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Search results for: TEMPERATURE STABILIZATION
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Photovoltaic module temperature stabilization with the use of phase change materials
PublicationThe worldwide growth of photovoltaics (PVs) has formed an exponential curve for more than four decades. During this period of time, PVs have evolved from a pure niche market of small-scale applications towards becoming a mainstream electricity source. The influence of temperature on the electrical parameters of crystalline silicon solar cells and solar modules is well described in the literature. In order to diminish these effects,...
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Stabilization of the pyrochlore phase of Mn2Sb2O7 by double substitution
PublicationPolycrystalline samples of (Ce4+Mn2+3)(Ga3+Sb5+3)O14 were synthesized by a high-temperature solid-state reaction. In contrast with the parent Mn2Sb2O7 compound that adopts a rhombohedral or monoclinic structure at T > 600 °C, the pyrochlore structure of CeMn3GaSb3O14 is retained up to at least T = 1070°C. High-resolution synchrotron x-ray diffraction measurements show no sign of a superstructure or distortion from cubic symmetry...
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Tailoring structural properties of lanthanum orthoniobates through an isovalent substitution on the Nb-site
PublicationTetragonal polymorph of lanthanum orthoniobate can be stabilized to room temperature by the substitution of Nb with an isovalent element. LaNb1-xAsxO4 (0 < x ≤ 0.3), where As is an element stabilizing tetragonal structure, were successfully synthesized with combined co-precipitation and solid-state reaction method. The phase transition temperature, above which the material has tetragonal structure, decreases linearly with increasing...
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Phase Change Thermal Energy Storage – The Experience of the Materials Preparation for the Specific Applications.
PublicationThermal energy storage and temperature stabilization is very important in many engineering applications. There are three kinds of thermal energy storage: sensible heat storage, latent heat storage and reversible chemical reaction heat storage. Phase change materials (PCM) absorb, store and release large amounts of energy in the form of latent heat, at constant temperature, called the transition temperature. The amount of heat...
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Influence of the low ambient temperature on the start-up process of hydraulic pumps
PublicationStarting hydraulic pumps in low ambient temperatures may cause: decreased hydraulic-mechanical efficiency, larger vibration of hydraulic installation, faster wear and more frequent damage to the elements of pumps, change of material properties of elements, increase of pressure drop. As a result of pressure drop in the suction pipe, large underpressure may be experienced, causing incomplete filling of pump working chambers with...
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FFT spectrum based matching algorithm for activedynamic thermography
PublicationIn Active Dynamic thermography (ADT) sequences of consecutive temperature distributions are analyzed. In biomedical applications of ADT, the problems of a patient's movements in front of a thermal camera should be eliminated before data analysis. Complete mechanical stabilization of the patients is impossible due to natural voluntary and involuntary moves caused by pulse breathing, etc. This paper presents a simple and efficient...
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Meiothermus ruber cells as β-galactosidase activity biocatalyst
PublicationThe current study allowed to establish the possibility of using whole cells of thermophilic bacteria Meiothermus ruber as a biocatalyst with β-galactosidase activity. β-galactosidases are used for hydrolysis of lactose as well as for oligosaccharides synthesis. The advantages of using whole bacterial cells catalysis is not only elimination of tedious, expensive protein isolation and/or purification but also stabilization of enzymes...
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Phase change thermal energy storage – the experience of the materials preparation for the specific applications.
PublicationThermal energy storage and temperature stabilization is very important in many engineering applications. There are three kinds of thermal energy storage: sensible heat, latent heat and reversible chemical reaction heat. Phase change materials (PCM) absorb, store and release large amounts of energy in the form of latent heat, at constant temperature, called the transition temperature. Many innovative applications could be found...
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Effect of osmolytes on the thermal stability of proteins: replica exchange simulations of Trp-cage in urea and betaine solutions
PublicationAlthough osmolytes are known to modulate the folding equilibrium, the molecular mechanism of their effect on thermal denaturation of proteins is still poorly understood. Here, we simulated the thermal denaturation of a small model protein (Trp-cage) in the presence of denaturing (urea) and stabilizing (betaine) osmolytes, using the all-atom replica exchange molecular dynamics simulations. We found that urea destabilizes Trp-cage...
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Post-Pyrolytic Carbon as a Phase Change Materials (PCMs) Carrier for Application in Building Materials
PublicationThis article covers new application for char as a carrier of phase-change materials (PCM) that could be used as an additive to building materials. Being composed of bio-char and PCM, the granulate successfully competes with more expensive commercial materials of this type, such as Micronal® PCM. As a PCM carrier, char that was obtained from the pyrolysis of chestnut fruit (Aesculus hippocastanum) with different absorbances of the...
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Configurations of H 3 + (H2)n clusters and their energies
PublicationThe H-3(+) ion plays an important role in low temperature astrophysical and laboratory plasmas. It is considered as the initiator of many ion-molecule chemistries. Also its clusters with H-2 are quite interesting. We study configurations of the H-3(+)(H-2)(n) clusters for n = 1 up to n = 12 as a simple test system. Total energies for these structures, with zero point vibration corrections have been calculated. Stabilization energies...
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Atmospheric degradation mechanism of anthracene initiated by OH•: A DFT prediction
PublicationDensity functional theory (DFT) calculations at the M06-2X/def2-TZVP level have been employed to investigate the atmospheric oxidation mechanism of anthracene (ANT) initiated by HO•. Direct hydrogen atom abstraction from the ANT using HO• takes place hardly at ambient conditions while the addition of HO• to the C1, C2, and C4 sites are thermodynamically and kinetically more advantageous. The addition reactions are controlled by...
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Thermal stabilization and permanent deformation resistance of LWA/PCM-modified asphalt road surfaces
PublicationThis paper presents the results of attempts at reducing the problem of solar overheating of asphalt road pavement surfaces, resulting in weakening and accelerated destruction of the aforementioned structures. To protect pavement surfaces against periodic overheating, standard asphalt mixture AC 16 W 35/50, used for binder course, has been modified by replacing one of the aggregate fractions from the mineral mixture with lightweight...
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The impact of carbon black particle size on curing characteristics of GTR modified with bitumen
Open Research DataPresented data shows an impact of particle size of GTR and three different loadings of carbon black on curing characteristics of GTR modified with bitumen. Samples were prepared using a two-roll mill – all in the same manner. After 24 hours of stabilization at ambient conditions they were submitted to the curing analysis via Rheometer Monsanto 100S....
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Possibilities and benefits of a new method of modifying conventional building materials with phase-change materials (PCMs)
PublicationThe paper presents a current study devoted to the optimization of the amount of PCM present within traditional building materials, utilized in this case in hollow-brick walls. Authors focus on proposing an alternative to typical direct addition of PCM to existing building materials: introducing two- and three-component mixtures, based on a porous PCM carrier, which in this case was construction aggregate. Preliminary studies of...
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Comprehensive stabilization of all streams of solid residues formed during sewage sludge thermal treatment – Case study
PublicationModern wastewater treatment plants are currently struggling with the problem of processing and ecological management of sewage sludge. Thermal utilization is a frequently used practice of excess sludge utilization especially in large wastewater treatment plants, which seems to be a quite promising concept. However, during thermal treatment, fractions of ashes and dusts are generated. Such wastes, especially the dust fraction, can...
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Protein thermal stabilization in aqueous solutions of osmolytes
PublicationProteins’ thermal stabilization is a significant problem in various biomedical, biotechnological, and technological applications. We investigated thermal stability of hen egg white lysozyme in aqueous solutions of the following stabilizing osmolytes: Glycine (GLY), N-methylglycine (NMG), N,N-dimethylglycine (DMG), N,N,N-trimethylglycine (TMG), and trimethyl-N-oxide (TMAO). Results of CD-UV spectroscopic investigation were compared...
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Integrated dewatering and stabilization system as an environmentally friendly technology in sewage sludge management in Poland
PublicationSludge treatment reed beds (STRBs) are an environmentally friendly technology which provides integrated dewatering and stabilization of sewage sludge. STRBs do not require the use of chemicals to improve the dewatering process. STRB is both, a low-emission and a low-energy-consuming method. After the stabilization process, sludge is characterized by the chemical composition similar to that of humus. The aim of the paper is to present...
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Influence of Osmolytes on Protein and Water Structure: A Step To Understanding the Mechanism of Protein Stabilization
PublicationResults concerning the thermostability of hen egg white lysozyme in aqueous solutions with stabilizing osmolytes, trimethylamine-N-oxide (TMAO), glycine (Gly), and its N-methyl derivatives, N-methylglycine (NMG), N,N-dimethylglycine (DMG), and N,N,N-trimethylglycine (betaine, TMG), have been presented. The combination of spectroscopic (IR) and calorimetric (DSC) data allowed us to establish a link between osmolytes’ influence on...
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Non-Adaptive Rotor Speed Estimation of Induction Machine in an Adaptive Full-Order Observer
PublicationIn the sensorless control system of an induction machine, the rotor speed value is not measured but reconstructed by an observer structure. The rotor speed value can be reconstructed by the classical adaptive law with the integrator. The second approach, which is the main contribution of this paper, is the non-adaptive structure without an integrator. The proposed method of the rotor speed reconstruction is based on an algebraic...
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The Application of the Thermal Stabilization Prompted by the Ice Cover Expansion Considering the Energy Production Optimization in the Dam-Reservoir Coupled Systems on the Vistula River
PublicationIn this study, the thermal stabilization of a water resource together with an energy production optimization in the power plant of the dam–reservoir coupled system is conducted. This coupled dam system is designed to consist of a primary (Włocławek) and secondary (Siarzewo) dam due to the erosion control aspect. The other beneficial aspect of this coupled dam design is to have an additional power plant, with the aim of achieving...
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Sludge Treatment Reed Beds (STRBs) as a Eco-solution of Sludge Utilization for Local Wastewater Treatment Plants
PublicationSewage sludge is a by-product of wastewater treatment processes. In Poland, the amout of sewage sludge has been still growing in recent years, due to inhencement of pollutants removal in wastewater treatment plants (WWTPs). One of the systems used to transform sewage sludge into fertilizer is a technology called Sludge Treatment Reed Beds (STRBs). Reed systems are periodically irrigated with sewage sludge with a low dry matter...
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Ionic liquids for nano- and microstructures preparation. Part 1: Properties and multifunctional role
PublicationIonic liquids (ILs) are a broad group of organic salts of varying structure and properties, used in energy conversion and storage, chemical analysis, separation processes, as well as in the preparation of particles in nano- and microscale. In material engineering, ionic liquids are applied to synthesize mainly metal nanoparticles and 3D semiconductor microparticles. They could generally serve as a structuring agent or as a reaction...
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An Intergrated Model of Motion, Steering, Positioning and Stabilization of an Unmanned Autonomous Maritime Vehicle
PublicationIn the paper the aim of an interdisciplinary research is presented. The research method is introduced. An object the unmanned autonomous maritime vehicle is briefly described. The key research problem concerns a combined model of the vehicle motion including the loads of lift and hydrodynamic nature. The model takes into account the gravity and displacement forces, resistance and thrust forces, lift and other hydrodynamic forces....
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Optimal state feedback controller for balancing cube
PublicationIn this paper, a nonlinear balancing cube system is considered, the concept for which is based on an inverted pendulum. The main purpose of this work was the modelling and construction of a balancing cube with the synthesis of the control system. The control objectives included swing-up and stabilization of the cube on its vertex at an unstable equilibrium. Execution of the intended purpose required, first, deriving a cognitive...
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Polish experience in operation of sludge treatment reed beds
PublicationSludge Treatment Reed Beds (STRBs) is the technology of sludge treatment, which is based on natural processes occurring in the environment, in specially designed and operated facilities to achieve benefits for the environment. Integrated dewatering and stabilization occur in reed systems. For economic and environmental reasons it is an attractive solution, especially in rural areas where there are no appropriate facilities. In...
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Enzyme immobilization on magnetic nanoparticles
PublicationImmobilized enzymes have been commonly used in many branches of industry, biotechnology, medicine and also in analytical chemistry. Their use provides many advantages in comparison with free enzymes including repeated, easy recovery of the enzyme and improvement in enzyme stability. Enzymes are strong and specific catalysts, but are also expensive and fragile. Their immobilization and stabilization may reduce reaction costs, which...
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Challenges associated with the design of a small unmanned autonomous maritime vehicle
PublicationThe paper contains the preliminary results of the research connected with development of a small unmanned autonomous maritime vehicle. First of all a general description of research is introduced. Next, a concept of a vehicle is presented. Then, a brief description of a research method is given. Next, the current research problems under way are introduced. They concern the ballasting, motion and precise position stabilization system...
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A Reaction of Thioamides with Zinc Ammoniates Leading to Simple Amidines. Discovery of a New Zwitterionic Monomethylamidine
PublicationThe reaction of thioamides with the R1R2N-ZnCl ammoniates leads to N-mono-, N,N'-di-, N,N-disubstituted, and unsubstituted amidines with high concns. of amines in abs. ethanol. The efficient direct formation of the N,N'-dimethylamidine can be explained by a greater reactivity of methylamine compared with dimethylamine. Discovery of a new zwitterion (induced by a carbonyl oxygen) suggests that the stabilization in the thymine...
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Convenient Syntheses of N-Methylthioamides: A Migration of the H2S Molecule in the Thioamide-nitrile System
PublicationThe reaction of thioamides with the R1R2N-ZnCl ammoniates leads to N-mono-, N,N'-di-, N,N-disubstituted, and unsubstituted amidines with high concns. of amines in abs. ethanol. The efficient direct formation of the N,N'-dimethylamidine can be explained by a greater reactivity of methylamine compared with dimethylamine. Discovery of a new zwitterion (induced by a carbonyl oxygen) suggests that the stabilization in the thymine...
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Modeling of performance and safety of a multi-task unmanned autonomous maritime vehicle = Modelowanie ruchu i bezpieczeństwa wielozadaniowego bezzałogowego autonomicznego pojazdu wodnego
PublicationAt the beginning of the paper the aim of research is presented. Then the method is introduced. Next, the unmanned autonomous maritime vehicle is briefly described. The following chapter concerns a model of vehicle performance including the ballasting and motion. Some information on an integrated steering, positioning and stabilization system of the vehicle is briefly presented in the paper. Such the system enables to obtain a fully...
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Potential fertilizing properties of sewage sludge treated in the Sludge Treatment Reed Beds (STRB)
PublicationIn research the fertilizer value of sludge from reed beds is evaluated based on the sampling sludge on different depths from 4 Danish STRB after long periods of stabilization. The dewatering efficiency of sewage sludge in the STRB is comparable to mechanical dewatering. The long-term stabilization of sewage sludge progressively decreases the concentration of organic matter due to the process of humification. The aim of the work...
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Stability analysis of a road scarp in the Carpathian Mountains and methods of its protection
PublicationThe purpose of the study was to analyse the stability of a road scarp endangered by a landslide and to consider some measures for its stabilization. The potential landslide could unfavourably alter the shape of the slope, thus a religious sanctuary situated above the slope. The present research has resulted in suggestions of possible protection methods, namely, drainage, soil nailing, installation of piles, supporting the scarp...
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Ancillary services to grids provided with distributed generation
PublicationThe paper introduces system for utilization of the customer-side generated energy. Additionally system can secure some ancillary services to grids. Those services include: current active filtering, load voltage stabilization and in case of grid voltage faults - uninterruptible load supplying (possible with energy storage device). Presented experimental results confirm flexibility of this arrangement in processes of power delivery...
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Effect of different crystalline structures on W/O and O/W/O wax emulsion stability
PublicationtThe possibility of emulsion stabilization using mineral and vegetable wax particles only (without sur-factant) was investigated. Mineral waxes, paraffin wax and ceresin, and a vegetable wax, carnauba wax,were used. The content of the wax particles and the water to oil proportion were found crucial for thestability of all emulsions. Some emulsions were also produced with a liquid wax (i.e. jojoba oil). Themultiple light scattering...
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Current advances in membrane processing of wines: A comprehensive review
PublicationBackground Membrane-based operations, especially pressure-driven membrane operations, are today well-established procedures for various applications in the wine industry thanks to their intrinsic properties and undoubted advantages over traditional methods. Emerging membrane processes, such as pervaporation, electrodialysis and osmotic distillation, forward osmosis, membrane contactors, offer new and interesting perspectives to...
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Molecular basis of the osmolyte effect on protein stability: a lesson from the mechanical unfolding of lysozyme
PublicationOsmolytes are a class of small organic molecules that shift the protein folding equilibrium. For this reason, they are accumulated by organisms under environmental stress, and find applications in biotechnology where proteins need to be stabilized or dissolved. However, despite years of research, debate continues over the exact mechanisms underpinning the stabilizing and denaturing effect of osmolytes. Here, we simulated the mechanical...
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Dynamic variables limitation for backstepping control of induction machine and voltage source converter
PublicationDynamic variables limitation for backstepping control of induction machine and voltage source converter The paper presents the method of control of an induction squirrel-cage machine supplied by a voltage source converter. The presented idea is based on an innovative method of the voltage source converter control, consisting in direct joining of the motor control system with the voltage source rectifier control system. The combined...
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Power Electronic Transformer For Smart Grid Application
PublicationIn this paper the control system of Power Electronic Transformer (PET) for the Smart Grid application is proposed. The structure of PET is based on two Cascaded H-bridge (CHB) converters. The electrical energy is transferred between converters using Dual-Active-Bridges (DAB) and high-frequency transformers. This type of coupling has been used to connect the DC-links of all H-bridges. The proposed control system for PET makes it...
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Novel adaptive flux observer for wide speed range sensorless control of induction motor
PublicationA new adaptive flux observer of induction motor is presented in the paper. The Lyapunov theory is utilized for derivation of the adaptation law of rotor flux angular speed, which acts as unknown parameter in an augmented induction motor model. In the field weakening region, where stray fluxes are comparable with rotor flux magnitude, the air-gap flux stabilization is proposed. An air-gap flux multiscalar model is derived for stator...
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Feedback Control of Multiphase Induction Machines with Backstepping Technique
PublicationThe paper presents the control possibility of five phase induction machines. In the proposed solution the machine model vector form is not transformed to the (dq)-coordinate system, that is connected to rotor flux vector, but utilizes the stationary system ( αβ ). Moreover, the nonlinear model linearization is based on demonstrated nonlinear variables transformation for i-orthogonal ( αβ )(n) planes. By introducing the backstepping...
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EMI attenuation in a DC-DC buck converter using GaN HEMT
PublicationA dc-dc buck converter using gallium nitride (GaN) high electron mobility transistors (HEMT) is experimentally investigated at the discontinuous current mode (DCM) and at the triangular current mode (TCM) operation. The paper objective is to specify the power conversion efficiency and attenuation of common mode (CM) and differential mode (DM) noise voltage, measured at the line impedance stabilization network (LISN) for compared...
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Stabilization of Solid Residues Obtained During Sewage Sludge Thermal Treatment
PublicationCurrently wastewater treatment plants are still dealing with the problem of ecological management of sewage sludge. Nowadays, thermal utilization is considered the most eco-friendly way of processing excess sludge. However, during mentioned process, fractions of ashes and dusts are generated. Such wastes, especially dusts fraction, can be potentially harmful for the environment and wastes should be stabilized before further management....
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Influence of sludge treatment processes on heavy metal speciation
PublicationSludge composition is depending on sewage quality and also affected by processing methods such as thickening, stabilization and dewatering. During those processes some of sludge's undesirable properties might be reduced or enhanced.The objective of the study is the assessment of the influence of sludge processing on selected heavy metals partitioning between phases (aqueous and particle) and sludge. Sludge from the WWTP in Gdansk...
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ADAPTIVE BACKSTEPPING TRACKING CONTROL FOR OVER-ACTUATED DP MARINE VESSEL WITH INERTIA UNCERTAINTIES
PublicationDesigning a tracking control system for an over-actuated dynamic positioning marine vessel in the case of insufficient information on environmental disturbances, hydrodynamic damping, Coriolis forces and vessel inertia characteristics is considered. The designed adaptive MIMO backstepping control law with control allocation is based on Lyapunov control theory for cascaded systems to guarantee stabilization of the marine vessel...
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Sewage gardens - constructed wetlands for single family households
PublicationDuring the last 30 years the increase of interest in low-cost decentralized and small wastewater treatment plants (WWTP) is observed in Europe. For this purpose sand filters, stabilization ponds, mini reactors with activated sludge, trickling filters and treatment wetlands are used. Among the listed facilities treatment wetlands (TWs) offer effective and reliable treatment efficiency, being at the same time low-cost and simple...
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Propensity of salicylamide and ethenzamide cocrystallization with aromatic carboxylic acids
PublicationThe cocrystallization of salicylamide (2-hydroxybenzamide, SMD) and ethenzamide (2-ethoxybenzamide, EMD) with aromatic carboxylic acids was examined both experimentally and theoretically. The supramolecular synthesis taking advantage of the droplet evaporative crystallization (DEC) technique was combined with powder diffraction and vibrational spectroscopy as the analytical tools. This led to identification of eleven new cocrystals...
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Atom-economic thiophosphoroselenenylations of C–H acid esters and amides
PublicationThree improved thiophosphoroselenenylation procedures of CHacids, including derivatives of malonic and acetyl-, phosphono-, 4-nitrophenyl- and 3-pyridylacetic acids, have been described and compared to previously reported thiophosphoroselenylation of diethyl malonate using bis(disopropoxyphosphinothioyl)diselenide alone or with the aid of methyl iodide. The use of iodine makes it possible to utilize both equivalents of the selenenylating...
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Electrophoretic co-deposition of Mn1.5Co1.5O4, Fe2O3 and CuO: Unravelling the effect of simultaneous addition of Cu and Fe on the microstructural, thermo-mechanical and corrosion properties of in-situ modified spinel coatings for solid oxide cell interconnects
PublicationA systematic microstructural, thermo-mechanical and electrical characterization of simultaneous Fe–Cu doped Mn–Co spinel coatings processed by electrophoretic co-deposition on Crofer 22 APU is here reported and discussed. An innovative approach for the simultaneous electrophoretic deposition of three spinel precursors is designed, conceived and optimised, with the aim of outlining time- and energy-saving spinel modification routes....
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Specific Binding of Cholesterol to the Amyloid Precursor Protein: Structure of the Complex and Driving Forces Characterized in Molecular Detail
PublicationC99 is the C-terminal membrane-bound fragment of the amyloid precursor protein that is cleaved by γ-secretase to release Aβ peptides, the hallmark of Alzheimer’s disease (AD). Specific interactions of C99 with cholesterol have been proposed to underlie the recognized role of cholesterol in promoting amyloidogenesis. By using molecular dynamics simulations, we studied cholesterol binding to C99 in a lipid bilayer. We determined...