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Wyniki wyszukiwania dla: LOW-TEMPERATURE DSC MICROWAVE HYDROTHERMAL SYNTHESIS ZRO2–ALO(OH) NANOPOWDERS THERMAL STABILITY WATER DECOMPOSITION HIGH-TEMPERATURE DSC–MS
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Thermal and physical properties of ZrO2–AlO(OH) nanopowders synthesised by microwave hydrothermal method
PublikacjaIndustrially relevant nanopowder was synthesised by microwave hydrothermal synthesis to obtain well-controlled composition (ZrO2–AlO(OH) system) which was found to determine a number of physical and thermal characteristics. This study reports variation of particle size, density, specific surface area (SSABET), as well as thermal behaviour of nanopowder mixtures of ZrO2–AlO(OH) in the whole range of compositions. It was found that...
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Mechanism of Reduced Sintering Temperature of Al2O3–ZrO2 Nanocomposites Obtained by Microwave Hydrothermal Synthesis
PublikacjaA novel method to obtain Al2O3–ZrO2 nanocomposites is presented. It consists of the co-precipitation step of boehmite (AlO(OH)) and ZrO2, followed by microwave hydrothermal treatment at 270 ◦ C and 60 MPa, and by calcination at 600 ◦ C. Using this method, we obtained two nanocomposites: Al2O3–20 wt % ZrO2 and Al2O3–40 wt % ZrO2. Nanocomposites were characterized by Fourier transformed infrared spectroscopy, Raman spectroscopy,...
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The role of hydrogen bonding on tuning hard-soft segments in bio-based thermoplastic poly(ether-urethane)s
PublikacjaThis work describes the preparation of bio-based thermoplastic poly(ether-urethane)s (TPU) via a prepolymer method and investigates the effect of varying the interphase hydrogen-bonding (H-bonding) on physicochemical, thermal and mechanical properties. This was achieved by varying the glycol type and molar ratio of [NCO]/[OH] groups used during the prepolymer chain extending step. The TPUs’ chemical structure was analyzed by Fourier...
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Brain perfusion imaging with the use of parametric modelling basing on DSC-MRI data
PublikacjaW pracy do estymacji parametrów perfuzji mózgu: przepływu krwi mózgowej (cerebral blood flow, CBF), objętości krwi mózgowej (cerebral blood volume, CBV) oraz średniego czasu przejścia (mean transit time, MTT) wykorzystano pomiary DSC-MRI (Dynamic Susceptibility Contrast Magnetic Resonance Imaging). W modelowaniu danych MRI zastoswoano model trzykompartmentowy. Przedstawiono i porównano dwa podejścia do identyfikacji modelu różniące...
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Chemical Characteristics and Thermal Oxidative Stability of Novel Cold-Pressed Oil Blends: GC, LF NMR, and DSC Studies
PublikacjaPlant oils contain a high content of unsaturated fatty acids. Studies of food products have revealed a considerable disproportion in the ratio of ω6 to ω3. This article presents information on the healthful qualities of eight new oil blends that contain a beneficial proportion of ω6 to ω3 fatty acids (5:1), as well as their degradation during heating at 170 and 200 °C. The fatty acid profile was analyzed by gas chromatography (GC),...
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Field Evaluation of High Modulus Asphalt Concrete Resistance to Low-Temperature Cracking
PublikacjaHigh-modulus asphalt concrete has numerous advantages in comparison to conventional asphalt concrete, including increased resistance to permanent deformations and increased pavement fatigue life. However, previous studies have shown that the construction of road pavements with High Modulus Asphalt Concrete (HMAC) may significantly increase the risk of low-temperature cracking. Those observations were the motivation for the research...
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Molecular mobility of water protons under interaction with chemically modified starches. DSC and HMR-relaxation investigations
PublikacjaThe change of water protons mobility in the system chemically modified starches – water were investigated by DSC and NMR-relaxation methods. The amount of unfrozen water at subzero temperature as well as additional unfrozen water which appears after gelatinization have lower values for chemically modified starches in comparison with the native starch. The proton spin-spin relaxation time Т2 for chemically modified starch samples,...
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Proton Conducting Ceramic Powder Synthesis by a Low Temperature Method
PublikacjaMolten salt synthesis (MSS) is a simple method for the preparation of ceramic powders with specific morphology. The main role of the molten salts is to increase the reaction rate and lower the reaction temperature. It occurs because of much higher mobility of reactants in the liquid medium than in the solid state. In this work the molten salt synthesis was applied to produce ceramic powders of La0995Ca0005NbO4 and BaCe09−xZrxY01O3....
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TG-FTIR, DSC and quantum chemical studies of the thermal decomposition of quaternary methylammonium halides
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On thermal stability of piezo-flexomagnetic microbeams considering different temperature distributions
PublikacjaBy relying on the Euler–Bernoulli beam model and energy variational formula, we indicate critical temperature causes in the buckling of piezo-flexomagnetic microscale beams. The corresponding size-dependent approach is underlying as a second strain gradient theory. Small deformations of elastic solids are assessed, and the mathematical discussion is linear. Regardless of the pyromagnetic effects, the thermal loading of the thermal...
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DSC and thermal stability investigation of novel poly(ester-ether) glycolsand poly(ester-ether)urethanes.
PublikacjaOtrzymano serie nowych poli(estro-etero)dioli z kwasu adypinowgo.........
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Polyurethane/Silane-Functionalized ZrO2 Nanocomposite Powder Coatings: Thermal Degradation Kinetics
PublikacjaA polyurethane (PU)-based powder coating reinforced with vinyltrimethoxysilane (VTMS)-functionalized ZrO2 nanoparticles (V-ZrO2) for thermal stability was developed. Chemical structure, microstructure and thermal degradation kinetics of the prepared coatings were investigated. The peak of aliphatic C–H vibrating bond in the Fourier transform infrared (FTIR) spectrum of V-ZrO2 was a signature of VTMS attachment. Scanning electron...
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High-Energy-Low-Temperature Technologies for the Synthesis of Nanoparticles: Microwaves and High Pressure
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Oxygen Aspects in the High-Pressure and High-Temperature Sintering of Semiconductor Kesterite Cu2ZnSnS4 Nanopowders Prepared by a Mechanochemically-Assisted Synthesis Method
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Effect of ZrO2 on corrosion behaviour of chromium coatings
PublikacjaW celu zbadania wpływu cząstek ZrO2 na zachowania korozyjne powłok chromowych pokryto stal chromem z elektrolitów Cr(VI) z dodatkiem i bez ZrO2. Właściwości korozyjne osadzonych warstw zbadano w elektrolicie 0,01 mol L(-1) kwasu siarkowego plus 0,5 mol L(-1) siarczanu sodu za pomocą metody spektroskopii impedancyjnej i woltamperometrii cyklicznej. Zaproponowano elektryczny obwód zastępczy dla procesu korozji i wyznaczono pęd korozji....
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A new viscoelastic method of calculation of low-temperature thermal stresses in asphalt layers of pavements
PublikacjaThe paper presents a new method of calculation of thermal stresses in asphalt layers of pavements induced by cooling or heating. The method, developed by the author, is based on the analytical solution for the linear viscoelastic Burgers model extended numerically for the case of asphalt layers whose rheological parameters are strongly dependent on temperature. The coefficient of thermal expansion and Poisson’s ratio may optionally...
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Limitations of DSC-MRI for quantitative brain perfusion.
PublikacjaArtykuł przedstawia ograniczenia metody DSC-MRI w ilościowej ocenie przepływów mózgowych. W zakresie pięciu różnych grup zagadnień przeprowadzono testy symulacyjne oraz obliczenia na podstawie badań fantomowych i in-vivo. Pokazano i omówiono wyniki badań.
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High temperature corrosion of evaporator tubes with thermal sprayed coatings
PublikacjaDegradation examinations of outer surface of low-emission steam boiler evaporator tubes are presented in the paper. Metallographic evaluation of scale morphology, its micro sites chemical composition analysis and distribution of elements on cross sections have been performed. Water-wall tubes were exposed in steam boiler for up to two years period. Common tubes made of 16Mo3 steel suffered sulphide and molten salts corrosions....
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Performance of the very high-temperature heat pump with low GWP working fluids
PublikacjaTraditional heat pumps are a very attractive pro-ecological solutions for a number of applications, including providing of heating or heat recovery from industrial processes. The application range of heat pumps could be greatly enlarged when the operating temperature would be increased to 130-150°C and/or the temperature lift can be increased to 50-100 K. In the paper, the very high temperature vapour-compressor based single stage...
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Influence of High Temperature Oxidation on Hydrogen Absorption and Degradation of Zircaloy-2 and Zr 700 Alloys
PublikacjaThe present research was aimed at determining the effects of the oxide layers on hydrogen absorption, microstructure and mechanical properties of the Zircaloy- 2 and Zr 702 alloys. The oxidation was made at 350 °C, 700 °C and 900 °C for 10 to 30 min in laboratory air, followed by hydrogen cathodic charging for 72 h and annealing at 400 °C for 4 h. The slow strain rate tests were carried out on oxidized, charged and annealed specimens. The...
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High temperature proton conduction in LaSbO4
PublikacjaLanthanum orthoantimonate was synthesized using a solid‐state synthesis method. To enhance the possible protonic conductivity, samples with the addition of 1 mol% Ca in La‐site, were also prepared. The structure was studied by the means of X‐ray diffraction, which showed that both specimens were single phase. The materials crystallized in the space group P2 1 /n. Dilatometry revealed that material expands non‐linearly with the...
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A DSC and NMR-Relaxation study of the molecular mobility of water protons interacting with chemically modified starches
PublikacjaChanges in the mobility of water protons in the chemically modified starches (CMS)–water system are studied by differential scanning calorimetry and NMR relaxation. The amounts of unfrozen water at negative temperatures and additional (after gelation) unfrozen for CMS are lower than those for native starch. The proton spin–spin relaxation time T2 for CMS samples, conventionally attributed to the water fraction in starch granules,...
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Experimental and theoretical study of a vertical tube in shell storage unit with biodegradable PCM for low temperature thermal energy storage applications
PublikacjaThis article presents the experimental investigations of the coconut oil-based TES module for HVAC applications in the ambient and-sub ambient temperature range. To properly study this problem modular experimental module and test loop were developed. Special attention has been paid to study the physical mechanism of the melting/solidification process for natural substance (coconut oil) which has perspectives to be used in thermal...
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Impact of low-temperature sintering on the Fe-based amorphous coatings
PublikacjaBulk metallic glasses (BMGs) have gained a lot of attention in recent years due to their outstanding properties such as high hardness and excellent wear and corrosion resistance. However, they are restricted in industrial applications due to their extreme brittleness. Iron based amorphous coatings from BMGs are the best solution to use them by overcoming the problem of extreme brittleness. The coatings can be sprayed by various...
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Comparison of low-temperature cracks intensity on pavements with high modulus asphalt concrete and conventional asphalt concrete bases
PublikacjaHigh modulus asphalt concrete (HMAC) base courses provide very good resistance to rutting and fatigue but they can increase the risk of low-temperature cracking as compared with conventional asphalt concrete (AC). The article presents the comparison of these two road materials in terms of low-temperature cracking. The statistical method based on the ordered logistic regression model was used. The analysis was based on results of...
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Structure versus hydrolytic and thermal stability of bio-based thermoplastic polyurethane elastomers composed of hard and soft building blocks with high content of green carbon
PublikacjaNowadays, sustainability plays a key role in the design and synthesis of new materials. One of the methods for the preparation of green materials is incorporation into their structure the monomers with a high content of green carbon. Therefore, the aim of this work was to investigate the influence of the type and molecular mass of two bio-based polyester polyols and bio-glycol on the properties of aliphatic partially bio-based...
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Vertical Temperature Stratification of the Gulf of Gdansk Water
PublikacjaThe Baltic Sea is characterized by variable hydroacoustic conditions, which depend on hydrological conditions throughout the year. The temperature of the water is the factor that has the greatest impact on the changes in the speed of the sound in this basin. Even at a small depth, we can observe a large temperature gradient affecting the accuracy of the conducted research using hydroacoustic devices. A characteristic feature of...
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Modeling of low calorific gas burning in a deficient oxygen environment and high-temperature oxidizer
PublikacjaThe experimental research will be performed using the experimental facility with a combustion chamber. The oxygen concentration in combustion oxidizers will be varied from 21% by volume (normal) air to 2%. The test combustion chamber will be fed with propane or methane as the reference fuel, then with low calorific fuels as test gases obtained by mixing various combustible components, e.g. H2, CH4, CO, and neutral gases, e.g. N2,...
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Evaluation of Low Temperature Properties of Rubberized Asphalt Mixtures
PublikacjaThe paper presents low-temperature test results of asphalt mixtures designed with use of bitumen modified by crumb rubber and also SBS polymer. Laboratory tests were conducted on two types of asphalt mixtures for wearing course – stone matrix asphalt (SMA 8) and porous asphalt (PA 8). This paper presents results of the following laboratory tests at low temperatures: TSRST test, three point bending creep test, fracture toughness...
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HIGH TEMPERATURE HEAT PUMPS – PERSPECTIVE HEATING SYSTEMS?
PublikacjaIn the paper presented are authors own concepts of high temperature compressor heat pumps for the utilisation of medium and low temperature sources of heat. Working fluids for use in high temperature heat pumps are discussed, as well as the criteria for their selection. Analyses are presented for the production of in the upper steam source at 130 °C. One-stage systems and cascade systems were analyzed. An analysis of the coefficient...
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Field investigation of low-temperature cracking and stiffness moduli on selected roads with conventional and high modulus asphalt concrete
PublikacjaHigh Modulus Asphalt Concrete (HMAC) was introduced in Poland as a one of the solutions to the problem of rutting, type of deterioration common in the 1990s. After first encouraging trials in 2002 HMAC was widely used for heavily loaded national roads and motorways. However some concerns were raised about low-temperature cracking of HMAC. This was the main reason of the studies presented in this article were started. The article...
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Low-temperature high-pressure cryogelation of nanooxides
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The Impact of Homogeneity of High Modulus Asphalt Concrete Layer on Low-Temperature Cracking
PublikacjaDuring winter season of 2012 numerous transverse cracks developed in high-modulus asphalt concrete (HMAC) base of newly constructed motorway. Pavement cracked both in transverse joint locations and in the area between them. Research which was conducted during investigation of the causes and mechanisms of cracking consisted of: field examination, laboratory testing of specimens cored out of the existing pavement, computational analyses...
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Temperature influences on shear stability of a nanosize plate with piezoelectricity effect
PublikacjaPurpose The purpose of this paper is to predict the mechanical behavior of a piezoelectric nanoplate under shear stability by taking electric voltage into account in thermal environment. Design/methodology/approach Simplified first-order shear deformation theory has been used as a displacement field. Modified couple stress theory has been applied for considering small-size effects. An analytical solution has been taken into account...
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High temperature corrosion resistance of porous hastelloy alloy
PublikacjaTo further understand the suitability of Ni-Cr-base alloy for solid oxide fuel cell (SOFC), a commercial Ni-Cr-Fe-Mo alloy, Hastelloy X was selected and evaluated for oxidation behaviour under high temperature conditions. HastelloyX was chosen due to its unusual resistance to oxidizing, reducing and neutral atmospheres. For long term stability of metal supported fuel cell, the corrosion resistance plays a vital role and must be...
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Influence of the low ambient temperature on the start-up process of hydraulic pumps
PublikacjaStarting hydraulic pumps in low ambient temperatures may cause: decreased hydraulic-mechanical efficiency, larger vibration of hydraulic installation, faster wear and more frequent damage to the elements of pumps, change of material properties of elements, increase of pressure drop. As a result of pressure drop in the suction pipe, large underpressure may be experienced, causing incomplete filling of pump working chambers with...
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Hydrothermal synthesis of vanadium ammonium compounds – the crucial role of the pressure
PublikacjaDue to the structural diversity and chemical activity, vanadium oxides and their derivatives are continuingly in the great interest of scientist. In a large family of vanadium compounds, one of the most interesting are ammonium vanadates (with the general formula (NH4)xVyOz). They have received much attention because of their promising application as cathode material in mono- and multivalent-ion batteries [1]. Hydrothermal synthesis...
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The Influence of Thin Gold Electrodes on the High-Temperature Impedance of Oxide Glasses
PublikacjaThe influence of thin gold electrodes on the electrical measurements of glasses at high temperatures was studied using impedance spectroscopy. The impedance was measured several times over a wide frequency range from 10 mHz to 1 MHz and the temperature ranged from 213 to 673 K under air and nitrogen atmospheres. The results showed a drop in the conductivity of more than an order of magnitude at a temperature around 603 K during...
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High-temperature properties of titanium-substituted yttrium niobate
Publikacjahe defect fluorite titanium-doped yttrium niobate samples Y3Nb1−xTixO7−δ have been synthesized and investigated by the means of high-temperature X-ray diffraction, dilatometry, and thermogravimetry. Thermal expansion coefficients (TECs) as well as chemical expansion coefficients for material with 5, 10, and 15 mol% of titanium were determined. All investigated samples exhibit chemical contraction caused by Ti doping. The values...
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Influence of chemical structure on physicochemical properties and thermal decomposition of the fully bio-based poly(propylene succinate-co-butylene succinate)s
PublikacjaIn this work, two polyesters and four copolyesters were studied. All materials were synthesized to obtain the monomers dedicated for thermoplastic polyurethane elastomers. For this type of PUR, the monomers should characterize by appropriate selected physicochemical properties and macromolecular structure distribution, which depends on synthesis conditions. The study of chemical structure with extensive and knowledgeable analysis...
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Microwave-assisted synthesis of zinc derivatives of potato starch
PublikacjaZincatated potato starch was prepared in a solid-state, microwave-assisted reaction using generated in situ sodium tetrahydroxozincate [Na2Zn(OH)4]. For comparison, zincatation of starch was also carriedout on convectional heating. Depending on the irradiation conditions, the products of either mono- or crosslinking esterification were formed. Higher power applied at shorter exposition offered products ofmonoesterification, and...
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Investigation of low-temperature cracking in newly constructed high-modulus asphalt concrete base course of a motorway pavement
PublikacjaThe paper presents the issue of low-temperature transverse cracks which have developed in newly constructed base courses made of high-modulus asphalt concrete mix (HMAC). Numerous transverse cracks developed in the analysed HMAC base during the winter season before the pavement was actually completed, both at the transverse joint locations and in the areas between them. This had not happened so far on such a scale during road construction...
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Zastosowanie metod NMR i DSC do badania mieszanek zawierających olej palmowy
PublikacjaW pracy badano olej palmowy oraz mieszanki oleju palmowego z uwodornionym lub ciekłym olejem rzepakowym o różnym składzie procentowym. W metodach NMR i DSC stosowano podobne sposoby termostatowania tzn. próbki przed analizą były termostatowane przez 1 godz. w temp 0oC (podobnie jak tłuszcz uwodorniony w normie ISO) lub przez 16 godz. w temp. 10oC (podobnie jak olej palmowy w normie ISO). Dodatkowo metodą DSC analizowano wszystkie...
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Glass-ceramic sealants and steel interconnects: accelerated interfacial stability and reactivity tests at high temperature
PublikacjaHigh-temperature reactions between glass-ceramic sealants and Fe-Cr alloy interconnects may lead to the formation of undesirable phases, and consequently degradation of solid oxide fuel/electrolyser devices. In this work, three different glass-ceramic sealants (Na-containing, Ba-containing, Sr-containing compositions) and Fe22Cr stainless steel powders (raw and pre-oxidised) are considered in order to test their chemical reactivity...
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Status report on high temperature fuel cells in Poland – Recent advances and achievements
PublikacjaThe paper presents recent advances in Poland in the field of high temperature fuel cells. The achievements in the materials development, manufacturing of advanced cells, new fabrication techniques, modified electrodes and electrolytes and applications are presented. The work of the Polish teams active in the field of solid oxide fuel cells (SOFC) and molten carbonate fuel cell (MCFC) is presented and discussed. The review is oriented...
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PROBLEMS OF THE STARTING AND OPERATING OF HYDRAULIC COMPONENTS AND SYSTEMS IN LOW AMBIENT TEMPERATURE (PART IV) MODELLING THE HEATING PROCESS AND DETERMINING THE SERVICEABILITY OF HYDRAULIC COMPONENTS DURING THE STARTING-UP IN LOW AMBIENT TEMPERATURE
PublikacjaDesigners of hydraulically driven machines and devices are obliged to ensure during design process their high service life with taking into account their operational conditions. Some of the machines may be started in low ambient temperature and even in thermal shock conditions (due to delivering hot working medium to cold components). In order to put such devices into operation appropriate investigations, including experimental...
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Measurement of temperature-dependent viscosity and thermal conductivity of alumina and titania thermal oil nanofluids
PublikacjaThe results of simultaneous measurements of dynamic viscosity, thermal conductivity, electrical conductivity and pH of two nanofluids, i.e. thermal oil/Al2O3 and thermal oil/TiO2 are presented. Thermal oil was selected as a base liquid because of possible application in ORC systems as an intermediate heating agent. Nanoparticles were tested at the concentration of 0.1%, 1% and 5% by weight within temperature range from 20°C to...
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Low-temperature synthesis of silicon carbide powder using shungite
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MEASUREMENT OF TEMPERATURE-DEPENDENT VISCOSITY AND THERMAL CONDUCTIVITY OF ALUMINA AND TITANIA THERMAL OIL NANOFLUIDS
PublikacjaIn this study results of simultaneous measurements of dynamic viscosity, thermal conductivity, electrical conductivity and pH of two nanofluids, i.e. thermal oil/Al2O3 and thermal oil/TiO2 are presented. Thermal oil is selected as a base liquid because of possible application in ORC systems as an intermediate heating agent. Nanoparticles were tested at the concentration of 0.1%, 1% and 5% by weight within temperature range from...
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Numerical analysis of high temperature minichannels heat exchanger performance
PublikacjaNowadays, the most difficult technological challenge in energy sector is connected with the gas micro-CHP units, dedicated to the distributed power generation. They are expected to be of high efficiency and at the same time of compact in size. Regarding the first reason, significant increase in microturbine efficiency can only be achieved by increase in the engine operating temperature. Therefore, one of the critical elements in...