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Search results for: solid state reaction
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Promotion of borophene/NiO-based electrocatalyst for oxygen evolution reaction
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Fast method for the determination of the charge transfer coefficient of an electrode reaction
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The overabundance of excited hydrogen atoms produced in the H2++ furan reaction
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Promotion of borophene/NiO-based electrocatalyst for oxygen evolution reaction
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Arylation of enelactams using TIPSOTf: reaction scope and mechanistic insight
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Carbon Nanohorns as Reaction Nanochambers – a Systematic Monte Carlo Study
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Photochemical and thermal reaction of intermediates in the phenylnitrene rearangment inside a hemicarcerand
PublicationBroadband irradiation (λ > 320 nm) of hemicarceplex H1 between −74 °C and −84 °C, produces encapsulated didehydroazepine (2), triplet phenylnitrene (3PN), 2-azabicyclo[3.2.0]hepta-1,3,6-triene (6), and 4-azaspiro[2.4]hepta-1,4,6-triene (7). The highly strained anti-Bredt imine 6 is formed from 2 via a photochemical four-electron electrocyclization. Under the irradiation conditions, 6 rearranges further to azaspirene 7. In addition,...
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Frequency distribution of chemical oscillations in the closed Belousov Zhabotinsky reaction.
PublicationW publikacji przedstawiono wykorzystanie metody STFT (krótkoczasowej transformaty Fouriera) do analizy oscylacji chemicznych. Badano rejestry potencjałowe reakcji Biełousowa Żabotyńskiego. Wykazano niestacjonarność analizowanych przebiegów. Wykazano liniową zależność pomiędzy częstotliwością oscylacji a stężeniem jednego z komponentów reakcji (bromian potasu). Udowodniono przydatność analizy czasowo-częstotliwościowej do analizy...
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Dynamic electrochemical impedance spectroscopy of the first order electrode reaction
PublicationCiągłe transformaty STFT sinusoidalnego sygnału pobudzenia i odpowiedzi prądowej zostały wyznaczone dla reakcji elektrodowej pierwszego rzędu. Wyznaczono impedancję elektrody w łącznej dziedzinie czasu i częstotliwości. Wykonano pomiary dla reakcji redukcji Cd(II) na rtęciowej elektrodzie kroplowej w funkcji potencjału. Przedstawiono możliwość wyznaczenia chwilowych widm impedancyjnych. Opisano zależność rezystancji przeniesienia...
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Methane formation over TiO2–based photocatalysts: reaction pathways
PublicationThe effects of organic impurities adsorbed or incorporated into semiconductors structure on the photocatalytic products are noteworthy. For this purpose, the as-prepared Ag, Au and Pdmodified TiO2 samples were exposed to UV-vis irradiation in various gas atmospheres (CO2, N2, 600 ppm CO2 in N2, and 13CO2) in order to clarify the route of CH4 formation in the process of photocatalytic CO2 reduction. In the presented research it...
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Quantum-state transfer in spin chains via isolated resonance of terminal spins
PublicationWe propose a quantum-state transfer protocol in a spin chain that requires only the control of the spins at the ends of the quantum wire. The protocol is to a large extent insensitive to inhomogeneity caused by local magnetic fields and perturbation of exchange couplings. Moreover, apart from the free evolution regime, it allows one to induce an adiabatic spin transfer, which provides the possibility of performing the transfer...
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Letter to the Editor: Discussion on the Paper “State-of-the-Art of Research on Seismic Pounding Between Buildings with Aligned Slabs”
PublicationThe paper “State-of-the-art of research on seismic pounding between buildings with aligned slabs” (by Kharazian and López-Almansa) has recently been published in the journal of Archives of Computational Methods in Engineering. It can be considered as a kind of continuation of previous ‘state-of-the-art’ publications, including two papers and a book. Unfortunately, the paper contains a number of misleading or wrong statements as...
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Tailoring a low-energy ball milled MnCo2O4 spinel catalyst to boost oxygen evolution reaction performance
PublicationThe development of cost-efficient oxygen evolution reaction (OER) catalysts is one of the most important tasks facing modern techniques for hydrogen production. In this work, for the first time, a low-energy ball milling process of MnCo2O4 (MCO) spinel powders, with a mechanical modification time exceeding 1 day was used. After 6 days of ball-milling, the obtained overpotential of the electrocatalyst reached the value of 375 mV...
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Four-state stochastic model of changes in the reliability states of a motor vehicle
PublicationThe properties of semi-Markov processes have been generally characterized and the applicability of the theory of such processes to the determining of the reliability of motor cars and other road vehicles has been explained. A formal description of the process of changes in the motor vehicle technical states considered as reliability states and a model of this process in the form of a one-dimensional stochastic process have been...
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State of the art in sample preparation for human breast milk metabolomics—merits and limitations
PublicationHuman breast milk (HBM) contains metabolites that are diverse in chemical structure and concentration. These metabolites range from high-abundance to low-abundance compounds and from polar to nonpolar. This complex nature of HBM makes HBM samples difficult to analyze, especially in global metabolomic studies for the determination and characterization of complete sets of metabolites. In this review, the state of the art in sample...
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Numerical model for thin liquid film with evaporation and condensation on solid surfaces in systems with conjugated heat transfer
PublicationCondensation and evaporation processes from wetted surfaces are of utmost importance in many technological or industrial applications. In many devices such as home-appliances and air conditioning systems just to name a few, condensation and evaporation processes greatly impact their performance and energy efficiency; The physics of these processes is quite complex, involving conjugate heat transfer among solid–liquid film-gaseous...
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Conductivity improvement of Ce0.8Gd0.2O1.9 solid electrolyte
PublicationW pracy przedstawiono metodę zwieszenia przewoności domieszkowanego tlenku ceru wprowadzając podczas syntezy 2% wapnia. Zbadano metody wprowadzenia wapnia z użyciem prekursorów polimerowych. Uzyskano zwiększenie przewodności oraz syntezowalności elektrolitu stałego.
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The structure and conductivity of solid polyurethane electrolyte
PublicationPrzedstawiono badania właściwości i struktury stałych elektrolitów poliuretanowych. Otrzymano je z prepolimeru zsyntezowanego z MDI oraz PTMG. Jako przedłużacz łańcucha wykorzystano butanodiol. W celu poprawy przewodnictwa domieszkowano poliuretan solami LiClO4 lub LiCl, które wprowadzono za pomocą wytłaczarki dwuślimakowej. Otrzymane elektrolity poddano badaniom: wytrzymałościowym, twardości, spektroskopii FTIR oraz przewodnictwa...
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Superconductivity in the Einstein solid V Al10.1
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The structure and conductivity of solid polyurethane electrolytes
PublicationPrzedmiotem badań były stałe elektrolity poliuretanowe otrzymane w wyniku syntezy MDI, PTMO, BD oraz TG z DMPA. Domieszkowanie LiCl zostało wykonane przy zastosowaniu przedłużacza. Badano przewodnictwo jonowe otrzymanych elektrolitów stałych przy użyciu technik stało i zmiennoprądowych. Przedstawiono również wyniki badań z wykorzystaniem technik mikroskopii elektronowej oraz FTIR-ATR.
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Solid road environment and its hazards
PublicationAccidents that involve vehicles departing the road tend to have very high severity, as they often result in the vehicle hitting a permanent obstacle (which can be a ree, a pole, facility pillar, front wall of a culvert or a barrier). In recent years, this type of accident caused approx. 19% of all road deaths in Poland. A particularly high risk can be observed on roads located in northern and western...
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Automatic assessment of the motor state of the Parkinson's disease patient --a case study
PublicationThis paper presents a novel methodology in which the Unified Parkinson's Disease Rating Scale (UPDRS) data processed with a rule-based decision algorithm is used to predict the state of the Parkinson's Disease patients. The research was carried out to investigate whether the advancement of the Parkinson's Disease can be automatically assessed. For this purpose, past and current UPDRS data from 47 subjects were examined. The results...
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Deep eutectic solvents with solid supports used in microextraction processes applied for endocrine-disrupting chemicals
PublicationThe determination of endocrine-disrupting chemicals (EDCs) has become one of the biggest challenges in Analytical Chemistry. Due to the low concentration of these compounds in different kinds of samples, it becomes necessary to employ efficient sample preparation methods and sensitive measurement techniques to achieve low limits of detection. This issue becomes even more struggling when the principles of the Green Analytical Chemistry...
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State of the Art in Open Platforms for Collaborative Urban Design and Sharing of Resources in Districts and Cities
PublicationThis work discusses recent developments in sharing economy concepts and collaborative co-design technology platforms applied in districts and cities. These developments are being driven both by new technological advances and by increased environmental awareness. The paper begins by outlining the state of the art in smart technology platforms for collaborative urban design, highlighting a number of recent examples. The case of peer-to-peer...
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Chitosan pyrolysis in the presence of a ZnCl2/NaCl salts for carbons with electrocatalytic activity in oxygen reduction reaction in alkaline solutions
PublicationThe one-step carbonization of low cost and abundant chitosan biopolymer in the presence of salt eutectics ZnCl2/NaCl results in nitrogen-doped carbon nanostructures (8.5 wt.% total nitrogen content). NaCl yields the spacious 3D structure, which allows external oxygen to easily reach the active sites for the oxygen reduction reaction (ORR) distinguished by their high onset potential and the maximum turnover frequency of 0.132 e...
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Direct measurements of odorous volatile organic compounds present in biosolids cakes by Proton Transfer Reaction – Mass Spectrometry Technique
PublicationThis paper show the results of investigation of concentration of odorous chemical compounds emitted upon ageing of anaerobically stabilised biosolids that could contribute to the overall odour character of nuisance emissions. Biosolids samples from wastewater treatment plant were collected in spring time. Concentrations of volatile organic compounds using a US EPA flux hood and Proton Transfer Reaction-Time of Flight-Mass Spectrometry...
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The general state of preservation of immovable monuments in connection with the primary function – comparison of 2003 and 2016
Open Research DataThe following dataset compares the structure of the register of immovable monuments in Poland regarding the general state of preservation of the objects in connection with the primary function for 2003 and 2016. The included types contain the following ones: sacred, defensive, public, parks, residential, farmhouses, industrial, cemeteries and others....
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Experimental review of the performances of protective coatings for interconnects in solid oxide fuel cells
PublicationFerritic stainless steel interconnects are used in solid oxide fuel cells; however, coatings are required to improve their performance. Although several types of coatings have been proposed, they have been scarcely investigated under similar conditions. This study compares the characteristics of uncoated Crofer 22 APU and eight different coatings on Crofer 22 APU for up to 3000 h at 800 ◦C. The coatings were deposited at various...
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Effects of La0.8Sr0.2MnO3 and Ag electrodes on bismuth-oxide-based low-temperature solid electrolyte oxygen generators
PublicationIn this study, La0.8Sr0.2MnO3 (LSM) was used as the ceramic electrode in a (Bi1.50Y0.50)0.98Zr0.04O3+δ (BYO)-based solid electrolyte oxygen generator (SEOG) and its performance was compared with that of a previously studied high-fire Ag electrode. Among La0.6Sr0.4Co0.2Fe0.8O3, LaNi0.6Fe0.4O3, Cu1.4Mn1.6O4, and LSM materials, only LSM materials did not trigger any chemical reaction or interdiffusion with BYO at temperatures up to...
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Fluid–solid interaction on a thin platelet with high-velocity flow: vibration modelling and experiment
PublicationThe paper concerns the nonlinear behaviour of a thin platelet that is streamlined in an aerodynamic tunnel. The air velocity in the aerodynamic tunnel was at 858.9 km/h or 0.7 Ma (Ma—Mach number is a dimensionless quantity in fluid dynamics representing the ratio of flow velocity past a boundary to the local speed of sound). This experiment was numerically simulated using FSI (fluid–solid interaction) tools, namely the coupling...
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Free-standing TiO2 nanotubes decorated with spherical nickel nanoparticles as a cost-efficient electrocatalyst for oxygen evolution reaction
PublicationHere, we report significant activity towards the oxygen evolution reaction (OER) of spherical nickel nanoparticles (NPs) electrodeposited onto free-standing TiO2 nanotubes (TNT) via cyclic voltammetry. It has been shown that simple manipulation of processing parameters, including scan rate and number of cycles, allows for formation of the NPs in various diameters and amounts. The polarization data with respect to transmission electron...
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High performance LaNi1-xCoxO3-δ (x = 0.4 to 0.7) infiltrated oxygen electrodes for reversible solid oxide cells
PublicationOxygen electrodes prepared by infiltration of yttria stabilized zirconia backbone with Ce0.8Gd0.2O1.95 barrier layer and LaNi1-xCoxO3-δ (x=0.4 to 0.7) catalyst for application in reversible solid oxide cells have been studied. The effect of temperature and Ni:Co ratio on their phase composition, microstructure and electrochemical properties are discussed. It was shown that oxygen electrodes infiltrated with LaNi0.5Co0.5O3-δ had...
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A new method for real-time monitoring of volatiles in frying fumes using proton transfer reaction mass spectrometry with time-of-flight analyse
PublicationTo safeguard the consumers’ well-being, it is necessary to develop novel methods for determination of carcinogens in food, including volatiles generated during frying. The currently used procedures for analysis of volatile fraction of vegetable oils are not based on real-time measurements and thus do not enable the determination of carcinogenic compounds in frying fumes; instead, only the headspace or liquid fraction is sampled....
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Concentration and sources of polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) in surface soil near a municipal solid waste (MSW) landfill
PublicationDue to a continuous demand of land for infrastructural and residential development there is a public concern about the condition of surface soil near municipal solid waste landfills. A total of 12 surface (0–20 cm) soil samples from a territory near a landfill were collected and the concentration of 16 PAHs and 7 PCB congeners were investigated in these samples. Limits of detection were in the range of 0.038–1.2 μg/kg for PAHs...
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The impedance of hydrogen oxidation reaction in a proton exchange membrane fuel cell in the presence of carbon monoxide in hydrogen stream
PublicationEvaluation of performance of a proton exchange membrane fuel cell, which is affected by carbon monoxide that pollutes the hydrogen stream, was presented. This influence was studied for carbon monoxide concentration of 125–325 ppb, which are close to values specified in ISO 14687:2019 standard. Performed studies provided crucial information for further development of fuel cell as an energy source for automotive application. Impedance...
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ADAPTIVE PREDICTIONS OF THE EURO/ZŁOTY CURRENCY EXCHANGE RATE USING STATE SPACE WAVELET NETWORKS AND FORECAST COMBINATIONS
PublicationThe paper considers the forecasting of the euro/Polish złoty (EUR/PLN) spot exchange rate by applying state space wavelet network and econometric forecast combination models. Both prediction methods are applied to produce one-trading-day- ahead forecasts of the EUR/PLN exchange rate. The paper presents the general state space wavelet network and forecast combination models as well as their underlying principles. The state space...
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A Model of Thermal Energy Storage According to the Convention of Bond Graphs (BG) and State Equations (SE)
PublicationThe main advantage of the use of the Bond Graphs method and State Equations for modeling energy systems with a complex structure (marine power plants, hybrid vehicles, etc.) is the ability to model the system components of different physical nature using identical theoretical basis. The paper presents a method of modeling thermal energy storage, which is in line with basic BG theory. Critical comments have been put forward concerning...
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Key results from the numerical FEM analysis of the imperfect dome's state of displacements
Open Research DataThis dataset consists of an XLS file with the key results from the numerical FEM analysis of the imperfect dome's state of displacements.
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Sensitive simultaneous determination of 19 fluorobenzoic acids in saline waters by solid-phase extraction and liquid chromatography–tandem mass spectrometry
PublicationA solid-phase extraction (SPE) procedure using C18 stationary phase was optimized for the preconcentration of 19 fluorinated derivatives of benzoic acid (FBA): mono-, di-, tri-, and tetrafluorosubstituted in the ring, trifluoromethylbenzoic acid and 3,5-bistrifluoromethyl benzoic acid from undiluted salt-rich (>20%) reservoir waters. Quantitative (>90%) retention/elution of 16 out of 19 analyte compounds was achieved allowing a...
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The role of aluminium in metal–organic frameworks derived carbon doped with cobalt in electrocatalytic oxygen evolution reaction
PublicationWater electrolysis is one of the most crucial processes in the development of new energy sources, where ultra-clean fuel is produced - hydrogen. Oxygen evolution reaction (OER) is the sluggish process of overall water splitting. Therefore, this study presents the design, characterization and electrochemical study of cobalt-based electrocatalysts embedded into porous carbons derived from an Al-metal–organic...
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UE regional state aid for territories with low standard of living
Open Research DataThe dataset encompassed a choice of important legal acts, a list of selected Polish bibliography and a list of important individual decisions issued on the topic of regional state aid ( for investment purposes) in Poland in the periods 2007- 2013 and 2014- 2020. Thanks to that the reader gets the possibility to acquire basic knowledge on the abovementioned...
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On-line assessment of oil quality during deep frying using an electronic nose and proton transfer reaction mass spectrometry
PublicationWe describe a novel method for the quality assessment of oil utilized for deep frying. The method is based on the analysis of frying fumes using a custom electronic nose. The quality score could be obtained after less than 3 min of analysis and without interrupting the frying process or sampling the oil directly. The obtained results were correlated with the peroxide value using a multivariate linear regression model. The most...
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The State and Critical Assessment of the Sharing Economy in Europe
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State-of-the-art bolometers - principles, devices, applications
PublicationW artykule omówiono zasady działania bolometrów wykorzystywanych w detekcji fal elektromagnetycznych, w zakresie od mikrofal, poprzez pormieniowanie terahercowe, do promieniowania X. Przedstawiono materiały stosowane w wytwarzaniu bolometrów, oraz reprezentatywne konstrukcje nowoczesnych bolometrów, w tym bolometrów nadprzewodzących i wykorzystujących efekty kwantowe. Zaprezentowano wybrane zastosowania tych detektorów w technice,...
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Polarization state analysis in optical coherence tomography
PublicationW artykule zaprezentowano metody analizy stanu polaryzacji światła w systemach optycznej tomografii kohererentnej. Przedstawiono różne konfiguracje systemu PS-OCT wraz z ich parametrami oraz właściwościami. Omówiono zasadę pomiaru stanu polaryzacji ściatła przy użyciu systemu PS-OCT oraz przeprowadzono dyskusję nad przydatnością metody do badania struktury materiałów silnie rozpraszających promieniowanie.
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State Interventionism in Agricultural Land Turnover in Poland
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State of global health – hypertension burden and control
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History of the State Medical Rescue Service in Poland
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Dendrimers against fungi – A state of the art review
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Dynamic Perfect hashing with finite-state automata
PublicationMinimalna doskonała funkcja mieszająca dostarcza odwzorowania zbioru n niepowtarzalnych słów w zwarty zakres n liczb całkowitych. Gdy jest realizowane za pomocą automatów skończonych, odwzorowanie wynika z porządku słów (zwykle alfabetycznego) w zbiorze. Dodanie nowych słów zmieniłoby porządek słów rozpoznawanych przez automat, zmieniając całe odwzorowanie i czyniąc je bezużytecznym w wielu dziedzinach. Dlatego nazywamy je statycznym....