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Search results for: RESPONSE SHIFT
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Anatomy of noise in quantitative biological Raman spectroscopy
PublicationRaman spectroscopy is a fundamental form of molecular spectroscopy that is widely used to investigate structures and properties of molecules using their vibrational transitions. It relies on inelastic scattering of monochromatic laser light irradiating the specimen. After appropriate filtering the scattered light is dispersed onto a detector to determine the shift from the excitation wavelength, which appears in the form of...
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The CON−H…+NH2 Blue-Shifting H-Bond Stabilizing Effect on Z Secondary Amides and Cyclic System Conformational Rearrangement through an Alkylamine-Chain Migration Pathway
PublicationThe paper is focusing on the amide linkage exceptional properties and usage of chemistry (conformational rearrangement, geometrical stereoisomers, spectroscopic blue shift phenomenon, protonation and deprotonation reactions, synthetic scope, and mechanistic implications). Hydrogen-bond-stabilized acylation reactions of a diamine with thioamides or nitriles reveal how substituents influence both the outcome of stereoselectivity...
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One-dimensional chaos in a system with dry friction: analytical approach
PublicationWe introduce a new analytical method, which allows to find chaotic regimes in non-smooth dynamical systems. A simple mechanical system consisting of a mass and a dry friction element is considered. The corresponding mathematical model is being studied. We show that the considered dynamical system is a skew product over a piecewise smooth mapping of a segment (the so-called base map). For this base map we demonstrate existence of...
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In-situ monitoring of electropolymerization processes at boron-doped diamond electrodes by Mach-Zehnder interferometer
PublicationIn this work, the Mach-Zehnder interferometer was designed to monitor the electrochemical processes conducted at boron-doped diamond electrode surface. The diamond electrodes were synthesized via Microwave Plasma-Assisted Chemical Vapor Deposition on optical grade quartz glass. The achieved transmittance in working are of diamond electrodes reached 55 %. A cage system-based Mach-Zehnder interferometer was used which allowed the...
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Designing efficient A-D-A1-D-A type fullerene free acceptor molecules with enhanced power conversion efficiency for solar cell applications
PublicationThe achievement of highly efficient power conversion efficiency (PCE) is a big concern for non-fullerene organic solar cells (NF-OSCs) because PCE can depend on numerous variables. Here, new five novel acceptor molecules without fullerenes were developed and investigated using DFT (density functional theory) and TD-DFT (time dependent-density functional theory). Compared to the recently synthesized molecule (PZ-dIDTC6), the developed...
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Analytical Estimation of Power Losses in a Dual Active Bridge Converter Controlled with a Single-Phase Shift Switching Scheme
PublicationMicro-grid solutions around the world rely on the operation of DC/DC power conver- sion systems. The most commonly used solution for these topologies is the use of a dual active bridge (DAB) converter. Increasing the efficiency and reliability of this system contributes to the improvement in the stability of the entire microgrid. This paper discussed an analytical method of energy efficiency and power loss estimation in a single...
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Optical-Fiber Microsphere-Based Temperature Sensors with ZnO ALD Coating—Comparative Study
PublicationThis study presents the microsphere-based fiber-optic sensor with the ZnO Atomic Layer Deposition coating thickness of 100 nm and 200 nm for temperature measurements. Metrological properties of the sensor were investigated over the temperature range from 100 °C to 300 °C, with a 10 °C step. The interferometric signal was used to monitor the integrity of the microsphere and its attachment to the connecting fiber. For the sensor...
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Category Adaptation Meets Projected Distillation in Generalized Continual Category Discovery
Publication"Generalized Continual Category Discovery (GCCD) tackles learning from sequentially arriving, partially labeled datasets while uncovering new categories. Traditional methods depend on feature distillation to prevent forgetting the old knowledge. However, this strategy restricts the model’s ability to adapt and effectively distinguish new categories. To address this, we introduce a novel technique integrating a learnable projector...
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Wykrywanie on-line anomalii w odebranym sygnale PSK za pomocą zespolonej pulsacji chwilowej
PublicationJednym z głównych problemów w analizie sygnałów PSK (ang. Phase Shift Keying) jest wykrywanie anomalii występujących w sygnale odebranym. Większość urządzeń stosowanych do analizy sygnałów PSK (np. oscyloskopy cyfrowe, analizatory widma) w celu wykrycia anomalii wykorzystuje algorytm EVM (ang. Error Vector Magnitude) w którym bada się, on-line, różnicę między konstelacją PSK, a skupieniami odebranych symboli zespolonych. W związku...
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Model-Based Evaluation of N2O Production Pathways in the Anammox-Enriched Granular Sludge Cultivated in a Sequencing Batch Reactor
PublicationA mechanistic model was developed as an extension of the Activated Sludge Model No. 1 to describe three nitrous oxide (N2O) production pathways in a laboratory-scale anammox-enriched granular sequencing batch reactor. Heterotrophic denitrification and two processes mediated by ammonia oxidizing bacteria (AOB), that is, ammonia (NH4+) oxidation via hydroxylamine (NH2OH) and autotrophic denitrification, were considered. A systematic...
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Failure Monitoring and Condition Assessment of Steel-Concrete Adhesive Connection Using Ultrasonic Waves
PublicationAdhesive bonding is increasingly being incorporated into civil engineering applications. Recently, the use of structural adhesives in steel-concrete composite systems is of particular interest. The aim of the study is an experimental investigation of the damage assessment of the connection between steel and concrete during mechanical degradation. Nine specimens consisted of a concrete cube and two adhesively bonded steel plates...
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T cell Activation Is Driven by an ADP-Dependent Glukosinase Linking Enhanced Glycolysis with Mitochondrial Reactive Oxygen Species Generation
PublicationMitochondria-originating reactive oxygen species control T cell receptor (TCR)-induced gene expression. Here, we show that TCR-triggered activation of ADP-dependent glucokinase (ADPGK), an alternative, glycolytic enzyme typical for Archaea, mediates generation of the oxidative signal. We also show that ADPGK is localized in the endoplasmic reticulum and suggest that its active site protrudes toward the cytosol. The ADPGK-driven...
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Image Segmentation of MRI image for Brain Tumor Detection
Publicationthis research work presents a new technique for brain tumor detection by the combination of Watershed algorithm with Fuzzy K-means and Fuzzy C-means (KIFCM) clustering. The MATLAB based proposed simulation model is used to improve the computational simplicity, noise sensitivities, and accuracy rate of segmentation, detection and extraction from MR...
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Multidecadal (1960-2011) shoreline changes in Isbjornhamna (Hornsund, Svalbard)
PublicationAsection of a gravel−dominated coast in Isbjørnhamna (Hornsund, Svalbard) was analysed to calculate the rate of shoreline changes and explain processes controlling coastal zone development over last 50 years. Between 1960 and 2011, coastal landscape of Isbjørn− hamna experienced a significant shift from dominated by influence of tide−water glacier and protected by prolonged sea−ice conditions towards storm−affected and rapidly...
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Towards an Understanding of the Stability Assessment of Floating Buildings
PublicationOne of the most important aspects of the design of floating facilities such as ships, floating offshore structures or floating houses is stability. Its impact on both general safety and operational aspects renders it a fundamental consideration already in preliminary design stages. Usually, the concept of sufficient stability of floating buildings is associated with the ability to keep an allowed heel angle and residual freeboard,...
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Femtosecond Er-doped fiber laser source tunable from 872 to 1075 nm for two-photon vision studies in humans
PublicationWe report the development of a widely-tunable femtosecond fiber laser system and its application for two-photon vision studies. The source is based on an Er-doped fiber laser with spectral shift up to 2150 nm, followed by a second harmonic generation module to generate a frequency-doubled beam tunable from 872 to 1075 nm. The source delivers sub-230 fs pulses with nearly-constant duration over the entire tuning range, with output...
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Long-term comparative evaluation of an acoustic climate in selected schools before and after the acoustic treatment
PublicationThe results of long-term continuous noise measurements in two selected schools are presented in the paper. Noise characteristics were measured continuously there for approximately 16 months. Measurements started eight months prior to the acoustic treatment of the school corridors of both schools. An evaluation of the acoustic climates in both schools, before and after the acoustic treatment, was performed based on comparison of...
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An Optimized Ka-Band Low Profile Dual-Polarized Transmitarray Antenna With 2D Beam Switching
PublicationThis article presents an optimized dual-polarized transmitarray antenna (TA) designed for MIMO applications at the Ka-band, capable of switching beams in two directions. The antenna aperture uses a small unit cell with three layers of Taconic RF-35 dielectric substrates, which can be easily fabricated using PCB technology. The unit cell achieved a 360-degree phase shift and a transmission magnitude exceeding –0.4 dB at 28 GHz....
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Reduction of the Velocity Impact on the Magnetic Flux Leakage Signal
PublicationThe velocity effect on the magnetic flux leakage (MFL) signal was investigated in this paper. Experiments were performed for velocity of the MFL tool within the range of 0–2 m/s. The velocity was not constant during each measurement to imitate real operational conditions of the MFL tool. Two components of the leakage were measured, i.e. the tangential to the motion direction (x) and the normal to the investigated surface (z). In...
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Spectroscopic and photophysical properties of ZNTPP in a room temperature ionic liquid
PublicationThe steady-state absorption and emission spectra and the time-resolved Soret- and Q-band excited fluorescence profiles of the model metalloporphyrin, ZnTPP, have been measured in a highly purified sample of the common room temperature ionic liquid, [bmim][PF(6)]. S(2)-S(0) emission resulting from Soret-band excitation behaves in a manner completely consistent with that of molecular solvents of the same polarizability. The ionic...
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The use and development of e-learning systems in educational projects
PublicationThe article introduces the problem of usage and development of e-learning systems among Polish universities. Easily accessible internet and IT development led to changes in education. Through the use of IT tools, e-learning has become an increasingly popular form of education. Presently, majority of Polish universities use an e-learning system of their own choosing designed to support the didactic processes. The goal of the article...
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Protective and Suppressing Electromagnetic Interference Properties of Epoxy Coatings Containing Nano-Sized NiZn Ferrites
PublicationNano-crystalline ferrites with the chemical formula NixZn(1−x)Fe2O4, where x = 0, 0.2, 0.4, 0.6, 0.8, 1.0, were synthesized using a co-precipitation method. The obtained ferrites were investigated by X-ray diffraction (XRD). The corrosion inhibiting behavior of nano-sized ferrites was tested using carbon steel samples and 10% aqueous ferrite extracts. Results were compared with previous data obtained for micro-sized ceramic ferrites....
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The Undisrupted Growth of the Airbnb Phenomenon between 2014–2020. The Touristification of European Cities before the COVID-19 Outbreak
PublicationAs a result of the Airbnb eruption, not only has the character of the short-term rental market been completely transformed, but the decades long growth in tourism has also been further accelerated. Therefore, due to the new demands of the tourism economy, the major shift in the usage of historic city centers occurred–the process of ‘touristification’, that results in the emergence of its new, unsustainable form. Despite the significance...
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Computer support of analysis optical spectra measurements
PublicationVerification of measurement errors has a big impact on assessment of accuracy of conducted measurements and obtained results. In many cases computer simulation results are compared with measurement results in order to evaluate measurement errors. The purpose of our research was to check the accuracy of measurements made with Fabry-Perot interferometer working in the transmission mode. In measurement setup, a 1310 nm superluminescent...
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Computer Support of Analysis of Optical Spectra Measurements
PublicationThe verification of measurement errors has a big impact on the assessment of the accuracy of conducted measurements and obtained results. In many cases, computer simulation results are compared with measurement results in order to evaluate measurement errors. The purpose of our research was to check the accuracy of measurements made with a Fabry–Perot interferometer working in the transmission mode. In the measurement setup, a...
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A gap waveguide-based mechanically reconfigurable phase shifter for high-power Ku-band applications
PublicationThis paper presents a novel design of a low-loss, reconfgurable broadband phase shifter based on groove gap waveguide (GGW) technology. The proposed phase shifter consists of a folded GGW and three bends with a few pins forming the GGW and one bend attached to a movable plate. This movable plate allows for adjustments to the folded waveguide length, consequently altering the phase of electromagnetic waves. The advantage of GGW...
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Tailoring optical constants of few-layer black phosphorus coatings: Spectroscopic ellipsometry approach supported by ab-initio simulation
Publication2D black phosphorus (BP) has attracted extensive attention as an anisotropic platform for novel optoelectronic and polarizing optics applications. Insight into the factors that tune the optical and polarizing properties of 2D BP reveals their essential influence on BP-based photonic and optoelectronic devices. In this work, studies of the optical constants of few-layer black phosphorus coatings are studied and discussed, with particular...
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Optical properties of thin TiO2 film deposited on the fiber optic sensor head
PublicationThe presented study was focused on investigation of the titanium dioxide (TiO2) thin film deposited on the fiber tip. The intention of this investigation was using TiO2 film in the construction of the optical fiber sensor head. In the demonstrated construction TiO2 thin layer was deposited on the tip of a commonly used telecommunication single mode optical fiber (SMF-28) by means of the Atomic Layer Deposition (ALD). Thickness...
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Creating dynamic maps of noise threat using pl-grid infrastructure; materiały konferencyjne
PublicationThis paper presents functionality and operation results of the system for creating dynamic maps of noise thread with the use of the PL-Grid infrastructure integrated with distributed sensors network for measuring, modeling and rendering noise level distribution. The work presented provides a demonstration of the services being prepared within the PLGrid Plus project. Specific computational environments, so called domain grids,...
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Effect of osmolytes of different type on DNA behavior in aqueous solution. Experimental and theoretical studies
PublicationOsmolytes, the small organic molecules accumulated in cells under environmental stress, can modulate the stability of biopolymers such as proteins and DNA. In spite of many years of research, there is no established molecular mechanism of the influence of osmolytes on DNA structure. Here, we used two model osmolytes that denature (urea) or stabilize (trimethylglycine, TMG) proteins to study their effect on DNA in aqueous solutions...
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Assembly of 1D Granular Structures from Sulfonated Polystyrene Microparticles
PublicationBeing able to systematically modify the electric properties of nano- and microparticles opens up new possibilities for the bottom-up fabrication of advanced materials such as the fabrication of one-dimensional (1D) colloidal and granular materials. Fabricating 1D structures from individual particles offers plenty of applications ranging from electronic sensors and photovoltaics to artificial flagella for hydrodynamic propulsion....
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Synchrotron radiation photoemission spectroscopy of the oxygen modified CrCl3 surface
PublicationWe investigate the experimentally challenging CrCl3 surface by photon energy dependent photoemission (PE). The core and valence electrons after cleavage of a single crystal, either in a ultrahigh vacuum (UHV) or in air, are studied by keeping the samples at 150 1C, aiming at confirming the atomic composition with respect to the expected bulk atomic structure. A common spectroscopic denominator revealed by data is the presence of...
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Overcoming Challenges of Virtual Scrum Teams: Lessons Learned Through an Action Research Study
PublicationAfter the COVID-19 breakout, agile teams found themselves in situations that “pure agilists” and textbooks on agile methods had preferred to ignore. Whereas agile mindsets helped them to quickly shift to remote work, mere virtualization of agile practices often proved insufficient, and several challenges emerged. This paper reports on an Action Research project carried out in Lufthansa Systems Poland with the aim of (1) revisiting...
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Highly effective asphaltene-derived adsorbents for gas phase removal of volatile organic compounds
PublicationA novel nitrated asphaltene-derived adsorbent (Asf-Nitro) was prepared using facile isolation and modification procedures. The successful modification was confirmed by Fourier-transform infrared spectroscopy (FTIR). The nitrated adsorbent was evaluated in terms of dispersive and specific interactions, Lewis acid-base properties and adsorption isotherms by means of inverse gas chromatography (IGC). Nitration was found to be extremely...
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Mutual Interaction between Temperature and DO Set Point on AOB and NOB Activity during Shortcut Nitrification in a Sequencing Batch Reactor in Terms of Energy Consumption Optimization
PublicationRecently, many wastewater treatment plants (WWTPs) have had to deal with serious problems related to the restrictive requirements regarding the euent quality, as well as significant energy consumption associated with it. In this situation, mainstream deammonification and/or shortened nitrification-denitrification via nitrite (so-called “nitrite shunt”) is a new promising strategy. This study shows the mechanisms and operating conditions...
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Curing epoxy with ethylenediaminetetraacetic acid (EDTA) surface-functionalized Co Fe3-O4 magnetic nanoparticles
PublicationIn this work, the bulk and surface composition of Fe3O4 supermagnetic nanoparticles were modified for efficient epoxy curing. The bare, ethylenediaminetetraacetic acid (EDTA) capped, and cobalt (Co)-doped EDTA capped Fe3O4 nanoparticles were synthesized electrochemically. The crystalline structure and phase information, surface capping, morphology and magnetization behavior of nanoparticles were studied by X-Ray diffraction (XRD),...
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Influence of Annealing Atmospheres on Photoelectrochemical Activity of TiO2 Nanotubes Modified with AuCu Nanoparticles
PublicationIn this article, we studied the annealing process of AuCu layers deposited on TiO2 nanotubes (NTs) conducted in various atmospheres such as air, vacuum, argon, and hydrogen in order to obtain materials active in both visible and UV–vis ranges. The material fabrication route covers the electrochemical anodization of a Ti plate, followed by thin AuCu film magnetron sputtering and further thermal treatment. Scanning electron microscopy...
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The use of fungi in biofiltration to remove hydrophobic volatile organic compounds
PublicationThe growing importance placed on air quality by environmental regulations and public opinion necessitate the minimization and removal of volatile organic compound emissions (VOCs), including odours. The removal of hydrophobic VOCs from the air by biological methods remains a major technical challenge (despite its importance in the shift to green engineering). A potential solution to this challenge is the use of fungi in biofiltration....
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Temperature Effects on Weigh-in-Motion Accuracy Using Steering Axle Load Spectrum
PublicationWeigh-in-motion systems (WIM) serve as valuable sources of traffic load data. The determination of axle load spectra using WIM data is pivotal for calculating load equivalency factors and predicting pavement distresses through M-EPDG. Among various factors affecting WIM accuracy, temperature changes stand out as particularly influential. This paper examines the influence of temperature on WIM-collected data, utilizing the steering...
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Elucidating photoluminescent properties of Eu‐doped Ca–Al–Si–O(–N) glasses and the local structures of Eu ions
PublicationEuropium (Eu) ion–doped luminescent materials have attracted considerable attention for their numerous optical applications. Eu-doped Ca–Al–Si–O(–N) glasses were synthesized from a mixture of oxynitride glasses and Eu2O3 powder using a standard melt-quenching technique in a radiofrequency furnace. The source Eu trivalent ions primarily changed to Eu2+ during melting, and the ratio of Eu2+ ions increased with an increase in Eu content...
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Compatibility of Sustainable Mater-Bi/poly(ε-caprolactone)/cellulose Biocomposites as a Function of Filler Modification
PublicationDespite their popularity and multiplicity of applications, wood–polymer composites (WPCs) still have to overcome particular issues related to their processing and properties. The main aspect is the compatibility with plant-based materials which affects the overall performance of the material. It can be enhanced by strengthening the interfacial adhesion resulting from physical and/or chemical interactions between the matrix and...
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Development of an Advanced Control Algorithm for DAB DC/DC Converters: Inrush Current Limitation and Enhanced Operation in Transient States.
PublicationThe publication addresses the dynamic state challenges encountered during development of a dual active bridge (DAB) converter within DC microgrid systems. The conventional startup method is identified as instigating a cascade of unfavorable outcomes, encompassing elevated starting current, transformer current asymmetry, DC voltage distortions, EMI and heightened thermal stress on semiconductor components. Additionally, it necessitates...
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Study on the Coastline Evolution in Sopot (2008–2018) Based on Landsat Satellite Imagery
PublicationThe coastline is the boundary between the water surface in a reservoir or watercourse and the land, which is characterised by high instability and functional diversity. For these reasons, research on coastal monitoring has been conducted for several decades. Currently, satellite images performed with synthetic aperture radars (SARs) are used to determine its course and variability together with high-resolution multispectral imagery...
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Creating Dynamic Maps of Noise Threat Using PL-Grid Infrastructure
PublicationThe paper presents functionality and operation results of a system for creating dynamic maps of acoustic noise employing the PL-Grid infrastructure extended with a distributed sensor network. The work presented provides a demonstration of the services being prepared within the PLGrid Plus project for measuring, modeling and rendering data related to noise level distribution in city agglomerations. Specific computational environments,...
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Supercomputing Grid-Based Services for Hearing Protection and Acoustical Urban Planning, Research and Education
PublicationSpecific computational environments, so-called domain grids, are developed within the PLGrid Plus project in order to prepare specialized IT solutions, i.e., dedicated software implementations and hardware (infrastructure adaptation), suited for particular research group demands. One of the PLGrid Plus domain grids, presented in this paper, is Acoustics. The article describes in detail two kinds of the acoustic domain services....
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In vitro affinity of Deinococcus radiodurans MutS towards mismatched DNA exceeds that of its orthologues from Escherichia coli and Thermus thermophilus
PublicationThe mismatch binding protein MutS is responsible for the recognition of mispaired and unpaired bases, which is the initial step in DNA repair. Among the MutS proteins most extensively studied in vitro are those derived from Thermus thermophilus, Thermus aquaticus and Escherichia coli. Here, we present the first report on the in vitro examination of DNA mismatch binding activity of MutS protein from Deinococcus radiodurans and confront...
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Communication: Inside the water wheel: Intrinsic differences between hydrated tetraphenylphosphonium and tetraphenylborate ions
PublicationTetraphenylphosphonium tetraphenylborate (TPTB) is a common reference electrolyte in physical chemistry of solutions allowing for a convenient partitioning of thermodynamic properties into single-ion contributions. Here, we compute on the basis of ab initio molecular dynamics simulations the infrared (IR) spectra for hydrated constituent ions of the TPTB assumption. Using spectral decomposition techniques, we extract important...
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Wetlands in flux: looking for the drivers in a central European case
PublicationPlanet Earth is undergoing significant changes which are driven by natural and anthropogenic factors. However, it is difficult to identify the drivers and their effect on the environment and ecosystems because there are many interdependencies. In this study we present a multi-parameter approach to assess the effect of changes in human-induced and natural drivers on a wetland ecosystem. The study area is one of the most prominent...
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Study of microstress state of P91 steel using complementary mechanical Barkhausen, magnetoacoustic emission, and X-ray diffraction techniques
PublicationThe paper deals with assessment of microstress state of martensite P91 steel using three complementary techniques: mechanical Barkhausen emission, magnetoacoustic emission (MAE), and X-ray diffraction (XRD) profile analysis. Magnetic coercivity Hc and microstructure were investigated with inductive magnetometry and magnetic force microscopy (MFM), respectively. Internal stress level of P91 steel was modified by heat treatment....
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Mechanism of antifreeze protein functioning and the “anchored clathrate water” concept
PublicationIn liquid water, there is a natural tendency to form aggregates that consist of water molecules linked by hydrogen bonds. Such spontaneously formed aggregates are surrounded by a "sea" of disordered water molecules, with both forms remaining in equilibrium. The process of creating water aggregates also takes place in the solvation water of proteins, but in this case the interactions of water molecules with the protein surface shift...