Search
Filters
total: 1068
-
Catalog
- Publications 822 available results
- Journals 64 available results
- Publishing Houses 2 available results
- People 25 available results
- Inventions 1 available results
- Projects 4 available results
- Research Teams 1 available results
- e-Learning Courses 15 available results
- Open Research Data 134 available results
displaying 1000 best results Help
Search results for: protonic ceramics
-
LDI MAGIC Laser Direct Imaging Material and process developments for next Generation Integrated Chipless RFID
ProjectsProject realized in Department of Microwave and Antenna Engineering according to M-ERA.NET3/2021/123/LDI MAGIC/2022 agreement from 2022-12-30
-
Charge-assisted N(+)–H···(−)S hydrogen bonds in the crystal structure of selected diammonium thiophenolates.
PublicationNew salts of thiophenol with three flexible aliphatic diamines H2N(CH2)nNH2 (n = 2, 4 and 6) have been synthesized and characterized by elemental analyses, IR spectroscopy and X-ray crystallography in order to analyze their supramolecular architecture. Structural analyses indicate that in the crystals, proton transfer has occurred, with the –SH group giving (+)N–H···S(−) hydrogen bonding interaction. The structure of compound 1...
-
Investigations on the removal of hydrophobic odorous volatile organic compounds by biotrickling filtration monitored with electronic nose
PublicationThe presented paper presents the results of research on the removal of selected hydrophobic volatile organic compounds (VOCs) from their mixture with air by means of a trickled-bed biofiltration. The efficiency of the removal of toluene and α-pinene, as model VOCs, in a three-section biotrickling filter is evaluated using GCFID and additionally monitored with an electronic nose. The results show that the removal of the model mixture...
-
Geometrically Nonlinear Analysis of Functionally Graded Shells Based on 2-D Cosserat Constitutive Model
PublicationIn this paper geometrically nonlinear analysis of functionally graded shells in 6-parameter shell theory is presented. It is assumed that the shell consists of two constituents: ceramic and metal. The mechanical properties are graded through the thickness and are described by power law distribution. Formulation based on 2-D Cosserat constitutive model is used to derive constitutive relation for functionally graded shells. Numerical...
-
Szlifowanie jednostronne ściernicami o spoiwie niklowym z ziarnami z regularnego azotku boru
PublicationPrzedstawiono wyniki badań eksperymentalnych szlifowania jednostronnego stali stopowej 40H i ceramiki beztlenkowej SSiC z zastosowaniem ściernic o spoiwie niklowym z ziarnami z regularnego azotku boru B107 i B64. Zaprezentowano uzyskane wartości liniowego ubytku materiałowego oraz parametru Ra chropowatości powierzchni. Scharakteryzowano ogólnie zużycie czynnej powierzchni ściernicy.
-
Szlifowanie jednostronne ściernicami o spoiwie niklowym z ziarnami z regularnego azotku boru
PublicationPrzedstawiono wyniki badań eksperymentalnych szlifowania jednostronnego stali stopowej 40H i ceramiki beztlenkowej SSiC z zastosowaniem ściernic o spoiwie niklowym z ziarnami z regularnego azotku boru B107 i B64. Zaprezentowano uzyskane wartości liniowego ubytku materiałowego oraz parametru Ra chropowatości powierzchni. Scharakteryzowano ogólnie zużycie czynnej powierzchni ściernicy.
-
Wybrane problemy szlifowania powierzchni płaskich z kinematyką docierania
PublicationW pracy przedstawiono teoretyczne i doświadczalne podstawy szlifowania powierzchni płaskich z kinematyką docierania. Dokonano kompleksowej analizy zastosowanych układów kinematycznych szlifierek. Przeprowadzono eksperymenty szlifowania jednostronnego ściernicami o spoiwie galwanicznym z ziarnami diamentowymi (D107, D64 i D46) oraz z regularnego azotku boru (B107 i B64). Innowacyjność ściernic polegała na zróżnicowanym utwierdzeniu...
-
Electrical properties of nanostructures in lead-silicate glasses and nanocomposites doped with iron oxide
Open Research DataElectrical properties of iron oxide nanostructures observed in silicate glasses and glass-ceramics were studied. Two different sets of glass samples were prepared. The first group of samples has the composition of (50 − 0.5x)SiO2–(50 − 0.5x)PbO– xFe2O3, where x = 15, 20 and 25 (in mol%). Composition of the second group was 50SiO2–(50−x)PbO–xFe2O3, where...
-
Magnetic properties of of lead-silicate glasses and nanocomposites doped with iron oxide
Open Research DataMagnetic properties of iron-doped glasses and glass-ceramics were studied. Two different sets of glass samples were prepared. The first group of samples has the composition of (50 − 0.5x)SiO2–(50 − 0.5x)PbO– xFe2O3, where x = 15 and 20 (in mol%). Composition of the second group was 50SiO2–(50−x)PbO–xFe2O3, where x=15, 20 and 25 (in mol%). All sampleswere...
-
Molecular heteroconjugation equilibria in (n-butylamine + acetic acid) systems in binary (dimethyl sulfoxide + 1,4-dioxane) solvent mixtures
PublicationWyznaczono stałe kwasowe Ka(HA), Ka(BH+) oraz stałe równowagi KAHA-, KBHE+ i KAHB, w układach (n-butyloamina + kwas octowy) bez przeniesienia protonu w binarnych mieszaninach rozpuszczalników (DMSO + 1,4-dioksan). Wartości stałych wyznaczono z wykorzystaniem metody miareczkowania potencjometrycznego przy stałej sile jonowej. Stwierdzono, iż stałe heterokoniugacji molekularnej w badanych mieszaninach rozpuszczalników są liniowo...
-
Thermogravimetric analysis data of hydration in air and nitrogen for BaCe0.6Zr0.2Y0.1M0.1O3-δ (M = Fe, Pr, Tb)
Open Research DataThe dataset consists of 6 files of thermogravimetric analysis (TGA) data. The TGA experiments of hydration for BaCe0.6Zr0.2Y0.1Fe0.1O3-δ (BCZYFe), BaCe0.6Zr0.2Y0.1Pr0.1O3-δ (BCZYPr), and BaCe0.6Zr0.2Y0.1Tb0.1O3-δ (BCZYTb) were conducted on Netzsch STA 449.
-
Water uptake and energetics of the formation of barium zirconate based multicomponent oxides
PublicationA group of multi-component oxides based on BaZrO3 have been prepared using a solid-state reaction method and examined in terms of their water uptake and thermodynamics of formation. Depending on the type and amount of acceptor substitution, the synthesized compounds exhibit various proton defect concentrations, reaching up to 0.2 mol/mol for a compound containing 10 different elements in the B-sublattice, where 50% of them are...
-
Zastosowanie narzędzi ze spoiwem galwanicznym w mikroszlifowaniu powierzchni płaskich
PublicationW pracy przedstawiono wyniki z badań mikroszlifowania powierzchni płaskich w zmodyfikowanym układzie docierarki jednotarczowej z zastosowaniem narzędzi ze spoiwem galwanicznym. Czynną powierzchnię narzędzia pokryto ziarnami diamentowymi D64 i D107 oraz borazonowymi B64 i B107. Badaniom poddane zostały przedmioty wykonane z ceramiki technicznej o średnicy 34 mm.
-
Cavitation erosion degradation of Belzona® coatings
PublicationIn hydrocarbon and maritime industry there is a constant need of materials and coatings withstanding severe conditions. One of adverse phenomena present there is cavitation erosion. The paper presents evaluation of cavitation resistance of three different steel coatings. Belzona 2141 (ACR-Fluid Elastormer), 1321 (Ceramic S-Steal) and 5831 (ST-Barrier) were deployed on P110 steel and subjected to ultrasound cavitation in distilled...
-
Degradation of metal implants covered with silver
PublicationSilver was known for its antibacterial properties as long ago as in antiquity. The silver ions have ability to join the bacteria surface. Low density of silver ions Ag+ influence the protons through the bacteria surface, which results in total destruction of the cell. Antibacterial activity of silver remains in proportion with the density of silver ions Ag+ in the environment.
-
Electric and magnetic properties of Lanthanum Barium Cobaltite
PublicationThe cubic Ba0.5La0.5CoO3‐δ was synthesized using solid state reaction. The structural properties were determined by the simultaneous refinement of Synchrotron Powder X‐ray Diffraction and Neutron Powder Diffraction data. Iodometric titration was used to examine the oxygen stoichiometry and average cobalt oxidation state. Low‐temperature magnetic studies show soft ferromagnetic character of fully oxidized material, with θP = 198(3)...
-
Electrophoretic co-deposition of Fe2O3 and Mn1,5Co1,5O4: Processing and oxidation performance of Fe-doped Mn-Co coatings for solid oxide cell interconnects
PublicationThe “in-situ” Fe-doping of the manganese cobalt spinel was achieved by electrophoretic co-deposition of Mn1,5Co1,5O4 and Fe2O3 powders followed by a two-step reactive sintering treatment. The effects on the coating properties of two different Fe-doping levels (5 and 10 wt.% respectively) and two different temperatures of the reducing treatment (900 and 1000 °C) are discussed. Samples with Fe-doped coatings demonstrated a lower...
-
Low temperature deposition of dense MnCo 2 O 4 protective coatings for steel interconnects of solid oxide cells
PublicationIn this work manganese cobalt spinel (MnCo2O4) coatings were deposited on steel substrates by spray pyrolysis at 390 °C. This is at much lower temperatures than previously reported (typically in excess of 900 °C). It was possible to produce coatings with well controlled thickness (2-5-10 μm). The as-deposited coatings were evaluated for their microstructural changes and electrical conductivity up to 800 °C. Results confirm the...
-
Preparation and characterisation of iron substituted Mn1.7Cu1.3-xFexO4 spinel oxides (x = 0, 0.1, 0.3, 0.5)
PublicationSpinel oxides with the general formula Mn1.7Cu1.3-xFexO4 (x= 0, 0.1, 0.3, 0.5) were prepared and evaluated in this work for their properties at high temperatures. The effect of partially substituting Cu by Fe has not been studied so far for this group of materials and is thus evaluated in this work. Mn1.7Cu1.3-xFexO4 powders were synthesised by a soft chemistry process and studied in terms of crystallographic phase analysis, electrical...
-
Processing of Ce0.8Gd0.2O2-δ barrier layers for solid oxide cells: The effect of preparation method and thickness on the interdiffusion and electrochemical performance
PublicationCe0.8Gd0.2O1.9 (CGO) barrier layers are required to mitigate the chemical reactions between Sr-containing oxygen electrode materials and Zr-based oxygen ion conductors in high-temperature solid oxide cells. Barrier layers produced by different methods were studied in this work. As a reference, a cell with no barrier layer was measured. The application of the powder-processed barrier layers, considerably increases the performance....
-
Evaluation of 316L porous stainless steel for SOFC support
PublicationW pracy przedstawiono wyniki badań stali typu 316L związanych z zastosowaniem w tlenowych ogniwach paliwowych.
-
Physicochemical properties of rock salt-type ordered Sr2MMoO6 (M=Mg, Mn, Fe, Co, Ni) double perovskites
Publication -
Influence of free carbon on the Young's modulus and hardness of polymer‐derived silicon oxycarbide glasses
Publication -
Processing of polymer‐derived, aerogel‐filled, SiC foams for high‐temperature insulation
Publication -
Structural phase transitions in multicomponent La0.2Nd0.2Sm0.2Gd0.2RE50.2NbO4 (RE5 = Ho, Y, Tb, Eu, Pr) oxides
PublicationIn this work, the influence of compositional complexity on the structural and thermal properties of multicomponent rare-earth ortho-niobates from the La0.2Nd0.2Sm0.2Gd0.2RE50.2NbO4 (RE5 = Ho, Y, Tb, Eu, Pr) series have been investigated. Based on X-ray powder diffraction studies using synchrotron radiation, it was found that all tested materials were pure single-phase compositions and showed stability in the monoclinic I2/c crystal...
-
CuMn1.7Fe0.3O4 – RE2O3 (RE=Y, Gd) bilayers as protective interconnect coatings for Solid Oxide Cells
PublicationEfficient replacement of materials based on critical elements such as cobalt is one of the greatest challenges facing the field of solid oxide cells. New generation materials, free of cobalt show potential to replace conventional materials. However, these materials are characterized by poor ability to block chromium diffusion. This article described the study of CuMn1.7Fe0.3O4 (CMFO) spinel combined with single metal oxide (Y2O3...
-
Fabrication of wormhole-like YSZ and Ni-YSZ by the novel soft-hard template CTAB/NaCl-assisted route. Suppressing Ni coalescence in SOFC
PublicationA novel one-pot synthesis route leading to the formation of a wormhole-like structure was developed for the successful fabrication of porous YSZ and Ni-YSZ systems. This method involved co-precipitation in the presence of the micelle-forming agents CTAB/Pluronic P123 and crystallising NaCl. The obtained skeletons were mechanically stable and presented almost 50% uniform, open porosity without using any additional pore-formers....
-
Three electrode configuration measurements of electrolyte-diffusion barrier-cathode interface
PublicationMeasurements of a system consisting of cathode/doped ceria diffusion barrier/doped zirconia electrolyte were made using two- and three-electrode configuration. Results obtained on a three-electrode measurement configuration were compared with and reflect the results obtained in two-electrode configuration. Three-electrode measurements allowed separating the impact of the symmetrical interface in the investigated system. They also...
-
Coatings for improvement of high temperature corrosion resistance of porous alloys
PublicationPorowate stopy metaliczne są potencjalnymi podłożami nośnymi dla tlenkowych ogniw paliwo. Ich stosowanie obniża cenę ogniw paliwowych, co zaowocuje ich szybszą komercjalizacą. Jednak są one podatne na korozję w wysokich temperaturach. Dotychczas brak jest metod, które mogą poprawić rezystancję korozyjną porotawych stopów w wysokich temperaturach porowatych stopy do zastosowań SOFC. W tym artykule zaproponowano sposób na poprawę...
-
Comparison of Cu1.3Mn1.7O4 spinels doped with Ni or Fe and synthesized via wet chemistry and solid-state reaction methods, designed as potential coating materials for metallic interconnects
PublicationThe influence of the method applied to synthesize Cu-Mn-O spinel was evaluated. The methods selected for the investigation were EDTA gel processes and solid-state reaction synthesis. From the obtained powders, sinters were prepared and assessed in terms of their properties as potential coating materials. Additionally, the influence of Ni and Fe dopants was evaluated. The results show that the EDTA gel processes method seems to...
-
Elucidating photoluminescent properties of Eu‐doped Ca–Al–Si–O(–N) glasses and the local structures of Eu ions
PublicationEuropium (Eu) ion–doped luminescent materials have attracted considerable attention for their numerous optical applications. Eu-doped Ca–Al–Si–O(–N) glasses were synthesized from a mixture of oxynitride glasses and Eu2O3 powder using a standard melt-quenching technique in a radiofrequency furnace. The source Eu trivalent ions primarily changed to Eu2+ during melting, and the ratio of Eu2+ ions increased with an increase in Eu content...
-
Electrophoretic co-deposition of Mn1.5Co1.5O4, Fe2O3 and CuO: Unravelling the effect of simultaneous addition of Cu and Fe on the microstructural, thermo-mechanical and corrosion properties of in-situ modified spinel coatings for solid oxide cell interconnects
PublicationA systematic microstructural, thermo-mechanical and electrical characterization of simultaneous Fe–Cu doped Mn–Co spinel coatings processed by electrophoretic co-deposition on Crofer 22 APU is here reported and discussed. An innovative approach for the simultaneous electrophoretic deposition of three spinel precursors is designed, conceived and optimised, with the aim of outlining time- and energy-saving spinel modification routes....
-
Characteristics of La0.8Sr0.2Ga0.8Mg0.2O3-delta -supported micro-tubular solid oxide fuel cells with bi-layer and tri-layer electrolytes
PublicationIn this study, La0.8Sr0.2Ga0.8Mg0.2O3−δ (LSGM)-supported micro tubular solid oxide fuel cells (T-SOFCs) with two different configurations, one containing an LSGM–Ce0.6La0.4O2−δ (LDC) bi-layer electrolyte (Cell A) and one containing an LDC–LSGM–LDC tri-layer electrolyte (Cell B), were fabricated using extrusion and dip-coating. After optimizing the paste formulation for extrusion, the flexural strength of the dense and uniform LSGM...
-
La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3-δ oxygen electrodes for solid oxide cells prepared by polymer precursor and nitrates solution infiltration into gadolinium doped ceria backbone
PublicationInfiltration is a method, which can be applied for the electrode preparation. In this paper oxygen electrode is prepared solely by the infiltration of La0.6Sr0.4Co0.2Fe0.8O3‐δ (LSCF) into Ce0.8Gd0.2O2-δ (CGO) backbone. The use a polymer precursor as an infiltrating medium, instead of an aqueous nitrate salts solution is presented. It is shown that the polymer forms the single-phase perovskite at 600 °C, contrary to the nitrates...
-
Niskokoherentny, interferometryczny system do badaniawłaściwości materiałów ceramicznych
PublicationPrzedstawiono światłowodowy system dwuwymiarowej wizualizacjiniejednorodnych struktur warstw ceramicznych. Omówiono projekti fizyczną realizację układu wykorzystującego optyczną, niskokoherentną reflektometrię optyczną, która umożliwia nieinwazyjne i bezkontaktowe obrazowanie wewnętrznych struktur różnych materiałówsilnie rozpraszających promieniowanie. Przedstawiono przykładowewyniki pomiarów wewnętrznych warstw ceramiki LSFO....
-
Zagospodarowanie proszku krzemowego, wytworzonego z odzyskanych w procesie recyklingu uszkodzonych ogniw modułów fotowoltaicznych = Utilization of silicon powder, recovered in the PV cell's production and recycling processes
PublicationW artykule przedstawiono wyniki analizy proszku krzemowego różnego pochodzenia i wskazano możliwości technologiczne zagospodarowania proszku krzemowego: jako podstawowego surowca do produkcji nowych ogniw fotowoltaicznych, jako dodatku do stali stopowych, poprawiających ich własności mechaniczne (twardość, wytrzymałość na rozciąganie, udarność) oraz jako materiału do wytwarzania ceramiki, bazującej na proszkach niemetali.
-
Characterization of PLZT Thin Films for Fast Electro-Optical Sampling Circuits
PublicationW artykule omówiono technologię wytwarzania cienkich warstw wybranych kompozycji ceramik ołowiowo-lantanowo-cyrkonowo-tytanowych, nazywanych ceramikami PLZT. Przedstawiono wyniki badań jakości warstw za pomocą techniki XRD. wyniki pomiaru grubości warstw, ich względnej przenikalności dielektrycznej i współczynnika załamania. Omówiono kierunki dalszych prac.
-
Superadditivity of two quantum information resources
PublicationEntanglement is one of the most puzzling features of quantum theory and a principal resource for quantum information processing. It is well known that in classical information theory, the addition of two classical information resources will not lead to any extra advantages. On the contrary, in quantum information, a spectacular phenomenon of the superadditivity of two quantum information resources emerges. It shows that quantum...
-
Ewa Kamieńska-Piotrowicz dr hab. inż.
People -
Odporność splątania w układach wielocząstkowych na lokalny szum - wyjazd badawczy do ICFO - The Institute of Photonic Sciences
ProjectsProject realized in Katedra Fizyki Atomowej, Molekularnej i Optycznej from 2018-10-19
-
Wear in siding friction tests. Ring-on-ring contact. Sintered alumina ceramics (98%). Paraffin oil lubrication. Specim. sets #20-#21, #22-#23, #24-#25, #26-#27, #28-#29,#30 - #31. Run time: 0-4h. High frequency burst recording.
Open Research DataWear in sliding friction tests in ring-on-ring contact. Sintered alumina ceramics (98%) in self-mated contact. Lubrication: paraffin oil. Sliding velocity: 0.2 m/s. Mean contact stress: 10 MPa. Test rig: PT-3 Tribometer. High frequency burst recording.Running time: 0 - 4h.Specimen sets:Specim. sets (# [upper, rotating] - #[lower, non-rotating]):#20-#21,...
-
Wojciech Sadowski prof. dr hab. inż.
PeopleWojciech Sadowski (born 2 February 1954 in Ostaszewo, Poland), scientist, engineer, professor at Gdansk University of Technology, specialist in solid state body physics, nanotechnology, optoelectronics. In 1973 he completed his high school education at High School Nicolaus Copernicus in Chelmno. In 1979 he graduate from Leningrad Electrotechnical Institute in Russia (former Soviet Union) with specialism in dielectrics and semiconductors....
-
Conductivity, structure, and thermodynamics of Y2Ti2O7–Y3NbO7 solid solutions
PublicationThe defect fluorite yttrium niobate Y3NbO7 and pyrochlore yttrium titanate Y2Ti2O7 solid solutions have been synthesized via a solid state synthesis route. The resulting stoichiometry of the oxides is Y2+xTi2−2xNbxO7, where x = 0 to x = 1. All of the samples were single-phase; however, for those with a predominant fluorite phase, a small amount of additional pyrochlore phase was detected. The volume of the solid solution unit cells...
-
Educational and cognitive aspects of adaptation of nonuse spaces in monumental sacral objects.
PublicationThe area of attics and towers in historic churches in Europe are yet quite inaccessible places for visitors, shrouded in the atmosphere of mysticism, hiding many secrets. Introduction of the new public function into the non-used zones of the monumental sacral objects has many aspects including educational and cognitive ones which are discussed in the following article. The article indicates items that can be found in the zone above...
-
A review: Fabrication of porous polyurethane scaffolds
PublicationThe aim of tissue engineering is the fabrication of three-dimensional scaffolds that can be used for the reconstruction and regeneration of damaged or deformed tissues and organs. A wide variety of techniques have been developed to create either fibrous or porous scaffolds from polymers, metals, composite materials and ceramics. However, the most promising materials are biodegradable polymers due to their comprehensive mechanical...
-
Impact of strontium non-stoichiometry of SrxTi0.3Fe0.7O3-δ on structural, electrical, and electrochemical properties for potential oxygen electrode of intermediate temperature solid oxide cells
PublicationThis work presents the results of a comprehensive study on the impact of the A-site non-stoichiometry of SrxTi0.3Fe0.7O3-δ (x = 0.90, 0.95, 1.00, 1.05) ceramics on their physicochemical properties. The materials were fabricated by the conventional solid-state reaction method and their structure was determined by X-ray diffractometry, X-ray photoelectron spectroscopy and electron microscopy. Their sintering and thermal expansion...
-
Materiały dla jednowarstwowych ogniw paliwowych
PublicationA composite material, which may be further applied as a single layer fuel cell, was synthesizes using solid state synthesis method. Composite consisted of two components. The first was a nanoeramic proton conductor - calcium doped lanthanum niobate. The second one was a nanoceramic semiconductor oxide composed of lithium, nickel and zinc oxides respectively.
-
Structural change of carbon supported Pt nanocatalyst subjected to a step-like potential cycling in PEM FC
PublicationIn this paper we present detailed X-ray absorption fine structure (XAFS), X-ray diffraction (XRD) and transmission electron microscopy (TEM) investigations of the changes in the local geometric and electronic structure of Pt nanoparticles used as a cathode catalyst in proton exchange membrane fuel cell (PEMFC), working under controlled potential cycling conditions.
-
Nanokrystaliczne warstwy ceramiczne otrzymywane metodą pirolizy aerozolowej w tlenkowych ogniwach paliwowych
PublicationNiniejsza rozprawa doktorska dotyczy badań materiałów wytwarzanych w postaci cienkich, nanokrystalicznych warstw ceramicznych metodą pirolizy aerozolowej dla zastosowań w tlenkowych ogniwach paliwowych (SOFC). Badane są trzy możliwe obszary zastosowań wytwarzanych warstw tj. osadzanie powłok ochronnych na stalowych interkonektorach dostarczających gazy do elektrody tlenowej, wytwarzanie bariery ochronnej zapobiegającej dyfuzji...
-
Materials for energy storage and conversion devices 2022/2023
e-Learning CoursesElectrodes: Metals as electrodes in aqueous and non-aqueous systems, metal nanoparticles. Collectors current. 3D, 2D, 1 D carbons, carbon nanomaterials. Organic semiconductors "Synthetic metals" - p-type, n-type. Inorganic semiconductors: oxides, selenides, sulfides, others. Intercalated electrodes. Mixed conductors (MIEC). Photo-active semiconductor materials. Electrolytes. Water electrolytes in commercial products. Electroactive...