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Investigation of the Efficiency of a Dual-Fuel Gas Turbine Combustion Chamber with a Plasma‒Chemical Element
PublicationThe study is devoted to the possibility of increasing the efficiency of the working process in dual-fuel combustion chambers of gas turbine engines for FPSO vessels. For the first time, it is proposed to use the advantages of plasma‒chemical intensification of the combustion of hydrocarbon fuels in the dual-fuel combustion chambers, which can simultaneously operate on gaseous and liquid fuels. A design scheme of a combustion chamber...
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Signals Features Extraction in Radioisotope Liquid-Gas Flow Measurements using Autocorrelation Function
PublicationKnowledge of the two-phase flow structure is essential for the proper conduct of industrial processes. Description of liquid-gas flow regimes is possible by using of data analysis in time, frequency, or state-space domain. In this research studies, the autocorrelation function is applied for analysis of signals obtained for liquid-gas flow by use gamma-ray absorption. The experiments were carried out on the laboratory hydraulic...
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Waste management in the mining industry of metals ores, coal, oil and natural gas - A review
PublicationWaste generated due to mining activity poses a serious issue due to the large amounts generated, even up to 65 billion tons per year, and is often associated with the risk posed by its storage and environmental management. This work aims to review waste management in the mining industry of metals ores, coal, oil and natural gas. It includes an analysis and discussion on the possibilities for reuse of certain types of wastes generated...
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Barium boron aluminum silicate glass system for solid state optical gas sensors
PublicationRecent increasing demand for new eco-friendly materials and for low cost fabrication process for use in optical sensors field, raise concern about alternative materials for this application. We have designed two glass-ceramics compositions from the quaternary ROAl2O3- SiO2-B2O3(R=Ba) alkali-earth aluminum silicate system, labeled B72 and B69, with high refractive index (>1.6), large values of Abbe number (94.0 and 53.0, respectively),...
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New bis(azobenzocrown)s with dodecylmethylmalonyl linkers as ionophores for sodium selective potentiometric sensors
PublicationNovel biscrowns 1 and 2 were synthesized from 13-membered azobenzocrown ethers containing bromoalkylenoxy chains in para position relative to the azo group. The synthesized diester molecules are dodecylmethylmalonic acid derivatives differing by the linker length. The synthesized compounds have the potential of being used as sodium ionophores in ion-selective electrodes. They were characterized and used as ionophores in classic...
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Natural radioactivity of solid and liquid phases from shale oil and gas prospection in Pomerania
PublicationIonizing radiation intensity data and estimation of equivalent absorbed dose from solid and liquid samples from prospection of shale gas and oil at selected sites in Pomerania are presented. Naturally occurring radioactive materials (NORM) are associated with geological formations or fluids and can be enhanced during oil and gas production. They appear in e.g. drilling cuttings, flow back water, produced water, scale and sludge....
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Systemy aktywizacji, przetwarzania i wizualizacji danych AIS na potrzeby projektu netBaltic
PublicationSystem AIS (Automatic Identification System), zaprojektowany dla zapewnienia bezpieczeństwa żeglugi, służy do przekazywania w swoich komunikatach, wymienianych między jednostkami pływającymi, istotnych informacji geolokalizacyjnych. Znaczenie tych informacji wydaje się duże w kontekście planów budowy testowej instalacji, szerokopasmowej sieci teleinformatycznej netBaltic na morzu. W artykule przedstawiono wyniki dotyczące budowy...
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Experimental investigation of domestic micro-CHP based on the gas boiler fitted with ORC module
PublicationThe results of investigations conducted on the prototype of vapour driven micro-CHP unit integrated with a gas boiler are presented. The system enables cogeneration of heat and electric energy to cover the energy demand of household. The idea of such system is to produce electricity for own demand or for selling it to the electric grid – in such situation the system user will became the prosumer. A typical commercial gas boiler,...
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A strategy for GPS data processing in a precise local network during high solar activity
PublicationThis paper presents the analyses connected with reduction of errors from ionospheric refraction using GPS data from local satellite networks. This is particularly essential during rising solar activity. The Bernese GPS Software v. 4.2 was used, as an analytical tool. The test data included measurements from a geodynamic network SUDETES situated in the Sudety Mountains across the border between the Czech Republic and Poland. A local...
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Intercomparison of TEC obtained from the IRI model to the one derived from GPS measurements
PublicationIRI (International Reference Ionosphere) is a well-known standard of the ionosphere, but nowadays GPS permanent observations are also the base of the regional and global ionosphere models. In this paper, comparison of TEC (Total Electron Content) derived from the IRI model to the global TEC parameters derived from GPS measurements is presented. Global TEC maps show, that GPS derived ionosphere models, in opposition to the IRI,...
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Bis-phosphonated carbon nanotubes: one pot synthesis and their application as efficient adsorbent of mercury
PublicationEffective, one-pot method of CNTs phosphonylation is presented. Cheap and readily available reagents are used, so the process can be easily transferred to large-scale production. The product was analyzed using spectroscopic methods (FTIR, UV-vis, XPS). Thermal properties of the bis-phosphonated nanotubes are reported for the first time. Newly obtained material was tested as an adsorbent for mercury removal from water. The sorption...
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Fragen und Beobachtungen zur Erhaltung der architektonischen Nachkriegsmoderne bis 1980 in Polen
PublicationRozdział w książce będącej przeglądem architektury powojennej w Europie. Książka dotyczy walorów i problemów ochrony budownictwa z lat powojennych w różnych krajach - głównie Niemczech, ale także w Europie Wschodniej. W rozdziale omówiono stan i problemy ochrony architektury do lat 80. XX w. w Polsce w tym w Gdyni i w Gdańsku. Wskazano na kontrowersje pojawiające się przy obejmowaniu ochroną budynków z lat 50. i 60. w Polsce.
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Standing Acoustic Waves and Relative Nonlinear Phenomena in a Vibrationally Relaxing Gas-Filled Resonator
PublicationStanding acoustic waves in one-dimensional resonator filled with vibrationally relaxing gas, are studied. Two regimes of excitation of molecular vibrational degrees of freedom are considered, equilibrium and nonequilibrium. The acoustic energy enlarges with time in the non-equilibrium regime and decreases otherwise before formation of discontinuity. After that, it decreases due to nonlinear absorption and tends to zero in equilibrium...
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Analiza dokładności wyznaczania różnicowych opóźnień fazowych w systemie wykrywania spoofingu GPS
PublicationSpoofing GPS jest atakiem polegającym na nadawaniu fałszywych sygnałów do odbiornika GPS, w celu wyznaczenia przez niego nieprawidłowych informacji o położeniu, prędkości i czasie. Istnieje potrzeba opracowania skutecznych metod jego wykrywania. Niniejszy artykuł opisuje metodę opartą na pomiarach opóźnień fazowych w układzie wieloantenowym. Przedstawiono analizę dotyczącą dokładności i precyzji estymacji różnic fazy, ustalono...
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Diagnostic tolerances' evaluation method of the start-up exhaust temperature of a naval gas turbine
PublicationThe conducted investigations aimed to elaborate the method of marking diagnostic tolerances of the exhaust temperature of a gas turbine observed during engine's start-up process. The diagnostic tolerances were determined by means of statistical inference by creating the hypothesis about a normal distribution of the start-up exhaust temperature's dispersion in the initial operation moment, which was subsequently verified applying...
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Catena-Poly[[(tetrahydrofuran-[kappa]O)lithium(I)]-bis([mu]-trimethylsilanolato-[kappa]2O:O)-gallium(III)-bis([mu]-trimethylsilanolato-[kappa]2O:O)-[(tetrahydrofuran-[kappa]O)lithium(I)]-[mu]-bromido]
PublicationThe title chain polymer compound, [GaLi2Br(C3H9OSi)4(C4H8O)2]n, was obtained in the reaction of GaBr3 with Me3SiOLi in toluene/tetrahydrofuran. The GaIII atom, located on a twofold rotation axis, is coordinated by four trimethylsilanolate ligands and has a distorted tetrahedral geometry. The LiI atom is four coordinated by one bridging Br atom located on an inversion centre, two trimethylsilanolate ligands and one tetrahydrofurane...
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Implementacja wykrywalnych usług typu REST na platformie Jakarta EE
PublicationNiniejszy rozdział przedstawia propozycję w jaki sposób może być realizowana implementacja wykrywalnych usług sieciowych opartych na stylu architektonicznym REST na platformie Jakarta EE. Zostały tutaj przedstawione zarówno podstawy teoretyczne niezależne od zastosowanej platformy technologicznej, jak i szczegóły implementacji w technologii JAX-RS wchodzącej w skład platformy Jakarta EE. W szczególności zostały tutaj przedstawione...
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Wielokryterialne Wspomaganie decyzji środowiskowych przy wydobywaniu węglowodorów z formacji łupkowych
PublicationPoszukiwanie i eksploatacja gazu z formacji łupkowych wymaga zidentyfikowania i uwzględnienia wielu czynników i uwarunkowań geologiczno-górniczych, ekonomiczno-finansowych, prawnych oraz szeroko rozumianych aspektów przestrzenno-środowiskowych. Poruszane zagadnienia prowadzą do zidentyfikowania problemów decyzyjnych, które mogą pojawiać się przy eksploatacji gazu z łupków, a które wiążą się z intensywnym korzystaniem z zasobów...
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Use of structural equation modeling in quantitative research in the field of management and economics: A bibliometric analysis in the systematic literature review
PublicationPURPOSE: This paper aims to provide a comprehensive review of scholarly research focusing on using quantitative methods and particularly structural equation modeling (SEM) in management and economics studies, as well as provide a bibliometric agenda including the time horizon of individual publications, the highest citation rate, geographic and industry areas, methodological context, and keywords. METHODOLOGY: A systematic literature...
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Influence of Different Biofuels on the Efficiency of Gas Turbine Cycles for Prosumer and Distributed Energy Power Plants
PublicationThe efficiency of a gas turbine can be affected by the use of different biofuels usually with a relatively Lower Heating Value (LHV). The paper evaluates the impact of calorific value of fuel on turbine performance and analyzes the possibilities of optimizing turbine construction from the point of view of maximum efficiency for a particular fuel. The several variants of design of small power microturbines dedicated to various biofuels...
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Identification of damages in the inlet air duct of a diesel engine based on exhaust gas temperature measurements
PublicationThe temperature of the exhaust gas of a diesel piston engine, measured in the characteristic control sections of its thermo-flow system, can be a valuable source of diagnostic information about the technical condition of the elements limiting the working spaces thus separated, including the turbocharging system, but also its fuel supply system and replacement of the medium. In standard marine engine measurement systems equipped...
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Comparison of noise reduction methods in radiometric correlation measurements of two-phase liquid-gas flows
PublicationTwo-phase liquid-gas flows occur frequently in the mining, energy, chemical, and petrochemical industries. One of non-contact methods used to analyse these flows is the gamma ray absorption method. However, the signals received from radiation detectors contain a significant stochastic noise, which makes them difficult to analyse. The article describes four methods of noise reduction in cross-correlation measurements of water-air...
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Evaluation of Three Peptide Immobilization Techniques on a QCM Surface Related to Acetaldehyde Responses in the Gas Phase
PublicationThe quartz-crystal microbalance is a sensitive and universal tool for measuring concentrations of various gases in the air. Biochemical functionalization of the QCM electrode allows a label-free detection of specific molecular interactions with high sensitivity and specificity. In addition, it enables a real-time determination of its kinetic rates and affinity constants. This makes QCM a versatile bioanalytical screening tool for...
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Application of fuzzy logic to determine the odour intensity of model gas mixtures using electronic nose
PublicationThe paper presents the possibility of application of fuzzy logic to determine the odour intensity of model, ternary gas mixtures (α-pinene, toluene and triethylamine) using electronic nose prototype. The results obtained using fuzzy logic algorithms were compared with the values obtained using multiple linear regression (MLR) model and sensory analysis. As the results of the studies, it was found the electronic nose prototype along...
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Novel analytical method for detection of orange juice adulteration based on ultra-fast gas chromatography
PublicationThe food authenticity assessment is an increasingly important issue in food quality and safety. The application of an electronic nose based on ultra-fast gas chromatography technique enables rapid analysis of the volatile compounds from food samples. Due to the fact that this technique provides chemical profiling of natural products, it can be a powerful tool for authentication in combination with chemometrics. In this article,...
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Bifurcation of equilibrium forms of a gas column rotating with constant speed around its axis of symmetry
PublicationWe will be concerned with the problem of deformation of the lateral surface of a column that rotates with constant speed around its axis of symmetry. The column is filled by a gas and our goal is to investigate the deformation of the lateral surface depending on the pressure of the gas.
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DESIGN ANALYSIS OF HYBRID GAS TURBINE - FUEL CELL POWER PLANT IN STATIONARY AND MARINE APPLICATIONS
PublicationThe paper concerns design analysis of a hybrid gas turbine power plant with a fuel cell (stack). The aim of this work was to find the most favorable variant of the medium capacity (approximately 50 MW) hybrid system. In the article, computational analysis of two variants of such a system was carried out. The analysis let to calculate capacity, efficiency of both variants and other parameters like flu gas temperature. The paper...
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UV Light-Modulated Fluctuation-Enhanced Gas Sensing by Layers of Graphene Flakes/TiO2 Nanoparticles
PublicationWe present experimental results of fluctuation-enhanced gas sensing by low-cost resistive sensors made of a mixture of graphene flakes and TiO2 nanoparticles. Both components are photocatalytic and activated by UV light. Two UV LEDs of different wavelengths (362 and 394 nm) were applied to modulate the gas sensing of the layers. Resistance noise was recorded at low frequencies, between 8 Hz and 10 kHz. The sensors’ response was...
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Identification of Substrates of Cytoplasmic Peptidyl-Prolyl Cis/Trans Isomerases and Their Collective Essentiality in Escherichia Coli
PublicationProtein folding often requires molecular chaperones and folding catalysts, such as peptidyl-prolyl cis/trans isomerases (PPIs). The Escherichia coli cytoplasm contains six well-known PPIs, although a requirement of their PPIase activity, the identity of their substrates and relative enzymatic contribution is unknown. Thus, strains lacking all periplasmic and one of the cytoplasmic PPIs were constructed. Measurement of their PPIase...
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Effectiveness of toluene separation from gas phase using supported ammonium ionic liquid membrane
PublicationAmmonium ionic liquids (ILs) are relatively cheap in synthesis and environmentally benign and despite that they have been very rarely used in gas separation. In this research we used several ammonium ILs as liquid membranes for removal of residual toluene from gas phase. Ionic liquids used in this study were composed of bis(trifluoromethylsulfonyl)imide anion [Tf2N] and trimethylbutylammonium [N1114], trietylbutylammonium [N2224],...
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Silica Gel Impregnated by Deep Eutectic Solvents for Adsorptive Removal of BTEX from Gas Streams
PublicationThe paper presents the preparation of new adsorbents based on silica gel (SiO2) impregnated with deep eutectic solvents (DESs) to increase benzene, toluene, ethylbenzene, and p-xylene (BTEX) adsorption efficiency from gas streams. The DESs were synthesized by means of choline chloride, tetrapropylammonium bromide, levulinic acid, lactic acid, and phenol. The physico-chemical properties of new sorbent materials, including surface...
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Durability evaluation of Ni‐Cr‐Mo super alloys in a simulated scrubbed flue gas environment
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Precipitation of Spherical Vaterite Particles via Carbonation Route in the Bubble Column and the Gas-Lift Reactor
PublicationSpherical vaterite particles were produced by carbonation of calcium chloride solution with addition of ammonia to facilitate CO2 absorption. Synthesis of calcium carbonate was carried out in a bubble column or gas-lift reactor. The course of the reaction was monitored by pH measurements. Precipitated solids were analyzed by Fourier-transformed infrared spectroscopy, x-ray powder diffraction and scanning electron microscopy, and...
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Toxicity of aqueous mixture of phenol and chlorophenols upon photosensitized oxidation initiated by sunlight or vis-lamp
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Development of New UV–vis Spectroscopic Microwave-Assisted Method for Determination of Glucose in Pharmaceutical Samples
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Monitoring of volatile organic compounds (VOCs) in atmospheric air. Part I. On-line gas analyzers
PublicationThe paper reviews the subject literature concerning the analytical instruments routinely used for monitoring volatile organic compounds in atmospheric air. The analyzers are classified as stationary or mobile according to their ease of transport. Stationary DOAS (Differential Optical Absorption Spectroscopy) analyzer is characterized, as are MIMS (Membrane Introduction Mass Spectrometry), MESI (Membrane Extraction with Sorbent...
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Studies on development of headspace - gas chromatographic determination of volatile fatty acids in troublesome environmental samples
PublicationBadania nad opracowaniem procedur oznaczania LKT w silnie zanieczyszczonych próbkach środowiskowych za pomocą techniki analizy fazy nadpowierzchniowej w połączeniu z chromatografią gazową z wykorzystaniem detektora płomieniowo-jonizacyjnego na etapie oznaczeń końcowych. Dobrano warunki ekstrakcji LKT do fazy nadpowierzchniowej oraz warunki chromatograficzne. Metodyka pozwala oznaczać LKT w bardzo skomplikowanych próbkach ciekłych...
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A headspace solid-phase microextraction method development and itsapplication in the determination of volatiles in honeys by gas chromatography
PublicationThe first part of the paper presents the detailed optimisation of all steps of the determination procedureof volatiles from Polish honeys by headspace solid-phase microextraction (HS-SPME) as the sample preparationmethod and gas chromatography/mass spectrometry (GC-MS) as the method of final determination.The methodology of semi-quantative analysis allowed the isolation and identification of volatile fractioncompounds from popular...
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Sample preparation for gas chromatographic determination of halogenated volatile organic compounds in environmental and biological samples
PublicationPodstawowym elementem przygotowania próbek środowiskowych i biologicznych do analizy jest etap izolacji i/lub wzbogacania polegający na przeniesieniu analitów z matrycy pierwotnej charakteryzującej się złożonym i często zmiennym składem (próbka oryginalna) do matrycy wtórnej z równoczesnym usunięciem substancji przeszkadzających (izolacja)i zwiększeniem stężenia analitów do poziomu powyżej granicy oznaczalności stosowanego przyrządu...
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Experimental and mathematical modelling study of gas combustion under the high-temperature and oxygen-deficient oxidizers
PublicationPraca przedstawia wyniki badań eksperymentalnych i modelowania numerycznego wpływu parametrów utleniacza za długość i objętość płomienia przy spalaniu paliwa gazowego w środowisku o wysokiej temperaturze i ubogim w tlen.
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1,4-Bis(2-methylstyryl)benzene doped PMMA fibre for blue range fluorescent applications
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ANN based evaluation of the NOx concentration in the exhaust gas of a marine two-stroke diesel engine
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Application of gas chromatography-olfactometry (GC-O) in analysis and quality assessment of alcoholic beverages - a review
PublicationW ostatnich latach prowadzone są intensywne badania nad aktywnością sensoryczną poszczególnych składników zapachów napojów alkoholowych i nad zależnościami pomiędzy zapachem, a składem chemicznym lotnej frakcji tych produktów z wykorzystaniem techniki chromatografii gazowej z detekcją olfaktometryczną (GC-O). GC-O jest techniką wykorzystującą możliwość oceny sensorycznej eluatu z kolumny chromatograficznej, przy czym dla każdego...
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Chromogenic derivatives of new bis(phenylhydrazono-1H-tetrazol-5-yl-acetonitriles) - synthesis and properties
PublicationDerivatives of bis(phenylhydrazono-1H-tetrazol-5-yl-acetonitriles) with oxygen and sulphur atoms in the structure of aliphatic chains were successfully synthesised. The correlation between the ligand structure and its complexation properties was investigated by absorption spectroscopy. The formation of complexes of presented compounds with metal cations (Cu2+, Ni2+, Zn2+, Co2+, Fe2+ and Pb2+) was studied. Ligands 5-8 were additionally...
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(1H-Pyrazole-[kappa]N)bis(tri-tert-butoxysilanethiolato-[kappa]2O,S)cadmium
PublicationThe CdII atom in the title complex, [Cd(C12H27O3SSi)2-(C3H4N2)], is penta-coordinated by two O and two S atoms from the O,S-chelating silanethiolate residue and one pyrazole N atom in a distorted trigonal-bipyramidal geometry. The pyrazole ligand forms an intramolecular N-H---O hydrogen bond.
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Application of Multiplicative Drift Correction and Component Correction methods on simulated gas sensor array responses
PublicationSensor response drift is one of the most challenging problems in gas-analyzing systems. Such systems, commonly called electronic noses, are expected to be reliable and reproducible in the long term. Due to the drift phenomena, electronic noses usability is limited to the relatively short period of time, and frequent recalibrations of device are required. Because it is very hard to fabricate sensors without drift, this phenomenon...
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Design analysis of combined gas-vapour micro power plant with 30 kW air turbine
PublicationThe article presents basic results of the design analysis of a combined gas-vapour micro power plant with a waste-heat boiler without exhaust reheat, working in the vapour section in the Organic Rankine Cycle (ORC) system. The analysis concerned working media most frequently used in those types of power plants and planned to be used in future. The object of the analysis was a micro power plant with a 30 kW gas (air) turbine for...
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A comparison of three solvent-free techniques coupled with gas chromatography for determining trihalomethanes in urine samples
PublicationDążenie do oznaczania lotnych analitów organicznych w próbkach płynów biologicznych charakteryzujących się złożonym, a często zmiennym składem matrycy, stanowi siłę napędową do działań analityków w zakresie poszukiwania nowych rozwiązań metodycznych i aparaturowych. Publikacja ta przedstawia porównanie trzech technik zastosowanych do tych celów: technikę analizy fazy nadpowierzchniowej z generacją strumienia ciekłego sorbentu...
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Continuous Monitoring of Thermooxidative Degradation Products of Polystyrene by Membrane Extraction with Sorbent Interface and Gas Chromatography
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Application of gas chromatographic data and 2D molecular descriptors for accurate global mobility potential prediction
PublicationMobility is a key feature affecting the environmental fate, which is of particular importance in the case of persistent organic pollutants (POPs) and emerging pollutants (EPs). In this study, the global mobility classification artificial neural networks-based models employing GC retention times (RT) and 2D molecular descriptors were constructed and validated. The high usability of RT was confirmed based on the feature selection...