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Search results for: AOR reactions
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Measurements of differential cross sections for elastic electron scattering in the backward direction by molecular oxygen.
PublicationZmierzono różniczkowe przekroje czynne na rozproszenie sprężyste elektronów na cząsteczkach tlenu w zakresie kątów rozproszenia 100-180 st., dla wybranych energii padających elektronów w przedziale 7-20eV. Do pomiarów wykorzystano metodę lokalnego pola magnetycznego.
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Case studies of resonance phenomena in high voltage overhead power lines with shunt reactors
PublicationMisguided design of the towers of power transmission lines can lead to serious problems such as voltage asymmetry, overvoltages, electric arc extinction difficulties or resonance – in case of double circuit line with shunt reactors. The paper points out those threats on example of 400 kV double circuit overhead transmission line with shunt reactors.
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TOTAL CROSS SECTIONS FOR ELECTRON SCATTERING FROM SELECTED HYDROCARBONS: THE SUBSTITUTIONAL AND ADDITIVITY EFFECTS
PublicationTotal cross sections (TCS) for electron scattering from selected alkyne molecules, ethylene and its derivatives are compared. All cross sections have been measured in a wide energy range, from about 1 eV up to 370 eV, with the same electrostatic electron spectrometer. The substitutional and additivity effects are indicated and discussed.
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Cross sections calculations for electron scattering from dimethylamine, NH(CH3)2, molecule
PublicationThe total cross section for single electron-impact ionization and the integral elastic cross section for electron scattering from dimethylamine have been calculated using the binary-encounter-Bethe model and the independent atom method, respectively.
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The Conceptual Research over Low-Switching Modulation Strategy for Matrix Converters with the Coupled Reactors
PublicationIn this paper, different Pulse Width Modulation (PWM) strategies for operating with a low-switching frequency, a topology that combines Conventional Matrix Converters (CMCs), and Coupled Reactors (CRs) are presented and discussed. The principles of the proposed strategies are first discussed by a conceptual analysis and later validated by simulation. The paper shows how the combination of CMCs and CRs could be of special interest...
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TIME-OF-FLIGHT DIFFERENTIAL ELECTRON SCATTERING FROM MOLECULAR TARGETS: BENCHMARK CROSS SECTIONS
PublicationWe report time-of-flight differential cross section (DCS) measurements for the electron impact excitation transition in H2. In this work, agreement between available theory and experiment is excellent overall, and marks a transition in electron molecule scattering where differential scattering of excitation is found to be in such precise agreement. We also prove that the newly built apparatus can be used for accurate measurement...
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Energy losses in the hydraulic rotational motor - definitions and relations for evaluation of the efficiency of motor and hydrostatic drive
PublicationStosowane dotychczas w badaniach naukowych i w praktyce przemysłowej metody oceny strat i sprawności energetycznej obrotowych silników hydraulicznych stosowanych w napędach hydrostatycznych dają błędne rezultaty, ponieważ obarczone są wpływem samych strat na parametry, w funkcji których straty i sprawności są oceniane.Celem pracy było zdefiniowanie w silniku parametrów pracy, rozwijanych mocy, występujących strat i sprawności energetycznej...
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Społeczny charakter public relations- praca specjalisty PR w społeczeństwie i dla społeczeństwa
PublicationArtykuł podkreśla społeczny charakter działań public relations, wzajemne oddziaływanie organizacji i społeczeństwa i stawia tezę, że kryterium etyczności działań public relations jest ich stopień zaangażowania lub wpływu na społeczeństwo: jeśli realizowana na rzecz podmiotu zlecającego strategia PR jest korzystna tylko dla jednej lub dwóch stron tzw trójkąta etycznego – zleceniodawcy i podmiotu realizującego, z pominięciem...
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The Algorithm of Modelling and Analysis of Latent Semantic Relations: Linear Algebra vs. Probabilistic Topic Models
PublicationThis paper presents the algorithm of modelling and analysis of Latent Semantic Relations inside the argumentative type of documents collection. The novelty of the algorithm consists in using a systematic approach: in the combination of the probabilistic Latent Dirichlet Allocation (LDA) and Linear Algebra based Latent Semantic Analysis (LSA) methods; in considering each document as a complex of topics, defined on the basis of separate...
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The effectiveness of financial and economic regulation of land relations in the context of stimulating entrepreneurial activity in the regions of Ukraine
PublicationSolving the problem of enhancing the efficiency of the financial and economic regulation of land relations contributes to the development of entrepreneurship in Ukraine. The purpose of the paper is to determine new incentives for encouraging entrepreneurial activity by increasing the efficiency of the financial and economic regulation of land relations by local governments. The study is based on applying the method for predicting...
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Comparison of Absorbed and Intercepted Fractions of PAR for Individual Trees Based on Radiative Transfer Model Simulations
PublicationThe fraction of absorbed photosynthetically active radiation (fAPAR) is a key parameter for estimating the gross primary production (GPP) of trees. For continuous, dense forest canopies, fAPAR, is often equated with the intercepted fraction, fIPAR. This assumption is not valid for individual trees in urban environments or parkland settings where the canopy is sparse and there are well-defined tree crown boundaries. Here, the distinction...
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Synthesis of conjugates of MDP and nor-MDP linked to tuftsin derivatives as potential immunomodulators
PublicationZsyntetyzowano nowe koniugaty muramylodipeptydu (MDP) i nor-muramylo-dipeptydu (nor-MDP) z pochodnymi tuftsyny zawierającymi wiązanie izopeptydowe na epsilon-aminowej grupie lizyny jako potencjalne immunomodulatory. Do syntezy wykorzystano metodę mieszanych bezwodników z chloromrówczanem izobutylu i N-metylomorfoliną w bezwodnym DMF. Końcowe produkty charakteryzowno za pomocą NMR, analizy elementarnej i analizy aminokwasowej na...
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Electron scattering by planar boron-containing molecules BX3(X=F, Cl, CD3)
PublicationPraca prezentuje absolutny całkowity przekrój na rozpraszanie elektronów dla drobiny B(CD3)3 w zakresie niskich i średnich energii, otrzymany liniową metodą transmisyjną. Porównanie wyników dla innych płaskich drobin zawierających bor jako atom centralny - BX3(X=F, Cl) ukazuje rolę atomów zewnętrznych w procesie rozpraszania.
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α-Pinene, 3-carene and d-limonene in indoor air of Polish apartments: The impact on air quality and human exposure
PublicationMonoterpenes are among most ubiquitous volatile organic compounds (VOCs) to be detected in indoor air. Since the quality of indoor air is considered important for inhabitants' well-being, the present study aimed at investigating impact of human activity on levels of selected monoterpenes applying passive sampling technique followed by thermal desorption and gas chromatography coupled mass spectrometry. One of the objectives of...
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Actions of a nitric oxide donor on prostaglandin production and angiogenic activity in the equine endometrium
PublicationNitric oxide (NO) plays an important role in prostaglandin secretion and angiogenesis in the reproductive system. In the present study, the roles of the NO donor spermine NONOate and tumour necrosis factor-alpha (TNF; as a positive control) in prostaglandin production and angiogenic activity of equine endometria during the oestrous cycle were evaluated. In addition, the correlation between NO production...
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Electronic Noses for Indoor Air Quality Assessment
PublicationThis chapter presents a proposal of the use of electronic noses in the monitoring of indoor air quality. The main focus is put on the detailed characteristics of today’s indoor air quality control methods, the types of pollution in the air, and the development of electronic noses for air testing. Currently, scientists seek methodological and structural solutions that would enable real-time online indoor air control. It has been...
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Treatment of malodorous air in biotrickling filters: A review
PublicationOdour nuisance, resulting mainly from the presence of the compounds containing osmophore group and characterized by low olfactory threshold, is associated with danger and may be the cause of negative psychosomatic symptoms. Among different methods of malodorous air treatment, biological methods are of importance, mainly due to reduced operating costs, high purification efficiency of voluminous gas streams characterized by low concentrations...
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Review of the determination of pesticide residues in ambient air
PublicationW publikacji dokonano przeglądu najważniejszych metodyk oznaczania pozostałości pestycydów w powietrzu zewnętrznym. W publikacji przedstawiono także techniki używane do oznaczeń końcowych. Obecnie najpopularniejszą techniką oznaczeń końcowych jest chromatografia gazowa bądź cieczowa sprzężona ze spektrometrem mas.
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Tor kolejowy w procesie regulacji geometrycznej
PublicationKoncepcja badań nad stanem naprężeń w szynach toru kolejowego, przeprowadzonych dotychczas w Politechnice Gdańskiej, polega na wymuszaniu przemieszczeń poziomych całego rusztu torowego za pomocą podbijarki. Podjęto próbę weryfikacji wcześniejszych ustaleń na drodze eksperymentów o bardziej szczegółowym charakterze. Stworzono odpowiednie stanowisko badawcze, usytuowane w eksploatowanym torze. Przyjęto sposób szacowania wielkości...
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Mercury emission to air, water and soil in Poland
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Changes in air tourism to Tunisia in 2009–2018
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Small photovoltaic setup for the air conditioning system
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Mobile monitoring system for gaseous air pollution
PublicationThe concept of a mobile monitoring system for chemical agents control in the air is presented. The proposed system can be applied to measure industrial and car traffic air pollution. A monitoring station is relatively small and can be placed on cars or public transportation vehicles. Measured concentrations of air pollutants are collected and transferred via the GSM network to a central data base. Exemplary results from a measurement...
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Mobile system for on-road measurements of air pollutants
PublicationW pracy zaprezentowano prototyp mobilnej stacji diagnostycznej do pomiarów stężeń typowych zanieczyszczeń powietrza (C6H6, NO2, NOx, CO i CO2) pochodzących z komunikacji w miastach. Nowością proponowanego systemu jest możliwość przeprowadzania pomiarów emisji zanieczyszczeń wzdłuż ciągów komunikacyjnych i w miejscach, w których nie mogą być zastosowane stacjonarne stacje monitoringowe. W proponowanym rozwiązaniu, urządzenie...
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Microorganisms in the air over wastewater treatment plant.
PublicationCelem pracy było aktywności źródeł emisji mikroorganizmów do powietrza na terenie oczyszczalni ścieków. Stwierdzono iż najwyższe liczebności bakterii występowały w rejonie piaskowników i komór recyrkulacji osadu czynnego. Natomiast liczba bakterii w rejonie komór napowietrzania była zbliżona do tła.
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Passive samplers in indoor air quality control
PublicationPrzedstawiono wyniki badań jakości powietrza wewnętrznego w 12 wybranych mieszkaniach usytuowanych na terenie aglomeracji Trójmiejskiej z wykorzystaniem techniki pasywnej (dozymetria pasywna typu permeacyjnego) oraz techniki dynamicznej (rurki sorpcyjne wypełnione sorbentem Tenax TA). Wykorzystując nowe podejście do sposobu kalibracji dokonano monitoringu zarówno poszczególnych lotnych związków organicznych jak i sumarycznej zawartości...
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Wavelet analysis of frequency of air bubble departure
PublicationPrzedstawiono wyniki nieliniowej analizy częstotliwośći generowania pęcherzyków powietrza z dysz o średnicy 0.75 mm, 1.61 mm oraz 2.76 mm umieszczonych 15 cm poniżej poziomu wody.
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Environmental fate of BTEX compounds in ambient air
PublicationAs a result of the industrialization and urbanization in the world, human pressure on the environment is intensifying, leading to detrimental changes in both biotic and abiotic compartments. One of the many consequences of this state of affairs is the increasing rate of emission into the atmosphere of volatile organic compounds, including the so-called BTEX (benzene, ethylbenzene, toluene, xylenes) compounds. The article reviews...
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Current air quality analytics and monitoring: A review
PublicationThis review summarizes the different tools and concepts that are commonly applied in air quality monitoring. The monitoring of atmosphere is extremely important as the air quality is an important problem for large communities. Main requirements for analytical devices used for monitoring include a long period of autonomic operation and portability. These instruments, however, are often characterized by poor analytical performance....
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Air quality policy in the U.S. and the EU – a review
PublicationThe high level of atmospheric pollution is a global problem that has taken on particular significance in recent years and will continue to grow in the near future. Air pollution directly affects the health, living organisms, vegetation, water, soil and buildings. Additionally, it moves easily even over long distances. Certain air pollutants influence the climate, cause negative processes in the protective ozone layer and contribute...
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Air flow phenomena in the model of the blind drift
PublicationIn the presented paper, Particle Image Velocimetry (PIV) has been used to investigate flow pattern and turbulent structure in the model of blind drift. The presented model exist in mining, and has been analyzed to resolve ventilation issues. Blind region is particularly susceptible to unsafe methane accumulation. The measurement system allows us to evaluate all components of the velocity vector in channel cross-section simultaneously....
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Influence of the air phase on water flow in dikes
PublicationNumerical models are often used to describe flow and deformation processes occurring in dikes during flood events. Modeling of such phenomena is a challenging task, due to the complexity of the system, consisting of three material phases: soil skeleton, pore water and pore air. Additional difficulties are transient loading caused by variable in time water levels, heterogeneity of the soil or air...
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Instrumental techniques used in the analysis of exhaled air
PublicationExhaled air composition changes depending on the health status of the patient, making it possible to use breath analysis for diagnosis and monitoring purposes. Despite the fact that it is not yet used in every day medical practice, it potential application could facilitate the diagnostics of various diseases such as metabolic disorders, respiratory tract and gastrointestinal diseases. Described in this paper are different application...
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Deep Eutectic Solvents and Their Uses for Air Purification
PublicationChemical compounds released into the air by the activities of industrial plants and emitted from many other sources, including in households (paints, waxes, cosmetics, disinfectants, plastic (PVC) flooring), may affect the environment and human health. Thus, air purification is an important issue in the context of caring for the condition of the environment. Deep eutectic solvents (DESs) as liquids with environmentally friendly...
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Reactions of lithiated diphosphanes R2P-P(SiMe3)LiTHF (R = tBu, iPr) with [(PNP)TiCl2]. Two different coordination types of phosphanylphosphido ligand to the metal center.
Publication[(PNP)TiCl2] (PNP = N[2-PiPr2-4-methylphenyl]2) reacts with one equivalent of lithium derivative of diphosphane R2P-P(SiMe3)LinTHF (R = tBu, iPr) in toluene and forms the first complex with g1-coordination [(PNP)Ti(Cl){g1-P(SiMe3)-PtBu2}] (1) and complex with g2-coordination [(PNP)Ti(Cl){g2-P(SiMe3)-PiPr2}] (2) of phosphanylphosphido ligands to the titanium center. The similar reaction with two equivalents of tBu2P-P(SiMe3)LinTHF...
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Comparative X-ray diffraction and Mössbauer spectroscopy studies of BiFeO3 ceramics prepared by conventional solid-state reaction and mechanical activation
PublicationThe aim of this work was to prepare BiFeO3 by modified solid-state sintering and mechanical activation processes and to investigate the structure and hyperfine interactions of the material. X-ray diffraction and Mössbauer spectroscopy were applied as complementary methods. In the case of sintering, BiFeO3 phase was obtained from the mixture of precursors with 3 and 5 % excess of Bi2O3 during heating at 1023 K. Small amounts of...
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Mechanism of the Reaction of Amines with 5-[(Aryl- or Alkylamino)hydroxymethylene]-2,2-dimethyl-1,3-dioxane-4,6-diones in the Presence of Chlorotrimethylsilane (Me3SiCl);
PublicationAddition of chlorotrimethylsilane (Me3SiCl) to the mixture of a carbamoyl‐substituted Meldrum's acid, i.e., a 5‐[(arylamino)hydroxymethylene]‐2,2‐dimethyl‐1,3‐dioxane‐4,6‐dione of type 1 and a secondary amine as nucleophile strongly accelerated the rate of their reaction. The reason for this phenomenon observed, during our previous research, remained, however, unclear. To elucidate the mechanism of this reaction, we assumed and...
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Complementary Use of Multi-dimensional Gas Chromatography and Proton Transfer Reaction Mass Spectrometry for Identification of Rapeseed Oil Quality Indicators
PublicationThe change of concentration of various volatiles generated during frying may be an indicator of oil quality. Chemical compounds such as aldehydes, ketones, alcohols and carboxyl acids are the products of oxidation during thermal degradation of edible oils. Shown in this work is a complementary use of GC×GC-TOFMS and PTR-MS for the detection and determination of quality indicators of rapeseed oil. The former technique was used for...
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Effect of drying parameters on the formation of early and intermediate stage products of the Maillard reaction in different plum (Prunus domestica L.) cultivars
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Effect of Cl/Ni molar ratio on the catalytic conversion of polypropylene into Cu–Ni/C composites and their application in catalyzing “Click” reaction
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Analytical investigation of phase assemblages of alkali-activated materials in CaO-SiO2-Al2O3 systems: The management of reaction products and designing of precursors
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Activation of the Normal Human Skin Cells by a Portable Dielectric Barrier Discharge-Based Reaction-Discharge System of a Defined Gas Temperature
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The reduction of (ImH)[trans-RuIIICl4(dmso)(Im)] under physiological conditions: preferential reaction of the reduced complex with human serum albumin
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Estimation of concentration equilibrium constants of reaction between mutagenic HAA and antimutagenic cabbage phytochemicals based on data from Ames test
PublicationWykorzystano dane testu Amesa, przy pomocy którego oceniono antymutagenne właściwości fitokompleksu kapusty w stosunku do modelowych kancerogennych heterocyklicznych amin aromatycznych (HAA), do oszacowania stężeniowych stałych reakcji HAA z izotiocyjanianami występującymi w tym warzywie. Wyznaczone stężeniowe stałe reakcji wskazują na dużą stabilność powstałych koniugatów, a zatem sugerują, że kapusta może efektywnie chronić organizm...
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Hazardous waste dewatering and dry mass reduction through hydrophobic modification by a facile one-pot, alkali-assisted hydrothermal reaction
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Kinetic and equilibrium studies of the proton and deuteron transfer reaction between bis(2,4-dinitrophenyl)methane and strong nitrogen bases in acetonitrile
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Highly Porous Carbon Flakes Derived from Cellulose and Nickel Phosphide Heterostructure towards Efficient Electrocatalysis of Oxygen Evolution Reaction
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Promotion of MXene (Ti3C2Tx) as a robust electrocatalyst for oxygen evolution reaction via active sites of ZIF-67 - In situ mechanism investigations
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Spray-Drying Impact the Physicochemical Properties and Formation of Maillard Reaction Products Contributing to Antioxidant Activity of Camelina Press Cake Extract
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Identification and Bioaccessibility of Maillard Reaction Products and Phenolic Compounds in Buckwheat Biscuits Formulated from Flour Fermented by Rhizopus oligosporus 2710
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