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Search results for: oxygen reduction reaction
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Solid Phase Photocatalytic Reaction on the Soot/TiO2 Interface: The Role of Migrating OH Radicals
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Changing the Ship Propulsion System Performances Induced by Variation in Reaction Degree of Turbocharger Turbine
PublicationArtykuł przedstawia szczegółowy model matematyczny układu napędu statku obejmującego: wolnoobrotowy silnik spalinowy okrętowy, śruba okrętowa oraz regulator prędkości kątowej. Model ten, następnie jest wykorzystany do badania symulacyjnego zachowania układu zarówno w stanach ustalonych jak i nieustalonych. Model jest zweryfikowany z wynikami eksperymentalnymi. Przedstawienie oryginalnej metody oceny wrażliwości układu względem...
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Ethylene photocatalytic decomposition in high temperature reaction chamber
Open Research DataData contain data logs of measurements performed on High Temperature Chamber "The Praying Mantis" coupled with SRI 8010 gas chromatograph. Measurement was performed for TiO2 irradiated by UV and under flowing of ethylene gas diluted in air and with the use of elevated temperature.
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Fine-Tuning the Photocatalytic Activity of the Anatase {1 0 1} Facet through Dopant-Controlled Reduction of the Spontaneously Present Donor State Density
PublicationThe present study highlights the importance of the net density of charge carriers at the ground state on photocatalytic activity of the faceted particles, which can be seen as a highly underexplored problem. To investigate it in detail, we have systematically doped {1 0 1} enclosed anatase nanoparticles with Gd3+ ions to manipulate the charge carrier concentration. Furthermore, control experiments using an analogical Nb5+ doped...
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Development of a spray-ejector condenser for the use in a negative CO2 emission gas power plant
PublicationOne promising solution for developing low-emission power technologies is using gaseous fuel combustion in pure oxygen when the exhaust gas mixture is composed of H2O and CO2, and where CO2 is separated after steam condensation. The paper presents the results of computational analyses providing to the Spray-Ejector Condenser (SEC) development, which is one of the crucial components of the negative CO2 gas power plant (nCO2PP) cycle...
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Imidazoacridinone antitumor agent C-1311 as a selective mechanism- based inactivator of human cytochrome P450 1A2 and 3A4 isoenzymes.
Publication5-Diethylaminoethylamino-8-hydroxyimidazoacridinone (C-1311), a promising antitumor agent that is also active against autoimmune diseases, was determined to be a selective inhibitor of the cytochrome P450 (CYP) 1A2 and 3A4 isoenzymes. Therefore, C-1311 might modulate the effectiveness of other drugs used in multidrug therapy. The present work aimed to identify the mechanism of the observed C-1311-mediated inactivation of CYP1A2...
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The Simulation of Activated Sludge System for Optimization of Predictive Aeration at Large WWTP
PublicationEffective use of biodegradable substrates as an internal carbon sources (ICS) for denitrification and EBPR and predicting performance of aeration systems during nitrification in activated sludge bioreactors, may be useful in realization the sustainable development by potentially saving energy consumption at WWTPs. A large number of WWTPs use activated sludge systems with an integrated removal of carbon, nitrogen and phosphorus...
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Retained features of embryonic metabolism in the adult MRL mouse
PublicationThe MRL mouse is an inbred laboratory strain that was derived by selective breeding in 1960 from the rapidly growing LG/J (Large) strain. MRL mice grow to nearly twice the size of other commonly used mouse strains, display uncommonly robust healing and regeneration properties, and express later onset autoimmune traits similar to Systemic Lupus Erythematosis. The regeneration trait (heal) in the MRL mouse maps to 14-20 quantitative...
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Analiza kondensatów oddechowych - wyzwanie dla analityków
PublicationOd lat 90-tych XX wieku coraz szerszym zainteresowaniem, zarówno w środowisku medycznym jak i analitycznym, cieszą się metody nieinwazyjne polegające na badaniu indukowanej plwociny, kondensatu oddechowego oraz na pomiarze składu powietrza wydychanego. Kondensaty oddechowe zawierają wszystkie substancje, jakie występują w płynie wyściełającym układ oddechowy. Ze względu na stosunkowo prosty skład matrycy są one idealnymi próbkami...
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Synthesis, physicochemical and theoretical studies on new rhodium and ruthenium dimers. Relationship between structure and cytotoxic activity
PublicationTwo dimeric compounds of the general formulae (Et3NH)2[Rh2(μ2-L)4Cl2] (1) (where L = thiophene-2-carboxylate) and [((η6-p-cymene)Ru)2(μ-Cl)3]PF6 (2) have been synthesized using a new method. The unique anionic complex 1 (space group P bca) has octahedral coordination in which the equatorial positions are occupied by the oxygen atoms of four thiophene-2-carboxylates in a paddle wheel fashion. In complex 2 (space group ), each Ru(II)...
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Combined partial denitrification/anammox process for nitrogen removal in wastewater treatment
PublicationRecently, the combined partial denitrification and anammox (PD/anammox) has received special attention as a viable alternative for N removal using organic matter present in municipal wastewater. In comparison with conventional nitrification-denitrification, PD/anammox provides enormous opportunities to achieve sustainable wastewater treatment due to the lack of dissolved oxygen (DO) demand, a smaller amount of organic carbon (C)...
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More Than just Antioxidants: Redox-Active Components and Mechanisms Shaping Redox Signalling Network
PublicationsettingsOrder Article Reprints This is an early access version, the complete PDF, HTML, and XML versions will be available soon. Open AccessReview More Than just Antioxidants: Redox-Active Components and Mechanisms Shaping Redox Signalling Network by Monika Kuczyńska,Patrycja Jakubek andAgnieszka Bartoszek *ORCID Faculty of Chemistry, Gdańsk University of Technology, 80-233 Gdańsk, Poland * Author to whom correspondence should...
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Kinetics of the Organic Compounds and Ammonium Nitrogen Electrochemical Oxidation in Landfill Leachates at Boron-Doped Diamond Anodes
PublicationElectrochemical oxidation (EO) of organic compounds and ammonium in the complex matrix of landfill leachates (LLs) was investigated using three different boron-doped diamond electrodes produced on silicon substrate (BDD/Si)(levels of boron doping [B]/[C] = 500, 10,000, and 15,000 ppm—0.5 k; 10 k, and 15 k, respectively) during 8-h tests. The LLs were collected from an old landfill in the Pomerania region (Northern Poland) and were...
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Thermoelectric properties of bismuth-antimony-telluride alloys obtained by reduction of oxide reagents
PublicationThe BieSbeTe alloys with different Bi/Sb/Te ratio were fabricated by an innovative method. For that purpose the oxide reagents were melted at high temperature, then quenched to form pellets, milled to a powder and finally reduced in hydrogen at various temperatures. Complex structures consisting of connected thin layers forming a continuous path between nano- and micrometer size grains have been obtained. The electrical conductivity,...
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Shading, Dusting and Incorrect Positioning of Photovoltaic Modules as Important Factors in Performance Reduction
PublicationThe amount of solar radiation reaching the front cover of a photovoltaic module is crucial for its performance. A number of factors must be taken into account at the design stage of the solar installation, which will ensure maximum utilization of the potential arising from the location. During the operation of a photovoltaic installation, it is necessary to limit the shading of the modules caused by both dust and shadowing by trees...
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Recent advances in visible light-driven water oxidation and reduction in suspension systems
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A plateau-valley separation approach (PVSA) for reduction of the end-effect in surface metrology
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Reduction Process of Iron Catalyst Precursors for Ammonia Synthesis Doped with Lithium Oxide
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The effect of aluminium oxide on the reduction of cobalt oxide and thermostabillity of cobalt and cobalt oxide
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Reduction of spectral interferences in atmospheric pressure glow discharge optical emission spectrometry
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Critical study of crop-derived biochars for soil amendment and pharmaceutical ecotoxicity reduction
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Seeking Optimal Nutrition for Healthy Body Mass Reduction Among Former Athletes
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Self-organizing Artificial Neural Networks into Hydrographic Big Data Reduction Process
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Raman Spectra Measurements for Chemical Identifications - Aspect of Uncertainty Sources and Reduction of Their Effects
PublicationRaman spectrometers enable fast and non-contact identification of examined chemicals. These devices measure Raman spectra and compare with the spectra database to identify unknown and often illicit chemicals (e.g. drugs, explosives) usually without any sample preparation. Raman spectra measurements are a challenge due to noise and interferences present outside the laboratories (field applications). The design of a portable Raman...
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Web Questionnaire as Construction Method of Affect-annotated Lexicon - Risks Reduction Strategy
PublicationThe paper concerns credibility of construction methods for affect-annotated lexicons, specifically a web questionnaire is explored and evaluated. Web-based surveys are susceptible to some risks, which might influence credibility of the results, as some participants might perform random clicks or intentionally falsify the responses. The paper explores the risks and proposes some strategies to reduce them. The strategies are supported...
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Vertical vibration reduction and audible sound analysis in surface grinding with electroplated tools
PublicationOne of the first approaches to the development of a grinding process monitoring system based on audible sound sensors is presented in the paper. Electroplated diamond tools (abrasive D64 and D107) were used in a modified single-disc lapping machine configuration for flat grinding of ceramics (Al2O3). The main aim of the machine modification was to reduce the vertical vibration in order to decrease the tool wear and to increase...
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Rigid finite elements and multibody modelling used in estimation and reduction of rod vibrations
PublicationIn the paper, a mechanical set composed of a robot (manipulator) and of an elastic beam is considered. The beam is fixed to the top of the robot structure. In most of the similar cases, undesired vibrations can be excited in the beam. They are especially significant, when dynamics in the robot braking period is examined. In the paper, estimation and modification of length of the braking period is proposed, in order to reduce the...
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Experimental study of the fuel jet combustion in high temperature and low oxygen content exhaust gases
PublicationPrzeprowadzono badania eksperymentalne spalania pojedynczego strumienia paliwa gazowego. Paliwo podawano współosiowo do generowanych przez konwencjonalny palnik gazowy spalin o wysokiej temperaturze i niskiej zawartości tlenu. Badano wpływ zawartości tlenu w utleniaczu na widzialność płomienia i skład produktów spalania.
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Importance of benthic macrofauna and coastal biotopes for ecosystem functioning – Oxygen and nutrient fluxes in the coastal zone
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Experimental and mathematical modelling study of gas combustion under the high-temperature and oxygen-deficient oxidizers
PublicationPraca przedstawia wyniki badań eksperymentalnych i modelowania numerycznego wpływu parametrów utleniacza za długość i objętość płomienia przy spalaniu paliwa gazowego w środowisku o wysokiej temperaturze i ubogim w tlen.
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Irreversible alterations in the hemoglobin structure affect oxygen binding in human packed red blood cells
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Experimental study and numerical simulation of low calorific fuel combustion at different oxygen content in the oxydizer
PublicationW pracy przedstawiono wyniki badań eksperymentalnych oraz obliczeń numerycznych procesu spalania paliwa gazowego niskokalorycznego w utleniaczu o podwyższonej temperaturze i zmiennej zawartości tlenu. Badanym paliwem był gaz o składzie zbliżonym do paliwa pochodzącego z gazyfikacji biomasy. Spalanie przeprowadzano dla zmiennej wartości temperatury utleniacza oraz zawartości tlenu. Obliczenia numeryczne wykonano z wykorzystaniem...
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Charge distribution and magnetic interactions in PrBa2Cu3O7 with substitutional defects and oxygen disorder: the ab initio approach
PublicationW artykule zaprezentowano rezultaty kwantowomechanicznych obliczeń ''ab initio: struktury elektronowej układu PrBa2Cu3O7 zawierającego defekty substytucyjne (Pr_Ba) w podsieci barowo-tlenowej oraz wykazującego zaburzoną stechiometrię tlenową (O5). Badane defekty są odpowiedzialne za redystrybucję ładunku w układzie. Defekty Pr_Ba generują silnie zlokalizowane momenty magnetyczne, które oddziałują głównie na płaszczyzny miedziowo-tlenowe.
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Comparison of Cu1.3Mn1.7O4 spinels doped with Ni or Fe and synthesized via wet chemistry and solid-state reaction methods, designed as potential coating materials for metallic interconnects
PublicationThe influence of the method applied to synthesize Cu-Mn-O spinel was evaluated. The methods selected for the investigation were EDTA gel processes and solid-state reaction synthesis. From the obtained powders, sinters were prepared and assessed in terms of their properties as potential coating materials. Additionally, the influence of Ni and Fe dopants was evaluated. The results show that the EDTA gel processes method seems to...
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New reaction of dithiophosphoric acids with O-thioacylhydroxylamines. Nucleophilic substitution or single electron transfer process?
PublicationUdowodniono, że dipodstawione lub sterycznie przeszkodzone hydroksyloaminy reagują z przestrzennie rozbudowanymi S-tioacyloditiofosforanami dając odpowiednie O-tioacylohydroksyloaminy. Dalsza reakcja O-tioacylohydroksyloaminy z kwasem ditiofosforowym prowadzi do powstania disiarczku acylowo tiofosfo-rylowego oraz soli amoniowej kwasu ditiofosforowego. Wpływ pułapek rodnikowych na wydajność tej reakcji świadczy dobitnie, że w procesie...
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Metrological characteristics of the flat voltammetric electrode in time domain with a reversible electrochemical reaction running on the surface
PublicationW artykule przedstawiono właściwości metrologiczne płaskich elektrod woltamperometrycznych. Omówiono wpływ napięcia polaryzującego na wartości parametrów charakteryzujących te elektrody.
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The reaction heats and PM5 semiempirical studies of complexes formed between silicon podand and monovalent cations
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The reaction heats and PM5 semiempirical studies of complexes formed between silicon podand and Li+ cations
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The kinetics of substitution reaction of oxydiacetate and thiodiacetate copper(II) complexes with 1,10-phenanthroline and 2,2’-bipyridine
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The effects of confinement in pores built of folded graphene sheets on the equilibrium of nitrogen monoxide dimerisation reaction
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Reaction Chemistry & Engineering
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Enhanced photocatalytic, electrochemical and photoelectrochemical properties of TiO2 nanotubes arrays modified with Cu, AgCu and Bi nanoparticles obtained via radiolytic reduction
PublicationTiO2 nanotubes arrays (NTs), obtained via electrochemical anodization of Ti foil, were modified with monometallic (Cu, Bi) and bimetallic (AgCu) nanoparticles. Different amounts of metals’ precursors were deposited on the surface of NTs by the spin-coating technique, and the reduction of metals was performed via gamma radiolysis. Surface modification of titania was studied by EDS and XPS analysis. The results show that AgCu nanoparticles...
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A method of two-terminal excess noise measurement with a reduction of measurement system and contact noise
PublicationPrzedstawiono metodę i system do pomiaru szumów nadmiarowych dwójników elektrycznych ze znaczną redukcją wpływu szumów własnych systemu pomiarowego i szumów kontaków. Proponowana metoda może byc zastosowana do pomiaru szumów elementów z wyprowadzonymi końcówkami, bądź też struktur, gdy jako wzorcowy szum odniesienia może zostać zastosowany szum struktury rezystywnej wytworzonej bezpośrednio na strukturze w otoczeniu elementu testowanego.
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The laboratory experiments on reduction of organic pollutants load in was-tewater generated in fish processing industry
PublicationPrzeprowadzono próby obniżenia ładunku zanieczyszczeń w ściekach z przemysłu rybnego przed ich odprowadzeniem do sieci kanalizacji miejskiej. Wykorzystano koagulację do wydzielenia ze ścieków białek i tłuszczów. Uzyskany osad pokoagulacyjny dodawano do produkcji rybnych hydrolizatów białkowych. Zmodyfikowano metodę wytwarzania hydrolizatów poprzez zamianę kwasu siarkowego na fosforowy. Dzięki tej zmianie obniżono zawartość żelaza...
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Novel structure and size-reduction-oriented design of microstrip compact rat-race coupler
PublicationIn this paper, a novel structure of a miniaturized microstrip rat-race coupler has been proposed. Surrogate-based optimization procedures are applied to explicitly reduce the coupler size while maintaining equal power split at the operating frequency of 1 GHz and sufficient bandwidth for return loss and isolation characteristics. The optimization is performed using the objective function with four penalty components. The footprint...
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State of the art in the field of emission reduction of sulphur dioxide produced during coal combustion
PublicationThe need for clean coal technologies to reduce the adverse environmental impact of coal combustion products has been grounded. The article deals with information concerning present and future technologies, directed towards the struggle against air pollution by SO2, produced during coal combustion. Their classification and critical rating from economical and technological points of views (including those developed by authors) have...
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Methodology for implementing power plant efficiency standards for power generation: potential emission reduction
PublicationSome methods of generating power such as power generation through coal, natural gas, oil result in inevitable emissions of greenhouse gases. While power generation is necessary due to its increasing demand, it is important for power companies to generate their power in an efcient manner to reduce its efect on the environment. One of the most efective ways of tackling inefciency issues is through the implementation of efciency standard....
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Hydraulic servomechanism system. Examples of reduction of power losses in the variable pressure power supply
PublicationUkład serwomechanizmu hydraulicznego najczęściej stosowany, w którym rozdzielacz dławiący jest zasilany pompą wyporową o stałej wydajności, współpracującą z zaworem przelewowym, pracujący przy stałym ciśnieniu zasilania, osiąga wysoką wartość sprawności energetycznej jedynie w punkcie maksymalnej wartości obciążenia i prędkości sterowanego silnika. Oszczędności energii przy zasilaniu układu pompą o stałej wydajności mogą być osiągnięte...
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Fast frequency sweep based on the model order reduction technique for calculating scattering parametersjinjFDFDj
PublicationArtykuł prezentuje ulepszoną, efektywną metodę przemiatania częstotliwościowego dla metody FDFD. Liczba równań opisujących analizowaną strukturę jest redukowana za pomocą metody redukcjirzędu modeli, a następnie macierz wynikowa jest diagonalizowana. Kosztowne czasowo odwracanie dużych macierzy jest zastąpione prostym mnożeniem małej macierz diagonalnej przez wektor. Zaprezentowana metoda przemiatania częstotliwościowego może...
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TiO2 Processed by pressurized hot solvents as a novel photocatalyst for photocatalytic reduction of carbon dioxide
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