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Recent advances in hydrodynamic cavitation-based pretreatments of lignocellulosic biomass for valorization
PublikacjaRecently, the hydrodynamic cavitation (HC)-based pretreatment has shown high effectiveness in laboratories and even in industrial productions for conversion of lignocellulosic biomass (LCB) into value-added products. The pretreatment capability derives from the extraordinary conditions of pressures at ∼500 bar, local hotspots with ∼5000 K, and oxidation (hydroxyl radicals) created by HC at room conditions. To promote this emerging...
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Diamond protection for reusable ZnO coated fiber-optic measurement head in optoelectrochemical investigation of bisphenol A
PublikacjaDue to the global problem with plastic contaminating the environment, with bisphenol A (BPA) being one of the highest demand, effective monitoring and purification of the pollutants are required. The electrochemical methods constitute a good solution but, due to polymerization of electrochemical oxidation bisphenol A products and their adsorption to the surfaces, measurement head elements are clogged by the formed film. In this...
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In-situ monitoring of electropolymerization processes at boron-doped diamond electrodes by Mach-Zehnder interferometer
PublikacjaIn this work, the Mach-Zehnder interferometer was designed to monitor the electrochemical processes conducted at boron-doped diamond electrode surface. The diamond electrodes were synthesized via Microwave Plasma-Assisted Chemical Vapor Deposition on optical grade quartz glass. The achieved transmittance in working are of diamond electrodes reached 55 %. A cage system-based Mach-Zehnder interferometer was used which allowed the...
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Uniwersalny program komputerowy do projektowania zmiany kierunku trasy
PublikacjaW pracy przedstawiono kolejny program komputerowy stanowiący implementację algorytmu obliczeniowego dotyczącego projektowania zmiany kierunku trasy kolejowej, dostosowanego do techniki ciągłych pomiarów satelitarnych. Program ten ma charakter uniwersalny, gdyż w ogólnym przypadku obejmuje wprowadzenie do układu geometrycznego dwóch łuków kołowych o różnym promieniu, czyli zastosowanie łuku koszowego. Może się to okazać szczególnie...
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THE APPLICATION EFFECTS OF CONTINUOUS SATELLITE MEASUREMENTS OF RAILWAY LINES
PublikacjaThe paper presents results of satel lite surveying of the railway's rout es, which have been conducted just after starting in Poland (in 2008) the Active Geodesy Network ASG-EU POS. Afterwards it was possible to effectively utilize the GNSS survey ing results for the inventory of the (exploring) railways in service. Already at the beginning of 2009, the research team from Gdansk University of Technology and Naval Academy in Gdynia,...
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Fermi-liquid behavior of binary intermetallic compounds Y3 M (M = Co, Ni, Rh, Pd, Ir, Pt)
PublikacjaA series of polycrystalline samples of Y3 M (M = Co, Ni, Rh, Pd, Ir, Pt), intermetallic binary compounds were synthesized by the arc-melting method. Powder x-ray diffraction (pXRD) confirmed the orthorhombic cementite-type crystal structure and allowed for the estimation of the lattice parameters. Physical properties were investigated by means of electrical resistivity and heat capacity measurements between 1.9 K and 300 K. All...
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Structure redetermination, transport and thermal properties of the YNi3Al9 compound
PublikacjaSingle crystals of completely ordered variant of the YNi3Al9 compound were grown by self-flux method with excess of aluminum. The crystal structure of the title compound was redetermined from single crystal X-ray diffraction data. The structure adopts ErNi3Al9 type, space group R32, parameters of the unit cell a = 7.2838(2) Å, c = 27.4004(8) Å. The growth of relatively large single crystals of the YNi3Al9 compound, having completely...
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Ultrafast high-temperature sintering (UHS) of cerium oxide-based compound
PublikacjaUltrafast high-temperature sintering (UHS) is an innovative sintering technique that can densify ceramics in a few seconds, dramatically reducing the carbon footprint and firing costs. In this work, the feasibility of applying UHS in Gd-doped ceria (GDC) and GDC-Er-stabilized bismuth oxide (ESB) composite powders was investigated. At high UHS currents (22-24 A), a fully dense GDC sample with a large grain size was obtained. Nonetheless,...
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Progress in development of molecularly imprinted polymers as sorbents for sample preparation
PublikacjaSample preparation has been one of the most often investigated steps in analytical procedures.These investigations are focused on problems such as isolation of analytes from the sample matrix, matrix implification, analyte enrichment to the level above the detection limit of the instrumentation used, and the removal of interfering species to improve the final determination. Techniques based on solid (adsorption) and pseudo liquid...
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POSSIBILITY OF ASSESSMENT OF OPERATION OF SLIDING BEARINGS IN PISTON-CRANK MECHANISMS OF DIESEL ENGINES WITH REGARD TO LOAD AND TIME OF CORRECT WORK OF THE BEARINGS BY APPLYING ACOUSTIC EMISSION AS A DIAGNOSTIC SIGNAL
PublikacjaAbstract: The paper presents a possibility of determining (assessing) operation of sliding bearings with multilayer bushings in crank-piston mechanisms of diesel engines. Properties of load and wear, particularly fatigue and abrasive, are characterized in general. Acoustic emission as a diagnostic signal was proved to be useful for detection of the wear of sliding and barrier layers. Results of measurements of acoustic emission...
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Surface characteristics of glass fibres covered with an aluminum layer after a chemical modification process using secondary ion mass spectrometry (SIMS) and atomic force microscopy (AFM)
PublikacjaPrzedstawiono wyniki z badań powierzchni modyfikowanych włókien szklanych (przed i po procesie chemicznej modyfikacji ich powierzchni), które są kandydatem na przyszły oryginalny bezmatrycowy materiał odniesienia lotnych analitów etenu (C2H4) metodami spektrometrii mas jonów wtórnych oraz mikroskopii sił atomowych. Badania miały na celu obserwację zmian oraz procesów, jakie zaszły na powierzchni włókien szklanych pokrytych...
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Metal-Organic Framework (MOF)/Epoxy Coatings: A Review
PublikacjaEpoxy coatings are developing fast in order to meet the requirements of advanced materials and systems. Progress in nanomaterial science and technology has opened a new era of engineering for tailoring the bulk and surface properties of organic coatings, e.g., adhesion to the substrate, anti-corrosion, mechanical, flame-retardant, and self-healing characteristics. Metal-organic frameworks (MOFs), a subclass of coordinative polymers...
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Palm Oil Fuel Ash-Based Eco-Efficient Concrete: A Critical Review of the Short-Term Properties
PublikacjaThe huge demand for concrete is predicted to upsurge due to rapid construction developments. Environmental worries regarding the large amounts of carbon dioxide emanations from cement production have resulted in new ideas to develop supplemental cementing materials, aiming to decrease the cement volume required for making concrete. Palm-oil-fuel-ash (POFA) is an industrial byproduct derived from palm oil waste’s incineration in...
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Cooperation of ORC installation with a gas boiler as a perspective co-generation system for households
PublikacjaThis paper reports tests of an innovative micro-CHP unit prototype, consisting of a traditional gas boiler and organic Rankine cycle (ORC), which incorporates original system components such as an axial vapour microturbine, evaporator and condenser. The system co-generates heat and electricity for a single household or a group of households. Electricity is only a by-product during production of heat. While testing the prototype,...
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Numerical analysis of mechanical properties of an infill structure used in 3D printings
PublikacjaThe paper presents results of a numerical analysis focused on an identification of mechanical properties of an element created by using Fused Deposition Modelling additive manufacturing technique (FDM). There is presented a description of technology of the 3D printing, numerical model created by using the finite element method (FEM), as well as some problems referred to estimation of the mechanical properties of the printout. The...
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Advanced numerical modelling for predicting residual compressive strength of corroded stiffened plates
PublikacjaAn advanced methodology for predicting the residual compressive strength of corroded stiffened plates is developed here using the non-linear finite element method. The non-uniform loss of a plate thickness is accounted for on a macro-scale. In contrast, mechanical properties are changed using the constitutive model to reflect the corrosion degradation impact on a micro-scale. Three different stiffened plate thicknesses are considered,...
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Does being socially good save firms from bankruptcy? A systematic literature review and bibliometric analysis
PublikacjaThe purpose of the review was to find out, does being responsible saves firms from bank-ruptcy? What is the relationship between corporate social responsibility and default risk? What meth-ods and measures are used in the literature to evaluate this relationship? And what is the theoretical underpinning of the studies? Moreover, to explore what are the gaps for future work, Web of Science and Scopus databases were utilised to obtain...
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INTERNATIONALIZATION OF ENTERPRISES IN KAZAKHSTAN AS AN EXAMPLE OF INTERNATIONALIZATION PATTERNS IN THE AREA OF THE EURASIAN ECONOMIC UNION.
PublikacjaThe article aims to show the specificity of the internationalization of Kazakh enterprises, in particular, the pace, scope, intensity, and forms of their internationalization in the Eurasian Economic Union (EEU). The EEU is a relatively young grouping that was established in 2015 by the Republic of Armenia, the Republic of Belarus, the Republic of Kazakhstan, the Kyrgyz Republic and the Russian Federation. EEU creators try to give...
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Shear band evolution phenomena in direct shear test modelled with DEM.
PublikacjaA direct shear test is widely used in the geotechnical engineering field. It is an easy and quick test to measure the shear properties of soil. This test often replaces more expensive and difficult tri-axial shear test. Despite that the direct shear test is known and used for a long time, it is still not well investigated at the grain scale. This paper deals with the micro behaviour of the cohesionless sand inside the direct shear...
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A Review of Recent Advances in Human-Motion Energy Harvesting Nanogenerators, Self-Powering Smart Sensors and Self-Charging Electronics
PublikacjaIn recent years, portable and wearable personal electronic devices have rapidly developed with increasing mass production and rising energy consumption, creating an energy crisis. Using batteries and supercapacitors with limited lifespans and environmental hazards drives the need to find new, environmentally friendly, and renewable sources. One idea is to harness the energy of human motion and convert it into electrical energy...
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Simple Measurement Method for Resistive Sensors Based on ADCs of Microcontrollers
PublikacjaA new, complete measurement method for resistance measurement of resistive sensors for systems based on microcontrollers equipped with analog-to-digital converters (ADCs) is proposed. The interface circuit consists of only four resistors, including a resistive sensor and a reference resistor, connected directly to the microcontroller pins. It is activated only during measurements, which significantly reduces power consumption....
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Modelling reinforced concrete beams under mixed shear-tension failure with different continuous FE approaches
PublikacjaThe paper presents quasi-static numerical simulations of the behaviour of short reinforced concrete beams without shear reinforcement under mixed shear-tension failure using the FEM and four various constitutive continuum models for concrete. First, an isotropic elasto-plastic model with a Drucker-Prager criterion defined in compression and with a Rankine criterion defined in tension was used. Next, an anisotropic smeared crack...
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A constitutive law for concrete with smooth transition from continuous into discontinuous cracks’ description
PublikacjaPaper presents a constitutive model for concrete that combines a continuous and discontinuous crack’s description to simulate the concrete under tensile dominated loads. In a continuum regime, two different constitutive laws were used. First, a plasticity model with the Rankine failure criterion and an associated flow rule was used. Second, a constitutive law based on isotropic damage mechanics was formulated. Both model alternatives...
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Electrocatalytic gas sensor with reference layer
PublikacjaIn recent years electrochemical gas sensors based on solid state electrolytes have been intensively developed. They are easy to obtain, use and relative durable. Nasicon is one of the most promising materials, which have been used in construction of gas sensors. Most of these devices work in potentiometric or amperometric mode. However, some works are dedicated to sensors working in electrocatalytic mode. Principle of operation...
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Vegetable derived-oil facilitating carbon black migration from waste tire rubbers and its reinforcement effect
PublikacjaThree dimensional chemically cross-linked polymer networks present a great challenge for recycling and reutilization of waste tire rubber. In this work, the covalently cross-linked networks of ground tire rubber (GTR) were degraded heterogeneously under 150 °C due to the synergistic effects of the soybean oil and controlled oxidation. The degradation mechanism was discussed using Horikx theory and Fourier transformation infrared...
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Ordered TiO2 nanotubes: the effect of preparation parameters on the photocatalytic activity in air purification process
PublikacjaVertically ordered TiO2 nanotube arrays were synthesized by anodic oxidation of titanium foil in glycerol, ethylene glycol and water-based electrolytes. The effect of electrolyte composition, anodization voltage, ultrasonic treatment and calcination time on the morphology of the resulting thin films, as well as on their photocatalytic activity in toluene removal, used as a model volatile organic compound, was investigated. Toluene,...
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Electrodeposited Biocoatings, Their Properties and Fabrication Technologies: A Review
PublikacjaCoatings deposited under an electric field are applied for the surface modification of biomaterials. This review is aimed to characterize the state-of-art in this area with an emphasis on the advantages and disadvantages of used methods, process determinants, and properties of coatings. Over 170 articles, published mainly during the last ten years, were chosen, and reviewed as the most representative. The most recent developments...
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Towards spectroscopic monitoring of photoelectrodes: In-situ Raman photoelectrochemistry of a TiO2/prussian blue photoanode
PublikacjaHere, novel in-situ Raman photoelectrochemical measurements are performed. The obtained results have proved that it is possible to track the progress of a photoelectrochemical reaction that takes place on a semiconducting electrode using the spectroscopic method. As an exemplary system, the Ti/TiO2/Prussian blue electrode is investigated. Since TiO2 is an n-type semiconductor, it cannot act as an efficient anode in dark conditions....
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Effectiveness of a dual surface modification of metallic interconnects for application in energy conversion devices
PublikacjaA dual surface modification of an SOFC metallic interconnect with a Gd2O3 layer and an MnCo2O4 coating was evaluated. The tested samples were oxidized for 7000 h in air at 1073 K. Oxidation products were characterized using XRD, SEM-EDS, and confocal Raman imaging, and ASR was measured. The effect of gadolinium segregation at grain boundaries in Cr2O3 was evaluated using S/TEM-EDS. Area specific-resistance was measured and fuel...
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TiO2-C nanocomposite synthesized via facile surfactant-assisted method as a part of less energy-consuming LED-based photocatalytic system for environmental applications
PublikacjaA novel facile method was used to incorporate carbon into the titania structure. An alternative synthesis method of carbon-doped TiO2 has been proposed by using a widely used and cheap surfactant. During the process, cetyltrimethylammonium bromide plays a dual role, as a morphology modifier and as a carbon source. The presented approach allows obtained TiO2-C nanostructures to be anatase nanocrystals with carbon being deposited...
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Development of Strategies for AOB and NOB Competition Supported by Mathematical Modeling in Terms of Successful Deammonification Implementation for Energy-Efficient WWTPs
PublikacjaNovel technologies such as partial nitritation (PN) and partial denitritation (PDN) could be combined with the anammox-based process in order to alleviate energy input. The former combination, also noted as deammonification, has been intensively studied in a frame of lab and full-scale wastewater treatment in order to optimize operational costs and process efficiency. For the deammonification process, key functional microbes include...
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Randomly Functionalized Polyethylenes: In Quest of Avoiding Catalyst Deactivation
PublikacjaWell-defined randomly functionalized polyolefins produced by catalysis form an interesting class of polymers with great potential for various applications. One of the major challenges for the production of these materials forms the incompatibility of the commonly used electrophilic group 4 metal based catalysts and the desired nucleophilic, especially protic functionalities like hydroxyl and carboxylic acid groups. Although pacification...
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Cu supported on various oxides as a candidate catalyst for dry methane reforming in DIR-SOFCs systems
PublikacjaA series of Cu-support systems were tested as potential candidates for DIR-SOFC (Direct Internal Reforming SOFC) catalysts towards a dry reforming of methane (DRM). The various supports (-Al2O3, CeO2, ZrO2, SrTiO3) with comparable specific surface area (SSA), and additionally -Al2O3 with SSA an order of magnitude larger than that of the other supports has been applied. The obtained Cu-support systems were characterized in terms...
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Current status and future success of renewable energy in Pakistan
PublikacjaMismatch between energy demand and supply from last two decades has been increasing because of the domination of expensive imported oil in energy mix of Pakistan. To import crude oil Government paid US $ 9 billion in 2008–2009 to meet the energy demands...
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Opracowanie ekspertyzy dotyczącej przyczyn pękania łopatek wirnika SP turbiny PG1 typu 13UP55
PublikacjaZakres badań i analiz dotyczył ustalenia przyczyn pękania elementów łopatek wirnika SPA5 turbiny TG1 typu 13UP55 obejmował: 1. wykonanie badań składu chemicznego stali, z której wykonano łopatki dostarczone przez Zleceniodawcę dwoma metodami, 2. badania mikroobszarów zniszczenia łopatek na mikroskopie elektronowym skaningowym z mikroanalizatorem EDS, 3. badania metalograficzne makroskopowe i mikroskopowe fragmentów...
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Price convergence in the EU-an aggregate and disaggregate approach
PublikacjaThis article examines the price dispersion in the European Union (EU) over 15 years (1990-2005). An extensive overview of the literature offers inconclusive results with the half-lives of price shocks from 2.8 to 282 months. Until now, most of the empirical research has been either micro or macro based. In contrast, we conducted a complex analysis utilizing both aggregate and disaggregate price data. The macro approach is based...
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Crack monitoring in concrete beams under bending using ultrasonic waves and coda wave interferometry: the effect of excitation frequency on coda
PublikacjaConcrete is one of the most widely used construction materials in the world. In recent years, various non-destructive testing (NDT) and structural health monitoring (SHM) techniques have been investigated to improve the safety and control of the current condition of concrete structures. This study focuses on micro-crack monitoring in concrete beams. The experimental analysis was carried out on concrete elements subjected to three-point...
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COMPARISON OF SYSTEM ON CHIP TECHNOLOGIES FOR SPACE APPLICATIONS
PublikacjaThe paper presents a review of technologies available for the implementation of digital and mixed signal systems, particularly the system on a chip (SoC) for space applications. The phenomena encountered in the space environment are briefly presented, together with the known solutions, regarding the design of complex electronic systems. The most important norms regarding single die integrated circuits designed for space are also...
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Nanostructure and dielectric behavior of vanadate glasses containing BaTiO3
PublikacjaThe ac and dc electrical conductivity of barium titanate doped bismuth-vanadate as-quenched and heat-treated materials was measured in the frequency range from 1 mHz to 1 MHz and in the temperature range from 153 K to 423 K with the impedance spectroscopy method. The microstructure was investigated by means of XRD, scanning electron microscopy (SEM), atomic force microscopy (AFM) and confocal microscopy. The obtained results showed...
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Abilities, Motivations, and Opportunities of Furloughed Employees in the Context of Covid-19: Preliminary Evidence From the UK
PublikacjaThe Covid-19 global pandemic is a crisis like no other, forcing governments to implement prolonged national lockdowns in an effort to limit the spread of the disease. As organizations aim to adapt and remain operational, employers can suspend or reduce work activity for events related to Covid-19 and claim government support to subsidize employee wages. In this way, some employees are placed on furlough (i.e., temporary unemployment)...
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Variations in host surfaces morphology and biology of ciliate epibionts explaining distribution pattern of epibionts in the invasive signal crayfish Pacifastacus leniusculus (Dana, 1852)
Publikacjaciliates on the signal crayfish Pacifastacus leniusculus in relation to specialized structures of the host’s exoskeleton for the first time. This species is known to maintain a relatively clean carapace, but it is sometimes overgrown by other organisms. Epibionts cover different parts of the signal crayfish body, mainly antennae, antennules, maxillipedes III and pereiopods with inner edges of chelae; however, some parts of the...
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Heat recovery from the hybrid photovoltaic tile – experimental studies with the solar light simulator
PublikacjaConsidering the current development of micro-cogeneration energy sources, supported by the national prosumer policy and the act on the renewable energy sources, there is a great demand for the effective solar technologies. In this area, the photovoltaic cells with a combined conversion of the solar radiation energy into the electrical and thermal energy (PV/T cells) seem to be attractive. They are already widely available and treated...
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Corrosion Properties of Dissimilar AA6082/AA6060 Friction Stir Welded Butt Joints in Different NaCl Concentrations
PublikacjaA solid-state friction stir welding method which is increasingly used in the marine and shipbuilding industry, has been developed to produce welds with high mechanical properties. In seawater, the oxide layer of aluminium is attacked by Cl− ions resulting in its disruption and formation of pitting corrosion. It is particularly important to determine the electrochemical properties of the produced welds and to evaluate the efect...
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Modulation of dielectric properties in low-loss polypropylene-based composites at GHz frequencies: theory and experiment
PublikacjaPolymer composites with high dielectric constant and low loss tangent are highly regarded as substrates for modern high-speed electronics. In this work, we analyze the high-frequency dielectric properties of two types of composites based on polypropylene infused with high-dielectric-constant microparticles. Two types of fillers are used: commercial ceramics or titanium oxide ( TiO2) with different concentrations. The key observation...
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Numerical analyses of novel prefabricated structural wall panels in residential buildings based on laboratory tests in scale 1:1
PublikacjaThe paper presents experimental and numerical investigations on novel prefabricated composite building wall panels for residential building constructions. The wall panels were composed of reinforced concrete ribbed elements with the core from the EPS foam as the thermal insulation. The wall panels in the full-scale 1:1 were subjected to vertical loads. In the first step, the experiments were analysed with simple usual static methods....
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Biocompatibility and bioactivity of load-bearing metallic implants
PublikacjaThe main objective of here presented research is to develop the titanium (Ti) alloy base composite materials possessing better biocompatibility, longer lifetime and bioactivity behaviour for load-bearing implants, e.g. hip joint and knee joint endoprosthesis. The development of such materials is performed through: modeling the material behaviour in biological environment in long time and developing of new procedures for such evaluation;...
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Probing the Magnetic Anisotropy of Co(II) Complexes Featuring Redox-Active Ligands
PublikacjaCoordination complexes that possess large magnetic anisotropy (otherwise known as zero-field splitting, ZFS) have possible applications in the field of magnetic materials, including single molecule magnets (SMMs). Previous studies have explored the role of coordination number and geometry in controlling the magnetic anisotropy and SMM behavior of high-spin (S = 3/2) Co(II) complexes. Building upon these efforts, the present work...
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Studies on the charge density distribution in p-substituted phenylnitrenium cation
PublikacjaAniline and its derivatives are known to be mutagenic. This activity is caused by the formation of phenylnitrenium cations during aniline oxidation. Reactivity of the positively charged chemical species can be measured by means of s+ substituent constant. In this paper charge density distribution in p-substituted nitrenium cations and reactivity indices such as, hardness η, electronegativity χ , and electrophilicily ω were analyzed....
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Mechanochemically synthesized Mn3O4@β-cyclodextrin mediates efficient electron transfer process for peroxymonosulfate activation
PublikacjaThe rational surface engineering of heterogeneous catalysts is of great significance in advanced oxidation processes (AOPs) for eliminating refractory contaminants but remains challenging. In this study, β-cyclodextrin modified Mn3O4 (Mn3O4@β-CD) was prepared through a mechanochemical approach for peroxymonosulfate (PMS) activation, which achieved efficient bisphenol A (BPA) removal via electron transfer process (ETP). The reactive...
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Progress, Challenge, and Perspective of Bimetallic TiO2-Based Photocatalysts
PublikacjaBimetallic TiO2-based photocatalysts have attracted considerable attention in recent years as a class of highly active catalysts and photocatalysts under both UV and Vis light irradiation. Bimetallic noble metal structures deposited on TiO2 possess the ability to absorb visible light, in a wide wavelength range (broad LSPR peak), and therefore reveal the highest level of activity as a result of utilization of a large amount of...