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Influence of several biodegradable components added to pure and nanosilver-doped PMMA bone cements on its biological and mechanical properties
PublikacjaAcrylic bone cements (BC) are wildly used in medicine. Despite favorable mechanical properties, processability and inject capability, BC lack bioactivity. To overcome this, we investigated the effects of selected biodegradable additives to create a partially-degradable BC and also we evaluated its combination with nanosilver (AgNp). We hypothesized that using above strategies it would be possible to obtain bioactive BC. The Cemex...
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Enhanced electrochemical kinetics of highly-oriented (111)-textured boron-doped diamond electrodes induced by deuterium plasma chemistry
PublikacjaNovel highly-oriented (111)-textured boron-doped diamond electrodes (BDDD) featuring high electrochemical activity and electrode stability toward electrochemical analytics were fabricated by deuterium-rich microwave plasma CVD. The high flux deuterium plasma-induced preferential formation of (111)-faceted diamond as revealed by XRD. The highly-oriented diamond surface exhibited improved boron dopant incorporation and activation,...
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Electrochemical Stability of Few-Layered Phosphorene Flakes on Boron-Doped Diamond: A Wide Potential Range of Studies in Aqueous Solutions
PublikacjaTwo-dimensional phosphorene has attracted great interest since its discovery as a result of its extraordinary properties. Two-dimensional single crystals of phosphorene can be useful for electrochemical (EC) sensing applications due to their enhanced surface-to-volume ratio. We proposed to investigate the electrochemical performance of phosphorene deposited directly on boron-doped diamond (BDD) electrodes. Noncovalent interaction...
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Investigation of thin perovskite layers between cathode and doped ceria used as buffer layer in solid oxide fuel cells
PublikacjaIn this paper, thin perovskite layers between cathode material of solid oxide fuel cells and gadolinia-doped ceria buffer layer are investigated. Thin layers made of LaNi0.6Fe0.4O3-δ (LNF), La0.6Sr0.4Co0.2Fe0.8O3-δ (LSCF), or SrTi0.65Fe0.35O3-δ (STF) were symmetrically deposited by spin coating method from metallo-organic polymer precursors on a Ce0.8Gd0.2O2-δ (CGO) substrate. Porous and about 40-μm-thick LNF cathodes were deposited...
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N-doped mesoporous carbon nanosheets obtained by pyrolysis of a chitosan–melamine mixture for the oxygen reduction reaction in alkaline media.
PublikacjaBy simple thermal decomposition of low-cost precursors (chitosan, melamine) in an inert atmosphere, nitrogen-doped porous carbonaceous materials were prepared. The samples pyrolyzed at 700 C are composed of mainly mesoporous nitrogen-doped carbon nanosheets and partially graphitized carbon. The nanosheets contain a disordered area due to the strain imposed by the presence of nitrogen and/or oxygen groups in their structure. Some...
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ZnO-decorated green-synthesized multi-doped carbon dots from Chlorella pyrenoidosa for sustainable photocatalytic carbamazepine degradation
PublikacjaThe promising green synthesis of carbon dots (CDs) from microalga Chlorella pyrenoidosa was achieved using simple hydrothermal and microwave-assisted methods. Doping of nanomaterials by nonmetals (N, S, and P) was confirmed by X-ray photoelectron spectroscopy (XPS), while the existence of metals in the CDs was confirmed by inductively coupled plasma optical emission spectroscopy (ICP-OES) and transmission electron microscopy (TEM),...
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Automated measurement method for assessing thermal-dependent electronic characteristics of thin boron-doped diamond-graphene nanowall structures
PublikacjaThis paper investigates the electrical properties of boron-doped diamond-graphene (B:DG) nanostructures, focusing on their semiconductor characteristics. These nanostructures are synthesized on fused silica glass and Si wafer substrates to compare their behaviour on different surfaces. A specialized measurement system, incorporating Python-automated code, was developed for an in-depth analysis of electronic properties under various...
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Boron-doped diamond nanosheet volume-enriched screen-printed carbon electrodes: a platform for electroanalytical and impedimetric biosensor applications
PublikacjaThis paper focuses on the development of a novel electrode based on boron-doped diamond nanosheet full-volume-enriched screen-printed carbon electrodes (BDDPE) for use as an impedimetric biosensor. Impedimetric biosensors offer high sensitivity and selectivity for virus detection, but their use as point-of-care devices is limited by the complexity of nanomaterials’ architecture and the receptor immobilisation procedures. The study...
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Hopping or Tunneling? Tailoring the Electron Transport Mechanisms through Hydrogen Bonding Geometry in the Boron-Doped Diamond Molecular Junctions
PublikacjaMechanisms of charge transport in molecular junctions involving hydrogen bonds are complex and remain mostly unclear. This study is focused on the elucidation of the electron transfer in a molecular device consisting of two boron-doped diamond interfaces bound with an aromatic linker and a hydrogen bonding surrogating molecule. The projected local density of states (PLODS) analysis coupled with transmission spectra and current−voltage...
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Facile synthesis and characterization of graphene and N-doped graphene by CVD method from liquid precursors for promising electrode materials
PublikacjaIn this study, high-quality and few-layered graphene was synthesized using the chemical vapor deposition (CVD) method from liquid sources. Two different liquid carbon sources, pyridine, and benzene, were used and deposited on nickel foam under heat conditions using a bubbler in a quartz tube. X-ray diffraction (XRD) and Raman analysis confirmed the crystalline properties of graphene and N-doped graphene, demonstrating the high...
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Heterogeneous distribution of surface electrochemical activity in polycrystalline highly boron-doped diamond electrodes under deep anodic polarization
PublikacjaThe surface homogeneity of boron-doped diamond electrodes is variable and depends on anodic polarization conditions. The differentiation factor is the gradual and localized change in surface termination. A series of measurements under different polarization conditions was performed in order to investigate the scale of this effect. Nanoscale impedance microscopy (NIM) revealed large variation of surface resistance in individual...
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Diamond-Phase (Sp3-C) Rich Boron-Doped Carbon Nanowalls (Sp2-C): A Physico-Chemical And Electrochemical Properties
PublikacjaThe growth of B-CNW with different boron doping levels controlled by the [B]/[C] ratio in plasma, and the influence of boron on the obtained material’s structure, surface morphology, electrical properties and electrochemical parameters, such as -ΔE and k°, were investigated. The fabricated boron-doped carbon nanowalls exhibit activity towards ferricyanide redox couple, reaching the peak separation value of only 85 mV. The flatband...
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Linear and nonlinear impedance of alkali and iron doped silicate-lead glasses
Dane BadawczeLinear and nonlinear impedance was studied for lead-silicate glass samples doped with iron ions and alkaline oxides. The compositions of glasses were as follows: (in %mol) 50% SiO2, 25% PbO, 15% Fe2O3 and 15% one of alkaline oxides: Na2O, K2O, Li2O. All samples were prepared by the conventional melt quenching technique. The substrates were powdered...
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Magnetic properties of of lead-silicate glasses and nanocomposites doped with iron oxide
Dane BadawczeMagnetic properties of iron-doped glasses and glass-ceramics were studied. Two different sets of glass samples were prepared. The first group of samples has the composition of (50 − 0.5x)SiO2–(50 − 0.5x)PbO– xFe2O3, where x = 15 and 20 (in mol%). Composition of the second group was 50SiO2–(50−x)PbO–xFe2O3, where x=15, 20 and 25 (in mol%). All sampleswere...
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Structure and optical measurements of Eu doped tellurium oxide thin films
Dane BadawczeThin films were deposited by magnetron sputtering method and simultaneously heated at 200 oC. Presence of Eu ions and their valence states was confirmed by X-ray photoemission spectroscopy measurements. The structure of the films as well as the influence of europium dopant on crystalline structure of the films was examined by X-ray diffraction method. ...
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Optical properties of TeOx gels doped with a mix of rare-earth ions
Dane BadawczeThe DataSet contains the UV-Vis spectra of the TeOx gels doped with a mix of rare-earth ions. The material was obtained by the sol-gel method. The starting solution was prepared by mixing telluric acid (precursor) with thetraetylene glycol, water, and ethanol. Next, the different molar concentration of rare-earth ions was added, nitrates were used...
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Electrochemical oxidation of landfill leachate using boron-doped diamond anodes: pollution degradation rate, energy efficiency and toxicity assessment
PublikacjaElectrochemical oxidation (EO), due to high efficiency and small carbon footprint, is regarded as an attractive option for on-site treatment of highly contaminated wastewater. This work shows the effectiveness of EO using three boron-doped diamond electrodes (BDDs) in sustainable management of landfill leachate (LL). The effect of the applied current density (25–100 mA cm−2) and boron doping concentration (B/C ratio: 500 ppm, 10,000...
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Femtosecond Er-doped fiber laser source tunable from 872 to 1075 nm for two-photon vision studies in humans
PublikacjaWe report the development of a widely-tunable femtosecond fiber laser system and its application for two-photon vision studies. The source is based on an Er-doped fiber laser with spectral shift up to 2150 nm, followed by a second harmonic generation module to generate a frequency-doubled beam tunable from 872 to 1075 nm. The source delivers sub-230 fs pulses with nearly-constant duration over the entire tuning range, with output...
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Intrinsic and Dopant-Related Luminescence of Undoped and Tb Plus Tm Double-Doped Lithium Magnesium Phosphate (LiMgPO4, LMP) Crystals
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Charge transfer and europium trapped exciton states in Eu<sup>3+</sup>/Eu<sup>2+</sup> doped phosphors
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Corrigendum to “Binding energies of Eu2+ and Eu3+ ions in β-Ca2SiO4 doped with europium” [Opt. Mater. 35 (2013) 2107–2114]
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Facilitated transport of Zn(II), Cd(II) and Pb(II) across polymer inclusion membranes doped with imidazole azocrown ethers
PublikacjaZbadano transport jonów Pb(II), Cd(II) i Zn(II) przez polimerowe membrany inkluzyjne (PIM) przy użyciu imidazolowych azokoron. Badanie prowadzono dla wodnych roztworów azotanów metali o c(Me)=0,001M i pH=5,0. Polimerowe membrany inkluzyjne otrzymywano z trójoctanu celulozy (nośnik), plastyfikatora i jonoforu (jeden z imidazolowych eterów koronowych z ugrupowaniem azowym). Badane azokorony różniły sięmiejscem podstawienia imidazolu...
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Optimizing Ni–Cr patterned boron-doped diamond band electrodes: Doping effects on electrochemical efficiency and posaconazole sensing performance
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Tm3+/Ho3+co-doped germanate glass and double-clad optical fiber for broadband emission and lasing above 2 µm
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Structure and Luminescence Properties of Transparent Germanate Glass-Ceramics Co-Doped with Ni2+/Er3+ for Near-Infrared Optical Fiber Application
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Photocatalytic and Self-Cleaning Properties of Ag-Doped TiO2~!2009-10-16~!2009-10-30~!2010-01-27~!
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Electrochemical detection of 4,4',5,5'-tetranitro-1H,1'H-2,2'-biimidazole on boron-doped diamond/graphene nanowall electrodes
PublikacjaWe present a promising approach to the electroanalytical detection of a specific nitroaromatic explosive in landfill leachates (LLs) that originated from a municipal solid waste plant. The paper is focused but not limited to the sensing of 4,4',5,5'-tetranitro-1H,1'H-2,2'-biimidazole (TNBI) using differential pulse voltammetry and cyclic voltammetry. Highly electroactive nanocarbon was applied to determine low concentrations of...
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Highly selective impedimetric determination of Haemophilus influenzae protein D using maze-like boron-doped carbon nanowall electrodes
PublikacjaThis study reports a novel impedimetric immunosensor for protein D detection in purified and bacterial (Haemophilus influenzae, Hi) samples. The detection was based on antigen recognition by anti-protein D antibodies (apD) immobilised at the maze-like boron-doped carbon nanowall electrodes (B:CNW). The B:CNW electrodes were synthesised, and their surface was characterised by scanning electron microscopy (SEM) and X-ray photoelectron...
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Characterization methods of nickel nano-particles obtained by the ex-solution process on the surface of Pr, Ni-doped SrTiO3 perovskite ceramics
PublikacjaIn this paper, a novel electrode material based on Pr, Ni co-doped strontium titanate ( Sr0.7Pr0.3)xTi1−yNiyO3 with constant amount of 30% praseodymium dopant, different amount of nickel (y = 0.06 and y = 0.10) and additional nonstoichiometry in Sr-site (x = 1; x = 0.9 and x = 0.8) was investigated as fuel electrode for SOEC devices. A porous ceramics were prepared by solid-state reaction method. X-ray diffraction measurements...
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Electrochemical determination of nitroaromatic explosives at boron-doped diamond/graphene nanowall electrodes: 2,4,6-trinitrotoluene and 2,4,6-trinitroanisole in liquid effluents
PublikacjaThe study is devoted to the electrochemical detection of trace explosives on boron-doped diamond/graphene nanowall electrodes (B:DGNW). The electrodes were fabricated in a one-step growth process using chemical vapour deposition without any additional modifications. The electrochemical investigations were focused on the determination of the important nitroaromatic explosive compounds, 2,4,6-trinitrotoluene (TNT) and 2,4,6-trinitroanisole...
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Rare earth ions doped K 2 Ta 2 O 6 photocatalysts with enhanced UV–vis light activity
PublikacjaNew rare earth-doped K2Ta2O6 photocatalysts were successfully synthesized by hydrothermal method. The effect of dopant type (Y,Yb,Ho,Pr,Er) and amount of rare earth precursor (2,4,8 and 10 mol%) on the physicochemical and photocatalytic properties of RE-K2Ta2O6 have been investigated. All as-prepared materials were characterized by UV–vis diffuse reflectance spectroscopy, Brunauer-Emmett-Teller specific surface area measurement,...
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Optimizing Ni–Cr patterned boron-doped diamond band electrodes: Doping effects on electrochemical efficiency and posaconazole sensing performance
PublikacjaThere is growing interest in developing diamond electrodes with defined geometries such as, for example, micrometer-sized electrode arrays to acquire signals for electroanalysis. For electroanalytical sensing applications, it is essential to achieve precise conductive patterns on the insulating surface. This work provides a novel approach to boron-doped diamond patterning using nichrome masking for selective seeding on an oxidized...
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Efficient removal of 2,4,6-trinitrotoluene (TNT) from industrial/military wastewater using anodic oxidation on boron-doped diamond electrodes
PublikacjaWith growing public concern about water quality particular focus should be placed on organic micropollutants, which are harmful to the environment and people. Hence, the objective of this research is to enhance the security and resilience of water resources by developing an efficient system for reclaiming industrial/military wastewater and protecting recipients from the toxic and cancerogenic explosive compound – 2,4,6-trinitrotoluene...
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Monometallic nanoparticles decorated and rare earth ions doped KTaO3/K2Ta2O6 photocatalysts with enhanced pollutant decomposition and improved H2 generation
PublikacjaNew, monometallic nanoparticles (MNPs) decorated surface and rare earth (RE) ions doped lattice of perovskite-type (KTaO3)/pyrochlore-type (K2Ta2O6) photocatalysts were successfully prepared by facile hydrothermal incorporation of RE ions into KTaO3/K2Ta2O6 lattices followed by photodeposition of MNPs. The impact of noble metal type (MNPs = Au, Pt, Rh) and rare earth dopant type (RE = Er, Pr) on the physicochemical properties correlated...
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Results of SEM examination of nanohydroxyapatite coatings doped nanoCu particles on Ti13Zr13Nb alloy
Dane BadawczeThe database contains the images of the microstructure of the coatings observed with the SEM scanning electron microscope. The nanohydroxyapatite (nanoHAp) with the addition of copper nanoparticle (nanoCu) coatings deposited on the Ti13Zr13Nb alloy by an electrophoresis process were tested. Two different fractions of nanoCu (with average particles size...
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Topography of iron-phosphate glasses doped with niobium and titanium tested by confocal microscope
Dane BadawczeThe topography of phosphate-iron glasses containing niobium and titanium were investigated with the use of confocal miscroscope. Glass samples of the composition of 35P2O5-30Fe2O3-35Nb2O5, 35P2O5-30Fe2O3-27.5Nb2O5-7.5TiO2 and 35P2O5-30Fe2O3-20Nb2O5-15TiO2 (in %mol) were prepared by the conventional melt quenching technique. Appropriate amounts of reagents...
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Electrical properties of nanostructures in lead-silicate glasses and nanocomposites doped with iron oxide
Dane BadawczeElectrical properties of iron oxide nanostructures observed in silicate glasses and glass-ceramics were studied. Two different sets of glass samples were prepared. The first group of samples has the composition of (50 − 0.5x)SiO2–(50 − 0.5x)PbO– xFe2O3, where x = 15, 20 and 25 (in mol%). Composition of the second group was 50SiO2–(50−x)PbO–xFe2O3, where...
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Opposite pressure impact on electron-phonon coupling in Eu2+ and Ce3+ doped AlN
Dane BadawczeThis data analyzes the influence of pressure on electron–lattice interactions in the 5d excited states of Ce3+ and Eu2+ in the AlN host based on pressure-dependent photoluminescence and photoluminescence excitation spectra. High-pressure measurements on AlN samples doped with Eu2+ and Ce3+ ions reveal that the Stokes shift increases with pressure for...
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DSC and TG results for strontium ferrite molybdate: pristine La, or Nb-doped
Dane BadawczeThis dataset consists of DSC and TG data collected for SFM, LSFM (La-doped) and SFMNb (Nb-doped) compounds, which were undertaken to analyze the reoxidation process of reduced compounds and its transition to double-perovskite structure .The appropriate amount of the powder (~10 mg with 10% tolerance factor) were placed into the alumina crucible and...
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Electrochemical studies of Boron-Doped Diamond enriched Laser Induced Graphene structures
Dane BadawczeThis dataset contains electrochemical studies aimed to evaluate the capability of the utilization of laser-induced graphene (LIG) with incorporated boron-doped diamond nanowall (BDNW) hybrid nanostructures for microsupercapacitors. Selected results from this dataset were published in Advanced Functional Materials journal: https://doi.org/10.1002/adfm.202206097
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Scanning electron microscopy (SEM) images of the boron-doped carbon nanowalls surfaces
Dane BadawczeThe dataset contains the scanning electron micrographs (SEM), revealing the surface morphology of boron-doped carbon nanowalls electrodes on silicon substrates. The surface is characterized by nano-walled structures. The obtained electrodes were doped with boron at the level of [B]/[C] = 5000ppm in the gas atmosphere during the synthesis.
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Scanning electron microscopy (SEM) images of the boron-doped carbon nanowalls surfaces
Dane BadawczeThe dataset contains the scanning electron micrographs (SEM), revealing the surface morphology of boron-doped carbon nanowalls electrodes on silicon substrates. The surface is characterized by nano-walled structures. The obtained electrodes were doped with boron at the level of [B]/[C] = 2000ppm in the gas atmosphere during the synthesis.
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Stable Field Electron Emission and Plasma Illumination from Boron and Nitrogen Co‐Doped Edge‐Rich Diamond‐Enhanced Carbon Nanowalls
PublikacjaSuperior field electron emission (FEE) characteristics are achieved in edge-rich diamond-enhanced carbon nanowalls (D-ECNWs) grown in a single-step chemical vapor deposition process co-doped with boron and nitrogen. The structure consists of sharp, highly conductive graphene edges supplied by a solid, diamond-rich bottom. The Raman and transmission electron microscopy studies reveal a hybrid nature of sp3-diamond and sp2-graphene...
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Focused ion beam-based microfabrication of boron-doped diamond single-crystal tip cantilevers for electrical and mechanical scanning probe microscopy
PublikacjaIn this paper, the fabrication process and electromechanical properties of novel atomic force microscopy probes utilising single-crystal boron-doped diamond are presented. The developed probes integrate scanning tips made of chemical vapour deposition-grown, freestanding diamond foil. The fabrication procedure was performed using nanomanipulation techniques combined with scanning electron microscopy and focused ion beam technologies....
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Temperature and pressure dependence of the luminescence of Eu2+-doped fluoride crystals BaxSr1−xF2(x= 0, 0.3, 0.5 and 1): experiment and model
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Non-linear optical study of hierarchical 3D Al doped ZnO nanosheet arrays deposited by successive ionic adsorption and reaction method
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Study of Mid-Infrared Emission and Structural Properties of Heavy Metal Oxide Glass and Optical Fibre Co-Doped with Ho3+/Yb3+ Ions
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Broadband 1.5-2.1 µm emission in gallo-germanate dual-core optical fiber co-doped with Er3+ and Yb3+/Tm3+/Ho3+
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The thermoluminescence glow curve and the deconvoluted glow peak characteristics of erbium doped silica fiber exposed to 70–130 kVp x-rays
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Uniformity of Thermoluminescence and Optically Stimulated Luminescence Signals Over the Length of Doped LiMgPO4 Crystal Rods Grown by Micro-Pulling-Down Method
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