arene. Part 17. synthesis, extractive and ionophoric properties of p-tert-butylcalix[4]arene appended with hydroxamix acid moieties
PublicationThe synthesis and characterization of four p-tert-butylcalix[4]arene-hydroxamic acidc are reported. The dependence of the metal ion binding, assessed by liquid extraction of the metal nitrates from water into dichloromethane in individual and competitive experiments, on the ligand structure, is presented. The results showed that those ligands could be successfully used in separation process of trnasition and heavy metals often...
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A Ship Domain-Based Method of Determining Action Distances for Evasive Manoeuvres in Stand-On Situations
PublicationA ship encounter can be considered safe if neither of ships’ domains (defined areas around ships) is intruded by other ships. Published research on this includes optimising collision avoidancemanoeuvres fulfilling domain-based safety conditions.However, until recently there was no method, using ship’s domain to determine exact moment when a particular collision avoidance manoeuvre can still be successfully performed. The authors...
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Valorisation of bioplastics synthesised by liquefaction of celluloseusing hetero- and homogeneous catalysts
Open Research DataThe purpose of the present study was to test the effectiveness of a heterogeneous catalyst such as Nafion ion-exchange resin on the cellulose liquefaction process. The results obtained were compared with the bio-polyols obtained in a conventional way, using a homogeneous catalyst (sulfuric acid (VI)). Depending on the catalyst used and the temperature...
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Obrony prac doktorskich na Wydziale Chemicznym
EventsDn. 04.10.2022 r. o godz. 13.15 w Audytorium 1.4 Wydziału Chemicznego PG (budynek nr 5) odbędzie się w trybie hybrydowym publiczna obrona pracy doktorskiej mgr. inż. Dominika Knozowskiego.
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Storing Matter’technique in SIMS depth profile analysis
PublicationSecondary ion mass spectrometry (SIMS) is a very useful technique for the analysis of layered systems. It is based on the primary ion beam sputtering of solids and mass analysis of the emitted secondary ions. A main limitation of this technique results from the direct quantitative analysis, since the ionization efficiency of a given atom is highly influenced by the neighbouring atoms at the surface. This phenomenon is known as...
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Mechanism of Isomerization and Acid-Induced Transformations of 3-Hydroxy-4,4'-dimethoxy-3'-methyl-3-oxo-7,7'-bis(piperidino-carbonyloxy)-2,2'-spirobi-[2H,2'H,3H,3'H-benzo[b]thiophene]. Unusual Equilibrium between the Spiro and 3-Hydroxy-benzothiophene Systems.
PublicationStwierdzono, że 3'-hydroksy-4,4'-dimetoksy-3'-metylo-3-okso-7,7'-bis(piperydynokarbonyloksy)-2,2'-spirobi[2H,2'H,3H,3'H-benzo[b]tiofen] występuje w roztworach postaci mieszaniny dwóch diastereoizomerów pozostających w dynamicznej równowadze. Mechanizm tej równowagi oparty jest na odwracalnym otwarciu pierścienia z 1,5 przeniesieniem protonu i utworzeniu przjściowej formy 3-hydroksybenzotiofenu.
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ADOPTED ISOCHRONE METHOD IMPROVING SHIP SAFETY IN WEATHER ROUTING WITH EVOLUTIONARY APPROACH
PublicationThe paper is focused on adaptation of an isochrone method necessary for application to a weather routing system with evolutionary approach. Authors propose an adaptation of the isochrone method with area partitioning assuring that the route found by the adopted method would not cross land. In result, when applied to a weather routing system with evolutionary approach, this proposal facilitates creation of initial population, resulting...
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Locust bean gum as green and water-soluble binder for LiFePO4 and Li4Ti5O12 electrodes
PublicationLocust Bean Gum (LBG, carob bean gum) was investigated as an environmentally friendly, natural, and water-soluble binder for cathode (LFP) and anode (LTO) in lithium-ion batteries (Li-ion). For the frst time, we show LBG as an electrode binder and compare to those of the most popular aqueous (CMC) and conventional (PVDF) binders. The electrodes were characterized using TGA/DSC, the galvanostatic charge–discharge cycle test, cyclic...
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Results of the effect of mixtures of ketoprofen with three cations on the germination of Sorghum bicolor (sorghum) seeds
Open Research DataThe research data includes an attempt to verify whether the addition of cations (sodium, ammonium and potassium) at levels found in the environment would affect the toxicity of pharmaceuticals to Sorghum Bicolor grain. Ion concentrations were selected based on studies of water samples collected in water bodies receiving wastewater from wastewater treatment...
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Results of the effect of mixtures of ketoprofen with three anions on the germination of Sorghum bicolor (sorghum) seeds
Open Research DataThe research data includes an attempt to verify whether the addition of anions (bromide, chloride and fluoride) at levels found in the environment would affect the toxicity of pharmaceuticals to Sorghum Bicolor grain. Ion concentrations were selected based on studies of water samples collected in water bodies receiving wastewater from wastewater treatment...
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Electrical properties of Na2O-CaO-P2O5 glasses doped with SiO2 and Si3N4
PublicationSodium-calcium-phosphate glasses doped with SiO2 or Si3N4 having similar sodium ion concentrations were prepared by melt quenching. The conductivity was measured by impedance spectroscopy under nitrogen atmosphere in a wide frequency range (10 mHz–1 MHz) and wide temperature range (153–473 K). At 36.6 °C, DC conductivities of all glasses vary between 1.1 ∗ 10−12 and 8.9 ∗ 10−12 S cm−1 and have similar activation energies (between...
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Chromogenic macrocyclic derivatives of azoles - synthesis and properties,
PublicationNew azocrown ethers comprising imidazoles in the macrocycle have been synthesized. Imidazole, 2-methyl-, 4-methyl-, and 4-phenylimidazole were incorporated to form macrocyclic units by coupling with the appropriate bis-diazonium salts. The syntheseswere performed under high dilution conditions. The X-ray structure of a water adduct of the 21-membered crown ether derivative of 4-methylimidazole 8 has been solved. Metal...
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Synthesis and Spectroscopic Properties of New Bis-tetrazoles
PublicationSyntheses of N,N'-phenyltetrazole podands link with aliphatic chains containing oxygen, nitrogen and sulphur atoms, are described. The complexing properties of these compounds towards metal cations (Fe2+, Cu2+, Zn2+, Co2+, Ni2+) were investigated by absorption and infrared spectroscopy. The UV-Vis titrations were performed to estimate the stability constant values of the respective complexes with Cu2+ ion. Changes in UV-Vis absorption...
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Prognozowanie wpływu drgań komunikacyjnych na budynki mieszkalne za pomocą sztucznych sieci neuronowych i maszyn wektorów wspierających
PublicationDrgania komunikacyjne mogą stanowić duże obciążenie eksploatacyjne budynku, powodując zarysowania i spękania tynków, odpadanie wypraw, zarysowania konstrukcji, pękanie elementów konstrukcji lub nawet zawalenie się budynku. Pomiary drgań na rzeczywistych konstrukcjach są pracochłonne i kosztowne, a co ważne nie w każdym przypadku są one uzasadnione. Celem pracy jest analiza autorskiego algorytmu, dzięki któremu z dużym prawdopodobieństwem...
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Wczesny Mickiewicz jako zapowiadający się historiozof
PublicationThe paper shows young Mickiewicz’s family and historical experiences. It discussesthe knightly premises for his historiosophy and explains its radicalism and structureon the grounds of the knightly tradition. The study reveals the pre-Slavic deposits ofspiritual archeology in the Romantic poet. It proves that the activation of these depositsshaped Mickiewicz’s view on the collision between Poland and...
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On the validation of the LS-DYNA Geo Metro numerical model
PublicationThe paper presents experiences gained during work with numerical model of Geo Metro vehicle used for simulations of crash tests with road safety barriers. Attention is drawn to the subject of tire/wheel breakage during collision events. Some methods for improvement of the model are presented in the paper. Several results for the normative vehicle numerical tests are introduced. Simulations were carried out using LS-DYNA finite...
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Recognition and sensing of anions
PublicationMolecular ion recognition is one of the most intensively studied areas of supramolecular technology. The reason for this is the essential role that ions play in many biological as well as industrial processes. On the other hand, however, it has been proved that ions can have a negative impact on human health and the environment. For these reasons, it is extremly important to develop rapid and simple methods allowing the determination...
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Investigating the effects of structural pounding on the seismic performance of adjacent RC and steel MRFs
PublicationAn insufficient separation distance between adjacent buildings is the main reason for structural pounding during severe earthquakes. The lateral load resistance system, fundamental natural period, mass, and stiffness are important factors having the influence on collisions between two adjacent structures. In this study, 3-, 5- and 9-story adjacent reinforced concrete and steel Moment Resisting Frames (MRFs) were considered to investigate...
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Vibration signals collected for concrete beams with GFRP reinforcement subjected to elevated temperatures (120C-240C)
Open Research DataThe dataset contains the time domain signals obtained during dynamic tests of concrete beams reinforced with GFRP bars. The vibration were induced with the use of modal hammer, while the signals were collected by the accelerometers attached at the beam surface. The signals were captured before and after subjecting the concrete beams to elevated temperatures.