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Search results for: IITALIAN SOCIETY
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Triplet Formation and Triplet‐Triplet Annihilation Upconversion in Iodine Substituted Non‐Orthogonal BODIPY‐Perylene Dyads
PublicationBODIPY-perylene dyads have emerged as useful metal free sensitizers for triplet-triplet annihilation upconversion (TTAUC), these dyads are capable of efficient triplet generation via spinorbit charge transfer intersystem crossing (SOCT-ISC). This important route to triplet formation requires dyads in which two moieties are oriented perpendicular to each other. In this contribution, we give a deeper insight on the behavior of recently...
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Computational analysis of substituent effects on proton affinity and gas-phase basicity of TEMPO derivatives and their hydrogen bonding interactions with water molecules
PublicationThe study investigates the molecular structure of 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) and its derivatives in the gas phase using B3LYP and M06-2X functional methods. Intermolecular interactions are analyzed using natural bond orbital (NBO) and atoms in molecules (AIM) techniques. NO2-substituted TEMPO displays high reactivity, less stability, and softer properties. The study reveals that the stability of TEMPO derivatives...
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Syntheses and Structures of Transition Metal Complexes with Phosphanylphosphinidene Chalcogenide Ligands
PublicationThe reactivity of the phosphanylphosphinidene complex [(DippN)2W(Cl)(η2-P-PtBu2)]− (1) toward chalcogens (Ch = Se, S) was studied. Reactions of stoichiometric amounts of 1 with chalcogens in DME yielded monomeric tungsten complexes with phosphanylphosphinidene chalcogenide ligands of the formula tBu2P−P−Ch (Ch = Se (in 2) and S (in 5)), which can be regarded as products of the addition of a chalcogen atom to a P=W bond in starting...
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Novel molecules containing structural features of NSAIDs and 1,2,3-triazole ring: Design, synthesis and evaluation as potential cytotoxic agents
PublicationFor the first time the template containing structural features of more than one NSAIDs and the 1,2,3-triazole ring was explored for the identification of potential cytotoxic agents. These new and complex molecules were predicted to be effective inhibitors of PDE4B by molecular modelling studies in silico. The multi-step synthesis of these compounds were carried out starting from the well-known drug nimesulide and involved the use...
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The Substantial Improvement of Amphotericin B Selective Toxicity Upon Modification of Mycosamine with Bulky Substituents
PublicationAbstract: Background: It is assumed that the unfavorable selective toxicity of an antifungal drug Amphotericin B (AmB) can be improved upon chemical modification of the antibiotic molecule. Objective: The aim of this study was verification of the hypothesis that introduction of bulky substituents at the amino sugar moiety of the antibiotic may result in diminishment of mammalian vitro toxicity of thus prepared AmB derivatives. Methods:...
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Electrochemical and in silico approaches for liver metabolic oxidation of antitumor-active triazoloacridinone C -1305
Publication5-Dimethylaminopropylamino-8-hydroxytriazoloacridinone (C-1305) is a promising antitumor compound developed in our laboratory. A better understanding of its metabolic transformations is still needed to explain the multidirectional mechanism of pharmacological action of triazoloacridinone derivatives at all. Thus, the aim of the current work was to predict oxidative pathways of C-1305 that would reflect its phase I metabolism. The...
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Mapping the Transglycosylation Relevant Sites of Cold-Adapted β-D-Galactosidase from Arthrobacter sp. 32cB
PublicationB-Galactosidase from Arthrobacter sp. 32cB (ArthbetaDG) is a cold-adapted enzyme able to catalyze hydrolysis of beta-D-galactosides and transglycosylation reaction, where galactosyl moiety is being transferred onto an acceptor larger than a water molecule. Mutants of ArthbetaDG D207A and E517Q were designed to determine the significance of specific residues and to enable formation of complexes with lactulose and sucrose and to...
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Are We Facing a Tsunami of Vaccine Hesitancy or Outdated Pandemic Policy in Times of Omicron? Analyzing Changes of COVID-19 Vaccination Trends in Poland
PublicationIn this study, we analyzed Polish COVID-19 vaccination data until January 2023 from the European Centre for Disease Prevention and Control to understand individual decision making during the milder Omicron wave. Our findings show a general decline in subsequent vaccine uptake. As the number of government-provided doses increased, completion rates among certain low-risk groups dropped to less than 1%. Elderly individuals, especially...
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Opracowanie i walidacja procedury oznaczania jonów nieorganicznych (w tym jonów rodankowych - biomarkera narażenia na składniki dymu tytoniowego) z wykorzystaniem techniki chromatografii jonowej w próbkach mleka kobiecego
PublicationNarażenie człowieka na toksyczne związki obecne w dymie tytoniowym może skutkować występowaniem wielu chorób odtytoniowych. Szczególny problem stanowią kobiety w ciąży oraz położnice, ponieważ związki chemiczne obecne w dymie tytoniowym mogą przenikać od matki do dziecka, co może powodować znane skutki narażenia na te substancje zarówno w organizmie matki jak i dziecka. W związku ze szkodliwością dymu tytoniowego konieczne jest monitorowanie...
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Game-based Sprint retrospectives: multiple action research
PublicationIn today’s fast-paced world of rapid technological change, software development teams need to constantly revise their work practices. Not surprisingly, regular reflection on how to become more effective is perceived as one of the most important principles of Agile Software Development. Nevertheless, running an effective and enjoyable retrospective meeting is still a challenge in real environments. As reported by several studies,...
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Efektuacyjność modelu mentalnego przedsiębiorczości
PublicationArtykuł prezentuje dwa modele przedsiębiorczości: tradycyjny (kauzalny) i efektuacyjny. Zgodnie z modelem kauzalnym najważniejszymi czynnikami sukcesu firmy jest strategiczne planowanie i konkurencyjność. W modelu efektuacyjnym znaczenie mają posiadane przez przedsiębiorcę zasoby, elastyczne reagowanie na szanse pojawiające się w otoczeniu i budowanie relacji biznesowych z otoczeniem. Celem artykułu jest ocena efektuacyjności mentalnego...
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Płeć a motywacje przedsiębiorcze oraz podejmowane przez mikroprzedsiębiorców decyzje zarządcze
PublicationWiększość doniesień literaturowych z badań nad wpływem płci na funkcjonowanie przedsiębiorstw wskazuje na gorsze wyniki kobiet w tym obszarze, zarówno pod względem liczby kobiet w biznesie, jak i osiągnięć firm prowadzonych przez kobiety. Badania te jednak często nie uwzględniają różnic w wielkości początkowej firm, nie biorą także pod uwagę celów i planów ich właścicieli. W wielu wypadkach te ostatnie nie są znane, bowiem analiza...
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Spurring the community involvement in planning - lessons from post-socialist cities
PublicationPublic participation and community involvement in planning processes is – in general – not a new topic for contemporary planners. But in many parts of the world – including the post-socialist countries like Poland or Russia – we can still face the lack of understanding of importance of proper community involvement in planning and development processes. Situation in these countries is significantly different from both highly-developed...
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Amberlyst-15 catalysed synthesis of novel indole derivatives under ultrasound irradiation: Their evaluation as serotonin 5‑HT2C receptor agonists
PublicationA series of indole based novel Schiff bases was designed as potential agonists of 5‑HT2C receptor that was supported by docking studies in silico. These compounds were synthesized via Amberlyst-15 catalysed condensation of an appropriate pyrazole based primary amine with the corresponding indole-3-aldehyde under ultrasound irradiation at ambient temperature. A number of target Schiff bases were obtained...
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Conjugates of Ciprofloxacin and Levofloxacin with Cell-Penetrating Peptide Exhibit Antifungal Activity and Mammalian Cytotoxicity
PublicationSeven conjugates composed of well-known fluoroquinolone antibacterial agents, ciprofloxacin (CIP) or levofloxacin (LVX), and a cell-penetrating peptide transportan 10 (TP10-NH2) were synthesised. The drugs were covalently bound to the peptide via an amide bond, methylenecarbonyl moiety, or a disulfide bridge. Conjugation of fluoroquinolones to TP10-NH2 resulted in congeners demonstrating antifungal in vitro activity against human...
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Sugar matters: sugar moieties as reactivity-tuning factors in quercetin O-glycosides
PublicationQuercetin, one of the most abundant flavonoids in plant-based foods, commonly occurs in nature in various glycosylated forms. There is still a less explored aspect regarding the cause of its glycosides diversity, depending on the sugars moiety attached. This work focuses on four widespread quercetin glycosides—hyperoside, isoquercitrin, quercitrin and rutin—by testing property-tuning capacity of different sugar moieties and thus...
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Opracowanie dogodnej metody tworzenia wiązań S-C o hybrydyzacji atomu węgla sp oraz sp2
PublicationBadania przeprowadzone w Katedrze Chemii Organicznej Wydziału Chemicznego Politechniki Gdańskiej na przestrzeni ostatnich kilku lat, pokazały wszechstronność pochodnych kwasu neopentylidenofosforoditiowego. Dotychczasowe wyniki badań doprowadziły mnie do opracowania nowych strategii syntetycznych, umożliwiających otrzymywanie związków zawierających wiązanie C-S o hybrydyzacji atomu węgla sp oraz sp2. Analizując wyniki badań opracowałam...
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Load path sensitivity and multiaxial fatigue life prediction of metals under non-proportional loadings
PublicationEngineering components often operate under complex loadings, in which the variable amplitude multiaxial stresses are raised by geometric discontinuities including holes, grooves, fillets and shoulders, etc. Besides, the non-proportional loading will lead to the rotation of maximum principal stress/strain and additional fatigue damage of structural elements in service. Consequently, the multiaxial and non-proportional loading have...
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Risk assessment for tram traffic on tramway bridges
PublicationMiejski transport szynowy wielu miastach stanowi istotny element systemu transportowego i jest przestrzennie rozwijającym się systemem zapewniającym mieszkańcom codzienną obsługę transportową. Bezpieczeństwo pasażerów transportu szynowego i użytkowników dróg jest jednym z najważniejszych czynników, który należy uwzględnić w trakcie projektowania infrastruktury oraz w ocenie operacyjnej systemu miejskiego transportu tramwajowego....
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Universities’ journey towards sustainability- systematic literature review
PublicationPurpose: This research aims to identify a sustainable university's key features. It is an essential step in tracing the topics discussed in the context of a sustainable university and their evolution in the scientific discourse. Design/methodology/approach: This paper relies on a systematic literature review (SLR) conducted using two scholarly databases: Emerald and Scopus. The timeframe selected by the authors for reviewing the...
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In situ spectroelectrochemical and theoretical study on the oxidation of a 4H-imidazole-ruthenium dye adsorbed on nanocrystalline TiO2thin film electrodes
PublicationTerpyridine 4H-imidazole-ruthenium(ii) complexes are considered promising candidates for use as sensitizers in dye sensitized solar cells (DSSCs) by displaying broad absorption in the visible range, where the dominant absorption features are due to metal-to-ligand charge transfer (MLCT) transitions. The ruthenium(iii) intermediates resulting from photoinduced MLCT transitions are essential intermediates in the photoredox-cycle...
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Anticancer Properties of Amino Acid and Peptide Derivatives of Mycophenolic Acid
PublicationBackground: Although Mycophenolic Acid (MPA) is applied as prodrugs in clinic as an immunosuppressant, it also possesses anticancer activity. MPA acts as Inosine-5’-Monophosphate Dehydrogenase (IMPDH) inhibitor, where the carboxylic group at the end of the side chain interacts with Ser 276 of the enzyme via hydrogen bonds. Therefore, MPA derivatives with other polar groups indicated high inhibition too. On the other hand, potent...
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Unveiling the electron-induced ionization cross sections and fragmentation mechanisms of 3,4-dihydro-2H-pyran
PublicationThe interactions of electrons with molecular systems under various conditions are essential to interdisciplinary research fields extending over the fundamental and applied sciences. In particular, investigating electron-induced ionization and dissociation of molecules may shed light on the radiation damage to living cells, the physicochemical processes in interstellar environments, and reaction mechanisms occurring in combustion...
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Z polskiej leksykografii biograficznej, nekrologicznej i komemoratywnej. Rosja i ZSRS a Polska – ofiary antycywilizacji. (Bibliografia prac z lat 1832–2021 – w wyborze)
PublicationNiniejszy artykuł przedstawia wybrane kwestie z zakresu polskiej leksykografii biograficznejw perspektywie genologicznej. Autorka proponuje wyodrębnienie nowegorodzaju – leksykografii nekrologicznej i komemoratywnej. Stwierdza, że nie powstałana gruncie polskiej nauki praca monograficzna poświęcona zagadnieniom leksykografiibiograficznej. Istnieją jedynie publikacje w postaci tematycznych/problemowych
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Getting to know the potential of social media in forest education
PublicationThe development of social network sites not only facilitates the acquisition and deepening of knowledge but also provides the possibility of easily contacting foresters, specialists in natural sciences and nature enthusiasts. In addition, for some years...
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Job-related emotions and job burnout among civil servants: examining the shape of the relationship in cross-sectional and longitudinal models
PublicationWstęp: Związek pozytywności, czyli proporcji między pozytywnymi a negatywnymi emocjami, z wypaleniem zawodowym może przybierać kształt krzywoliniowy. Ponadto z perspektywy teoretycznej jest to relacja przyczynowo - skutkowa, w której pozytywność jest proksymalnym, a wypalenie – dystalnym wymiarem dobrostanu zawodowego. Dotychczasowe badania były jednak prowadzone najczęściej w planie poprzecznym i testowały relacje prostoliniowe....
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Ships - inspiring objects in architecture
PublicationSea-going vessels have for centuries fascinated people, not only those who happen to work at sea, but first and foremost, those who have never set foot aboard a ship. The environment in which ships operate is reminiscent of freedom and countless adventures, but also of hard and interesting maritime working life. The famous words of Pompey: “Navigare necesseest, vivere non estnecesse” (sailing is necessary, living – is not necessary),...
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New Unsymmetrical Bisacridine Derivatives Noncovalently Attached to Quaternary Quantum Dots Improve Cancer Therapy by Enhancing Cytotoxicity toward Cancer Cells and Protecting Normal Cells
PublicationThe use of nanoparticles for the controlled drug delivery to cells has emerged as a good alternative to traditional systemic delivery. Quantum dots (QDs) offer potentially invaluable societal benefits such as drug targeting and in vivo biomedical imaging. In contrast, QDs may also pose risks to human health and the environment under certain conditions. Here, we demonstrated that unique combination of nanocrystals core components...
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New Chalcones Derivatives With Potent Antitumor Activity And Their Metabolism In Vitro
PublicationChalcone derivatives exhibit a broad range of biological activities, with antioxidant and cytotoxic properties among the most studied. Despite numerous reports on chalcones as cytotoxic, and potentially anticancer agents, very little is know on their actual mechanism of activity. Generally, chalcones are considered as antimitotic agents, which interfere with tubulin assembly.We have recently developed a new class of chalcones with...
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Trust Management Method for Wireless Sensor Networks
PublicationA Wireless Sensor Network (WSN) is a network of spatially distributed autonomous sensors to monitor physical or environmental conditions, such as temperature, sound, pressure, etc. and to cooperatively pass their data to the main location. The first wireless network that bore any real resemblance to a modern WSN is the Sound Surveillance System (SOSUS), developed by the United States Military in the 1950s to detect and track Soviet...
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Lipopolysaccharides: regulated biosynthesis and structural diversity
PublicationThe cell envelope of Gram-negative bacteria contains two distinct membranes, an inner (IM) and an outer (OM) membrane, separated by the periplasm, a hydrophilic compartment that includes a thin layer of peptidoglycan. The most distinguishing feature of such bacteria is the presence of an asymmetric OM with phospholipids located in the inner leaflet and lipopolysaccharides (LPSs) facing the outer leaflet. The maintenance of this...
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Dyskryminacja versus admiracja. Pracownicy w starszym wieku w wybranych teoriach i koncepcjach ekonomicznych
PublicationStarzenie się ludności to zjawisko globalne [Kijak, Szarota, 2013, s. 6]. Oznacza ono zmiany w strukturze wieku ludności, polegające na rosnącej liczbie i udziale osób reprezentujących starsze grupy wiekowe w populacji ogółem. Pociąga za sobą zmiany jakościowe – na różnych poziomach życia społecznego i gospodarczego [Szatur-Jaworska, 2013, s. 348]. Rynek pracy stanowi jeden z wymiarów, w...
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Teams tools. Leading high-performance teams with different types of intelligence
PublicationThe subject of this paper is the analysis of necessary tools for global teams, image of the team leader, styles of leadership in global teams. The analysis is based on selected examples from high-performance teams with visible results. The purpose of the work is to answer for the following questions: What are the characteristics of the leading global teams? Which style of leadership use the global teams? Is a female leader different...
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Residual Current Devices: Selection, Operation, and Testing
PublicationIn this book, the idea for residual current protection has been presented. The evolution in construction types of residual current devices, which has taken place over decades, is discussed. Types and functional properties of the contemporary residual current devices are described. The main parameters of these devices, from the point of view of their selection and application, are indicated. Special constructions of the protective...
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The Russian Federation in European Union Programmes
PublicationSince the early 1990s, the European Union has been supporting socio-economic transformations in the former Soviet Union states, including the Russian Federation. Initially, this assistance was provided in the framework of the TACIS Programme, offering long-term, non-repayable aid. In 1991–2006 Russia received EUR 2.7bn for the restructuring of the state enterprise sector, establishment of private companies, state administration...
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Architektura a dekonstrukcja. Przypadek Petera Eisenmana i Bernarda Tschumiego
PublicationArchitecture and Deconstruction Case of Peter Eisenman and Bernard Tschumi Introduction Towards deconstruction in architecture Intensive relations between philosophical deconstruction and architecture, which were present in the late 1980s and early 1990s, belong to the past and therefore may be described from a greater than...
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Products of Photo- and Thermochemical Rearrangement of 19-Membered di-tert-Butyl-Azoxybenzocrown
PublicationThe preparation and characterization of products of the photochemical and thermochemical rearrangements of 19-membered azoxybenzocrowns with two, bulky, tert-butyl substituents in benzene rings in the para positions to oligooxyethylene fragments (meta positions to azoxy group, i.e., t-Bu-19-Azo-O have been presented. In photochemical rearrangement, two colored typical products were expected, i.e., 19-membered o-hydroxy-m,m′-di-tert-butyl-azobenzocrown...
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Style liderów. Analiza na podstawie wybranych przykładów z polityki, kultury oraz indywidualnych wywiadów pogłębionych
PublicationStyle liderów. Analiza na podstawie przykładów z polityki, kultury oraz indywidualnych wywiadów pogłębionych " Angelica Pegani Tematem niniejszej pracy stały się style liderów, ich analiza na podstawie wybranych przykładów z polityki, kultury oraz badań własnych. Celem pracy jest udzielenie odpowiedzi na pytania: jakie są cechy charakterystyczne lidera? Które style liderów występują w świecie polityki i kultury? Czy kobieta...
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Wystawa indywidualna "Jesteś przewrażliwiona!", Kolonia Artystów - Dolne Miasto
Publication„Myśli coraz intensywniej o swojej twarzy, której dziewczęca dziecinność czyni go śmiesznym w oczach kobiety, cały jest wcielony w swą dziecinną twarzyczkę, która tężeje, drętwieje i (o, rozpaczy!) czerwieni się!”. Może to banalne, ale Patryk Różycki wciąż dotyka kwestii własnej kondycji i tożsamości. Sam sobie zadaje pozornie naiwne pytania o to, kim był kiedyś i czy tym kimś nadal jest. Drży. Dryfuje pomiędzy skrajnymi...
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Synthetic, Structural, and Spectroscopic Characterization of a Novel Family of High-Spin Iron(II) [(β-Diketiminate)(phosphanylphosphido)] Complexes
PublicationThis work describes a series of iron(II) phosphanylphosphido complexes. These compounds were obtained by reacting lithiated diphosphanes R2PP(SiMe3)Li (R = t-Bu, i-Pr) with an iron(II) β-diketiminate complex, [LFe(μ2-Cl)2Li(DME)2] (1), where DME = 1,2-dimethoxyethane and L = Dippnacnac (β-diketiminate). While the reaction of 1 with t-Bu2PP(SiMe3)Li yields [LFe(η1-Me3SiPPt- Bu2)] (2), that of 1 with equimolar amounts of i-Pr2PP(SiMe3)Li,...
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Pozwól płynąć swojemu produktowi
PublicationAutor: Joanna Czerska Autorki i współautorki rozdziałów: Anna Sarbiewska:15.2 OEE dla maszynMarzena Leszczyk-Kabacińska:18. 5S i wizualizacja pracy w gnieździe19. Standaryzacja pracy w gnieździe22. Program ciągłego doskonalenia Recenzja naukowa:Prof. zw. ds. hab. Bogdan Nogalski, Uniwerystet Gdański, 27.02.2010 --- Jeśli poszukujesz...
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Elective surgery system strengthening: development, measurement, and validation of the surgical preparedness index across 1632 hospitals in 119 countries
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