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Search results for: EXTRACTION
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Effect of the ionic liquids on extraction of aromatic and sulfur compounds from the model petrochemical stream
PublicationSuitability of a imidazolium ionic liquids (ILs) as solvents in dearomatization and desulfurization in the ternary systems and in a model multicomponent systems has been analyzed. With this aim, ternary liquid-liquid phase equilibrium data (LLE) have been obtained for ternary mixtures of {IL + benzene, or toluene, or thiophene, or 2-butanethiol + hexane}, or {IL + benzene + 2-methylpentane} at T = 298.15 K and ambient pressure,...
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ANALYSIS OF THE IMPACT OF MASS FLOW EXTRACTION ON THE CHANGE OF PARAMETERS IN A LABYRINTH SEAL USING THE STODOLA METHOD
PublicationLabyrinth seals are an important element of a steam turbine set design. The use of diagnostic extraction makes it possible to control the operation of a seal by providing information on the thermodynamic parameters along the length of the seal. Diagnostic extraction has a considerable impact on the change of the parameters, the amount of the extracted mass. This article describes the dependence of pressure in the clearance downstream...
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ANALYSIS OF THE IMPACT OF MASS FLOW EXTRACTION ON THE CHANGE OF PARAMETERS IN A LABYRINTH SEAL USING THE STODOLA METHOD
PublicationLabyrinth seals are an important element of a steam turbine set design. The use of diagnostic extraction makes it possible to control the operation of a seal by providing information on the thermodynamic parameters along the length of the seal. Diagnostic extraction has a considerable impact on the change of the parameters, the amount of the extracted mass. This article describes the dependence of pressure in the clearance downstream...
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The dispersive micro-solid phase extraction method for MS-based lipidomics of human breast milk*
PublicationA simple and rapid microextraction method ensuring high lipidome coverage was developed for liquid chromatography mass spectrometry (LC-MS)-based lipidomics of human breast milk. The dispersive microsolid phase extraction (D-µ-SPE) technique, coupled with the design of experiment (DoE) method, enabled the study of the influence of several conditions (desorption solvent, stationary phase ratio, and sorption and desorption time)...
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Deep eutectic solvents in analytical sample preconcentration Part B: Solid-phase (micro)extraction
PublicationOne of the key challenges of modern analytical chemistry is the monitoring of trace amounts of contaminants using sensitive and selective instrumental techniques. Due to the variety and complexity of some samples, it is often necessary to properly prepare a sample and to perform a preconcentration of trace amounts of analytes. In line with the principles of Green Analytical Chemistry (GAC), it is important for an analytical procedure...
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Assessment of particular abdominal aorta section extraction from contrast-enhanced computed tomography angiography
PublicationThe aim of this work is to improve the accuracy of extraction of a particular abdominal aorta section and to reduce the distortion in three-dimensional Computed Tomography Angiography (CTA) images. Imaging modality and quality plays crucial role in the medical diagnostic process, thus ensuring high quality of images is essential at every stage of acquisition and processing.Noise is defined as a disturbance of the image quality...
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Application of magnetic nanoparticles for magnetic solid-phase extraction in preparing biological, environmental and food samples
PublicationThe need to obtain meaningful results as the basis for determining the content of trace amounts of analytes has become the driving force behind the development of modern analytical techniques, including sample-preparation techniques, such as solid-phase extraction (SPE). Recently, great interest was aroused in the use of magnetic nanoparticles (MNPs) in SPE. These materials exhibit high selectivity, and, in small amounts, can provide...
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Modeling and MANOVA studies on toxicity and endocrine potential of packaging materials exposed to different extraction schemes
PublicationThe stability of the linings of packaging that is in contact with the goods stored has been of major concern during decades of the development of packaging materials. In this work, an attempt was undertaken to assess the applicability of using two bioassays (Microtox® and XenoScreen YES/YAS) in estimating the stability of packaging (cans, caps, multilayer material) and the impact of their degradation on the toxicity of some simulated media....
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New achievements in the field of extraction of trace analytes from samples characterized by complex composition of the matrix
PublicationWithout any doubt, the monitoring of compounds present in samples at trace or ultra-trace level usually requires a preliminary step of isolation and/or enrichment of analytes due to the fact that majority of analytical techniques are not sensitive enough for direct determination of trace compounds. On the other hand, sample preparation is considered as crucial part of whole analytical procedures, in particular in samples characterized...
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Hydrophobic deep eutectic solvents as “green” extraction media for polycyclic aromatic hydrocarbons in aqueous samples
PublicationThe paper presents novel nonionic and hydrophobic deep eutectic solvents which were synthesized from natural compounds, i.e., thymol, ±camphor, decanoic and 10-undecylenic acids. Fundamental physicochemical properties of the synthesized deep eutectic solvents were determined, followed by their application as extractants in ultrasound-assisted dispersive liquid-liquid microextraction to isolate and enrich polycyclic aromatic hydrocarbons...
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Development of SPME fiber coatings with tunable porosity for physical confinement of ionic liquids as an extraction media
PublicationExtending the use of ionic liquids in sample preparation techniques remains a challenge. This paper presents procedures enabling the easy application of ionic liquids to the SPME technique. For this purpose, two approaches for producing a porous silica coating on a metal rod were investigated. Two silica precursor and porogen systems were used in the research: K2SiO3 + Formamide and Tetramethyl-orthosilicate + Polyethylene oxide....
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Extraction and evaluation of gas-flow-dependent features from dynamic measurements of gas sensors array
PublicationGas analyzers based on gas sensors are the devices which enable recognition of various kinds of volatile compounds. They have continuously been developed and investigated for over three decades, however there are still limitations which slow down the implementation of those devices in many applications. For example, the main drawbacks are the lack of selectivity, sensitivity...
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Giant Reed (Arundo donax L.) Fiber Extraction and Characterization for Its Use in Polymer Composites
PublicationThis work describes an extraction method for giant reed fibers from stems and leaves based on chemical soaking and crushing through a rolling mill. Obtained fibers, together with the shredded plant (stems + leaves), are characterized in terms of chemical composition, thermal stability, morphology, and crystallinity. Mechanical properties of fibers have also been assessed (single fiber tensile tests). The results show that the proposed...
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Device characteristics extraction by low frequency noise measurements; Someresults on the state-of-the-art MOSFET´s
PublicationPrzedstawiono wyniki pomiarów i analizy szumów tranzystorów MOSFET z izolatorem bramki wykonanym z SiO2 i HfO2. Wyniki pomiarów wykorzystano do oszacowania gęstości aktywnych stanów na powierzchni użytego tlenku i porównano z wynikami otrzymanymi metodą charge-pumping.
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Determination of pesticides in water using new solid phase extraction technique - speedisk and speedisk column.
PublicationW publikacji opisano zastosowanie nowych narzędzi do ekstrakcji do fazy stałej: szybkie dyski i szybkie kolumienki (speedisk i speedisk column). Zaprezentowano ich zastosowanie do ekstrakcji pestycydów z próbek wody, przy zastosowaniu różnych rozpuszczalników.
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Development of a Method Based on Natural Deep Eutectic Solvents for Extraction of Flavonoids from Food Samples
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Supercritical fluid extraction of algae enhances levels of biologically active compounds promoting plant growth
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The Copper(II) Ions Solvent Extraction with a New Compound: 2,6-Bis(4-Methoxybenzoyl)-Diaminopyridine
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Application of a magnetically separable Zr-MOF for fast extraction of palladium before its spectrophotometric detection
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Glycerolic Licorice Extracts as Active Cosmeceutical Ingredients: Extraction Optimization, Chemical Characterization, and Biological Activity
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Continuous Monitoring of Thermooxidative Degradation Products of Polystyrene by Membrane Extraction with Sorbent Interface and Gas Chromatography
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Synthesis and structural properties of carbon/alumina composites: Practical application in solid phase extraction of explosives
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Self-adaptive heat extraction controller for solar thermal tower operational with molten salt tanks
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Small signal admittance spectroscopy applied for extraction of charge carrier mobility in thin organic layers
PublicationPraca przedstawia nowy sposób wyznaczania ruchliwości nośników ładunku w cienkich warstwach organicznych w oparciu o pomiary widm małosygnałowej admitancji.
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Understainding solid-phase microextraction: key factors influencing the extraction process and trends in improving the technique
PublicationAnalytical chemists are faced with the daunting challenges of accurately monitoring the state of the environment and the processes taking place in it and of determining an enormous range of analytes often present in trace and ultratrace amounts in sample matrixes with complex or variable compositions. Further challenges are presented by the need to introduce new methodologies into current analytical practice and equipment to comply...
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Green energy extraction for sustainable development: A novel MPPT technique for hybrid PV-TEG system
PublicationThe Photovoltaic (PV) module converts only a small portion of irradiance into electrical energy. Most of the solar energy is wasted as heat, resulting in a rise in PV cell temperature and a decrease in solar cell efficiency. One way to harvest this freely available solar thermal energy and improve PV cell efficiency is by integrating PV systems with thermoelectric generators (TEG). This cogeneration approach of the hybrid PV-TEG...
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Application of polyethylene glycol-coated iron oxide nanoparticles for magnetic solid phase extraction of copper from seawater samples and its determination by graphite furnace atomic absorption spectrometry using response surface methodology for optimization of extraction
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Magnetic deep eutectic solvents as efficient media for extraction of furfural and 5-hydroxymethylfurfural from aqueous samples
PublicationThe extraction of furfural (FF) and 5-hydroxymethylfurfural (HMF) from hydrolysates is currently one of the main challenges in bio-refinery. In this work, the separation of FF and HMF from the aqueous phase was carried out using a new type of green solvents – Magnetic Deep Eutectic Solvents (MDES). A conductor-like screening model for realistic solvents (COSMO-RS) was used for the preselection of 400 MDES. MDES which exhibit the...
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Deep eutectic solvents based assay for extraction and determination of zinc in fish and eel samples using FAAS
PublicationA new assay based on effective (high recovery) extraction by means of deep eutectic solvents (DESs) was developed for ppb level determination of zinc in fishes and eel samples. Choline chloride and Phenol in a 1:2 M ratio was selected as optimal DES-based extraction solvent. 8-Hydroxy quinoline was used as a chelating agent for zinc ions. The optimized conditions were found at pH value of 8, ligand concentration of 10 mg/L, THF...
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Extraction pathways and purification strategies towards carminic acid as natural-based food colorant: A comprehensive review
PublicationAs a current trend of fabricating healthier products, food manufacturing companies seek for natural-based food colorant aiming to replace the synthetic ones, which apart from meeting sensorial and organoleptic aspects, they can also act as health promoters offering additional added value. Carminic acid is a natural based food colorant typically found in several insect taxa. However, there are current approaches which pursue the...
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Phenolic compounds from Nerium oleander leaves: microwave assisted extraction, characterization, antiproliferative and cytotoxic activities
PublicationA microwave-assisted extraction (MAE) method was used for the extraction of phenolic compounds from Nerium oleander leaves. The influence of variables such as ethanol concentration, microwave power, irradiation time and liquid/solid ratio on polyphenol extraction was modelled using a second-order regression equation based on response surface methodology (RSM). The optimal conditions for MAE were: extraction solvent 35% ethanol...
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Alginate-based sorbents in miniaturized solid phase extraction techniques - Step towards greenness sample preparation
PublicationIn response to growing concerns about environmental degradation, one of the main areas of research activity in recent years has been to make sample preparation methods more sustainable and eco-friendly. The increasing greenness of this step can be achieved by minimizing the usage of reagents, automating individual stages, saving energy and time, and using non-toxic, biodegradable substances. Therefore, the use of natural materials...
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The new silica-based coated SPME fiber as universal support for the confinement of ionic liquid as an extraction medium
PublicationThe new silica-based SPME fiber coating is reported for the first time as universal support purposed to confinement of ionic liquid as an extraction medium. Fiber coating was prepared by the sol-gel process, using potassium silicate (K2SiO3) as a precursor and dimethylformamide (DMF) as a pore-forming medium. The concept of synthesis assumes obtaining a solid porous material on the surface of the glass rod and, being characterized...
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Application of Aqueous Biphasic Systems Extraction in Various Biomolecules Separation and Purification: Advancements Brought by Quaternary Systems
PublicationAqueous biphasic systems (ABS) extraction is a simple, selective, efficient and easy to scale-up technology that, over the years, has attracted a considerable attention from the researcher community as an alternative methodology in downstream processing of a wide variety of biomolecules. This review summarizes and discusses the fundamental features of ABS, as well as its advantages and disadvantages, as a separation and purification...
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Time window based features extraction from temperature modulated gas sensors for prediction of ammonia concentration
PublicationElectronic gas recognition systems, in literature commonly referred as electronic noses, enable the recognition of a type and a concentration of various volatile compounds. Typical electronic gas-analyzing device consists of four main elements, namely, gas delivery subsystem, an array of gas sensors, data acquisition and power supply circuits and data analysis software. The commercially available metal-oxide TGS sensors are widely...
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Identification of chicken egg fertility using SVM classifier based on first-order statistical feature extraction
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Multivariable optimization of ultrasound-assisted solvent extraction of bee pollen prior to its element analysis by FAAS
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Chlorine-free extraction and structural characterization of cellulose nanofibers from waste husk of millet (Pennisetum glaucum)
PublicationThis study aims to extract cellulose nanofibers (CNFs) from a sustainable source, i.e. millet husk, which is an agro-waste worthy of consideration. Pre-treatments such as mercerisation, steam explosion, and peroxide bleaching (chlorine-free) were applied for the removal of non-cellulosic components. The bleached millet husk pulp was subjected to acid hydrolysis (5% oxalic acid) followed by homogenization to extract CNFs. The extracted...
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Novel anion receptors: hybrid materials based on quaternary ammonium salts for selective extraction of dichromate ions
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Extraction Methods of 10-Deacetylbaccatin III, Paclitaxel, and Cephalomannine from Taxus baccata L. Twigs: A Comparison
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The Influence of Purge Times on the Yields of Essential Oil Components Extracted from Plants by Pressurized Liquid Extraction
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SPECTROPHOTOMETRIC DETERMINATION OF FOUR NAPHTHALENE SULFONATES IN SEAWATER AFTER THEIR MOLECULARLY IMPRINTED STIR BAR SORPTIVE EXTRACTION
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The application of single drop extraction technique for chromatographic determination of solvent residues in edible oils and pharmaceutical products
PublicationW pracy przedstawiono zalety i wady techniki ekstrakcji do pojedynczej kropli, będącą prostą i tanią alternatywą dla mikroekstrakcji do fazy stacjonarnej. Ponadto opisano dwie analityczne procedury do chromatograficznego oznaczania wybranych rozpuszczalników organicznych (heksanu, benzenu, toluenu oraz trichlorometanu, 1,1,1-trichloroetanu, tetrachlorometanu, trichloroetylenu, tetrachloroetenu)w olejach jadalnych i próbkach farmaceutycznych....
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GC-FID determination of C2-C4 aliphatic monocarboxylic acids in aqueous samples preceded by solvent extraction
PublicationEkstrakcja za pomocą eteru metylo-tert-butylowego (MTBE) została wykorzystana do izolacji krótkołańcuchowych alkanowych kwasów monokarboksylowych (2-4 atomy węgla w cząsteczce) z próbek o matrycy wodnej. Całkowita wydajność dwukrotnej ekstrakcji z próbek wodnych kwasów: octowego, propionowego i masłowego wynosiła odpowiednio ok. 55% , ok. 90% i ponad 90%. Wydajności ekstrakcji są porównywalne z wartościami uzyskiwanymi w przypadku...
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Application of ultrasound-assisted solvent extraction of porous membrane packed liquid samples for polyphenols determination in wine samples
PublicationPolyphenols play a crucial role in a proper human health maintenance as well as their presence very often correspond to the quality assessment of producs like wine. Thus, their monitoring is of high interest. However, as they occur in a complex matrices their extraction is very often necessary prior the analysis. Herein, a new ultrasound-assisted solvent extraction of porous membrane packed liquid sample technique has been optimized...
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2,6-Bis((benzoyl-R)amino)pyridine (R = H, 4-Me, and 4-NMe2) Derivatives for the Removal of Cu(II), Ni(II), Co(II), and Zn(II) Ions from Aqueous Solutions in Classic Solvent Extraction and a Membrane Extraction
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Latest Insights on Novel Deep Eutectic Solvents (DES) for Sustainable Extraction of Phenolic Compounds from Natural Sources
PublicationPhenolic compounds have long been of great importance in the pharmaceutical, food, and cosmetic industries. Unfortunately, conventional extraction procedures have a high cost and are time consuming, and the solvents used can represent a safety risk for operators, consumers, and the environment. Deep eutectic solvents (DESs) are green alternatives for extraction processes, given their low or non-toxicity, biodegradability, and reusability....
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Comparison of oil yield and quality obtained by different extraction procedures from salmon (Salmo salar) processing byproducts
PublicationThe content and composition of lipids in different byproducts (skins, heads, and backbones) from mechanically processed farmed Atlantic salmon were determined and compared with that obtained from wild salmon. Three different procedures were used to establish the optimal conditions of oil extraction (at high temperature −95°C, “cold” extraction at temperature not exceeding 15°C and enzyme assisted with Alcalase). “Cold” extraction...
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Deep eutectic solvent-based shaking-assisted extraction for determination of bioactive compounds from Norway spruce roots
PublicationPolyphenolic compounds play an essential role in plant growth, reproduction, and defense mechanisms against pathogens and environmental stresses. Extracting these compounds is the initial step in assessing phytochemical changes, where the choice of extraction method significantly influences the extracted analytes. However, due to environmental factors, analyzing numerous samples is necessary for statistically significant results,...
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A solid phase extraction–ion chromatography with conductivity detection procedure for determining cationic surfactants in surface water samples
PublicationA new analytical procedure for the simultaneous determination of individual cationic surfactants (alkyl benzyl dimethyl ammonium chlorides) in surface water samples has been developed. We describe this methodology for the first time: it involves the application of solid phase extraction (SPE – for sample preparation) coupled with ion chromatography–conductivity detection (IC-CD – for the final determination). Mean recoveries of...