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Search results for: EXHAUST GAS RECIRCULATION
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Hold-Up Problems in International Gas Trade: A Case Study
PublicationThe infrastructure required for international natural gas trade is considerable, which often leads to hold-up problems and supply disruptions. This study discusses disruptions of gas supply from Algeria, Indonesia, Russia, and Turkmenistan since the early 1980s. The novelty of this study is its focus on the issues related to transit countries, which are rarely considered in the literature. The results of the study classify supply...
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The Influence of Synthetic Oxygenates on Euro IV Diesel Passenger Car Exhaust Emissions
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Dependence of the toxic components exhaust emission from the car engine starting temperature
PublicationW publikacji opisano wyniki badań empirycznych zależności stężeń toksycznych składników spalin od stanu cieplnego silnika w chwili rozruchu. Zwrócono uwagę na duże stężenia w pierwszych kilkudziesięciu sekundach po rozruchu. Badano silniki samochodów osobowych zarówno w eksploatacji jak i na hamowni podwoziowej.
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Method of selecting the LS-SVM algorithm parameters in gas detection process
PublicationIn this paper we showed the method of resistive gas sensors data processing. The UV irradiation and temperature modulation was applied to improve gas sensors’ selectivity and sensitivity. Noise voltage across the sensor’s terminals (proportional to its resistance fluctuations) was recorded to estimate power spectral density. This function was an input data vector for LS-SVM (least squares – support vector machine) algorithm, which...
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APPLICATION OF ULTRAFAST GAS CHROMATOGRAPHY TO RECOGNIZE ODOR NUISANCE
PublicationPotentialities of ultrafast gas chromatography applied to periodical monitoring of odor nuisance originating from a municipal landfill have been examined. The results of investigation on classification of the atmospheric air samples collected in a vicinity of the landfill during winter and summer season have been presented. The investigation was performed using ultrafast gas chromatography of Fast/Flash GC type HERACLES II by Alpha...
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Problems of gas detection by resistance fluctuations in gas sensors
PublicationPrzedstawiono problemy budowy dystrybutora gazów oraz próbek zapachowych do badań sensorów gazu. Podano układ elektroniczny wykorzystywany do rejestracji fluktuacji rezystancji obserwowany w czujnikach gazu. Załączono przykładowe wyniki obserwacji sygnałów losowych.
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Polypyrrole based gas sensor for ammonia detection
PublicationThe nature of polypyrrole response to toxic gases does not allow using the sensor in a conventional way. The main aim of this study is to acquire the information about the concentration using different approaches: a linear approximation, a non-linear approximation and a tangent method. In this paper a two-steps procedure for sensor response measurements has been utilized. Polypyrrole films were electrochemically synthesized on...
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Roadmap on dynamics of molecules and clusters in the gas phase
PublicationThis roadmap article highlights recent advances, challenges and future prospects in studies of the dynamics of molecules and clusters in the gas phase. It comprises nineteen contributions by scientists with leading expertise in complementary experimental and theoretical techniques to probe the dynamics on timescales spanning twenty orders of magnitudes, from attoseconds to minutes and beyond, and for systems ranging in complexity...
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Thermal self-action effects of acoustic beam in a vibrationally relaxing gas
PublicationThermal self-action of acoustic beam in a molecular gas with excited internal degrees of molecules’ freedom, is studied. This kind of thermal self-action differs from that in a Newtonian fluid. Heating or cooling of a medium takes place due to transfer of internal vibrational energy. Equilibrium and non-equilibrium gases, which may be acoustically active, are considered. A beam in an acoustically active gas is self-focusing unlike...
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Concentration levels of selected analytes in the gas phase of an e-cigarette aerosol
PublicationThe aerosols generated from e-cigarettes are composed of liquid and gas phases resulting from vapourized e-liquid. The apportioning of substances from e-liquid into the liquid and gas phases during e-cigarette use has not been extensively studied. Partitioning of e-liquid components between the gas and the liquid phase of the aerosol influences the substances inhaled and exhaled by the users, leading to second-hand exposure. It...
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Wavelet Transform Analysis of Temperature Modulated Gas Sensor Response
PublicationThe aim of the study was to evaluate whether it is possible to extract the information about the gas concentration despite the influence of humidity. Commercial semiconductor sensor response was examined under the application of a periodic temperature change. The data was collected using measurement protocol for different concentrations of ammonia at specified levels of relative humidity. In this work we focused on the evaluation...
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Novel stationary phases based on asphaltenes for gas chromatography
PublicationWe present the results of investigations on the possibility of the application of the asphaltene fraction isolated from the oxidized residue from vacuum distillation of crude oil as a stationary phase for gas chromatography. The results of the investigation revealed that the asphaltene stationary phases can find use for the separation of a wide range of volatile organic compounds. The experimental values of Rohrschneider/McReynolds...
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An electronic nose based on the semiconducting and electrochemical gas sensors
PublicationThe practical application of human nose for fragrance recognition is severely limited by the fact that our sense of smell is subjective and gets tired easily. Consequently, there is a significant need for an instrument that can be a substitution of the human sense of smell. Development of an electronic nose devices is an active area of research starting from pioneering research of Dodd and Persuad in the mid-1980s. Such systems...
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Fluctuation-enhanced scent sensing using a single gas sensor
PublicationScent or aroma sensing during aromatherapy can be carried out by applying only a single resistance gas sensor (TGS - Taguchi Gas Sensors). This paper considers the efficiency of detection of essential oils by DC resistance and its fluctuations observed in TGS sensors. A detailed study has been conducted for scents emitted by five popular essential oils using three sensor types (TGS 2600, TGS 2602, TGS 823). The research was focused...
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Comparison of an Electronic Nose Based on Ultrafast Gas Chromatography, Comprehensive Two-Dimensional Gas Chromatography, and Sensory Evaluation for an Analysis of Type of Whisky
PublicationWhisky is one of the most popular alcoholic beverages. There are many types of whisky, for example, Scotch, Irish, and American whisky (called bourbon). The whisky market is highly diversified, and, because of this, it is important to have a method which would enable rapid quality evaluation and authentication of the type of whisky. The aim of this work was to compare 3 methods: an electronic nose based on the technology of ultrafast...
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Control of mass concentration of reagents by sound in a gas with nonequilibrium chemical reactions
PublicationThe weakly nonlinear dynamics of a chemically reacting gas is studied. Nonlinear interaction of acoustic and nonacoustic types of motion are considered. We decompose the base equations using the relationships of the gas-dynamic perturbations specific for every type of motion. The governing equation for the mass fraction of a reagent influenced by dominating sound is derived and discussed. The conclusions concern the equilibrium...
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Assessment, optimisation and working fluid comparison of organic rankine cycle combined with negative CO2 gas power plant system
PublicationThis study aims to investigate the application of the Organic Rankine Cycle (ORC) as an alternative to low-pressure expansion in the negative CO2 power plant (nCO2PP). The reason for this study is that a detailed analysis of nCO2PP indicates a certain amount of waste heat present in the exhaust gas from the high-to-intermediate pressure gas turbine. Some of this energy can be used by the application of the expansion in a low-pressure...
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The effects of gas exposure on the graphene/AlGaN/GaN heterostructure under UV irradiation
PublicationThis work demonstrates a graphene/AlGaN/GaN sensing device with two-dimensional electron gas (2DEG) toward nitrogen dioxide (NO2), tetrahydrofuran, and acetone detection under UV light irradiation. We propose combining measurements of the DC characteristics with a fluctuation-enhanced sensing method to provide insight into the gas detection mechanisms in the synergistic structure of highly stable GaN and gas-sensitive graphene....
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Experimental investigation of domestic gas boiler fitted with ORC module
PublicationIn the paper the prototype of innovative domestic cogenerative ORC system, consisting of a conventional gas boiler and a small size axial vapour microturbines (in-house designed for ORC and the commercially available for Rankine cycle (RC)), evaporator and condenser were scrutinised. In the course of study the fluid working temperatures, rates of heat, electricity generation and efficiency of the whole system were obtained. The...
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Development of Gas Sensor Array for Methane Reforming Process Monitoring
PublicationThe article presents a new method of monitoring and assessing the course of the dry methane reforming process with the use of a gas sensor array. Nine commercially available TGS chemical gas sensors were used to construct the array (seven metal oxide sensors and two electrochemical ones). Principal Component Regression (PCR) was used as a calibration method. The developed PCR models were used to determine the quantitative parameters...
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OPTIMIZATION OF THE LAST STAGE OF GAS-STEAM TURBINE USING A HYBRID METHOD
PublicationThis paper relates to the CFD calculation of a new turbine type which is in the phase of theoretical analysis, because the working fluid is a mixture of steam and gas generated in wet combustion chamber. At first, this article concentrates on a possibility of streamlining the flow efficiency of a last stage of axial turbine working on gas-steam mixture using a hybrid of the particle swarm optimization algorithm with the Nelder-Mead...
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Thermal failure of a second rotor stage in heavy duty gas turbine
PublicationThe impulse mode of operation and the supply of various types of fuels causes frequent failures even in the heavy duty gas turbines. The paper presents the ravages of second rotor stage failure in a gas turbine. The excessive thermal elongation rise caused by fuel change was indicated as the main cause. We applied nonlinear numerical analysis, preceded by thermodynamic calculations of the turbine and visual inspection of the effects...
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Preparation and characterization of asphaltene based adsorbents for gas-solid adsorption systems
PublicationThe dissertation presents results of the experimental research on asphaltene-based adsorbents (support coated with asphaltene layer) for gas-solid adsorption systems, with special reference to volatile organic compounds (VOCs) removal from gas streams. Analysis of gas adsorption properties revealed that asphaltenes isolated from oxidized bitumen have strong affinity toward VOCs. Interactions with target gas molecules, and selectivity...
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Inlet air fogging of marine gas turbine in power output loss compensation
PublicationThe use of inlet air fogging installation to boost the power for gas turbine engines is widely applied in the power generation sector. The application of fogging to mechanical drive is rarely considered in the literature [1]. This paper will cover some considerations relating to its application to gas turbines in ship drive. There is an important evaporative cooling potential throughout the world when the dynamic data is evaluated,...
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Low and high energy explosive materials used in shale gas recovery
PublicationNowadays the explosives are widely used in many areas of life, including industry and mining. A wide range of explosive materials is used in the petroleum industry - from low to high explosives. Recently, as the unconventional oil and gas production became possible, explosives are also found to be used in perforators during the pre-completion stage of the fracturing process. This paper presents literature on theoretical and practical...
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Domestic ORC micro-CHP combined with a commercial gas boiler
PublicationThe chapter presents the results of experimental studies conducted during the launch of the first in Poland demonstration prototype of the micro ORC coupled to a domestic gas boiler. The accomplished studies indicated the possibility for the ORC module to work with such boiler (autonomous source of heat) with a prototype single-stage axial micro turbine as the expansion machine. Confirmation of that fact has been delineated in...
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Special Issue on “Advanced Liquid Waste and Gas Waste Treatment Processes”
PublicationThe editorial contains a short review of the content of the Special Issue on waste gas and liquid streams treatment strategies.
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Non-Wave Variations in Temperature Caused by Sound in a Chemically Reacting Gas
PublicationA weakly nonlinear generation of non-acoustic modes in the field of sound in a gas is considered. An exotericchemical reaction of A->B type, which takes place in a gas, may be reversible or not. Two types of sound areconsidered, low-frequency and high-frequency as compared with the characteristic time of a chemical reaction.For both these cases, the governing equations of non-acoustic modes are derived and conclusions of the efficiencyof...
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CuO-decorated MOF derived ZnO polyhedral nanostructures for exceptional H2S gas detection
PublicationConsidering that H2S is a hazardous gas that poses a significant risk to people's lives, research into H2S gas sensors has garnered a lot of interest. This work reports a CuO/ZnO multifaceted nanostructures(NS) created by heat treating Cu2+/ZIF-8 impregnation precursors, and their microstructure and gas sensing characteristics were examined using various characterization techniques (XRD, XPS, SEM, TEM, and BET). The as-prepared...
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Non-Linear Interaction of Harmonic Waves in a Quasi-Isentropic Flow of Magnetic Gas
PublicationThe diversity of wave modes in the magnetic gas gives rise to a wide variety of nonlinear phenomenaassociated with these modes. We focus on the planar fast and slow magnetosound waves in the geometryof a flow where the wave vector forms an arbitrary angleθwith the equilibrium straight magnetic field.Nonlinear distortions of a modulated signal in the magnetic gas are considered and compared to thatin unmagnetised gas. The case of...
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Operational causes of fatigue failures within the passages of gas turbine engines
PublicationThe short profile of a fatigue wear process of gas turbine engine's constructional elements has been introduced in the article. The primary causes of a fatigue cracks formation within the mechanical system as well as within the passages of the engine have been showed. Especial attention was devoted to the low-cycle fatigue, what is associated with unsteady thermal-flow processes being worked out in the passages.The selected damages...
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Occurrence and Determination of Volatile Fatty Acids in Landfill Leachate and Gas
PublicationIn landfills containing biological matter volatile fatty acids (VFAs) are generated at high rate at the early stage of waste disposal and their content in leachate is high as compared to the leachate from old parts of landfill since they are converted to methane gas. Monitoring of the leachate for the content of VFAs can help determine the processes occurring in waste and possible effect of the leachate on the environment in the...
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Occurrence and Determination of Volatile Fatty Acids in Landfill Leachate and Gas
PublicationIn landfills containing biological matter volatile fatty acids (VFAs) are generated at high rate at the early stage of waste disposal and their content in leachate is high as compared to the leachate from old parts of landfill since they are converted to methane gas. Monitoring of the leachate for the content of VFAs can help determine the processes occurring in waste and possible effect of the leachate on the environment in the...
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Two-Dimensional Gas Chromatography Coupled With Mass Spectrometry in Food Analysis
PublicationThe development of instrumental analytical techniques provided the opportunity for in-depth characterization of many food matrices. In particular, the use of gas chromatography coupled with mass spectrometry gives impressive results in terms of quality and authenticity testing, conducting food freshness evaluations and contamination assessments. A new variant of gas chromatography, namely two-dimensional gas chromatography (GC...
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Radioisotope measurements of the liquid-gas flow in the horizontal pipeline using phase method
PublicationThe paper presents application of the gamma-absorption method to a two-phase liquid-gas flow investigation in a horizontal pipeline. The water-air mixture was examined by a set of two Am-241 radioactive sources and two NaI(Tl) scintillation probes. For analysis of the electrical signals obtained from detectors the cross-spectral density function (CSDF) was applied. Results of the gas phase average velocity measurements for CSDF...
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Degradation of protective coatings in steel chimneys of flue gas desulfurisation system
PublicationThis paper presents problems associated with corrosion of steel stacks and changes in philosophy of corrosion protection when implemented into flue gas desulphurization systems. In-situ tests were taken by means of electrochemical impedance spectroscopy at the stack which discharges flue gas before wet lime/limestone desulphurization. A very quick electrolyte absorption by the spherical infill vinylester coating was found using...
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Influence of Exhaust System Setup on Working Zone Pollution by Dust during Sawing of Particleboards
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Sulfur Driven Nucleation Mode Formation in Diesel Exhaust under Transient Driving Conditions
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Investigation of Exhaust Emissions from DI Diesel Engine During Cold and Warm Start
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Exhaust Emission from Passenger Cars During Engine Cold Start and Warm-Up
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Negative carbon dioxide gas power plant integrated with gasification of sewage sludge
PublicationOne of the primary objectives of the negative carbon dioxide gas power plant (nCO2PP) is to develop an innovative technology confirming the possibility of the use of sewage sludge to produce electricity while having a positive impact on the environment. In this paper, a mathematical model is presented to estimate thermodynamic parameters of the system in relation to the gasification process and changes in such parameters in the...
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Dissociative ionization dynamics of dielectric gas C3F7CN
PublicationFluoronitrile C3F7CN is a promising candidate for the replacement of SF6 dielectric gas in high-voltage insulation. We present a combined experimental and theoretical study on its ionization dynamics probed in the 0-100 eV energy range. We exploited the total ion collection technique to determine the absolute ionization cross section, mass spectrometry to determine the fragment branching ratios and ab initio nonadiabatic molecular...
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CLAY MINERALS – MINERALOGY AND PHENOMENON OF CLAY SWELLING IN OIL & GAS INDUSTRY
PublicationAmong the minerals found in the earth's crust, clay minerals are of the widest interest. Due to the specific properties such as plasticity, absorbing and catalytic properties clay minerals are used in many industries (oil & gas, chemistry, pharmacy, refractory technology, ceramics etc.). In drilling, a phenomenon of swelling clays is frequently observed. It has an important impact on the cementing quality. During the last few decades...
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The effect of aeration mode (intermittent vs. continuous) on nutrient removal and greenhouse gas emissions in the wastewater treatment plant of Corleone (Italy)
PublicationThe paper reports the results of an experimental study aimed at comparing two configurations of a full-scale wastewater treatment plant (WWTP): conventional activated sludge (CAS) and oxic-settling-anaerobic process (OSA) with intermittent aeration (IA). A comprehensive monitoring campaign was carried out to assess multiple parameters for comparing the two configurations: carbon and nutrient removal, greenhouse gas emissions, respirometric...
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Nitrogen dioxide gas-sensing detection with GO modified CuO thin films
PublicationGas sensors have been continuously developed over the last few decades for several applications including air quality monitoring, automotive industry and recently for medical use. Gas sensors are usually based on metal oxides (MOXs), such as SnO2, TiO2, ZnO, WO3, CuO. Recently, new materials such as graphene oxide and heterostructures of graphene oxide and metal oxides are utilized for gassensing applications.
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Mobile Gas Chromatographs Coupled with Mass and Ion Mobility Spectrometers and their Applications
PublicationThe articles describes the developments un combining of mass and ion mobility spectrometers (MS, IMS0 with miniature gas chromatographs (GC). The examples of applications of miniaturised GC-MS and GC-IMS devices are presented.
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Effects of UV light irradiation on fluctuation enhanced gas sensing by carbon nanotube networks
PublicationThe exceptionally large active surface-to-volume ratio of carbon nanotubes makes it an appealing candidate for gas sensing applications. Here, we studied the DC and low-frequency noise characteristics of a randomly oriented network of carbon nanotubes under NO2 gas atmosphere at two different wavelengths of the UV light-emitting diodes. The UV irradiation allowed to sense lower concentrations of NO2 (at least 1 ppm) compared to...
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Enhanced visible light-activated gas sensing properties of nanoporous copper oxide thin films
PublicationMetal oxide gas sensors are popular chemoresistive sensors. They are used for numerous tasks, including environmental and safety monitoring. Some gas-sensing materials exhibit photo-induced properties that can be utilized for enhanced gas detection by modifying the sensor selectivity and sensitivity when illuminated by light. Here, we present the gas sensing characteristics of highly nanoporous Cu2O thin films towards both electrophilic...
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Electrical responses of nanoporous NiO films for light-activated nitrogen dioxide and acetone gas sensing
Open Research DataThe chemoresistive sensor response of nanoporous NiO films prepared by advanced gas deposition was investigated with and without simultaneous light irradiation, to detect nitrogen dioxide and acetone gases. The presented data show electrical responses presented as sensor resistance or relative changes in sensor resistance under selected environment...
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UV-Light-Induced Fluctuation Enhanced Sensing by WO3-Based Gas Sensors
PublicationWO3-based gas sensors were investigated under UV-light irradiation and at different working temperatures with the object of achieving superior sensitivity and selectivity. Resistance fluctuations in the WO3 layer were studied together with dc resistance measurements. The data were taken in synthetic air, ethanol, nitrogen dioxide, and mixtures of these gases. We conclude that UV irradiation can easily be applied to enhance the...