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Wyniki wyszukiwania dla: TRANSITION METAL COMPLEXES
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Copper(I) halide cluster-based coordination polymers modulated by chiral ditopic dithiodianthranilide ligands: synthesis, crystal structure and photoluminescence
PublikacjaReaction of copper(I) halides with chiral dithiodianthranilidesmdtaandbdtaafforded polymeric complexeswhere polynuclear CuX clusters were linked together by ditopic bridging ligands into 1D chains or 2D layerstructures. In the case of racemic ligands double stranded chain polymers were formed where the Cu4X4(X = I or Br) cores are connected by enantiomeric pairs of the ditopic ligands. In contrast, a homochiralmdtaligand created...
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Właściwości katalityczne i biomedyczne związków zawierających jony rutenu(II) oraz rutenu(III)
PublikacjaRuthenium complexes appear in scientific publications mainly as catalysts in the olefins metathesis process. In this review, we want to indicate the research niche regarding the use of ruthenium(II) and ruthenium(III) complexes in other catalytic processes, i.e. polymerization or epoxidation of olefins and depolymerization. We would like to combine the catalytic properties of ruthenium(II,III) complex compounds with their biomedical...
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The XRD diffraction patterns of Ce0.8La0.2O2/Ni prepared using soft template method and impregnation
Dane BadawczeThe dataset includes XRD patterns of Ce0.8La0.2O2-s nanopowders (nanoparticles,nanocatalyst) prepared using soft template method and further impregnated with 10wt.%Ni using aqueous nitrate solution.
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π-Indenyl substituted zirconium compounds containing terminal bondedphosphanylphosphido ligands [Ind2Zr(Cl){(Me3Si)P-PR2-jP1}]. Synthesis,X-ray analysis and NMR studies
PublikacjaPraca prezentuję reakcję kompleksów indenylowych cyrkonu z solami litowymi difosfanów o ogólnym wzorze R2P-P(SiMe3)Li, gdzie R = tBu, Et2N, iPr2N. W wyniku tych reakcji otrzymano 3 nowe kompleksy fosfanylofosfidowe.Otrzymane nowe kompleksy zbadano przy pomocy technik rentgenowskiej analizy strukturalnej i NMR.Dichloro-bis(indenyl)zirconium(IV) reacts with lithium derivatives of diphosphanes R2P-P(SiMe3)Li (R = tBu, Et2N, iPr2N)...
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Arch./Urban Project II
Kursy OnlineA design studio focused on issues related to the creation of sustainable and climate-responsible facilities. The design task is related to the concept of development of the Gdańsk University of Technology campus. The implemented project will be both a task related to urban and architectural design. A very important element of the design process will be a smooth transition between various scales and problems that architects and...
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The methylome and transcriptome of fetal skin: implications for scarless healing
PublikacjaAim: Fetal skin is known to heal without scarring. In mice, the phenomenon is observed until the 16–17 day of gestation – the day of transition from scarless to normal healing. The study aims to identify key methylome and transcriptome changes following the transition. Materials & methods: Methylome and transcriptome profiles were analyzed in murine dorsal skin using microarray approach. Results & conclusion: The genes associated...
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Extended phase diagram of RNiC2 family: Linear scaling of the Peierls temperature
PublikacjaPhysical properties for the late-lanthanide-based RNiC2 (R = Dy, Ho, Er, and Tm) ternary compounds are reported. All the compounds show antiferromagnetic ground state with the Néel temperature ranging from 3.4 K for HoNiC2 to 8.5 K for ErNiC2. The results of the transport and galvanomagnetic properties confirm a charge density wave state at and above room temperature with transition temperatures TCDW = 284, 335, 366, and 394 K for...
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Synthesis of CoFe2O4 Nanoparticles: The Effect of Ionic Strength, Concentration, and Precursor Type on Morphology and Magnetic Properties
PublikacjaThe present study highlights the effect of metal precursor types (SO4 2¯, Cl¯, and NO3¯), their concentration, and the influence of ionic strength of reaction environment on the morphology, surface, and magnetic properties of CoFe2O4 particles. The magnetic nanoparticles were obtained by chemical coprecipitation in alkaline medium at increasing metal concentration in the range of 0.0425 mol·dm-3 to 0.17 mol·dm-3 and calcination...
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NADBUDOWY I RENOWACJE ELEWACJI Z WYKORZYSTANIEM MATERIAŁÓW I ELEMENTÓW LEKKIEJ OBUDOWY
PublikacjaW artykule omówiono podział i charakterystykę lekkich przegród budowlanych. Przedstawiono możliwości zmian elewacji i wykonywania nadbudowy. Opisano kolejne kroki przygotowania inwestycji dotyczącej projektowania i realizacji nadbudowy obiektu budowlanego.
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The effect of preparation route on structure and photocatalytic properties of bimetallic nanoparticles (Au/Pd, and Au/Pt) deposited at TiO2 surface
PublikacjaNoble metal nanoparticles have often been used to enhance the photocatalytic activity of TiO2 and to extend the absorption wavelength from the ultraviolet to visible region. Bimetallic nanoparticles, composed of two different metal elements, can exhibit peculiar electronic, optical, and catalytic or photocatalytic properties that are absent in the corresponding monometallic nanoparticles. In this work we show the effect kind and...
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Krzywa przejściowa z wygładzoną krzywizną dla dróg kolejowych
PublikacjaW pracy przedstawiono koncepcję nowej postaci krzywej przejściowej, o liniowym przebiegu krzywizny na długości i wygładzonymi rejonami skrajnymi. Może ona stanowić alternatywę dla tzw. gładkich krzywych przejściowych, o nieliniowym przebiegu krzywizny na całej długości. Została tutaj wykorzystana uniwersalna metoda identyfikacji krzywych przejściowych za pomocą równań różniczkowych. Wyznaczono ogólne równania krzywizny oraz odpowiednie...
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Application of semi-Markov processes for evaluation of diesel engines reliability with regards to diagnostics
PublikacjaThe paper presents semi-Markov models of technical state transitions for diesel engines, useful for determination of their reliability, as a result of the conducted statistical empirical studies. Interpretation of technical states provided for this sort of engines refers to ship main engines, i.e. engines employed in propulsion systems of sea-going ships. The considerations recognize diesel engine as a diagnosed system (SDN), of...
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Lower rim substituted p-tert-butyl-calix[4]arene. Part 17. synthesis, extractive and ionophoric properties of p-tert-butylcalix[4]arene appended with hydroxamix acid moieties
PublikacjaThe synthesis and characterization of four p-tert-butylcalix[4]arene-hydroxamic acidc are reported. The dependence of the metal ion binding, assessed by liquid extraction of the metal nitrates from water into dichloromethane in individual and competitive experiments, on the ligand structure, is presented. The results showed that those ligands could be successfully used in separation process of trnasition and heavy metals often...
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Sample Rate Conversion Based on Frequency Response Masking Filter
PublikacjaThe sample rate conversion with high resampling ratios requires low-pass digital filters with very narrow transition band which results in high computational complexity and makes filter design problematic. Therefore in this work we propose to use the FRM method, which breaks the filter with a narrow transition band into a group of filters with reduced design requirements. These decreases the number of non-zero coefficients and...
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Geometry of cycling track
PublikacjaThe paper describes the problems related to shaping of the geometry of the cycling track. The method of selection of the angle at the track curve is presented. Issues related to the selection of the appropriate transition curve and the superelevation section along the transition curve are presented. Reference to the recommendations presented in the literature and scientific papers has been made. Special attention...
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Removal and speciation of heavy metals in the constructed wetland treating landfill leachate
PublikacjaThe results of heavy metals removal and speciation of metals at two treatment wetlands receiving landfill are discussed. The first TW is a surface flow facility consisting of 10 ponds. The next TW is a newly constructed pilot-scale facility consisting of three beds with alternately vertical and horizontal sub-surface flow. The metals concentrations were analysed in leachate(both TWs) and bottom sediments (surface flow TW). Seasonal...
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Looking for the Optimal Location of an Eco-District within a Metropolitan Area: The Case of Tricity Metropolitan Area
PublikacjaCompact housing structures located in city centers are considered to be the most energy and environmentally eective, mainly due to the access to services, transport networks and municipal infrastructures. There is the question of why so many of the acknowledged ecological housing complexes are located on the outskirts of cities or suburbs. Numerous cities decide to introduce strategies either to densify city centers, hoping to...
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TIME-OF-FLIGHT DIFFERENTIAL ELECTRON SCATTERING FROM MOLECULAR TARGETS: BENCHMARK CROSS SECTIONS
PublikacjaWe report time-of-flight differential cross section (DCS) measurements for the electron impact excitation transition in H2. In this work, agreement between available theory and experiment is excellent overall, and marks a transition in electron molecule scattering where differential scattering of excitation is found to be in such precise agreement. We also prove that the newly built apparatus can be used for accurate measurement...
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MATERIAŁY I ELEMENTY STOSOWANE DO WYKONANIA LEKKIEJ OBUDOWY cz. 1. Materiały metalowe
PublikacjaW artykule przedstawiono stosowane w lekkich obudowach materiały metalowe i kształtowane z nich wyroby. Omówiono charakterystyczne parametry i różnice technologiczne występujące w produkcji wyrobów. Przedstawiono ocenę odporności korozyjnej materiałów.
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Model dynamic electrochemical impedance spectroscopy (DEIS) results obtained with various DC polarization rates
Dane BadawczeThe dataset contains results of model dynamic electrochemical impedance spectroscopy studies carried out on a setup of 10 diodes in series, which were connected in parallel with a condenser. The impedance data were acquired every 1 s (the analytic window length for Fourier Transform was 1 s). The model system was polarized between 0 and +8 V with DEIS...
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Quest for the Molecular Basis of Improved Selective Toxicity of All-Trans Isomers of Aromatic Heptaene Macrolide Antifungal Antibiotics
PublikacjaThree aromatic heptaene macrolide antifungal antibiotics, Candicidin D, Partricin A (Gedamycin) and Partricin B (Vacidin) were subjected to controlled cis-trans to all trans photochemical isomerization. The obtained all-trans isomers demonstrated substantially improved in vitro selective toxicity in the Candida albicans cells: human erythrocytes model. This effect was mainly due to the diminished hemotoxicity. The molecular modeling...
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Thermophysical properties of the phase change material mixtures – preliminary studies on macromolecular hydrocarbons example.
PublikacjaThe aim of this work is a theoretical and experimental analysis of the macromolecular hydrocarbon mixtures composition and the impact on thermophysical parameters of the phase change materials (PCM) made from these mixtures. The analysis of the current state of knowledge extended by the author’s own studies have been presented. Thermophysical characteristics of the hydrocarbons and their mixtures have been specified, in such a...
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Thermophysical Properties of the Phase Change Material Mixtures – Preliminary Studies on Macromolecular Hydrocarbons Example.
PublikacjaThe aim of this work is a theoretical and experimental analysis of the macromolecular hydrocarbons mixtures composition and the impact on thermophysical parameters of the phase change materials (PCM) made from these mixtures. The analysis of the current state of knowledge extended by the author's own studies have been presented. Thermophysical characteristics of the hydrocarbons and their mixtures have been specified, in such a...
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Phoenixin-14 effect on viability and THBS2 and CDH1 expression in 12Z endometriosis cell line
Dane BadawczePhoenixin-14 is a neuropeptide produced by the paraventricular nuclei of the anterior hypothalamus that regulates reproductive system functions. Its level in patients with endometriosis is reduced and may be the cause of dysregulated HPG-axis. Our study tested endometriosis-specific concentrations of PNX-14 on endometrial epithelial cell line 12Z in...
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Chromium-Catalyzed CO2–Epoxide Copolymerization
PublikacjaIminopyrrole, aminopyrrole, and aminophosphine ligands were complexed with various chromium sources, producing eight complexes that were tested for their catalytic behavior toward epoxide–CO2 copolymerization. As elucidated by MALDI-TOF-MS, copolymerizations afforded polycarbonates and poly(ether-carbonates) exhibiting linear or cyclic topologies.
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Nowe związki w układzie R2TGe3 (R-ziemia rzadka, T-metal przejściowy)
ProjektyProjekt realizowany w Katedra Fizyki Ciała Stałego zgodnie z porozumieniem 0142/DIA/2018/47 z dnia 2018-09-19
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Cation sensing by diphenyl-azobenzocrowns
PublikacjaMetal cations complexation and proton binding by 13- and 16-membered diphenyl-azobenzocrowns and diphenyl-hydroxyazobenzocrowns were studied in acetonitrile using spectroscopic methods: UV–vis spectroscopy, spectrofluorimetry, and 1H NMR spectroscopy. Phenyl moieties in benzene rings were found to affect binding strength alkali and alkaline earth metal cations and hydrogen ion, and affect tautomeric equilibrium of hydroxyazobenzocrowns....
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Możliwości wydłużania krzywych przejściowych w układach geometrycznych torów
PublikacjaW pracy przedstawiono analizę problemu wydłużania krzywych przejściowych, wykorzystując do tego celu analityczną metodę projektowania. Podstawę analizy stanowiły obliczenia numeryczne przeprowadzone dla zestawu parametrów charakteryzujących standardowy układ geometryczny: krzywa przejściowa – łuk kołowy – krzywa przejściowa (w wersji niesymetrycznej). Ocenie poddano różnice rzędnych poziomych układu istniejącego oraz układu z...
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Nanoparticles preparation using microemulsion systems
PublikacjaMetallic nanoparticles become of current interests because they exhibit unique properties compared with those of metal atoms or bulk metal due to the quantum size effect and their large surface area, which make them attractive for applications in optics, electronics, catalysis biology and medicine. TiO2 has been used for environmental remediation purposes such as in the purification of water and air and also solar-to chemical energy...
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Determination of metals in water samples by atomic absorption spectrometry and flame emission spectrometry
PublikacjaMetal species in environmental waters are relevant to characterize the metal toxicity, the mobility between different environmental compartments, and for remediation purposes in case of contamination. The concentration of many trace metals in natural water samples are generally at µg/l level. The paper describes determination of metals in water samples based on flame atomic emission and flame atomic absorption spectrometry.
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Development of the Polish energy sector through transformation and harmonization with the European energy and climate policy
PublikacjaThe paper presents the dilemmas of energy sector development vs European energy policy due to the way of energy transition. The identification of barriers and opportunities for the development of the power industry is presented. The possibilities of using modern energy technologies for the processes of energy transformation are described. The path useful to achieving climate and energy goals is determined. The new method of electricity...
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An investigation on the chemistry of the R2P=P ligand: reactions of a phosphanylphosphinidene complex of tungsten(VI) with electrophilic reagents
PublikacjaThe nucleophilic properties of the title compound [(2,6-i-Pr2C6H3N)2(Cl)W(η2-t-Bu2PvP)]Li·3DME (1) were investigated in reactions with selected electrophilic reagents such as MeI, M(CO)5THF (M = Cr, Mo, W), AlCl3, and GaCl3. Methylation of 1 by MeI yields phosphanylphosphido complexes [(2,6-i-Pr2C6H3N)2W(X)(1,2-η-t-Bu2PvP–CH3)] (X = Cl, I) (2-Cl/2-I) with the formation of a new P–C bond. Moreover, 1 reacts with electrophilic compounds...
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Chronographic Imprint of Age-Induced Alterations in Heart Rate Dynamical Organization
PublikacjaBeat-to-beat changes in the heart period are transformed into a network of increments between subsequent RR-intervals, which enables graphical descriptions of short-term heart period variability. Three types of such descriptions are considered: (1) network graphs arising from a set of vertices and directed edges, (2) contour plots of adjacency matrices A, representing the networks and transition matrices T, resulting from A, and (3)...
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Crossover from charge density wave stabilized antiferromagnetism to superconductivity in Nd1−xLaxNiC2 compounds
PublikacjaThe path from the charge density wave antiferromagnet NdNiC2 to the noncentrosymmetric superconductor LaNiC2 is studied by gradual replacement of Nd by La ions. The evolution of physical properties is explored by structural, magnetic, transport, magnetoresistance, and specific heat measurements. With the substitution of La for Nd, the Peierls temperature is gradually suppressed, which falls within the BCS mean-field relation for...
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Assessment of the Feasibility of Energy Transformation Processes in European Union Member States
PublikacjaThe energy transition is now treated in most countries as a necessary condition for their long-term development. The process of energy transformation assumes the simultaneous implementation of the Sustainable Development Goals, which are a major challenge for modern economies and introduce significant restrictions in their functioning. Our study aims to group EU member states according to their ability to achieve energy transition...
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Determination of moisture resistance of covered electrodes according to PN-EN ISO 14372
PublikacjaMoisture present in the electrode covering is one of the sources of diffusible hydrogen in welded joints. In order to study the diffusible hydrogen content in deposited metal, a stand for moisturizing covered electrodes, in accordance with the PN-EN ISO 14372 standard, was built. After the stand was completed, a test of moisturizing the electrodes was carried out and measurements of the diffusible hydrogen content in deposited...
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Diffusible hydrogen management in underwater wet self-shielded flux cored arc welding
PublikacjaThis article reports the effect of underwater wet welding parameters and conditions on the diffusible hydrogen content in deposited metal for welding with a self-shielded flux cored wire. The diffusible hydrogen content in deposited metal was determined using the glycerin method according to the Plackett-Burman design determining the significance of the effect of the stick out length, welding current, arc voltage, travel speed...
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DSC and TG results for strontium ferrite molybdate: pristine La, or Nb-doped
Dane BadawczeThis dataset consists of DSC and TG data collected for SFM, LSFM (La-doped) and SFMNb (Nb-doped) compounds, which were undertaken to analyze the reoxidation process of reduced compounds and its transition to double-perovskite structure .The appropriate amount of the powder (~10 mg with 10% tolerance factor) were placed into the alumina crucible and...
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Mono- and polynuclear Co(II) silanethiolates with aliphatic diamines
PublikacjaFour Co(II) complexes, [Co{SSi(OtBu)3}2(dmpda)] 1, [Co{SSi(OtBu)3}2(bda)2]n2 [Co{SSi(OtBu)3}2(pda)2]n3 and [Co{SSi(OtBu)3}2(hda)2]n4 [dmpda = 3-(dimethylamino)-1-propylamine; bda = 1.4-butanediamine; pda = 1.5-pentanediamine; had = 1.6-hexanediamine] have been synthesized and characterized using X-ray diffraction. Complex 1 is mononuclear and contains Co(II) coordinated by dmpda molecule in chelating mode, whereas compounds 3 and...
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Supramolecular Synthesis Based on a Combination of Se···N Secondary Bonding Interactions with Hydrogen and Halogen Bonds
PublikacjaExamination of the solid state structures of 2,1,3-benzoselenadiazole complexes with hydrogen or halogen bond donors has demonstrated that the 2,1,3-benzoselenadiazole molecules preferably form centrosymmetric dimers with use of [Se–N]2 supramolecular synthon, whereas the two remaining nitrogen atoms not involved in the [Se–N]2 supramolecular interactions can act as acceptors of hydrogen or halogen bonds. Cocrystallization of selenadiazoles...
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Molecular Structures of the Phospha-Wittig Reaction Intermediate: Initial Step in the Synthesis of Compounds with a C═P–P Bond as Products in the Phospha-Wittig Reaction
PublikacjaThe phospha-Wittig reactivity ofβ-diketiminate titanium(III) complexes with phosphanylphosphido ligands was investigated. The reactions of [MeNacNacTi(Cl){η2-P(SiMe3)-PtBu2}] and [MeNacNacTi(Cl){η2-P(SiMe3)-P(Ph)tBu}] with acetone conducted in toluene solution under mild conditions led to the phospha-Wittig intermediates [{(ArN=C(Me)CHC(Me)=NAr)(C(Me)2O}Ti(Cl){PtBu2-P(SiMe3)C(Me)2O}] (1) and [{(ArN=C(Me)CHC(Me)=NAr) (C-(Me)2O}Ti(Cl){P(Ph)tBu-P(SiMe3)C(Me)2O}]...
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Modified Manganese Phosphate Conversion Coating on Low-Carbon Steel
PublikacjaConversion coatings are one of the primary types of galvanic coatings used to protect steel structures against corrosion. They are created through chemical reactions between the metal surface and the environment of the phosphating. This paper investigates the impact that the addition of new metal cations to the phosphating reaction environment has on the quality of the final coating. So far, standard phosphate coatings have contained...
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Study on Microstructure-Property Relationship of Inconel 617 Alloy/304L SS Steel Dissimilar Welds Joint
PublikacjaWelding of Inconel 617 (IN617) alloy and austenitic 304L SS steel has been attempted using the autogenous Laser Beam Welding (LBW) process. Characterization of dissimilar weldments was performed on either side of the fusion boundaries. The metallographic results showed that the inhomogeneous microstructure formation for weld metal contained columnar and cellular dendrites near the interface, whilst the columnar, cellular and equiaxed...
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UKŁADY KONSTRUKCYJNE LEKKIEJ OBUDOWY
PublikacjaW artykule przedstawiono rozwiązania konstrukcyjne przegród zewnętrznych lekkiej obudowy jednowarstwowych (nieizolowanych termicznie), wielowarstwowych (izolowanych termicznie) oraz szklano-metalowych. Omówiono procesy modyfikacji konstrukcji ścian. Podano przykładowe rozwiązania.
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Nitrogen dioxide gas-sensing detection with GO modified CuO thin films
PublikacjaGas sensors have been continuously developed over the last few decades for several applications including air quality monitoring, automotive industry and recently for medical use. Gas sensors are usually based on metal oxides (MOXs), such as SnO2, TiO2, ZnO, WO3, CuO. Recently, new materials such as graphene oxide and heterostructures of graphene oxide and metal oxides are utilized for gassensing applications.
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Analysis of guided wave propagation in adhesive joints of steel rods
PublikacjaThe aim of the study is the elastic wave propagation in adhesive joints of metal rods that are one of the simplest kind of glue connections. They are consisted of two metal members and an adhesive layer joining two parts together. The analysis is directed to technical diagnostics of such type of connections. Longitudinal and transversal guided waves were excited in prepared joints. Signals of propagating waves were registered in...
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Charge density wave and crystalline electric field effects in TmNiC2
PublikacjaSingle crystals of TmNiC2 were grown by the optical floating-zone technique and were investigated by x-ray diffraction (XRD), thermal expansion, electrical resistivity, specific heat, and magnetic susceptibility measurements. Single-crystal XRD reveals the formation of a commensurate charge density wave (CDW) characterized by a CDW modulation vector q2c = (0.5, 0.5, 0.5), which is accompanied by a symmetry change from the orthorhombic...
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The particle method for simulation of self-organization phenomena
PublikacjaThe aim of the work was to design, implement, and use, in a number of experiments, an abstract software environment (an artificial world)suitable for modelling systems consisting of many moving and interactingobjects distributed in space. The environment, named DigiHive, is directed towards modeling of complex systems manifested by processes of self-organization, self-reproduction and self modifications. The environment is mainly...
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Multi-Analytical Techniques for the Study of Burial Clothes of Polish King Sigismund III Vasa (1566–1633) and His Wife Constance Habsburg (1588–1631)
PublikacjaThe subjects of this research are the burial clothes of Polish King Sigismund III Vasa and his wife Constance, which were woven and embroidered with silk and metal threads. Fragments of the textiles underwent spectroscopic, spectrometric, and thermogravimetric analyses. The hydrofluoric acid extraction method was improved to isolate various classes of dyes from the textile samples that had direct contact with human remains. High-performance...
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Reactions of the Lithiated DiphosphinetBu2P-P(SiMe3)Li with [(η6-C6H6)RuCl2]2in the Presence of Tertiary Phosphines
PublikacjatBu2P–P(SiMe3)Li reacted with [(η6-C6H6)RuCl2]2at–40 °C in the presence of PR3(PR3=PEt3,PEt2Ph, PEtPh2) by the nucleophilic addition of the tBu2P–P(SiMe3) moiety to the benzene ring to yield solely the complexes [(R3P)2Ru(Cl)-{η5-C6H6(Me3SiP–PtBu2)}] (1). These products decomposed slowly at ambient temperature to yield benzene, Ru clusters, and small amounts of the dinuclear ruthenium complexes [{(R3P)2Ru}2(μ,η2:2-P2)2Ru(PR3)2](Ru–Ru)(6)....