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Search results for: ZCS
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Coking Study in Anode Materials for SOFCs: Physicochemical Properties and Behavior of Mo-Containing Perovskites in CO and CH4 Fuels
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Efficient and Economically Favorable Co-Free Air Electrodes for Solid Oxide Cells
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Operando EPR Study of Radical Formation in Anion-Exchange Membrane Fuel Cells
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Selective Adsorption of Methyl Orange and Methylene Blue by Porous Carbon Material Prepared From Potassium Citrate
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Reference Electrodes with Ionic Liquid Salt Bridge: When Will These Innovative Novel Reference Electrodes Gain Broad Acceptance?
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Kinetic Description of the Membrane–Solution Interface for Ion-Selective Electrodes
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Engineering a de Novo Transport Tunnel
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Tailoring Diffusional Fields in Zwitterion/Dopamine Copolymer Electropolymerized at Carbon Nanowalls for Sensitive Recognition of Neurotransmitters
PublicationThe importance of neurotransmitter sensing in the diagnosis and treatment of many psychological illnesses and neurodegenerative diseases is non-negotiable. For electrochemical sensors to become widespread and accurate, a long journey must be undertaken for each device, from understanding the materials at the molecular level to real applications in biological fluids. We report a modification of diamondized boron-doped carbon nanowalls...
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Synthesis Attempt and Structural Studies of Novel A2CeWO6 Double Perovskites (A2+ = Ba, Ca) in and outside of Ambient Conditions
PublicationSynthesis Attempt and Structural Studies of Novel A 2 CeWO 6 Double Perovskites (A 2+ = Ba, Ca) in and outside of Ambient Conditions Damian Wlodarczyk,* Mikolaj Amilusik, Katarzyna M. Kosyl, Maciej Chrunik, Krystyna Lawniczak-Jablonska, Michal Strankowski, Marcin Zajac, Volodymyr Tsiumra, Aneta Grochot, Anna Reszka, Andrzej Suchocki, Tomasz Giela, Przemyslaw Iwanowski, Michal Bockowski, and Hanka Przybylinska Cite This: ACS Omega...
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Organic Vapor Sensing Mechanisms by Large-Area Graphene Back-Gated Field-Effect Transistors under UV Irradiation
PublicationThe gas sensing properties of graphene back-gated field-effect transistor (GFET) sensors toward acetonitrile, tetrahydrofuran, and chloroform vapors were investigated with the focus on unfolding possible gas detection mechanisms. The FET configuration of the sensor device enabled gate voltage tuning for enhanced measurements of changes in DC electrical characteristics. Electrical measurements were combined with a fluctuation-enhanced...
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Nanodiamonds Doped with Manganese for Applications in Magnetic Resonance Imaging
PublicationNanodiamonds (NDs) are emerging with great potential in biomedical applications like biomarking through fluorescence and magnetic resonance imaging (MRI), targeted drug delivery, and cancer therapy. The magnetic and optical properties of NDs could be tuned by selective doping. Therefore, we report multifunctional manganese-incorporated NDs (Mn-NDs) fabricated by Mn ion implantation. The fluorescent properties of Mn-NDs were tuned...
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Materials for Mediator-free Electron Transfer in the Enzymatic Electrodes of Biobatteries and Biofuel Cells
PublicationWe present functionalization of single-walled carbon nanotubes (SWCNTs) and their application in the enzymatic fuel cells construction. SWCNTs were covalently modified with different types of aromatic moieties. Free radical reaction was employed to create direct carbon-carbon bond between moiety and SWCNTs. In second approach functionalization takes place through amide bonding. Functionalized SWCNTs were characterized by spectroscopy...
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Photocatalytically Active TiO2/Ag2O Nanotube Arrays Interlaced with Silver Nanoparticles Obtained from the One-Step Anodic Oxidation of Ti–Ag Alloys
PublicationThe development of a photocatalyst with remarkable activity to degrade pollutants in aqueous and gas phase requires visible lightresponsive stable materials, easily organized in the form of a thin layer (to exclude the highly expensive separation step). In this work, we present a one-step strategy for synthesizing material in the form of a self-organized TiO2/Ag2O nanotube (NT) array interlaced with silver nanoparticles (as in a...
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Evaluation of Praseodymium and Gadolinium Doped Ceria as a Possible Barrier Layer Material for Solid Oxide Cells
PublicationIn this work, nanocrystalline layers based on the Pr, Gd co-doped CeO2 were investigated. For the preparation of thin layers, lowtemperature spray pyrolysis technique was used. Different stoichiometries of the layers were produced for comparison on polished sapphire substrates. The microstructure of the prepared thin layers was studied by scanning electron microscopy (SEM), energydispersive X-ray spectroscopy (EDS) and X-ray diffractometry (XRD)....
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Randomly Functionalized Polyethylenes: In Quest of Avoiding Catalyst Deactivation
PublicationWell-defined randomly functionalized polyolefins produced by catalysis form an interesting class of polymers with great potential for various applications. One of the major challenges for the production of these materials forms the incompatibility of the commonly used electrophilic group 4 metal based catalysts and the desired nucleophilic, especially protic functionalities like hydroxyl and carboxylic acid groups. Although pacification...
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The Influence of Iron Doping on Performance of SrTi1-XFexO3-δ Perovskite Oxygen Electrode for SOFC
PublicationSolid Oxide Fuel Cells (SOFC) are based on electrolytes and mixed ionic and electronic conductivity (MIEC) materials. The need to reduce costs causes an increase in interest of new compounds suitable for operating temperatures between 600 °C and 800 °C. The SrTi1-xFexO3 (STF) perovskite material is a perspective material that could be used for the oxygen electrodes. In this work STF materials with different content of iron (x =...
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Effects of Na+, K+ and B3+ Substitutions on the Electrical Properties of La10Si6O27 Ceramics
PublicationDoping of Na and K at La sites and of B at Si site in La10Si6O27 with oxyapatite structure and fabrication of their ceramics were made by solid-state reaction method. It was found that partial substitution of Na+ and K+ on La sites decreased the sinterability of the La10Si6O27 based ceramics, whereas partial substitution of B3+ on Si site imporved the sinterability. Na+ and K+ substitutions in La10-xNaxSi6O27-x and La10-xKxSi6O27-x...
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Spray-BasedMethodforProtectingandRestoringHistoricAdobe WallsUsingNanomontmorilloniteClay
PublicationRestoringandprotectinghistoricbuildingsworldwideareimportant becauseheritagebuildingsarerecordsofthecivilizationsofvariouscountries.Herein, nanotechnologywasusedtorestorehistoricadobewalls.AccordingtotheIranPatent andTrademarkOffice(IRPATENT)102665,nanomontmorilloniteclayhasbeen selectedasanaturalandcompatiblematerialwithadobe.Furthermore,ithasbeenused asnanospraytobeaminimallyinvasivemethodtofillcavitiesandcracksintheadobe surface.Variouspercentagesofnanomontmorilloniteclay(1−4%)intheethanolsolvent...
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Optimum Choice of Randomly Oriented Carbon Nanotube Networks for UV-Assisted Gas Sensing Applications
PublicationWe investigated the noise and photoresponse characteristics of various optical transparencies of nanotube networks to identify an optimal randomly oriented network of carbon nanotube (CNT)-based devices for UV-assisted gas sensing applications. Our investigation reveals that all of the studied devices demonstrate negative photoconductivity upon exposure to UV light. Our studies confirm the effect of UV irradiation on the electrical...
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Signature of Oxide-Ion Conduction in Alkaline-Earth-Metal-Doped Y3GaO6
PublicationWe have studied alkaline-earth-metal-doped Y3GaO6 as a new family of oxide-ion conductor. Solid solutions of Y3GaO6 and 2% −Ca2+-, −Sr2+-, and −Ba2+-doped Y3GaO6, i.e., Y(3−0.06)M0.06GaO6−δ (M = Ca2+, Sr2+, and Ba2+), were prepared via a conventional solid-state reaction route. X-ray Rietveld refined diffractograms of all the compositions showed the formation of an orthorhombic structure having the Cmc21 space group. Scanning electron...
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Effects of Bromine Doping on the Structural Properties and Band Gap of CH3NH3Pb(I1–xBrx)3 Perovskite
PublicationAn experimental and theoretical study is reported to investigate the influence of bromine doping on CH3NH3Pb(I1−xBrx)3 perovskite for Br compositions ranging from x = 0 to x = 0.1, in which the material remains in the tetragonal phase. The experimental band gap is deduced from UV−vis absorption spectroscopy and displays a linear behavior as a function of bromine concentration. Density functional theory calculations are performed...
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Bismuth-Doped Nano Zerovalent Iron: A Novel Catalyst for Chloramphenicol Degradation and Hydrogen Production
PublicationIn this study, we showed that doping bismuth (Bi) at the surface of Fe0 (Bi/Fe0, bimetallic iron system)—synthesized by a simple borohydride reduction method—can considerably accelerate the reductive degradation of chloramphenicol (CHP). At a reaction time of 12 min, 62, 68, 74, 95, and 82% degradation of CHP was achieved with Fe0, Bi/Fe0-1 [1% (w/w) of Bi], Bi/Fe0-3 [3% (w/w) of Bi], Bi/Fe0-5 [5% (w/w) of Bi], and Bi/Fe0-8 [8%...
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Catalytic Mechanism of Non-Target DNA Cleavage in CRISPR-Cas9 Revealed by Ab Initio Molecular Dynamics
PublicationCRISPR-Cas9 is a cutting-edge genome editing technology, which uses the endonuclease Cas9 to introduce mutations at desired sites of the genome. This revolutionary tool is promising to treat a myriad of human genetic diseases. Nevertheless, the molecular basis of DNA cleavage, which is a fundamental step for genome editing, has not been established. Here, quantum–classical molecular dynamics (MD) and free energy methods are used...
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Andrzej Chybicki dr inż.
PeopleA graduate of the Faculty of Electronics, Telecommunications and Informatics at the Gdańsk University of Technology, PhD in technical sciences in the field of IT specializing in distributed data processing in IT . Aimed at exploiting the achievements and knowledge in the field of industrial research. He cooperated with a number of companies including OpeGieka Elbląg, Reson Inc., Powel Sp. z o. o., Wasat, Better Solutions, the European...
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ZARZĄDZANIE BEZPIECZEŃSTWEM INFORMACJI [2021/22]
e-Learning CoursesSemestr II Cel: Przekazanie aktualnej wiedzy dotyczącej analizy bezpieczeństwa i ochrony systemów technicznych przydatnej w projektowaniu i ocenie rozwiązań technologii operacyjnej OT, przemysłowego systemu sterowania ICS, technologii informacyjnych IT oraz technologii chmurowej CT i 5G w nawiązaniu do zasad inżynierii systemów.
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Low Cost Method for Location Service in the WCDMA System
PublicationA new and low cost method for a location service (LCS) in the Wideband Code Division Multiple Access (WCDMA) system is outlined. This method, which is called TDOA + RTT, enables calculation of the geographical position of a mobile station (MS) without knowledge of relative time differences (RTDs) between base stations (BSs). The TDOA+RTT method is based on the measurement of round trip times (RTTs) between the MS and the serving...
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Automatic Correction of Non-Anechoic Antenna Measurements using Low-Pass Filters
PublicationPrototype measurements belong to key steps in the development of antenna structures. They are normally performed in expensive facilities, such as anechoic chambers (ACs). Alternatively, antenna performance can be extracted (at a low cost) in non-anechoic conditions upon appropriate post-processing. Unfortunately, existing correction algorithms are difficult to set up and prone to failure, which limits their practical usefulness....
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Comparative analysis of three‐phase dual active bridge converter with different transformer topology and modern universal control for DC microgrids
PublicationThe presented work discusses issues related to the use of modern multiphase topologies of Dual Active Bridge (DAB)-type converters. Converters of this type are widely used in most DC microgrid applications. The introduction emphasizes a comparative analysis between single-phase and multi-phase DAB topologies within high-power DC microgrids, delving into their respective advantages, drawbacks, design procedures, and considerations...
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Micro‑ and nano‑ bentonite to improve the strength of clayey sand as a nano soil‑improvement technique
PublicationNano-additives results in the formation of nano-cementation (NC). This process is recently used to improve the durability of various building materials. NC used to improve the strength of untreated soil materials, also known as nano soil-improvement (NSI). In few years, the role of nano-additives in various types of soils were developed. In this research, the role of micro- and nano- size of bentonite as soil stabilizer was evaluated...
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BEZPIECZEŃSTWO W ENERGETYCE [2023/24]
e-Learning CoursesSemestr VII Cel: Przekazanie aktualnej wiedzy dotyczącej analizy niezawodności, bezpieczeństwa i ochrony obiektów energetyki przydatnej w projektowaniu i ocenie rozwiązań technologii operacyjnej OT, przemysłowego systemu sterowania ICS oraz technologii informacyjnych IT w nawiązaniu do zasad inżynierii systemów. Aspekty środowiskowe i bezpieczeństwa rozwoju energetyki jądrowej.
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Functional safety with cybersecurity for the control and protection systems on example of the oil port infrastructure
PublicationSafety and cybersecurity aspects consist of two different group of functional requirements for the industrial control and protection systems in the oil port installation. It is the main reason why the analyses of safety and cybersecurity shouldn’t be integrated directly. These article presented some important issues of the functional safety analysis with regard to cybersecurity aspects in the oil seaport infrastructure. The proposed...
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Małe stacje kolejowe - perstektywa adaptacji i szansa na przetrwanie
PublicationPonad 150 letni czas funkcjonowania kolei, to zarówno czs szybkiego rozwoju, na początku XX wieku i w okresie międzywojennym, gdy nastąpił szybki rozwój liczby nowych, ważnych odcinków kolejowych, oraz okres załamania, które obserwujemy od kilkudziesięciu lat. Przez początkowe dziesięsiolecia powstało wiele obiektów stacji kolejowych i obiektów towarzyszących, które w chwil obecnej wymagają pilej interwencji, by nieużytkowane,...
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Absencja chorobowa - szacunek niewytworzonego PKB
PublicationKoszty pośrednie spowodowane absencją chorobową bądź prezenteizmem pracowników są sporadycznie uwzględniane w polskich analizach ekonomicznych. Nie szacuje się wielkości utraconego PKB na skutek chorób, przedwczesnych zgonów, długiego dochodzenia do zdrowia oraz nie uwzględnia w wycenach farmakoekonomicznych. Brakuje jednolitej metodologii obliczania kosztów pośrednich. Celem opracowania jest oszacowanie, ile gospodarka narodowa...
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Zastosowanie modelu opad-odpływ do oszacowania spływu wód opadowych z górnej części zlewni potoku Strzyża w Gdańsku, poprzedzającego awarię zbiornika Nowiec II
PublicationW publikacji przedstawiono hydrologiczną charakterystykę zlewni górnej Strzyży w Gdańsku. Opracowano numeryczny model zlewni oparty na systemie obliczeniowym HEC-HMS. Do obliczeń wykorzystano metody proponowane przez SCS. Za pomocą stworzonego modelu wykonano symulację odpływu ze zlewni będącego skutkiem zaobserwowanego i zmierzonego intensywnego epizodu deszczowego. Opad ten wystąpił we wrześniu 2010 roku. Cały zanotowany epizod...
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Procedure based functional safety and information security management of industrial automation and control systems on example of the oil port installations
PublicationThe approach addresses selected technical and organization aspects of risk mitigation in the oil port installations with regard to functional safety and security requirements specified in standards IEC 61508, IEC 61511 and IEC 62443. The procedure for functional safety management includes the hazard identification, risk analysis and assessment, specification of overall safety requirements and definition of...
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Dylematy wyboru geosyntetyków w konstrukcjach
PublicationPrzedstawiono problemy wyborudylematy związane z wyborem rodzaju konstrukcji oraz rodzaju Przedstawiono problemy związane z wyborem wyrobu geosyntetycznego z uwzględnieniem kryteriów technicznych i ekoniomicznych możliwych rozwiązań.
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The influence of fuel type on heat balance of medium-speed engine
PublicationW artykule zaprezentowano analizę wpływu rodzaju zastosowanego paliwa na bilans cieplny silników średnioobrotowych stosowanych w energetyce stacjonarnej. Przedmiotem analizy są silniki ZS i ZI zasilane gazem ziemnym oraz silniki ZS zasilane olejem napędowym. Dodatkowo analizę uzupełniono o wyniki obliczeń wykonanych dla silników dwupaliwowych, tzn. silników, w których zapłon mieszanki paliwowo gazowej realizowany jest przez pilotażowy...
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Accumulation of radioisotopes and heavy metals in selected species of mushrooms
PublicationSeven species of forest mushrooms from different regions of Poland (edible: Imleria badia, Cantharellus cibarius, Xerocomus subtomentosus, Suillus luteus and inedible by humans but being food for animals: Paxillus involutus, Tylopilus felleus and Russula emetica) were analyzed for radioisotope activity (Cs-137, K-40, Bi-214 and Pb-210) as well as concentrations of heavy metals (aluminum, chromium, cadmium, manganese, iron, lead,...
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Structural, magnetic and spectral properties of tetrahedral cobalt(II) silanethiolates: a variety of structures and manifestation of field-induced slow magnetic relaxation
PublicationBlue crystals of five heteroleptic cobalt(II) silanethiolates 1–5 have been obtained by the reaction of [Co{SSi (tBuO)3}2(NH3)]2 with aminopyridines and aminomethylpyridines at an appropriate molar ratio and their structural, spectral, thermal and magnetic properties have been established and described. All complexes 1–5 contain Co(II) ions in a tetrahedral CoN2S2 environment formed by (tBuO)3SiS− residues and pyridines and present...
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Integrated approach for functional safety and cyber security management in maritime critical infrastructures
PublicationThe work is devoted important issues of the management in maritime critical infrastructure of functional safety analysis, in particular the safety integrity level (SIL) verification of safety functions to be implemented within the distributed control and protection systems with regard to cyber security aspects. A method based on quantitative and qualitative information is proposed for the SIL (IEC 61508, 61511) verification with...
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A Perspective on Fast-SPICE Simulation Technology
PublicationThis chapter presents an introduction to the area of accelerated transistor-level (‘fast-SPICE’) simulation for automated verification and characterization of integrated circuits (ICs) from technologist’s perspective. It starts with outlining goals, expectations and typical usage models for fast-SPICE simulators, stressing how they differ from regular SPICE tools. It continues with presenting and classifying core technologies typically...
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Analogue CMOS ASICs in Image Processing Systems
PublicationIn this paper a survey of analog application specific integrated circuits (ASICs) for low-level image processing, called vision chips, is presented. Due to the specific requirements, the vision chips are designed using different architectures best suited to their functions. The main types of the vision chip architectures and their properties are presented and characterized on selected examples of prototype integrated circuits (ICs)...
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Nano-structured Pt embedded in acidic salts of heteropolymolybdate matrices: MS EXAFS study
PublicationA structural study of Pt nano-catalysts is presented in the paper. The innovation in the case of the considered catalytic materials resides in the use a meso-microporous inorganic matrix of heteropolyacid salt of composition X2.5H0.5YMo12O40 where X = Rb, Cs and Y = P, Si as a catalyst support. Metallic nanoparticles were created by platinum ions reduction in a hot H2/Argon stream and were mainly located into matrix pores. As the...
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Smart Knowledge Engineering for Cognitive Systems: A Brief Overview
PublicationCognition in computer sciences refers to the ability of a system to learn at scale, reason with purpose, and naturally interact with humans and other smart systems, such as humans do. To enhance intelligence, as well as to introduce cognitive functions into machines, recent studies have brought humans into the loop, turning the system into a human–AI hybrid. To effectively integrate and manipulate hybrid knowledge, suitable technologies...
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TDOA versus ATDOA for wide area multilateration system
PublicationThis paper outlines a new method of a location service (LCS) in the asynchronous wireless networks (AWNs) where the nodes (base stations) operate asynchronously in relation to one another. This method, called asynchronous time difference of arrival (ATDOA), enables the calculation of the position of the mobile object (MO) through the measurements taken by a set of non-synchronized fixed nodes and is based on the measurement of...
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Determination of nine high-intensity sweeteners in various foods by high-performance liquid chromatography with mass spectrometric detection
PublicationAn analytical procedure involving solid-phase extraction (SPE) and high-performance liquid chromatography-mass spectrometry has been developed for the determination of nine high-intensity sweeteners authorised in the EU; acesulfame-K (ACS-K), aspartame (ASP), alitame (ALI), cyclamate (CYC), dulcin (DUL), neohesperidin dihydrochalcone (NHDC), neotame (NEO), saccharin (SAC) and sucralose (SCL) in a variety of food samples (i.e. beverages,...
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Model of process of wear sidle bearings of self ignition combustion engine
PublicationW artykule została podjęta próba przeanalizowania praktycznej przydatności modelu procesu zużycia głównych łożysk ślizgowych silnika spalinowego o ZS, opisującego zmienną szybkość ich zużycia. Analizie został poddany problem częstych zatrzymań i rozruchów silnika, gdyż z badań statystycznych wynika, że w tym czasie występuje największe zużycie łożysk ślizgowych.
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Selected problems of determining an efficient operation standard in contemporary heat-and-flow diagnostics
PublicationW referacie wymieniono przyczyny powodujące niejednoznaczności i trudności wyznaczania wzorca sprawnej pracy turbinowych siłowni lądowych i morskich. Przeanalizowano dwie z tych przyczyn: obniżenie wartości parametrów dolotowych czynników roboczych oraz zmiany w konfiguracji połączeń pomiędzy urządzeniami składowymi obiegów cieplnych. Jako remedium na wynikające stąd trudności zaproponowano model obliczeniowy obiegu cieplnego o...
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Numerical analysis of the container vessel's self-propulsion at different rudder deflection angles
PublicationNowadays, CFD becomes one of the most commonly used research method in ship hydrodynamics, limited to the analyses of hull resistance in calm water. With continuously improving computing power and increasingly more accurate numerical methods it is possible to simulate more complex cases. State of the art CFD tools also enable development of new ways of assessing ship maneuvering performance. This paper presents an attempt on...
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TIME-DOMAIN NUMERICAL EVALUATION OF SHIP RESISTANCE AND MOTION IN REGULAR WAVES BY USING THE CFD URANS METHOD
PublicationTaking into account the International Maritime Organisation’s (IMO) strategy to radically reduce the GHG emitted by the shipping industry towards zero emission operation, today's assessment of ship behaviour in waves, its seakeeping characteristics and resistance and their interrelation with fuel consumption and emissions are one of the most attended research subject. There are three methods to conduct this analysis, which are...