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Nanostructure of the laser-modified transition metal nanocomposites for water splitting
PublicationAlthough hydrogen is considered by many to be the green fuel of the future, nowadays it is primarily produced through steam reforming, which is a process far from ecological. Therefore, emphasis is being put on the development of electrodes capable of the efficient production of hydrogen and oxygen from water. To make the green alternative possible, the solution should be cost-efficient and well processable, generating less waste...
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Structural and Thermo-Mechanical Properties of Poly(ε-caprolactone) Modified by Various Peroxide Initiators
PublicationThe modification of poly(ε-caprolactone) (PCL) was successfully conducted during reactive processing in the presence of dicumyl peroxide (DCP) or di-(2-tert-butyl-peroxyisopropyl)-benzene (BIB). The peroxide initiators were applied in the various amounts of 0.5 or 1.0 pbw (part by weight) into the PCL matrix. The effects of the initiator type and its concentration on the structure and mechanical and thermal properties of PCL were...
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Silver-modified titania with enhanced photocatalytic and antimicrobial properties under UV and visible light irradiation
PublicationCommercial titania photocatalysts were modified with 2 wt% of silver by photodeposition. The properties of the samples were characterized by DRS, XPS, XRD, FE-SEM and STEM. The modified samples exhibited activity under visible light and enhanced activity under UV irradiation for 2-propanol and acetic acid oxidation, respectively. The time-resolved microwave conductivity (TRMC) analysis indicated that enhanced activity (2.5–8-fold...
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SEARCH-Journal of the Southeast Asia Research Centre for Communications and Humanities
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Wear of Ultra-thin DLC or Tungsten-modified DLC Coatings under Reciprocating Sliding
PublicationIn the paper results are presented from tests in reciprocating sliding of self mated specimens of DLC and tungsten modified DLC coatings on stainless steel substrate. The contact geometry chosen for the research task was ball on flat. The contacts were lubricated either with distilled water or medical saline solution. Results are presented with regard to wear resistance as a function of material type and lubricant used.
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Morphology, Photocatalytic and Antimicrobial Properties of TiO2 Modified with Mono- and Bimetallic Copper, Platinum and Silver Nanoparticles
PublicationNoble metal nanoparticles (NMNPs) enhanced TiO2 response and extended its activity under visible light. Photocatalytic activity of TiO2 modified with noble metal nanoparticles strongly depends on the physicochemical properties of NMNPs. Among others, the differences in the size of NMNPs seems to be one of the most important factors. In this view, the effect of the metal’s nanoparticles size, type and amount on TiO2 photocatalytic...
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Rheology of potato starch chemically modified with microwave-assisted reactions
PublicationNative potato starch was sulfated, selenated, borated, silicated and zincatated by means of microwave-assisted reactions with varying doses of relevant reagents. Resulting products were characterized involving rheological behavior of pastes, their weight-average molecular weight (Mw), and radius of gyration (Rg). Most of the pastes showed shear-thinning behavior, with the flow behavior index (n) below unity. The pastes of starch...
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Dielectric properties of modified graphene oxide filled polyurethane nanocomposites and its correlation with rheology
PublicationThis study aims at investigating the dynamic mechanical, dielectric and rheological properties of reinforced polyurethane (PU) nanocomposites containing hydrophilic graphene oxide (GO) and/or hydrophobic modified graphene oxide (mGO) sheets. The organic modification of GO was performed with 4,4′-methylenebis (phenyl isocyanate) (MDI) and the samples were prepared by solvent mixing. We found that addition of mGO provides a more...
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Modified SPWM Technique with Zero-Sequence Voltage Injection for a Five-Phase, Three-Level NPC Inverter
PublicationThis article presents a modified sinusoidal pulse-width modulation (SPWM) scheme for a five-phase, three-level neutral-point-clamped inverter. The modulation scheme deploys a modified min–max function to inject the zero-sequence components into the reference modulating signals; hence enabling the effective utilization of the DC-link voltage. Balanced split-input DC-link voltages were achieved through further incorporation of adjustable...
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Mechanical properties of two-stage concrete modified by silica fume
PublicationAbstract. Two-stage concretes, despite the fact that they have proven themselves in various types of construction, have not been studied to the same extent as traditional heavy concretes. Therefore, the article developed the composition of frame concrete with various additives in the composition of the cement-sand mortar. A comparison of the mechanical characteristics of the developed compositions with the addition of silica fume...
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Automatic Threat Detection for Historic Buildings in Dark Places Based on the Modified OptD Method
PublicationHistoric buildings, due to their architectural, cultural, and historical value, are the subject of preservation and conservatory works. Such operations are preceded by an inventory of the object. One of the tools that can be applied for such purposes is Light Detection and Ranging (LiDAR). This technology provides information about the position, reflection, and intensity values of individual points; thus, it allows for the creation...
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Pi of the Sky – all-sky, real-time search for fast optical transients
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In Search of Panacea—Review of Recent Studies Concerning Nature-Derived Anticancer Agents
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Chemical Munitions Search & Assessment—An evaluation of the dumped munitions problem in the Baltic Sea
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In search of environmental role of cylindrospermopsin: A review on global distribution and ecology of its producers
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Heteroleptic cobalt(II)tri-tert-butoxysilanethiolates in search of new biomimetic complexes
PublicationW ramach prowadzonych badań mających na celu syntezę układów mimikujących centra aktywne wybranych metaloprotein zostały otrzymane dwa nowe heterlopetyczne tri-tert-butoksysilanotiolany kobaltu(II) w reakcji bimetalicznego kompleksu kobaltu(II) zawierającego już reszty silanotiolanowe z pochodnymi pirydyny: 3,5-dimetylopirydyny i dibenzyloaminy. Otrzymane związki zostały scharakteryzowane strukturalnie za pomocą analizy rentgenostrukturalnej,...
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A SEARCH OF AN INDUCER GEOMETRY THAT IS BENEFICIAL FOR LIFTING PARAMETERS OF A LIFTED OBJECT OF A SELECTED SHAPE
PublicationThe literature describes acoustic levitation phenomena with the utilization of air squeeze film between the vibrating inducer and the lifted object. The objective of the study is to determine the shape of the inducer with vibration characteristics that would allow the levitation of an object of the assumed geometry. In this paper, the influence of the dimension ratio of the inducer on the frequency of the first mode of vibration...
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Expedited Optimization of Passive Microwave Devices Using Gradient Search and Principal Directions
PublicationOver the recent years, utilization of numerical optimization techniques has become ubiquitous in the design of high-frequency systems, including microwave passive components. The primary reason is that the circuits become increasingly complex to meet ever growing performance demands concerning their electrical performance, additional functionalities, as well as miniaturization. Nonetheless, as reliable evaluation of microwave device...
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In Search for Answers: Light4Health Online Course of Health Research for Interior Lighting Design
PublicationThree years ago, when I wrote an article in arc called: Human Centric Lighting. The New X Factor? (arc no. 108 Feb/Mar 2019), my intention was to raise questions in relation to the new topic and to find solid, research-based answers in the years to come. Today, I am happy to report that the lighting community, with the Light4Health Online Course of Health Research for Interior Lighting Design, has a useful tool, and consortium...
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Central-force decomposition of spline-based modified embedded atom method potential
PublicationCentral-force decompositions are fundamental to the calculation of stress fields in atomic systems by means of Hardy stress. We derive expressions for a central-force decomposition of the spline-based modified embedded atom method (s-MEAM) potential. The expressions are subsequently simplified to a form that can be readily used in molecular-dynamics simulations, enabling the calculation of the spatial distribution of stress in...
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The accuracy of a new approach to order determination for the Modified Prony method in swath mapping application
PublicationThis article presents the performance of a new approach to determine the model order for the modified Prony method applied to swath acoustic mapping. Key requirements for any mapping application are depth determination accuracy and angular resolution. Depth determination accuracy is strictly related to angular accuracy and geometrical relations between receiver and sources of the backscattered signal. Angular resolution determines...
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Water absorption and blistering of glass fibre-reinforced polymer marine laminates with nanoparticle-modified coatings
PublicationMacro and microstructural damage was studied in typical glass fibre-reinforced polymer laminates with two types of coating systems – (a) isophtalic gel coat: pure or mixed with SiO2 nanoparticles 5 wt% (5%N) or 10 wt% (10%N) and (b) a two-layer coating system: urethane-modified vinyl ester-based gel coat and additional polyester barrier coat layer. Accelerated tests were performed at 50C for 50 days for specimens with nanoparticle-modified...
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Photoelectrochemical characterization of nitrogen-modified TiO2
PublicationTrzy próbki tlenku tytanu(IV) o różnej zawartości azotu i różnych właściwościach fotokatalitycznych zostały wybrane do charakterystyki fotoelektrochemicznej. Efektem finalnym jest określenie położenia pasma wzbronionego i pasma przewodzenia w otrzymanych półprzewodnikach.
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Polyurethanes containing organically modified clay
PublicationW pracy zaprezentowano wyniki badań dotyczące wpływu nowego, krajowego, modyfikowanego glinokrzemianu (BZ-COCO) na elastomery poliuretanowe. Dla otrzymanych układów określono podstawowe właściwości mechaniczne, termiczne oraz przeprowadzono analizę struktury.
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Porous structure of natural and modified clinoptilolites
PublicationOpisano wyniki badań struktury porowatej naturalnych zeolitów. W badaniach wykorzystano technikę SEM oraz wyznaczono izotermy procesu adsorpcji-desorpcji azotu w temperaturze 77 st. K.
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Modified nanodiamond particle size studies by means of dynamic light scattering technique
PublicationThe Methods Utilizing the Phenomena of Light Scattering to Measure Particle Size distribution in different solvent, such as deionise water and alcohol and also to study the various structural formation when nanodiamond solution is placed on silicon surface. The purpose of this research project is divided into two parts to configure the measurement units for examining modified nanodiamond particles, examination...
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Modified nanodiamond particle size studies by means of dynamic light scattering technique
PublicationThe Methods Utilizing the Phenomena of Light Scattering to Measure Particle Size distribution in different solvent, such as deionise water and alcohol and also to study the various structural formation when nanodiamond solution is placed on silicon surface. The purpose of this research project is divided into two parts to configure the measurement units for examining modified nanodiamond particles, examination...
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Determination of the ionic conductivity of Sr-doped lanthanum manganite by modified Hebb–Wagner technique
PublicationThe Hebb–Wagne rpolarization method with the electron blocking electrode has been discussed in this paper in aim to determine a partial ionic conductivity of Sr-doped lanthanum manganite.The “limiting current” in the proposed system was measured using the two-point DC technique with additional Pt electrode between LSM and blocking electrode.The electrochemical model based on bulk diffusion processes and Boltzmann statistics has...
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Fabrication and Significant Photoelectrochemical Activity of Titania Nanotubes Modified with Thin Indium Tin Oxide Film
PublicationOrdered titanium dioxide nanotubes (TiO2NTs) modified with indium tin oxide (ITO) films were obtained via magnetron sputtering, in which ITO plate was used as a target, onto the as-anodized titania support followed by the calcination process. The morphology of fabricated material with deposited oxide was investigated using scanning electron microscopy. Raman and UV–Vis spectroscopies were utilized to characterize crystalline phase...
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An attempt to mechanistically explain the viscoelastic behavior of transparent epoxy/starch-modified ZnO nanocomposite coatings
PublicationThe effects of bare and starch-modified ZnO (ZnO-St) nanoparticles on viscoelastic and mechanical properties are studied by dynamic mechanical and tensile analyses. Transparent epoxy-based nanocomposite films are prepared by incorporating bare or starch-modified ZnO particles into the epoxy matrix. The results demonstrated that ZnO particles hindered the curing reactions and hence the final properties of the cured epoxy. As a result,...
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Preparation and photocatalytic activity of Nd-modified TiO2 photocatalysts: Insight into the excitation mechanism under visible light
PublicationTitanium dioxide (TiO2) nanoparticles (NPs) modified with neodymium (Nd) in the range between 0.1 and 1.0 mol% were prepared via the hydrothermal method. The samples obtained were characterized by diffuse reflectance spectroscopy (DRS), scanning electron microscopy (SEM), X-ray fluorescence (EDX), Brunauer–Emmett–Teller (BET) method, X-ray powder diffraction analysis (XRD), X-ray photoelectron spectroscopy (XPS) and photoluminescence...
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Rigid polyurethane foams modified with ground tire rubber - mechanical, morphological and thermal studies
PublicationRigid polyurethane foams, prepared by a single step method, were modified with the two types of ground tire rubber particles, i.e. untreated and thermo-mechanically reclaimed by using a co-rotating twin screw extruder. The foaming process as well as the structure and the physical, mechanical and thermal properties of the resulting foams were investigated. The presence of ground tire rubber decreased the velocity of polymerization....
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Experimental evaluation of high frequency side scan sonar as object search and identification tool
PublicationPraca prezentuje wyniki badań laboratoryjnych sonaru bocznego jako narzędzia dla pojazdu podwodnego, służącego do poszukiwań i identyfikacji obiektów leżących na dnie, w bliskich odległościach.
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In search of excellence in organizational strategy formation in the context of deterministic chaos: the case of Grupa Azoty
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Examining users’ preferences towards vertical graphical toolbars in simple search and point tasks
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Benchmarking Parallel Chess Search in Stockfish on Intel Xeon and Intel Xeon Phi Processors
PublicationThe paper presents results from benchmarking the parallel multithreaded Stockfish chess engine on selected multi- and many-core processors. It is shown how the strength of play for an n-thread version compares to 1-thread version on both Intel Xeon and latest Intel Xeon Phi x200 processors. Results such as the number of wins, losses and draws are presented and how these change for growing numbers of threads. Impact of using particular...
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When all we have is not enough: a search for the optimal method of quantifying inflation expectations
PublicationAlthough inflation expectations are pivotal variables for central banks, they are not directly observable. Therefore, central banks use qualitative survey results to proxy consumer expectations, and their quantification in this manner is often criticized. In this study, we investigate and identify an optimal quantification procedure for survey results based on a set of regression and probabilistic models. Specifically, we seek...
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Application of the Optimization Methods to the Search of Marine Propulsion Shafting Global Equilibrium in Running Condition
PublicationFull film hydrodynamic lubrication of marine propulsion shafting journal bearings in running condition is discussed. Considerable computational difficulties in non-linear determining the quasi-static equilibrium of the shafting are highlighted. The approach using two optimization methods (the particle swarm method and the interior point method) in combination with the specially developed relaxation technique is proposed to overcome...
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Polyurethanes modified with natural polymers for medical application. Part II. Polyurethane/gelatin, polyurethane/starch, polyurethane/cellulose
PublicationThis paper is a literature overview of biomedical PUR modifications with natural polymers such as starch, cellulose and gelatin. Properties like biodegradability and biocompatibility of modified PUR cause that these materials may be used as wound dressings, tissue scaffolds, tissue implants and also vascular grafts.
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Processing, Performance Properties, and Storage Stability of Ground Tire Rubber Modified by Dicumyl Peroxide and Ethylene-Vinyl Acetate Copolymers
PublicationIn this paper, ground tire rubber was modified with dicumyl peroxide and a variable content (in the range of 0–15 phr) of ethylene-vinyl acetate copolymers characterized by different vinyl acetate contents (in the range of 18–39 wt.%). Modification of ground tire rubber was performed via an auto-thermal extrusion process in which heat was generated during internal shearing of the material inside the extruder barrel. The processing,...
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Thermal stabilization and permanent deformation resistance of LWA/PCM-modified asphalt road surfaces
PublicationThis paper presents the results of attempts at reducing the problem of solar overheating of asphalt road pavement surfaces, resulting in weakening and accelerated destruction of the aforementioned structures. To protect pavement surfaces against periodic overheating, standard asphalt mixture AC 16 W 35/50, used for binder course, has been modified by replacing one of the aggregate fractions from the mineral mixture with lightweight...
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Ligand-Modified Boron-Doped Diamond Surface: DFT Insights into the Electronic Properties of Biofunctionalization
PublicationWith the increasing power of computation systems, theoretical calculations provide a means for quick determination of material properties, laying out a research plan, and lowering material development costs. One of the most common is Density Functional Theory (DFT), which allows us to simulate the structure of chemical molecules or crystals and their interaction. In developing a new generation of biosensors, understanding the nature...
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Influence of Annealing Atmospheres on Photoelectrochemical Activity of TiO2 Nanotubes Modified with AuCu Nanoparticles
PublicationIn this article, we studied the annealing process of AuCu layers deposited on TiO2 nanotubes (NTs) conducted in various atmospheres such as air, vacuum, argon, and hydrogen in order to obtain materials active in both visible and UV–vis ranges. The material fabrication route covers the electrochemical anodization of a Ti plate, followed by thin AuCu film magnetron sputtering and further thermal treatment. Scanning electron microscopy...
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Studies on Silver Ions Releasing Processes and Mechanical Properties of Surface-Modified Titanium Alloy Implants
PublicationDispersed silver nanoparticles (AgNPs) on the surface of titanium alloy (Ti6Al4V) and titanium alloy modified by titania nanotube layer (Ti6Al4V/TNT) substrates were produced by the chemical vapor deposition method (CVD) using a novel precursor of the formula [Ag5(O2CC2F5)5(H2O)3]. The structure and volatile properties of this compound were determined using single crystal X-ray diffractometry, variable temperature IR spectrophotometry...
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Enhanced photocatalytic, electrochemical and photoelectrochemical properties of TiO2 nanotubes arrays modified with Cu, AgCu and Bi nanoparticles obtained via radiolytic reduction
PublicationTiO2 nanotubes arrays (NTs), obtained via electrochemical anodization of Ti foil, were modified with monometallic (Cu, Bi) and bimetallic (AgCu) nanoparticles. Different amounts of metals’ precursors were deposited on the surface of NTs by the spin-coating technique, and the reduction of metals was performed via gamma radiolysis. Surface modification of titania was studied by EDS and XPS analysis. The results show that AgCu nanoparticles...
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UV-Vis-Induced Degradation of Phenol over Magnetic Photocatalysts Modified with Pt, Pd, Cu and Au Nanoparticles
PublicationThe combination of TiO2 photocatalyst and magnetic oxide nanoparticles enhances the separation and recoverable properties of nanosized TiO2 photocatalyst. Metal-modified (Me = Pd, Au, Pt, Cu) TiO2/SiO2@Fe3O4 nanocomposites were prepared by an ultrasonic-assisted sol-gel method. All prepared samples were characterized by X-ray powder diffraction (XRD) analysis, Brunauer-Emmett-Teller (BET) method, X-ray photoelectron spectroscopy...
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Tyre/road noise measurements on ISO tracks using the modified CPX method
PublicationTyre rolling noise test method specified in the UNECE Regulation 117 is directly used in the Tyre Labelling Directive. Noise level specified on EU Tyre Label of each new tyre available on the European market was determined based on vehicle coast-by noise measurements performed on the standard reference road surface proscribed in the ISO 10844:2014. Available data from investigations by the vehicle and tyre industry and results...
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Fe local structure in Pt-free nitrogen-modified carbon based electrocatalysts: XAFS study
PublicationThe paper presents a new results on the bonding environment (coordination number and geometry) and on oxidation states of Fe in nitrogen-modified Fe/C composites used as Pt-free catalysts for oxygen reduction in Direct Hydrogen Fuel Cells. Starting from glucose or fructose, two catalysts displaying different electrochemical performance were prepared and studied in the form of pristine powder and thin catalytic layer of electrode...
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Tetrahedrally modified MnMe0.1Co1.9O4 (Me = Zn, Mg, Li) spinels for non-enzymatic glucose sensing
PublicationIn this work, tetrahedrally modified MnMe0.1Co1.9O4 (Me = Zn, Mg, Li) spinels were prepared via the sol–gel synthesis method with subsequent ball-milling fragmentation. The prepared samples were evaluated as glucose–sensing catalyst. The reference MnCo2O4 spinel exhibited a sensitivity of 49 µA mM−1 cm−2 and a nonlinearity error of 5.2% in the response range from 0.02 to 1 mM. The partial substitution of cobalt in the reference...
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Simulation of unsteady flow over floodplain using the diffusive wave equation and the modified finite element method
PublicationWe consider solution of 2D nonlinear diffusive wave equation in a domain temporarily covered by a layer of water. A modified finite element method with triangular elements and linear shape functions is used for spatial discretization. The proposed modification refers to the procedure of spatial integration and leads to a more general algorithm involving a weighting parameter. The standard finite element method and the finite difference...